CN101230251A - Fugitive dust inhibiting agent and method of production thereof - Google Patents
Fugitive dust inhibiting agent and method of production thereof Download PDFInfo
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- CN101230251A CN101230251A CNA2007100173547A CN200710017354A CN101230251A CN 101230251 A CN101230251 A CN 101230251A CN A2007100173547 A CNA2007100173547 A CN A2007100173547A CN 200710017354 A CN200710017354 A CN 200710017354A CN 101230251 A CN101230251 A CN 101230251A
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Abstract
The invention discloses a degradable non-pollution environment-friendly flying dust inhibitor and the production method thereof. The material components are carboxyl cellulose sodium 0.3-2, modified starch 0.5-3, water 95-99.2. The invention includes the following steps: two third of the water volume and the carboxyl cellulose sodium are added into a reaction kettle; the carboxyl cellulose sodium is selected from methyl cellulose sodium and ethyl cellulose sodium, and is heated to 80-100 DEG C by steaming; after the carboxyl cellulose sodium is completely dissolved, the modified starch is added into slowly, and is stirred so as to be completely dissolved. The invention is a physical novel efficient flying dust preventing technology, the coverage principle is to use active adhesive to excite the activity of the bug dust on the surface of the flying dust, and to react with the active constituent of the flying dust to produce a sticking layer. The invention firms the bug dust on the surface of the flying dust by the enhancing function of a little of additive, has certain strength, and then can achieve the purpose of preventing flying dust. The invention is a degradable non-pollution environment-friendly covering agent.
Description
Technical field
The present invention relates to a kind of chemicals and production method, suppress the preparation and the production method thereof of airborne dust specifically.
Background technology
At present, the main atmospheric polluting material in the most of northern city of China is a pellet.Although it is a lot of to influence in the atmosphere factor of particulate matter, the airborne dust influence that coal yard and other diffusing stacking yard material stock ground (as the stacking field of tailings area, working-yard, material of construction and various place where the garage is piled ups etc.) produce particular locality can not be ignored.The main source of dust pollution is an airborne dust, battle field, Tu Chang in the construction site, and all there are serious airborne dust and starting material oneself consumption problem in the coal yard of enterprise, ash field and raw material, breeze, cindery accumulation place.These materials mostly are air storage greatly or spread at the stand.The surface, stock ground that spread at these air storages or stand, disturbance as air-flow (wind-force) will produce airborne dust, certainly will produce surrounding environment and pollute, as the high wind effect, can form local dust pollution band, this also is to cause one of higher major reason of pellet index in the northern city atmospheric environment, has caused serious harm to environment and HUMAN HEALTH.In the prior art, general employing regularly water spray is handled, because moisture evaporation is fast, and sprinkling frequency height, labour intensity is big, a large amount of waste water resources, and airborne dust DeGrain.
Summary of the invention
The object of the invention provides a kind of degradable free of contamination environment-friendly type Fugitive dust inhibiting agent.
Another object of the present invention provides a kind of production method of Fugitive dust inhibiting agent.
The present invention makes raw materials of effective components consisting of of percentage composition meter by weight:
Carboxy cellulose sodium 0.3~2, modified starch 0.5~3, water 95~99.2; Carboxy cellulose sodium is selected from sodium carboxymethylcellulose pyce and ethyl cellulose sodium, and modified starch is selected from esterification modified starch and α-change modified starch.
The production method of Fugitive dust inhibiting agent of the present invention comprises the following steps:
(1), in reactor, put into 2/3 of the water yield, add carboxy cellulose sodium, carboxy cellulose sodium is selected from sodium carboxymethylcellulose pyce and ethyl cellulose sodium, feed steam-heated cal(l)andria to 80 ℃~100 ℃, after carboxy cellulose sodium is all dissolved, add modified starch slowly, be stirred to whole dissolvings;
(2), add the water yield of residue 1/3, stir, be finished product.
The present invention is a kind of new and effective anti-airborne dust technology of physics method, and efficient insulating covering agent is made up of reactive adhesive and a small amount of auxiliary.Formation has the cured layer of certain intensity, covering airborne dust surface, it covers principle is to utilize reactive adhesive to excite airborne dust surface dust activity, react with the dust active ingredient, generate adhesive layer, and the enhancement by a small amount of admixture, make the dust curing of airborne dust top layer, and have certain intensity, thereby reach the purpose of anti-airborne dust.And be a kind of degradable free of contamination environment-friendly type insulating covering agent.
Insulating covering agent of the present invention is a kind of binding agent, during use it evenly is sprayed on particle surface, forms cured layer.This cured layer not only can bond together the pulverized coal particle of various particle diameters, and certain toughness is arranged, and can prevent airborne dust effectively.Simultaneously, according to environment protection requirement, this binding agent in process of production with use after, all can not produce new pollution to environment.Selecting with the synthetic high polymer in the organic and inorganic and natural adhesive of existing report is emulsion-type (water-based) insulating covering agent that base-material is re-dubbed, and has excellent practicality, and the semi-permeable membranes of formation has very strong cementing properties, toughness and tensile strength; According to practical situation, repetition test is determined the proportioning of each base-material, filler.Insulating covering agent is nontoxic, have no side effect, and cheap, excellent performance is free from environmental pollution, and raw material easily purchases, easy to use.
Environmental monitoring junction centre in Gansu Province's is left loading station (being adhesive for spraying) to train and is carried out the monitoring of Train Dynamic test airborne dust, and monitoring result sees Table 1, table 2.
Table 1 Train Dynamic is tested airborne dust monitoring result along the line
Unit: mg/m
3
Test conditions monitoring place | Do not spray tackiness agent coal dust airborne dust concentration | Coal dust airborne dust concentration behind the spray tackiness agent | Empty wagons (background values) | The coal dust airborne dust is subdued rate (%) before and after using tackiness agent |
Qun Dynasty line 44-54km place (0.5h) | 78.5 | 32.4 | 32.2 | 99.6 |
Qun Dynasty line 79-92km place (1.0h) | 33.5 | 14.2 | 13.2 | 95.1 |
Qun Dynasty line 263-273km place (east, Yanqing) | 85.3 | 24.1 | 23.4 | 98.9 |
Table 2 Train Dynamic test tunnel airborne dust monitoring result
Unit: mg/m
3
Test conditions monitoring place | Do not spray tackiness agent coal dust airborne dust concentration | Coal dust airborne dust concentration behind the spray tackiness agent | Empty wagons (background values) | The coal dust airborne dust is subdued rate (%) before and after using tackiness agent |
The Buddhist monk level ground | 30.1 | 30.3 * | 36.6 * | / |
No. two, Zhao family | 91.4 | 46.2 | 44.3 | 96.0 |
The flowers and fruits mountain | 163.2 | 78.6 | 76.1 | 97.1 |
The peasant household mausoleum | 46.0 | 29.5 | 28.4 | 93.8 |
Annotate: band
*Monitor value when data are meeting
From monitoring data as can be seen: adopt chemical spraying agent to cover the coal car top layer, can alleviate of the pollution of coal dust airborne dust to environment.Coal car airborne dust in service along the line is subdued rate between 95.1-99.6%, average out to 97.9%.Coal car in the tunnel airborne dust in service subdue rate between 93.8-97.1%, average out to 95.6%.
Embodiment
The following examples can make those skilled in the art more fully understand the present invention, but do not limit the present invention in any way.
Embodiment 1:
(1), in reactor, put into 2/3 of the 95 gram water yields, add 2 gram sodium carboxymethylcellulose pyces, feed steam-heated cal(l)andria to 80 ℃, make sodium carboxymethylcellulose pyce all after the dissolving, add 3 gram esterification modified starches slowly, be stirred to whole dissolvings; (2), add the water yield of residue 1/3, stir, be finished product.
Embodiment 2:
(1), in reactor, put into 2/3 of the 99.2 gram water yields, add 0.3 gram sodium carboxymethylcellulose pyce, feed steam-heated cal(l)andria to 100 ℃, make sodium carboxymethylcellulose pyce all after the dissolving, add 0.5 gram esterification modified starch slowly, be stirred to whole dissolvings; (2), add the water yield of residue 1/3, stir, be finished product.
Embodiment 3:
(1), in reactor, put into 2/3 of the 97 gram water yields, add 1 gram ethyl cellulose sodium, feed steam-heated cal(l)andria to 90 ℃, make ethyl cellulose sodium all after the dissolving, add 2 gram esterification modified starches slowly, be stirred to whole dissolvings; (2), add the water yield of residue 1/3, stir, be finished product.
Embodiment 4:
(1), in reactor, put into 2/3 of the 96 gram water yields, add 2 gram ethyl cellulose sodium, feed steam-heated cal(l)andria to 84 ℃, make ethyl cellulose sodium all after the dissolving, add 2 gram α-change modified starches slowly, be stirred to whole dissolvings; (2), add the water yield of residue 1/3, stir, be finished product.
Embodiment 5:
(1), in reactor, put into 2/3 of the 98 gram water yields, add 1 gram ethyl cellulose sodium, feed steam-heated cal(l)andria to 96 ℃, make ethyl cellulose sodium all after the dissolving, add 1 gram α-change modified starch slowly, be stirred to whole dissolvings; (2), add the water yield of residue 1/3, stir, be finished product.
Claims (2)
1. a Fugitive dust inhibiting agent is characterized in that making raw materials of effective components consisting of of percentage composition meter by weight: carboxy cellulose sodium 0.3~2, modified starch 0.5~3, water 95~99.2; Carboxy cellulose sodium is selected from sodium carboxymethylcellulose pyce and ethyl cellulose sodium, and modified starch is selected from esterification modified starch and α-change modified starch.
2. the production method of Fugitive dust inhibiting agent according to claim 1, it is characterized in that it comprises the following steps: (1), puts into 2/3 of the water yield in reactor, add carboxy cellulose sodium, carboxy cellulose sodium is selected from sodium carboxymethylcellulose pyce and ethyl cellulose sodium, feed steam-heated cal(l)andria to 80 ℃~100 ℃, after carboxy cellulose sodium is all dissolved, add modified starch slowly, be stirred to whole dissolvings;
(2), add the water yield of residue 1/3, stir, be finished product.
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CN101824303A (en) * | 2010-05-24 | 2010-09-08 | 北京嘉孚科技有限公司 | Dust-suppression agent and use method thereof |
CN101857793A (en) * | 2010-06-01 | 2010-10-13 | 天津理工大学 | Degradable dust suppressant and preparation method thereof |
CN102295915A (en) * | 2011-09-20 | 2011-12-28 | 北京中盛益世环保科技有限公司 | Dust inhibitor |
CN101619205B (en) * | 2009-08-13 | 2012-06-27 | 沈阳建筑大学 | Modified gelatin dust suppressant and preparation method thereof |
CN102604597A (en) * | 2012-02-27 | 2012-07-25 | 中国矿业大学(北京) | Coal dust suppressant and preparation method thereof |
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JP2014080543A (en) * | 2012-10-18 | 2014-05-08 | Taiheiyo Cement Corp | Composition for suppressing generation of dust, and hydraulic powder composition |
CN105586006A (en) * | 2014-10-21 | 2016-05-18 | 秦继军 | Raised dust inhibitor and production method thereof |
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CN101824303B (en) * | 2010-05-24 | 2012-05-23 | 北京嘉孚科技有限公司 | Dust-suppression agent and use method thereof |
CN101824303A (en) * | 2010-05-24 | 2010-09-08 | 北京嘉孚科技有限公司 | Dust-suppression agent and use method thereof |
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CN101857793A (en) * | 2010-06-01 | 2010-10-13 | 天津理工大学 | Degradable dust suppressant and preparation method thereof |
CN102295915A (en) * | 2011-09-20 | 2011-12-28 | 北京中盛益世环保科技有限公司 | Dust inhibitor |
CN102295915B (en) * | 2011-09-20 | 2014-01-01 | 北京中盛益世环保科技有限公司 | Dust inhibitor |
CN102604597A (en) * | 2012-02-27 | 2012-07-25 | 中国矿业大学(北京) | Coal dust suppressant and preparation method thereof |
CN102604597B (en) * | 2012-02-27 | 2014-03-05 | 中国矿业大学(北京) | Coal dust suppressant and preparation method thereof |
CN102627951A (en) * | 2012-04-23 | 2012-08-08 | 天津理工大学 | Method for preparing special covering agent for domestic garbage |
CN102627430A (en) * | 2012-04-23 | 2012-08-08 | 天津理工大学 | Preparation method of special covering agent for construction waste |
CN102627950A (en) * | 2012-04-23 | 2012-08-08 | 天津理工大学 | Preparation method for covering agent of sand for building |
JP2014080543A (en) * | 2012-10-18 | 2014-05-08 | Taiheiyo Cement Corp | Composition for suppressing generation of dust, and hydraulic powder composition |
CN103184034A (en) * | 2013-01-04 | 2013-07-03 | 北京阳光溢彩科技有限公司 | Ecological environment-friendly dust inhibitor |
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CN105586006A (en) * | 2014-10-21 | 2016-05-18 | 秦继军 | Raised dust inhibitor and production method thereof |
CN106632858A (en) * | 2016-11-22 | 2017-05-10 | 汪逸凡 | Preparation method of environment-friendly degradable dust depressor |
CN106675522A (en) * | 2016-12-29 | 2017-05-17 | 河南省九金科技有限公司 | Dust depressor for railway coal transport and use method of dust depressor |
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