[summary of the invention]
The present invention the invention provides a kind of rubbish leachate treatment method that is used for garbage burning factory in order to overcome above-mentioned the deficiencies in the prior art.
The technical solution adopted for the present invention to solve the technical problems is: a kind of rubbish leachate treatment method is provided, and it may further comprise the steps: pre-treatment; Biological treatment; Advanced treatment.
The scheme that the present invention solves further technical problem is: this pre-treatment may further comprise the steps: percolate is stayed for some time the flow of regulating and storing in an equalizing tank; Percolate is fed a reaction settling basin finish the suspended solids precipitation; Percolate is fed an ammonia blow-removing system stripping go out ammonia; Percolate is fed a pH value equalizing tank.
The scheme that the present invention solves further technical problem is: percolate is 10 days at the hydraulic detention time of equalizing tank.
The scheme that the present invention solves further technical problem is: in reaction settling basin, by adding flocculation agent and slaked lime, make that the suspended solids in the percolate is finished precipitation.
The scheme that the present invention solves further technical problem is: add a certain amount of sulfuric acid at pH value equalizing tank, percolate pH value is adjusted to neutrality.
The scheme that the present invention solves further technical problem is: this biological treatment may further comprise the steps: the percolate that pretreatment stage is handled feeds a heating system; Percolate is fed an anaerobic reation pool; Percolate is fed an Aerobic Pond carry out aerobic treatment.
The scheme that the present invention solves further technical problem is: this heating system is heated to 30-35 degree centigrade with percolate, carries out the anaeration in normal temperature reaction.
The scheme that the present invention solves further technical problem is: this anaerobic reation pool is a two-stage type UBF anaerobic reation pool.
The scheme that the present invention solves further technical problem is: this Aerobic Pond is the SBR pond of having added floating stuffing.
The scheme that the present invention solves further technical problem is: this advanced treatment may further comprise the steps: percolate is fed a filtering system to remove the suspended substance in the water; Just percolate feeds an ozone oxidation system, to being difficult to the biodegradable organic chemical oxidation that carries out in the water, makes pollution substance be oxidized into CO completely
2And H
2O; Percolate is fed a nanofiltration membrane treatment system, multiple larger molecular organics in the interception water; Standard compliant water is discharged.
Compared to prior art, the invention has the beneficial effects as follows: rubbish leachate treatment method of the present invention is at the characteristic of garbage burning factory percolate, adopt three stage treatment systems, and had many places to regulate the setting of facility, guaranteed the stable and high effective operation of whole system; The anaerobion that is arranged so that of two-stage UBF is able to good separation mutually, has improved the processing efficiency of anaerobic reactor; UBF has adopted the system of preheating simultaneously, can keep the stable of reactor operating temperature.
[embodiment]
Below in conjunction with drawings and Examples rubbish leachate treatment method of the present invention is described further.
Rubbish leachate treatment method of the present invention may further comprise the steps:
The S1 pre-treatment
This pre-treatment may further comprise the steps: percolate is stayed for some time the flow of regulating and storing in an equalizing tank; Percolate is fed a reaction settling basin finish the suspended solids precipitation; Percolate is fed an ammonia blow-removing system stripping go out ammonia; Percolate is fed a pH value equalizing tank.
Wherein at pretreatment stage, this equalizing tank is that a hydraulic detention time is 10 days a equalizing tank, the flow of percolate and water quality all are very unsettled, and this equalizing tank can play the effect of the flow of regulating and storing, and percolate can be finished anaerobic hydrolysis to a certain degree in the pond simultaneously.
In reaction settling basin, by adding flocculation agent and slaked lime, make that the suspended solids in the percolate is finished precipitation, simultaneously Ca (OH) by adding
2, ionizing event takes place in water:
Ca(OH)
2→Ca
2++2OH
-
This reaction has the beneficial effect of two aspects, and the first is regulated pH value to 10~11 of percolate, for follow-up ammonia stripping is got ready; It two is to pass through OH
-Heavy metal ion in ion and the percolate reacts, and generates precipitation of hydroxide, thereby precipitation and disengaging from percolate guarantees the steady running of subsequent biological treatment technology.
The ammonia blow-removing system, by air blast, from percolate with the NH of molecular state
3Stripping comes out, and forms ammonia, and at high altitude discharge.
Through after the stripping, percolate is fed a pH value equalizing tank, the actual pH situation according to percolate adds a certain amount of sulfuric acid, and the pH value is adjusted to neutrality, helps follow-up biological treatment.
The S2 biological treatment
This biological treatment may further comprise the steps: the percolate that pretreatment stage is handled feeds a heating system; Percolate is fed an anaerobic reation pool; Percolate is fed an Aerobic Pond carry out aerobic treatment.
Percolate enters biological treatment stage, at first is a heating system, and percolate is carried out to a certain degree heating, rises to 30-35 degree centigrade until the garbage filter liquid temp, carries out the anaeration in normal temperature reaction.
After heating system, enter two-stage type UBF anaerobic reation pool, the UBF anaerobic reation pool is the anaerobic reactor of the third generation, have many outstanding advantages, in this technology, for energy stable treated percolate, be provided with two-stage UBF anaerobic reactor, what wherein first step UBF played mainly is the effect of acidication, second stage UBF plays a part to produce methane fermentation, by the setting of two-stage UBF, makes that main two quasi-microorganisms of anaerobic reaction are kept respectively mutually in the UBF reactor, form separately independently running environment and condition, help improving the operational efficiency of UBF.
After UBF, the treatment stage of entering aerobe, percolate is fed the SBR pond that is added with floating stuffing, interpolation by floating stuffing, biofilm treatment system has been introduced active sludge processing system, can improve processing power and efficient greatly, the ability of denitrogenation dephosphorizing also is able to further raising in addition.Floating stuffing has been added in this SBR pond, the processing efficiency the treatment stage of having improved aerobe.
The S3 advanced treatment
This advanced treatment may further comprise the steps: percolate is fed a filtering system to remove the suspended substance in the water; Just percolate feeds an ozone oxidation system, to being difficult to the biodegradable organic chemical oxidation that carries out in the water, makes pollution substance be oxidized into CO completely
2And H
2O; Percolate is fed a nanofiltration membrane treatment system, multiple larger molecular organics in the interception water; Standard compliant water is discharged.
At first be that percolate is fed a filtering system,, remove the suspended substance in the water by the filtering separation effect of microfiltration membrane.
Then percolate is fed an ozone oxidation system,, can finish, make pollution substance be oxidized into CO completely being difficult to biodegradable organic chemical oxidation in the water by adding ozone
2And H
2O.This ozone oxidation system has very high operational efficiency, and the removal of pollution substance is had clearly effect.
Through after the ozone oxidation, percolate has entered the nanofiltration membrane treatment system, and nanofiltration membrane can be tackled larger molecular organics multiple in the water, guarantees that the organic concentration in the water outlet greatly reduces, and finally satisfies water quality standard.
Rubbish leachate treatment method of the present invention is at the characteristic of garbage burning factory percolate, adopted three stage treatment systems, and had the many places to regulate the setting of facility, guarantees the stable and high effective operation of whole system; The anaerobion that is arranged so that of two-stage UBF is able to good separation mutually, has improved the processing efficiency of anaerobic reactor; UBF has adopted the system of preheating simultaneously, can keep the stable of reactor operating temperature.