CN102504757A - Biological environment-friendly adhesion agent and preparation method thereof - Google Patents
Biological environment-friendly adhesion agent and preparation method thereof Download PDFInfo
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- CN102504757A CN102504757A CN2011103856566A CN201110385656A CN102504757A CN 102504757 A CN102504757 A CN 102504757A CN 2011103856566 A CN2011103856566 A CN 2011103856566A CN 201110385656 A CN201110385656 A CN 201110385656A CN 102504757 A CN102504757 A CN 102504757A
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Abstract
The invention provides a biological environment-friendly adhesion agent which is mainly prepared from Suaeda glauca Bge seedcake, matched with a surfactant, a thickener and an adhesive. The adhesion agent is applicable to the adhesion of soil sand grains to form a consolidation layer to prevent storms and dust. In addition, the adhesion agent is also can be used for adhering cartons, paper, plywood and the like. The invention also provides a preparation method of the adhesion agent. The sources of Suaeda glauca Bge seedcake which is the raw material of the adhesion agent are wide and the prepared adhesion agent is nontoxic, harmless, green and environment-friendly and has significant economic and social benefits.
Description
Technical field
The present invention relates to a kind of binder material, the biological environmental production type sticker that is main raw material specifically with the fluffy seedcake dregs of rice of alkali.
Background technology
Sticker is widely used in every field, like briquette binder, pellet binder, wood veneer bonding agent and sand-fixing binder etc.Use maximum stickers at present and make " synthetic adhesive " by polymer chemistry and petroleum chemistry.
Sticker mainly is to be used in desert and soil drifting serious area in the field of fixing the sand, and is used for the bonding of the grains of sand, and purpose is to form bonding course, prevents that dust storm from playing dirt.Traditional sand-fixing binder can be divided into: grout class, water glass class, petroleum products class and high molecular polymer super absorbent resin lipid.These sand-fixing binders can make face of land sandy soil be able to fix, and have certain stability and water-retentivity, thereby reach tackling quicksand and the purpose of administering the desertification soil.But the material cost that has is high, and the material that has can not be created good water and soil environment for plant-growth, the material that has even can pollute environment.Such as, after using, petroleum products class material is difficult to degraded, be stranded in for a long time in the sandy soil of top layer, cause secondary environmental pollution.Novel sand-fixing binder comprises: workers and peasants' forestry byproducts is carried out several types of ecotope sand fixation material, the mikrobe sand fixation material that utilizes microbial technique and the organic and inorganic synthetic composite sand consolidation materials etc. that modification handles.They have that use properties is good, resource and energy consumption is few, with plurality of advantages such as the ecotope consistency is good.
What sticker adopted in the wood veneer field usually is urea-formaldehyde resin, and being heated is easy to generate free formaldehyde, causes secondary pollution, and this also is the major cause that indoor formaldehyde exceeds standard.So it is the research direction of current main-stream that the development low levels does not even contain the sticker of free formaldehyde.
Sticker is that the accumulation of salt in the surface soil, moisture absorption phenomenon appear in water glass in actual use adopting sodium silicate binder, water glass aspect the carton bonding usually, and dung is come off, and effect is bad.So adopt the environment-friendly type sticker as substitute, wide prospect arranged.
In a word, " synthetic adhesive " that polymer chemistry and petroleum chemistry are made, the material cost that has is high, the performance that has is not good, have in addition environment caused secondary pollution, be detrimental to health.Therefore, study not only environmental protection but also cheap sticker important practical sense is arranged.
Summary of the invention
The objective of the invention is to obtain a kind of to ecological friendly biological environmental production type sticker.
Another object of the present invention is to provide a kind of preparation method of biological environmental production type sticker.
First aspect of the present invention provides a kind of biological environmental production type sticker, and said sticker mainly comprises the fluffy seedcake dregs of rice of alkali, tensio-active agent, thickening material and tackiness agent; In gross weight is 100 parts, and the parts by weight of said each main ingredient of sticker are:
The fluffy seedcake dregs of rice of alkali 1.2-4.0 part;
Tensio-active agent 0.4-1.0 part;
Thickening material 0.8-3.0 part;
Tackiness agent 0.5-1.5 part;
Sanitas 1.0-1.5 part;
All the other are water.
In a preferred embodiment, said alkali is fluffy is fluffy, the hard branch of Suaeda salsa, Suaeda heteroptera, angle alkali alkali one or more in fluffy.
In a preferred embodiment, the fluffy seedcake dregs of rice of said alkali are the tailing that the fluffy seed of alkali obtains after squeezing oil expression processing or solvent lixiviate.Need fragmentation, porphyrize during use, sieve, obtain particle diameter less than the fluffy seed cake powder of the alkali of 0.125mm.
In a preferred embodiment, said tensio-active agent is an X 2073, and its structure is linear chain structure, i.e. LAS.
In a preferred embodiment, said thickening material is an Xylo-Mucine, and by a kind of anionic macromolecular compound that makes after natural cellulose and caustic alkali and the monochloroacetic acid reaction, molecular weight is 6400 (± 1000), and density is 0.5-0.7g/cm
3
In a preferred embodiment, said tackiness agent is one or more among Z 150PH 17-88, Z 150PH 17-92 and the Z 150PH 17-99.
In a preferred embodiment, said sanitas is one or more in POTASSIUM SORBATE GRANULAR WHITE, phenylformic acid and the salt thereof.
In a preferred embodiment, the said biological environmental production type sticker viscosity that makes is the 40-1500 centipoise.
Another aspect of the present invention provides a kind of method for preparing biological environmental production type sticker, comprises the steps:
A) with the fluffy seedcake dregs of rice of said alkali crushing grinding to fine powder, sieve, get particle diameter less than the fluffy seed cake powder of the alkali of 0.125mm;
B) the fluffy seed cake powder of alkali that step a) is obtained places boiling water to do thermal treatment, boiling 30min; Take off then and leave standstill, be cooled between 65-75 ℃;
C) under continuous condition of stirring, Xylo-Mucine is slowly spread in the beaker equably, Xylo-Mucine is dissolved fully, subsequent use; Under continuous condition of stirring, Z 150PH is slowly added fully swelling, dispersion in the cold water about 20 ℃, then be warmed up to 95-100 ℃ of accelerate dissolution, no longer contain molecule up to solution, again through behind the 60 order stainless steel sift impurity screenings, can be subsequent use;
D) under the stirring velocity of 1000r/min, in the fluffy seed cake powder solution of the alkali that step b) obtains, slowly add X 2073 and polyvinyl alcohol solution earlier, stir 10min, slowly add carboxymethylcellulose sodium solution again, stir 20min; Then, the adjustment stirring velocity is 200r/min, continues to stir 60min, and the entire reaction course temperature is controlled between 65-75 ℃;
E) take off and leave standstill, be cooled to room temperature after, add said sanitas, stir 5min, promptly get said biological environmental production type sticker.Comparing the present invention with other stickers has the following advantages:
(1) the fluffy seedcake dregs of rice of alkali that the present invention adopts derive from the seed of plant, belong to agriculture byproduct.Adopt the main raw material of the fluffy seedcake dregs of rice of alkali, can solve the handling problems of the fluffy seedcake dregs of rice of alkali, realize the recycle value of this huge agricultural byproducts resource of the fluffy seedcake dregs of rice of alkali, reduce the usage quantity of industrial chemicals, cost is reduced greatly as synthetic adhesive.
(2) the present invention with the fluffy seedcake dregs of rice of alkali as main raw material(s), nontoxic, environmental protection.Be used for agricultural land soil and fix the sand, have good sand fixation, the protection period later again can be by soil microbial degradation, and is good with the ecological environment of soil consistency, can not work the mischief to agricultural land soil; Because of it contains abundant organic matter, also nutritive elements such as biomass nutriment and small amount of calcium phosphorus can be provided for farm crop.
(3) biological environmental production type sticker according to the invention also can be used as the tackiness agent of bonding carton, paper and wood veneer etc.
(4) preparation method according to the invention, the simple and easy handling of technology has been saved the cost of equipment, the energy and human input.
Embodiment
Embodiment 1
Suaeda salsa seedcake is broken, be ground to fine powder then, cross 120 mesh sieves, get Suaeda salsa seed cake powder 6.0g, place 500ml boiling water, boiling 30min is cooled between 65-75 ℃ then.
Weighing 4.0g X 2073, subsequent use; In beaker, contain the water of getting 100ml, place on the constant temperature blender with magnetic force, weighing 3.0g Xylo-Mucine under continuous condition of stirring, slowly spreads Xylo-Mucine in the beaker equably, and Xylo-Mucine is dissolved fully, and is subsequent use.
The Suaeda salsa seed cake powder solution of temperature between 65-75 ℃ is placed on the constant temperature blender with magnetic force, under the stirring velocity of 1000r/min, slowly adds X 2073 earlier, slowly add carboxymethylcellulose sodium solution again, stir 20min fast; Then, the adjustment stirring velocity is 200r/min, continues to stir 70min, and the entire reaction course temperature is controlled between 65-75 ℃.
Take off and leave standstill, reduce to room temperature after, add POTASSIUM SORBATE GRANULAR WHITE 5.0g, stir 5min, promptly get product.
Present embodiment prepares the The performance test results of biological environmental production type sticker and sees table 1.
Embodiment 2
Suaeda salsa seedcake is broken, be ground to fine powder then, cross 120 mesh sieves, get Suaeda salsa seed cake powder 10.0g, place 400ml boiling water, boiling 30min is cooled between 65-75 ℃ then.
Weighing 4.0g X 2073, subsequent use; In beaker, contain the water of getting 100ml, place on the constant temperature blender with magnetic force, weighing 8.0g Xylo-Mucine under continuous condition of stirring, slowly spreads Xylo-Mucine in the beaker equably, and Xylo-Mucine is dissolved fully, and is subsequent use; Other gets a beaker; Sheng is got the water of 100ml, and weighing 4.0g Z 150PH slowly adds fully swelling, dispersion in the cold water about 20 ℃ with these article while stirring; Then be warmed up to 95-100 ℃ of accelerate dissolution; No longer contain molecule up to solution, again through behind the 60 order stainless steel sift impurity screenings, can be subsequent use.
The Suaeda salsa seed cake powder solution of temperature between 65-75 ℃ is placed on the constant temperature blender with magnetic force; Under the stirring velocity of 1000r/min, slowly add X 2073 and polyvinyl alcohol solution earlier, stir 10min; Slowly add carboxymethylcellulose sodium solution again, stir 20min; Then, the adjustment stirring velocity is 200r/min, continues to stir 60min, and the entire reaction course temperature is controlled between 65-75 ℃.
Take off and leave standstill, reduce to room temperature after, add Sodium Benzoate 5.0g, stir 5min, promptly get product.
Present embodiment prepares the The performance test results of biological environmental production type sticker and sees table 1.
Embodiment 3
In the present embodiment, the preparation process of biological environmental production type sticker is identical with embodiment 1, and only the proportioning to preparation biological environmental production type sticker desired raw material changes.
Each raw material composition and proportioning required in the preparation process are distinguished as follows: (g)
Salt is the fluffy seed cake powder 6.0 of alkali also;
X 2073 3.0;
Xylo-Mucine 10.0;
POTASSIUM SORBATE GRANULAR WHITE 5.0;
Clear water 600.0.
Present embodiment prepares the The performance test results of biological environmental production type sticker and sees table 1.
Embodiment 4
In the present embodiment, the preparation process of biological environmental production type sticker is identical with embodiment 1, and only the proportioning to preparation biological environmental production type sticker desired raw material changes.
Each raw material composition and proportioning required in the preparation process are distinguished as follows: (g)
Suaeda salsa seed cake powder 8.0;
X 2073 4.0;
Xylo-Mucine 10.0;
POTASSIUM SORBATE GRANULAR WHITE 4.0;
Clear water 600.0.
Present embodiment prepares the The performance test results of biological environmental production type sticker and sees table 1.
Embodiment 5
In the present embodiment, the preparation process of biological environmental production type sticker is identical with embodiment 2, and only the proportioning to the no guarantor's type sticker desired raw material of preparation ring changes.
Each raw material composition and proportioning required in the preparation process are distinguished as follows: (g)
Suaeda salsa seed cake powder 10.0;
X 2073 4.0;
Xylo-Mucine 12.0;
Z 150PH 4.0;
Sodium Benzoate 4.0;
Clear water 600.0.
Present embodiment prepares the The performance test results of biological environmental production type sticker and sees table 1.
The biological environmental production type sticker for preparing among the embodiment 1-5 is carried out viscosity and cohesive strength test.Its medium viscosity adopts rotary viscosity measuring; Cohesive strength is represented with the ultimate compression strength that clay model can bear, and adopts no confining pressure appearance to measure.Test environment, temperature are 20 ℃.Test result is seen table 1.
Table 1
| Embodiment | Viscosity/centipoise | Ultimate compression strength/MPa | Quality guaranteed period |
| Embodiment 1 | 58.8 | 1.48 | 25 to 35 days |
| Embodiment 2 | 960.0 | 2.16 | 25 to 35 days |
| Embodiment 3 | 350.0 | 2.05 | 25 to 35 days |
| Embodiment 4 | 670.0 | 2.08 | 25 to 30 days |
| Embodiment 5 | 1030.0 | 2.12 | 25 to 30 days |
The preparation of clay model: biological environmental production type sticker and particle diameter is even according to 1: 7 ratio blending less than the soil particle of 0.125mm; Pack in the cylindrical die of Φ 50 * 60; Process clay model, place blast drier under 35 ℃ of conditions dry 24 hours, take out; The cylindrical clay model of exsiccant is all polished flat and is parallel to each other in two surfaces up and down, make it stressed even when test.
Claims (9)
1. biological environmental production type sticker, said sticker mainly comprises the fluffy seedcake dregs of rice of alkali, tensio-active agent, thickening material and tackiness agent; In gross weight is 100 parts, and the parts by weight of said each main ingredient of sticker are:
The fluffy seedcake dregs of rice of alkali 1.2-4.0 part;
Tensio-active agent 0.4-1.0 part;
Thickening material 0.8-3.0 part;
Tackiness agent 0.5-1.5 part;
Sanitas 1.0-1.5 part;
All the other are water.
2. biological environmental production type sticker according to claim 1 is characterized in that: said alkali is fluffy to be fluffy, the hard branch of Suaeda salsa, Suaeda heteroptera, angle alkali alkali one or more in fluffy.
3. biological environmental production type sticker according to claim 1 is characterized in that: the fluffy seedcake dregs of rice of said alkali are the tailing that the fluffy seed of alkali obtains after squeezing oil expression processing or solvent lixiviate; Need fragmentation, porphyrize during use, sieve, obtain particle diameter less than the fluffy seed cake powder of the alkali of 0.125mm.
4. biological environmental production type sticker according to claim 1 is characterized in that: said tensio-active agent is an X 2073, and its structure is linear chain structure, i.e. LAS.
5. biological environmental production type sticker according to claim 1; It is characterized in that: said thickening material is an Xylo-Mucine; By a kind of anionic macromolecular compound that makes after natural cellulose and caustic alkali and the monochloroacetic acid reaction; Molecular weight is 6400 (1000), and density is 0.5-0.7g/cm
3
6. biological environmental production type sticker according to claim 1 is characterized in that: said tackiness agent is one or more among Z 150PH 17-88, Z 150PH 17-92 and the Z 150PH 17-99.
7. biological environmental production type sticker according to claim 1 is characterized in that: said sanitas is one or more in POTASSIUM SORBATE GRANULAR WHITE, phenylformic acid and the salt thereof.
8. biological environmental production type sticker according to claim 1 is characterized in that: the said biological environmental production type sticker viscosity that makes is the 40-1500 centipoise.
9. the preparation method of the described biological environmental production type of claim 1 sticker is characterized in that, comprises the steps:
A) with the fluffy seedcake dregs of rice of said alkali crushing grinding to fine powder, sieve, get particle diameter less than the fluffy seed cake powder of the alkali of 0.125mm;
B) the fluffy seed cake powder of alkali that step a) is obtained places boiling water to do thermal treatment, boiling 30min; Take off then and leave standstill, be cooled between 65-75 ℃;
C) under continuous condition of stirring, Xylo-Mucine is slowly spread in the beaker equably, Xylo-Mucine is dissolved fully, subsequent use; Under continuous condition of stirring, Z 150PH is slowly added fully swelling, dispersion in the cold water about 20 ℃, then be warmed up to 95-100 ℃ of accelerate dissolution, no longer contain molecule up to solution, again through behind the 60 order stainless steel sift impurity screenings, can be subsequent use;
D) under the stirring velocity of 1000r/min, in the fluffy seed cake powder solution of the alkali that step b) obtains, slowly add X 2073 and polyvinyl alcohol solution earlier, stir 10min, slowly add carboxymethylcellulose sodium solution again, stir 20min; Then, the adjustment stirring velocity is 200r/min, continues to stir 60min, and the entire reaction course temperature is controlled between 65-75 ℃;
E) take off and leave standstill, be cooled to room temperature after, add said sanitas, stir 5min, promptly get said biological environmental production type sticker.
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| CN102863965A (en) * | 2012-10-15 | 2013-01-09 | 南开大学 | Eco-friendly sand stabilization dust depressor and preparation method thereof |
| CN103710066A (en) * | 2013-12-20 | 2014-04-09 | 广西柳州浚业科技有限公司 | Composite binder for industrial briquette and preparation method thereof |
| CN104178625A (en) * | 2014-08-21 | 2014-12-03 | 东北大学 | Method for preparing magnesite powder pellet for preventing explosion in smelting process |
| CN107033828A (en) * | 2017-05-23 | 2017-08-11 | 林玉萍 | A kind of water-based glue |
| CN107057794A (en) * | 2017-05-26 | 2017-08-18 | 桂林聚能环保科技有限责任公司 | A kind of house refuse modification forming and the method for gasification |
| CN108384556A (en) * | 2018-04-09 | 2018-08-10 | 王景硕 | A kind of preparation method of degradable sand-consolidating agent |
| CN109749685A (en) * | 2017-11-08 | 2019-05-14 | 丹阳市易通安全技术服务有限公司 | A kind of glued board adhesive composition and its preparation process |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102863965A (en) * | 2012-10-15 | 2013-01-09 | 南开大学 | Eco-friendly sand stabilization dust depressor and preparation method thereof |
| CN103710066A (en) * | 2013-12-20 | 2014-04-09 | 广西柳州浚业科技有限公司 | Composite binder for industrial briquette and preparation method thereof |
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| CN107033828A (en) * | 2017-05-23 | 2017-08-11 | 林玉萍 | A kind of water-based glue |
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| CN109749685A (en) * | 2017-11-08 | 2019-05-14 | 丹阳市易通安全技术服务有限公司 | A kind of glued board adhesive composition and its preparation process |
| CN108384556A (en) * | 2018-04-09 | 2018-08-10 | 王景硕 | A kind of preparation method of degradable sand-consolidating agent |
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| CN102504757B (en) | 2013-05-01 |
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