CN101225261A - Architectural interior anion waterproof putty powder and preparation method thereof - Google Patents

Architectural interior anion waterproof putty powder and preparation method thereof Download PDF

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Publication number
CN101225261A
CN101225261A CNA2008103003311A CN200810300331A CN101225261A CN 101225261 A CN101225261 A CN 101225261A CN A2008103003311 A CNA2008103003311 A CN A2008103003311A CN 200810300331 A CN200810300331 A CN 200810300331A CN 101225261 A CN101225261 A CN 101225261A
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powder
negative ion
calcium
waterproof putty
architectural interior
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CN101225261B (en
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周长喜
宋明宇
魏培哲
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Beijing Lions Hi Tech Co ltd
Lions Building Material (Beijing) Co.,Ltd.
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BEIJING CREAD BUILDING MATERIALS MANUFACTURING Co Ltd
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Abstract

The invention relates to a building interior anionic water resistant putty powder. The weight ratios of the components are 100 to 300 portions active calcium powder, 200 to 700 portions calcium carbonate powder, 50 to 200 portions anion powder, 1 to 10 portions cementing material and 1 to 5 portions cellulose; wherein, the anion powder is the mixed powder of ultrafine tourmaline powder and physical adsorption materials, the fineness of the ultrafine tourmaline powder is more than 2.6 Mum and the purity of the ultrafine tourmaline powder is more than 95 percent, the physical adsorption material is diatomite or modified active carbon and the weight of the physical adsorption material is 20 to 35 percent the total weight of the anion powder. The building interior anionic water resistant putty powder has the advantages that: the preparation method does not need the excitation of light energy sources and has not the danger of over standard radioactivity, so the removal ratios of formaldehyde and toluene is increased greatly, the putty powder plays the role of eliminating pollution and purifying air, meanwhile, the water resistant performance of the putty powder are enhanced.

Description

Architectural interior anion waterproof putty powder and preparation method thereof
(1) technical field
The present invention relates to a kind of construction wall putty powder, and the preparation method of this putty powder.
(2) background technology
The harmful minimum gas that discharges in constructional ornamental material and the furniture, the peculiar smell that produces as formaldehyde, ammonia, benzene and human body etc. swims in aerial, its occurrence status and form are complicated and diversified, what have exists with free gas molecule form, what have is formed positive ion by buoyant in the air a large amount of positive charge absorption, encirclement, the minimum gas molecule that has deposits on already present particle surface, is condensed into aerosol system etc.Just because of above positive ion or aerocolloidal existence, caused the indoor serious air of new finishing not have and dyed, HUMAN HEALTH has been caused great harm.In order to address this problem, the tourmaline powder that can go out negative ion has been adopted in more existing inventions in traditional putty powder, wherein a class be must join activate tourmaline powder with rare earth material, yet this putty powder has the danger that radioactivity exceeds standard; Second class is to add titanic oxide material in putty powder, form the photocatalyst anion material, but the condition that this materials purification air gets is excited just by light energy source can work.In addition, existing putty powder gets water resistance and all can not make people's satisfaction.In view of the equal defectiveness of above existing putty powder, therefore be necessary the further new material of development.
(3) summary of the invention
The purpose of this invention is to provide a kind of architectural interior anion waterproof putty powder and preparation method thereof, solving existing putty powder has danger that radioactivity exceeds standard, must be subjected to light energy source to excite the problem that just can purify air, and solve make putty powder improve decontamination, purify air effect, also improve the water resistance of putty powder simultaneously.
For achieving the above object, the present invention adopts following technical scheme:
This architectural interior anion waterproof putty powder is characterized in that by following weight part proportioning being:
100~300 parts of activated calcium powders;
200~700 parts of Paris whites;
50~200 parts of negative ion powders;
1~10 part of organic gel gel material;
1~5 part of Mierocrystalline cellulose;
Above-mentioned negative ion powder is the mixed powder of ultra-fine tourmaline powder and physisorption material, and wherein the fineness of ultra-fine tourmaline powder is more than the 2.6 μ m, and purity is more than 95%; Physisorption material is wherein a kind of of diatomite and modified activated carbon, and the weight of physisorption material accounts for 20%~35% of negative ion powder gross weight.
Above-mentioned activated calcium powder is a kind of, two or three the mixture in grey calcium powder, calcium hydroxide powder, the calcium oxide powder.
Above-mentioned Paris white is to be a kind of, two or three mixture in dry powder, chalk powder, the calcium carbonate superfine powder powder.
Above-mentioned organic gel gel material is a kind of, two or three the mixture in starch, pasted starch, the polyvinyl alcohol.
Above-mentioned Mierocrystalline cellulose is one or both the mixture in methylcellulose gum or the carboxymethyl cellulose.
The viscosity of above-mentioned methylcellulose gum or carboxymethyl cellulose is 300~10000 centipoises.
The preparation method of described architectural interior anion waterproof putty powder is characterized in that step is as follows:
Step 1 adds activated calcium powder, Paris white and the negative ion powder that accounts for proportioning weight half earlier in container, stirred 5~20 minutes;
Step 2 adds organic gel gel material and Mierocrystalline cellulose by proportioning, stirs 5~20 minutes;
Step 3 adds remaining activated calcium powder, Paris white and negative ion powder again, continues to stir 15~60 minutes, mixes the back discharging.
Compared with prior art the present invention has following characteristics and beneficial effect:
The present invention can self produce electrostatic field, water molecules by free state in the tank room, produce negative ion,, have absorption and charge neutrality effect because negative ion itself has static, the present invention has promptly utilized this characteristic of negative ion, when negative ion and airborne positive ion meet,, have absorption and electrically neutralizing effect because negative ion itself has static, so swim in airborne a part of free minimum gas molecule by after the negative ion absorption, because action of gravity drops on the ground; Electrically neutralization took place in the two when dusty gas that another part is positively charged and negative ion met, and formed no neutral charge molecule sedimentation nuclear and was deposited on the ground, made it purify, eliminate the purpose of obnoxious flavour thereby reach.
Its concrete reaction process is as follows:
Airborne gas molecule or water molecules are under the effect of extraneous factor and energy, and out-shell electron is broken away from nuclear constraint, promptly are positive electricity after jumping out from track, become positive aeroion.The electronics that is jumped out by airborne other gas molecule or water molecules capture in conjunction with and electronegative, become negative aeroion.Its polarity formula of ion common in the air has following several:
H +(H 2O) nH 3O 2 -(H 2O) nThe hydroxyl negative ion;
(H 3O)+(H 2O) nOH -(H 2O) nHydroxyl radical negative ion;
O+ (H 2O) nO 2 -(H 2O) nNegative oxygen ion;
The present invention can influence extraneous small molecules and the negative ion that produces, can play the effect that purifies air, mainly show the airborne positive ion that to adsorb and to neutralize, elimination is suspended in the airborne layer that wafts below 10 microns, elimination because of interior decoration and finishing material discharge as many poisonous, deleterious gases such as formaldehyde, ammonia, benzene, also can suppress the growth of bacterium, mould poison simultaneously.
The negative ion that the present invention produces is except playing an important role to purifying air.Can also protect HUMAN HEALTH.Indoor be coated with scrape negative ion putty powder after, himself produces electrostatic field, water molecules by free state in the tank room, produce negative ion, after negative aeroion enters respiratory tract, by electricity irritation, make respiratory tract be stained with a nerve ending impulse of excitation and pass to maincenter, by the neural reflex effect human body is produced physiological effect again.Negative aeroion works by body fluid.Promptly by principles such as responding to, adsorb and see through, with the electric metabolic process of charge affects blood colloid own and cell.Negative ion can increase the current potential of blood, and positive ion can weaken the current potential of blood.Thereby the component of the charged particle in the blood and distribution are changed.Negative aeroion is by exerting an influence to internal secretion, and nervous system regulation plays beneficial effect to human body.
Negative ion powder of the present invention is the mixed powder of ultra-fine tourmaline powder and physisorption material, and the fineness of ultra-fine tourmaline powder is greater than 2.6 μ m, and purity is greater than 95%, and physisorption material diatomite and modified activated carbon are porous mass.Both have improved greatly to the dispel rate of room air to free formaldehyde, toluene after cooperating, and the rate of dispeling of PARA FORMALDEHYDE PRILLS(91,95) is 90% in the 24h, and it is 35% that toluene is dispeled rate.The danger that does not have radioactivity to exceed standard than rare-earth activated tourmaline powder; Contrast the rate of dispeling that pure tourmaline powder has improved PARA FORMALDEHYDE PRILLS(91,95) toluene greatly; Contrast photocatalyst of titanium dioxide anion material has then overcome the restriction that excited by light energy source.Negative ion putty of the present invention has improved water tolerance greatly than the putty before the modification, and proof is no abnormal by rising to more than the 96h more than the immersion 48h after testing, (national standard is no abnormal for soaking 48h); Having improved pull strength greatly, is that to rise to 7 days pull strengths of normal curing be 1.2 MPas to 0.5 MPa by 7 days pull strengths of normal curing.Moreover, negative ion putty of the present invention cost per ton more in the past like product reduced 50-150 unit.
Correlation test data of the present invention such as following table:
Figure A20081030033100061
Figure A20081030033100071
The present invention carries out the negative aeroion generating capacity and detects through building material industry environmental monitoring center, sample panel is lain on the grating ion collector, and collector is put into 0.4m 3Airtight storehouse in, carry out continuously tested with still air ion tester, the average increasing amount of material negative ion is 1178/scm 2
The present invention asks upholstery environmental monitoring center to carry out formaldehyde, benzene, negative ion concentration through finishing material indoor environmental quality supervision inspection center of Chinese light industry federation, Beijing Ai Er and detects, and detection method is as follows:
Test is at two 1.5m 3Test chamber in carry out, one is sample chamber, another is blank cabin.
(40 * 40cm) in sample chamber with two samples.
The toluene source of release is placed on respectively in two cabins, tends to balance, open fan, make in source of release and the cabin air mixed even, close fan, it is starting point concentration that collected specimens is surveyed its concentration.
The 24h post-sampling is also measured the concentration value of formaldehyde in two cabins.
The benzene detection method is the same.
Detected result is as follows:
Test item Action time (h) Test conditions Detected result
Formaldehyde 24h Blank cabin 1.64mg/m 3
Formaldehyde 24h Sample chamber 0.75mg/m 3
Benzene 24h Blank cabin 1.34mg/m 3
Benzene 24h Sample chamber 0.92mg/m 3
Negative ion - - 1120/cm 3
Detected result shows that the present invention has tangible elimination effect to the formaldehyde in the room air, benzene.
In addition, the present invention carries out radioassay through national building materials industry radioactivity and objectionable impurities supervision and inspection center, for radioactive substance 226Ra, 232Th, 40K does not all detect, the danger that does not have radioactivity to exceed standard.
(4) embodiment
Embodiment one, and this architectural interior anion waterproof putty powder by following weight part proportioning is:
Activated calcium powder: 100~300 parts;
Paris white: 200~700 parts;
Negative ion powder: 50~200 parts;
Organic gel gel material: 1~10 part;
Mierocrystalline cellulose: 1~5 part;
Above-mentioned negative ion powder is the mixed powder of ancient piece of jade, round, flat and with a hole in its centre imperial or royal seal tourmaline powder and physisorption material, and wherein the fineness of ultra-fine tourmaline powder is more than the 2.6 μ m, and purity is more than 95%; Physisorption material is wherein a kind of of diatomite and modified activated carbon, and the weight of physisorption material accounts for 25%~30% of negative ion powder gross weight.Diatomite accounts for 2-5 part of putty powder total weight parts, and modified activated carbon accounts for 1-3 part of putty powder total weight parts.
Above-mentioned activated calcium powder is a kind of, two or three the mixture in grey calcium powder, calcium hydroxide powder, the calcium oxide powder.
Above-mentioned Paris white is to be a kind of, two or three mixture in dry powder, chalk powder, the calcium carbonate superfine powder powder.
Above-mentioned organic gel gel material is a kind of, two or three the mixture in starch, pasted starch, the polyvinyl alcohol.
Above-mentioned Mierocrystalline cellulose is one or both the mixture in methylcellulose gum or the carboxymethyl cellulose.
The viscosity of above-mentioned methylcellulose gum or carboxymethyl cellulose is 1000~5000 centipoises.
Embodiment two:
Ash calcium powder: 100 parts;
Dry powder: 200 parts;
45 parts of ancient piece of jade, round, flat and with a hole in its centre imperial or royal seal tourmaline powders;
15 parts in diatomite;
Starch: 2 parts;
Methylcellulose gum: 1 part.
Embodiment three:
150 parts in the mixture of ash calcium powder and calcium hydroxide powder;
Chalk powder: 300 parts;
70 parts of ancient piece of jade, round, flat and with a hole in its centre imperial or royal seal tourmaline powders;
30 parts of modified activated carbons;
Pasted starch: 4 parts;
Methylcellulose gum: 2 parts.
Embodiment four:
Calcium oxide powder: 200 parts;
500 parts in the mixture of chalk powder and calcium carbonate superfine powder powder;
120 parts of ancient piece of jade, round, flat and with a hole in its centre imperial or royal seal tourmaline powders;
45 parts in diatomite;
8 parts of polyvinyl alcohol;
Carboxymethyl cellulose: 3 parts.
Embodiment five:
300 parts in ash calcium powder, calcium hydroxide powder, calcium oxide powder three's mixture;
Paris white: 700 parts;
140 parts of ancient piece of jade, round, flat and with a hole in its centre imperial or royal seal tourmaline powders;
60 parts in diatomite;
10 parts in the mixture of starch and pasted starch;
Mierocrystalline cellulose: 5 parts.
The preparation method embodiment one of above-mentioned architectural interior anion waterproof putty powder:
Step 1 adds activated calcium powder, Paris white and the negative ion powder that accounts for about proportioning weight half earlier in container, stirred 10 minutes;
Step 2 adds organic gel gel material and Mierocrystalline cellulose by proportioning, stirs 10 minutes;
Step 3 adds remaining activated calcium powder, Paris white and negative ion powder again, continues to stir 30 minutes, mixes the back discharging.
Preparation method embodiment two of the present invention:
Add calcium powder 75kg in reactor in proportion, Paris white 350kg and negative ion powder 75kg open stirring, add organic gel gel material 5kg and Mierocrystalline cellulose 3kg after ten minutes, stir and add calcium powder 75kg again after ten minutes, Paris white 350kg and negative ion powder 75kg, continuation stirring discharging half an hour.
Constructional method of the present invention: after basic unit's face is handled totally, brushing one deck interfacial agents, blade coating 0.5~1mm negative ion putty powder, 1~2 time 0.5~1mm negative ion putty powder of blade coating moulding again after drying.

Claims (7)

1. architectural interior anion waterproof putty powder is characterized in that by following weight part proportioning being:
100~300 parts of activated calcium powders;
200~700 parts of Paris whites;
50~200 parts of negative ion powders;
1~10 part of organic gel gel material;
1~5 part of Mierocrystalline cellulose;
Above-mentioned negative ion powder is the mixed powder of ultra-fine tourmaline powder and physisorption material, and wherein the fineness of ultra-fine tourmaline powder is more than the 2.6 μ m, and purity is more than 95%; Physisorption material is wherein a kind of of diatomite and modified activated carbon, and the weight of physisorption material accounts for 20%~35% of negative ion powder gross weight.
2. architectural interior anion waterproof putty powder according to claim 1 is characterized in that: above-mentioned activated calcium powder is a kind of, two or three the mixture in grey calcium powder, calcium hydroxide powder, the calcium oxide powder.
3. architectural interior anion waterproof putty powder according to claim 1 is characterized in that: above-mentioned Paris white is to be a kind of, two or three mixture in dry powder, chalk powder, the calcium carbonate superfine powder powder.
4. architectural interior anion waterproof putty powder according to claim 1 is characterized in that: above-mentioned organic gel gel material is a kind of, two or three the mixture in starch, pasted starch, the polyvinyl alcohol.
5. architectural interior anion waterproof putty powder according to claim 1 is characterized in that: above-mentioned Mierocrystalline cellulose is one or both the mixture in methylcellulose gum or the carboxymethyl cellulose.
6. architectural interior anion waterproof putty powder according to claim 1 is characterized in that: the viscosity of above-mentioned methylcellulose gum or carboxymethyl cellulose is 300~10000 centipoises.
7. the preparation method of any described architectural interior anion waterproof putty powder of claim 1~6 is characterized in that step is as follows:
Step 1 adds activated calcium powder, Paris white and the negative ion powder that accounts for proportioning weight half earlier in container, stirred 5~20 minutes;
Step 2 adds organic gel gel material and Mierocrystalline cellulose by proportioning, stirs 5~20 minutes;
Step 3 adds remaining activated calcium powder, Paris white and negative ion powder again, continues to stir 15~60 minutes, mixes the back discharging.
CN2008103003311A 2008-02-04 2008-02-04 Architectural interior anion waterproof putty powder and preparation method thereof Expired - Fee Related CN101225261B (en)

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CN101942239A (en) * 2010-09-16 2011-01-12 吉林省兰舍硅藻新材料有限公司 Diatomite putty powder
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CN106752241A (en) * 2016-12-06 2017-05-31 啄木鸟漆业集团有限公司 A kind of anion jade putty
CN106759999A (en) * 2016-12-23 2017-05-31 安庆市大成防腐保温材料有限责任公司 A kind of heat insulating inner wall plate
CN107056130A (en) * 2017-04-11 2017-08-18 安徽省明美矿物化工有限公司 A kind of attapulgite clay powder with air purification function
CN108610672A (en) * 2017-05-25 2018-10-02 太仓安托建筑材料有限公司 A kind of interior wall diatom ooze coating
CN108342118A (en) * 2018-05-21 2018-07-31 绵阳品弘建筑保温材料有限公司 Except the interior wall activated carbon powder of lacquer putty for use on of formaldehyde and putty paste and preparation method thereof
CN109735158A (en) * 2019-01-08 2019-05-10 赵曦轮 A kind of coating construction process of indoor wall
CN109735158B (en) * 2019-01-08 2021-08-27 赵曦轮 Coating construction process for indoor wall surface
CN110305517A (en) * 2019-08-12 2019-10-08 中山爱因新材料有限公司 A kind of interior wall naturally plants this putty
CN111621184A (en) * 2020-07-07 2020-09-04 湖北恒自然新型建材科技有限公司 Surface layer latex putty powder and preparation method thereof
CN112409839A (en) * 2020-07-31 2021-02-26 江西和正建材有限公司 Anion interior wall putty powder and preparation method thereof
CN112646397A (en) * 2020-09-09 2021-04-13 湖南宜美瑞新材料有限公司 Inorganic white paint and preparation method and application thereof

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