CN101229949A - Mobile radioactive liquid waste treatment equipment - Google Patents

Mobile radioactive liquid waste treatment equipment Download PDF

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Publication number
CN101229949A
CN101229949A CNA2007100603916A CN200710060391A CN101229949A CN 101229949 A CN101229949 A CN 101229949A CN A2007100603916 A CNA2007100603916 A CN A2007100603916A CN 200710060391 A CN200710060391 A CN 200710060391A CN 101229949 A CN101229949 A CN 101229949A
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China
Prior art keywords
treatment equipment
waste water
liquid waste
plc
radioactive liquid
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CNA2007100603916A
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Chinese (zh)
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CN101229949B (en
Inventor
张铁林
孟琰彬
毛宝生
刘锋
曲德亮
毕鉴华
凌文
张亚奕
张凯
刘明亚
张琦
孟宪雄
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Research Institute of Physical and Chemical Engineering of Nuclear Industry
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Huahe New Technology Development Co Research Institute of Physical and Chemical Engineering of Nuclear Industry
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Abstract

The invention discloses a movable treatment device for radioactive waste water, which comprises a protecting vehicle, a heat preservation cabin, a treatment system of waste water, a PLC controlling system and an external connecting pipeline, wherein, the treatment system of waste waster consists of a liquid and solid separator, a pre-filter, an ultra-filter, a security filter, a reverse osmosis filter of two levels and a combined adsorption device; the PLC system consists of a PLC, a flow meter, a conductivity meter, a radioactivity detector and a pressure controlling device. The invention solves the contradiction between the low interception and adsorption efficiency of nuclide and small size under the condition of large flow, meanwhile, which solves the problems of integration of a plurality of techniques and protection of the movable treatment device of radioactive waste water and realizes automatic operation, safety and reliability in the overall process.

Description

Mobile radioactive liquid waste treatment equipment
Technical field:
The invention belongs to a kind of radioactive wastewater treatment unit, be specifically related to a kind of mobile radioactive liquid waste treatment equipment.
Background technology:
Nuclear power plants, nuclear machinery leakage accident and the attack of terrorism of radiocontamination scattering nature frequently appear in recent years, cause PE, public safety problem to become increasingly conspicuous, especially in the large-and-medium size cities of resident's population concentration, need the configuration mobile radioactive liquid waste treatment equipment to be used for nuclear pollution accident reply and dispose the radioactive wastewater processing that is produced.
In large-and-medium size cities, the water for cleaning that radioactive wastewater is handled generally is the municipal tap water, waste water saltiness after the disposal also should be less than 1000mg/L, after solid-liquid separation and flocculation treatment, adopt the slot type banking system according to request of national standard, the storagetank that equal volume is set simultaneously is used for that radionuclide separates, the clear water after the interception is deposited, and satisfies in use-testing room floor analytical equipment test water purifying radioactive activity and can discharge after exempting the activity index request.
The radioactive liquid waste treatment equipment of prior art is to adopt floor-treating device basically, has wherein adopted the technology of nanofiltration regulating YIN and YANG ion-exchanger, is difficult to accomplish miniaturization, lightweight, is not suitable for making mobile unit.Simultaneously the ratio of desalinization of nanofiltration membrane is lower, and it is bigger that the radionuclide performance of interception ionic state and high desalination rate reverse osmosis membrane are compared gap.In addition, the radioactive wastewater treatment system of prior art lacks necessary test set, can not carry out quantitative processing and control automatically.
Summary of the invention:
The present invention proposes in order to overcome the shortcoming that exists in the prior art, its objective is that providing a kind of can handle a large amount of radioactive wastewaters and transportable mobile radioactive liquid waste treatment equipment apace.
To achieve these goals, technical scheme of the present invention is: a kind of mobile radioactive liquid waste treatment equipment comprises protection car, insulated hold, Waste Water Treatment, PLC Controlling System and external connecting pipe road.
Described Waste Water Treatment comprises liquid-solid separator, prefilter, ultra filtration filter, two steps ro strainer, security personnel's strainer and built-up type adsorption unit, and described PLC Controlling System comprises PLC, flow instrument, conductivitimeter, radiation survey meter and voltage-controlled instrument.
The ultra filtration filter by hollow-fibre membrane and glass steel shell form, four groups of parallel connections.
Every grade of shared six reverse osmosis membranes of I and II reverse osmosis filter are respectively charged into three putaminas, three putamina series connection.
The built-up type adsorption unit is made up of six putaminas, six putamina parallel connections.
The invention solves the interception of nucleic under the big flow condition, adsorption efficiency is low and the contradiction of miniaturization, has solved the integrated and protection question of multiple technologies of mobile radioactive liquid waste treatment equipment simultaneously.Adopt the PLC Controlling System, realized the automated operation, safe and reliable of whole process.
Description of drawings
Fig. 1 is overall structural arrangement figure of the present invention;
Fig. 2 is a Waste Water Treatment structured flowchart of the present invention;
Fig. 3 is PLC Controlling System figure of the present invention.
Wherein:
1 protection car, 2 protection stereotypes
3 liquid-solid separators, 4 prefilters
5 ultra filtration filters, 6 security personnel's strainers
7 first-stage reverse osmosis filtration units, 8 two-pass reverse osmosis filtration units
9 built-up type adsorption unit 10PLC Controlling System
11 insulated holds, 12 antivibration frameworks
13 waste water inlet tubes, 14 backwater vent pipes
15 concentrated water drainages go out pipe 16 water purification vent pipes
17 wastewater disposal basins, 18 dense ponds
19 flow instruments, 20 conductivitimeters
21 radiation survey meters, 22 voltage-controlled instrument
23 supply leads
Embodiment
Below, with reference to drawings and Examples mobile radioactive liquid waste treatment equipment of the present invention is elaborated:
As shown in Figure 1, mobile radioactive liquid waste treatment equipment comprises protection car 1, insulated hold 11, Waste Water Treatment, five parts of PLC Controlling System and external connecting pipe road.Be provided with protection stereotype 2 between wheel house in protection car 1 and the railway carriage, be provided with antivibration framework 12 in the upper and lower of railway carriage, insulated hold 11 is arranged in the railway carriage.In insulated hold 11, Waste Water Treatment is installed, on protection car 1, also is provided with and the outside pipeline that is connected.
As shown in Figure 2, Waste Water Treatment comprises liquid-solid separator 3, prefilter 4, ultra filtration filter 5, security personnel strainer 6, two steps ro strainer 7,8 and built-up type adsorption unit 9.
Liquid-solid separator 3 is arranged in the waste water inlet tube 13, and its structure is that removable filter core is installed in the stainless steel steel cylinder.Its effect is that the particle colloid more than the millimeter level particle diameter is tackled, and prevents the appearance latch up phenomenon that prefilter is too early.
The filter core of prefilter 4 is to make pocket type with filter cloth, and the top is provided with handle, is convenient for changing, and is mainly used in the macrobead suspended substance that filters out in the waste water greater than 20 μ m.
Ultra filtration filter 5 by hollow-fibre membrane and glass steel shell form, four groups of parallel connections, be mainly used in and filter out in the waste water following minimum particle suspensions and the colloid of 0.1 μ m.
The structure of security personnel's strainer 6 is that the rich filter core of many lines is installed in housing, and its effect is to prevent the ultrafiltration inefficacy, the protection reverse osmosis membrane.
Concentration process of the present invention is finished by one, two two steps ro strainers 7,8, and its structure all is: every grade of shared six reverse osmosis membranes (R01, R02) are respectively charged into three putaminas, three putamina tandem workings.Its effect is: concentrate the various compositions hold back capacitive in the waste water, mainly comprise negatively charged ion such as positively charged ion such as cationic species, potassium, sodium, calcium, magnesium and negatively charged ion nucleic, carbonate, sulfate radical, chlorine root.In concentration process, the particulate matter that water-soluble organism and pre-treatment end can be removed fully also comprises that impurity such as bacterium, virus, radioactive substance almost completely hold back.
Built-up type adsorption unit 9 is made up of many putaminas, and the present invention is six, six putamina parallel connections.The absorption filter core is installed in putamina, in filter core, is provided with nonionic adsorption resin.Its effect is: the ion in the fresh water that the absorption reverse osmosis is come reaches emission standard.
Be respectively arranged with conductivity sensor μ S1, μ S2, μ S3 and μ S4 at the inlet of prefilter 4 and in the outlet of first-stage reverse osmosis strainer 7, built-up type adsorption unit 9 and two-pass reverse osmosis strainer 8.Be respectively arranged with flow sensor FL1 and FL2 at the inlet of ultra filtration filter 5 and the outlet of first-stage reverse osmosis strainer 7.In order to measure the pressure of processed medium, in pipeline, be provided with a plurality of pressure transmitter P1~P12.Outlet at built-up type adsorption unit 9 is provided with the radioassay transmitter.In pipeline, also be provided with a plurality of pump M1~M4.
As shown in Figure 3, full-automatic PLC Controlling System comprises PLC10, flow instrument 19, conductivitimeter 20, radiation survey meter 21 and voltage-controlled instrument 22.Symbol 23 expression supply leads.
Flow sensor FL1 and FL2 detect the signal of rate-of flow, are transferred under meter 19, with the set(ting)value contrast, if exceed set(ting)value, then signal are transferred to PLC, carry out Flow-rate adjustment control.
Pressure transmitter P1~P12 detects the pressure condition of medium, and signal is transferred to voltage-controlled instrument 22, with the set(ting)value contrast, if exceed set(ting)value, then signal is transferred to PLC, carries out Flow-rate adjustment control.
Conductivity sensor μ S1, μ S2, μ S3 and μ S4 detect the medium conductivity situation, and signal is transferred to conductivitimeter 20, with the set(ting)value contrast, if exceed set(ting)value, then signal are transferred to PLC, carry out Flow-rate adjustment control.
The radioassay transmitter detects the radioactivity situation of medium, and signal is transferred to radiation survey meter 21, with the set(ting)value contrast, if exceed set(ting)value, then signal is transferred to PLC, carries out radioactivity and regulates control.
The present invention adopts pre-filtering, ultra-filtration filters, two steps ro to filter and the built-up type adsorption unit, solved the interception of nucleic under the big flow condition, adsorption efficiency is low and the contradiction of miniaturization, has solved the integrated and protection question of multiple technologies of mobile radioactive liquid waste treatment equipment simultaneously.Adopt the PLC Controlling System, realized the automated operation of whole process.

Claims (4)

1. mobile radioactive liquid waste treatment equipment, comprise protection car (1), insulated hold (11), Waste Water Treatment, PLC Controlling System and external connecting pipe road, it is characterized in that: described Waste Water Treatment comprises liquid-solid separator (3), prefilter (4), ultra filtration filter (5), security personnel strainer (6), two steps ro strainer (7,8) and built-up type adsorption unit (9), and described PLC Controlling System comprises PLC (10), flow instrument (19), conductivitimeter (20), radiation survey meter (21) and voltage-controlled instrument (22).
2. mobile radioactive liquid waste treatment equipment according to claim 1 is characterized in that: ultra filtration filter (5) by hollow-fibre membrane and glass steel shell form, four groups of parallel connections.
3. mobile radioactive liquid waste treatment equipment according to claim 1 is characterized in that: every grade of shared six reverse osmosis membranes of two steps ro strainer (7,8) are respectively charged into three putaminas, three putamina series connection.
4. mobile radioactive liquid waste treatment equipment according to claim 1 is characterized in that: built-up type adsorption unit (9) is made up of six putaminas, six putamina parallel connections.
CN2007100603916A 2007-12-19 2007-12-19 Mobile radioactive liquid waste treatment equipment Active CN101229949B (en)

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Application Number Priority Date Filing Date Title
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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101684008B (en) * 2008-09-27 2012-06-06 上海轻工业研究所有限公司 Inorganic waste water reclamation movement expert system
CN102496397A (en) * 2011-12-23 2012-06-13 核工业理化工程研究院华核新技术开发公司 Mobile type nuclear-biochemical air and liquid waste treatment system
CN102522134A (en) * 2011-12-23 2012-06-27 核工业理化工程研究院华核新技术开发公司 Purification system for treating radioactive contamination water into drinking water
CN104071068A (en) * 2014-06-03 2014-10-01 江苏羊城净水设备有限公司 Sewage water treatment vehicle
CN104299667A (en) * 2014-09-18 2015-01-21 中国核动力研究设计院 Movable radioactive waste water far infrared treatment device
CN104392758A (en) * 2014-09-05 2015-03-04 中电投远达环保工程有限公司 Mobile radioactive waste liquid evaporation treatment device
CN105073228A (en) * 2013-02-15 2015-11-18 先进水处理公司 Integrated ultrafiltration and reverse osmosis desalination systems
CN106415733A (en) * 2014-05-28 2017-02-15 Itn纳诺维森股份公司 Method and system for removing radioactive nuclides from water
CN106448787A (en) * 2014-01-09 2017-02-22 清华大学 Method and device for treating radioactive wastewater
CN106531267A (en) * 2016-08-30 2017-03-22 长江勘测规划设计研究有限责任公司 Drainage system and method for underground nuclear power plant cavern group
CN106803439A (en) * 2015-11-26 2017-06-06 大亚湾核电运营管理有限责任公司 Mobile purifier, Liquid Radwaste Treatment and method for nuclear power station
CN107093483A (en) * 2017-04-27 2017-08-25 华北电力大学 A kind of radionuclide collection device
EP3160599A4 (en) * 2014-06-24 2018-04-25 Kurion, Inc. Mobile processing system for hazardous and radioactive isotope removal
US9981868B2 (en) 2010-04-02 2018-05-29 Kurion, Inc. Mobile processing system for hazardous and radioactive isotope removal
WO2019056213A1 (en) * 2017-09-20 2019-03-28 苏州北开生化设备有限公司 Working method for efficient and intelligent water treatment equipment with water quality detection function
CN109734227A (en) * 2019-03-21 2019-05-10 成都都成环保股份有限公司 A kind of universe water purification car
GB2583276B (en) * 2018-01-03 2023-03-29 Univ Tsinghua Method and system for concentrating and solidifying radionuclides in radioactive waste liquid

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1192396C (en) * 1996-01-11 2005-03-09 东芝株式会社 Treating apparatus for radioactive waste liquid
CN1281525C (en) * 2004-05-25 2006-10-25 侯立安 Method for treatment of radioactive waste water and system therefor
CN201154931Y (en) * 2007-12-19 2008-11-26 核工业理化工程研究院华核新技术开发公司 Mobile radioactive liquid waste treatment device

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101684008B (en) * 2008-09-27 2012-06-06 上海轻工业研究所有限公司 Inorganic waste water reclamation movement expert system
US9981868B2 (en) 2010-04-02 2018-05-29 Kurion, Inc. Mobile processing system for hazardous and radioactive isotope removal
CN102496397A (en) * 2011-12-23 2012-06-13 核工业理化工程研究院华核新技术开发公司 Mobile type nuclear-biochemical air and liquid waste treatment system
CN102522134A (en) * 2011-12-23 2012-06-27 核工业理化工程研究院华核新技术开发公司 Purification system for treating radioactive contamination water into drinking water
CN102522134B (en) * 2011-12-23 2014-08-20 核工业理化工程研究院华核新技术开发公司 Purification system for treating radioactive contamination water into drinking water
CN105073228A (en) * 2013-02-15 2015-11-18 先进水处理公司 Integrated ultrafiltration and reverse osmosis desalination systems
CN105073228B (en) * 2013-02-15 2018-08-28 蓝洋创新有限责任公司 Integrated ultrafiltration and reverse osmosis desalinization system
CN106448787B (en) * 2014-01-09 2018-10-02 清华大学 A kind of method and apparatus of Spent Radioactive water process
CN106448787A (en) * 2014-01-09 2017-02-22 清华大学 Method and device for treating radioactive wastewater
CN106415733A (en) * 2014-05-28 2017-02-15 Itn纳诺维森股份公司 Method and system for removing radioactive nuclides from water
CN104071068A (en) * 2014-06-03 2014-10-01 江苏羊城净水设备有限公司 Sewage water treatment vehicle
US20200002209A1 (en) * 2014-06-24 2020-01-02 Kurion, Inc. Mobile processing system for hazardous and radioactive isotope removal
US20220289609A1 (en) * 2014-06-24 2022-09-15 Veolia Nuclear Solutions, Inc. Mobile Processing System for Hazardous and Radioactive Isotope Removal
EP3160599A4 (en) * 2014-06-24 2018-04-25 Kurion, Inc. Mobile processing system for hazardous and radioactive isotope removal
US11807549B2 (en) 2014-06-24 2023-11-07 Veolia Nuclear Solutions, Inc. Mobile processing system for hazardous and radioactive isotope removal
EP3988181A1 (en) * 2014-06-24 2022-04-27 Veolia Nuclear Solutions, Inc. Mobile processing system for hazardous and radioactive isotope removal
US10689281B2 (en) 2014-06-24 2020-06-23 Kurion, Inc. Mobile processing system for hazardous and radioactive isotope removal
EP3552673A1 (en) 2014-06-24 2019-10-16 Kurion, Inc. Mobile processing system for hazardous and radioactive isotope removal
CN104392758A (en) * 2014-09-05 2015-03-04 中电投远达环保工程有限公司 Mobile radioactive waste liquid evaporation treatment device
CN104299667A (en) * 2014-09-18 2015-01-21 中国核动力研究设计院 Movable radioactive waste water far infrared treatment device
CN106803439A (en) * 2015-11-26 2017-06-06 大亚湾核电运营管理有限责任公司 Mobile purifier, Liquid Radwaste Treatment and method for nuclear power station
CN106531267A (en) * 2016-08-30 2017-03-22 长江勘测规划设计研究有限责任公司 Drainage system and method for underground nuclear power plant cavern group
CN106531267B (en) * 2016-08-30 2018-06-26 长江勘测规划设计研究有限责任公司 A kind of underground nuclear power station cavity group drainage system and method
CN107093483A (en) * 2017-04-27 2017-08-25 华北电力大学 A kind of radionuclide collection device
CN107093483B (en) * 2017-04-27 2024-04-09 华北电力大学 Radionuclide collection device
WO2019056213A1 (en) * 2017-09-20 2019-03-28 苏州北开生化设备有限公司 Working method for efficient and intelligent water treatment equipment with water quality detection function
GB2583276B (en) * 2018-01-03 2023-03-29 Univ Tsinghua Method and system for concentrating and solidifying radionuclides in radioactive waste liquid
CN109734227A (en) * 2019-03-21 2019-05-10 成都都成环保股份有限公司 A kind of universe water purification car

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Address after: 300384 Tianjin hi tech District of Xiqing City Huayuan Industrial Zone Development six road No. 6 Haitai green industry base building J room 104

Co-patentee after: Mao Baosheng

Patentee after: China core (Tianjin) New Technology Development Co., Ltd.

Co-patentee after: Liu Feng

Co-patentee after: Bi Jianhua

Address before: 300384, F, 6, gate 6, two weft Road, Tianjin yuan industry zone, 302

Co-patentee before: Mao Baosheng

Patentee before: Huahe New Technology Development Company, Research Institute of Physical and Chemical Engineering of Nuclear Industry

Co-patentee before: Liu Feng

Co-patentee before: Bi Jianhua

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20200310

Address after: 300180, No. 168 Jintang Road, Hedong District, Tianjin

Co-patentee after: Mao Baosheng

Patentee after: Inst. of Physics and Chemistry Engineering

Co-patentee after: Liu Feng

Co-patentee after: Bi Jianhua

Address before: 300384 Tianjin hi tech District of Xiqing City Huayuan Industrial Zone Development six road No. 6 Haitai green industry base building J room 104

Co-patentee before: Mao Baosheng

Patentee before: China core (Tianjin) New Technology Development Co., Ltd.

Co-patentee before: Liu Feng

Co-patentee before: Bi Jianhua