CN101221844B - Electric resistor with lead wire and manufacturing method thereof - Google Patents

Electric resistor with lead wire and manufacturing method thereof Download PDF

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Publication number
CN101221844B
CN101221844B CN2007100016245A CN200710001624A CN101221844B CN 101221844 B CN101221844 B CN 101221844B CN 2007100016245 A CN2007100016245 A CN 2007100016245A CN 200710001624 A CN200710001624 A CN 200710001624A CN 101221844 B CN101221844 B CN 101221844B
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China
Prior art keywords
resistor
wire
lead
mentioned
electrode cap
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Expired - Fee Related
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CN2007100016245A
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CN101221844A (en
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高木克己
宫泽直俊
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OKIAKA CO Ltd
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OKIAKA CO Ltd
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Abstract

The invention provides a resistor with a lead wire which is arranged inside a glass pipe of a mercury lamp, particularly relating to a resistor with a lead wire of which the gas generation quantity is still very low at the temperature of about 400 Celsius degrees when the mercury lamp starts and a manufacturing method thereof; the manufacturing method of the resistor with lead wire is characterized in that: a ceramic basal body(12) has the surface provided with a conduction film(13) and both ends embedded in an electrode cap(15) on which a lead wire(16) is welded, forming the resistor(11) with a lead wire; the resistor is heated to reach the temperature of between 350 and 500 DEG C and kept for form 40 minutes to 5 hours; the heating process of the resistor(11) with a lead wire is conducted in inert gases; the conduction film(13) on the resistor(11) with a lead wire is exposed to the outside.

Description

The resistor and the manufacture method thereof of band lead-in wire
Technical field
The present invention relates on the ceramic matrix surface, form conductive membranes such as carbon film, intercalation electrode cap on the two ends of ceramic matrix, cover (non-sheet) resistor of the band lead-in wire of welding lead at above-mentioned electrode cap, relate in particular to the resistor and the manufacture method thereof that can be arranged in the inner band lead-in wire that uses of mercury vapor lamp.
Background technology
Past is arranged in the starting circuit in the glass tube of mercury vapor lamp, adopts the resistor of band lead-in wire.In the glass tube of mercury vapor lamp, form about 400 ℃ high temperature during starting, and in resistor, switch on, so produce gas from the resistor of band lead-in wire.When the generating capacity of this gas is big, produce fuzzyly in the glass tube, starting circuit is caused harmful effect etc., hinder the normal starting state.
But, in the carbon film resistor of the known band lead-in wire that in high temperature, the most evil bad environment of high humidity, uses, after the operation that the part of carbon film is cut, be attached to 100 ℃~200 ℃ heat ageing steps (patent documentation 1) of heating more than 10 hours down.According to the narration of this patent documentation, by above-mentioned heat ageing, can be suppressed at cutting part carbon atom adhesion and reduce caused resistance change, can reduce resistance change, improve gasproof marquis reliability.
[patent documentation 1] spy opens flat 2-73601 communique
The problem that exists
Yet, in above-mentioned heat ageing, be arranged in the resistor of the band lead-in wire in the glass tube of mercury vapor lamp, when start, mercury vapor lamp reaches 400 ℃ high temperature approximately, so be imperfect from suppressing generation gas this point.
Summary of the invention
The present invention is In view of the foregoing and the scheme that proposes.Its objective is provides the resistor of the sort of band lead-in wire to be arranged in the glass tube of mercury vapor lamp, reaches the resistor and the manufacture method thereof of the band lead-in wire that the gas generating capacity is still very little under the situation of about 400 ℃ high temperature during the mercury vapor lamp starting.
In order to address the above problem, the manufacture method of the resistor of band lead-in wire of the present invention, it is characterized in that: on the surface of ceramic matrix, form conductive membrane, intercalation electrode cap on the two ends of ceramic matrix, cover welding lead at electrode cap, constitute resistor, this resistor heats in 350 ℃~500 ℃ scope, was kept 40 minutes~5 hours.Hope is carried out in inert gas the operation of resistor heats.The resistor of wishing this band lead-in wire exposes conductive membrane.
The effect of invention
According to the invention described above, to temperature about equally the temperature of resistor the time of band lead-in wire, heat-treat under the perhaps higher temperature with the mercury vapor lamp internal triggering, processing so fully can outgas.Therefore, in the product after heat treatment, be heated under 1 hour the situation of state maintenance of 400 ℃ of temperature, the generating capacity of gas is 1 * 10 -3Below the hPaL, can significantly reduce the gas generating capacity.Like this, can provide the resistor that can not produce or be suppressed at the band lead-in wire that problems such as bluring takes place in the mercury vapor lamp glass tube, help to improve the reliability of mercury vapor lamp.
Description of drawings
Fig. 1 is the front elevation of an execution mode of the expression resistor that relates to band of the present invention lead-in wire, and the left end portion of ceramic matrix is the sectional drawing of expression vertical section.
Fig. 2 is the curve chart of the heating-up temperature of expression heat treatment (degassing is handled), the process of abscissa express time, and ordinate is represented heating-up temperature.
Fig. 3 is the flow chart of an execution mode of the manufacturing process of the expression resistor that relates to band of the present invention lead-in wire.
Embodiment
Following with reference to accompanying drawing, describe embodiments of the present invention in detail.Fig. 1 represents to relate to an execution mode of the resistor of band lead-in wire of the present invention.
The resistor 11 of band lead-in wire forms the conductive membrane 13 that is made of carbon film on the surface of columned ceramic matrix 12.On conductive membrane 13, be provided for the cutting groove 14 of fine adjustment resistance.Intercalation electrode cap 15 on the two ends of ceramic matrix 12, and itself and conductive membrane 13 are conducted.On electrode cap 15, fix lead-in wire 16 by weld part 17.Here, electrode cap 15 is on the surface of the iron that is processed into the cap shape, forms plated copper film and nickel plated film and makes.And lead-in wire 16 is to have formed plated copper film on the iron wire material.
As shown in the figure, the outer insulating resin layer that is coated with that the resistor 11 of band lead-in wire does not cover the common conductive membrane that resistor had 13, conductive membrane is exposed.This is because be the blanket of nitrogen that is sealed by blanket of nitrogen in the glass tube of mercury vapor lamp, thus be not coated with insulating resin layer outside not needing originally, and also be in order to prevent that outer being coated with from producing gas on the insulating resin layer.
The resistor 11 of band lead-in wire, on the surface of ceramic matrix 12, form conductive membrane 13, intercalation electrode cap 15 on the two ends of ceramic matrix, cover welding lead 16 at electrode cap, constitute after the resistor, resistor is placed in the blanket of nitrogen in 350 ℃~500 ℃ scope, heats, kept 40 minutes~5 hours, final resistor is made in the processing (heat treatment) that outgases.Handle by this high-temperature degassing, can obtain at the gas generating capacity that is heated under 1 hour the situation of state maintenance of 400 ℃ of temperature is 1 * 10 -3The resistor of hPaL band lead-in wire following, that the gas generating capacity under hot environment is few.
Above-mentioned heat treated heating-up temperature wishes to adopt curvilinear figure shown in Figure 2.At first, in about 50 ℃ of down about 30 minutes of heating, then, be heated to about 400 ℃ with 1 hour 20 minutes from 50 ℃, maintenance is one hour under this state.Then, drop to 50 ℃, finish heat treatment step with about 3 hours waiting temperatures.
Maximum heating temperature, the condition of wishing to use according to reality (in mercury vapor lamp about 400 ℃) decides, perhaps according to heating than its stricter condition.Under too low temperature, can not remove and contain gas.And it is the influence to product performance is considered in the heating more than 500 ℃, so and inappropriate.Therefore, remove and contain gas, 350 ℃~500 ℃ scope heating, relatively suitably.
Retention time, the too short time can not fully be removed the gas that comprises in the resistor, so, wish to come setting-up time according to the situation of carrying out that gas is removed.In the present embodiment, be decided to be about 1 hour, only need about 5 hours, can fully remove the gas that inside comprises even increase also.Therefore, can think that the retention time is relatively more suitable in 40 minutes~5 hours scope.
Atmosphere during heat treatment has adopted inert gas, and this is in order to prevent the oxidation that goes between.In the present embodiment, in blanket of nitrogen, heat-treat.If but could prevent oxidation, so also could heat treatment in the inert gas beyond the blanket of nitrogen.Another reason be the resistor of wishing the band lead-in wire with the glass tube of mercury vapor lamp under the roughly the same state of the condition used (in blanket of nitrogen, using) heat-treat.
To having carried out above-mentioned heat treated resistor and not carried out outer heat treated resistor and carried out the analysis that takes place about gas respectively.Its result, as shown in Table 1." the no heat treatment " of table 1 is meant on the ceramic matrix that has formed carbon film, the intercalation electrode cap, the resistor behind the welding lead does not carry out above-mentioned heat treatment, in blanket of nitrogen, be heated to 400 ℃, the gas componant and the generating capacity that under 1 hour situation of maintenance under this state, are taken place." heat treatment is arranged " of table 1 is intercalation electrode cap on the ceramic matrix that has formed carbon film, resistor behind the welding lead is heat-treated (degassing is handled) according to the mode of above-mentioned Fig. 2, then, in the blanket of nitrogen atmosphere, be heated to 400 ℃, the composition and the generating capacity of the gas that under 1 hour situation of maintenance under this state, is taken place.
The gas generating capacity of (table 1) finished product
The generating capacity of wishing gas is as far as possible near 0, but by heat treatment (degassing is handled), is heated to 400 ℃, and at the gas generating capacity that keeps under this state under 1 hour the situation, desired value is 1 * 10 -3Below the hPaL.When being confirmed, the gas generating capacity under the above-mentioned condition obtains above result.
Nonheat-treated=3.10 * 10 -3HPaL
Heat-treatment=0.66 * 10 -3HPaL
As can be seen, as shown above, it is about 1/5 by heat treatment the gas generating capacity to be reduced to, and has reached above-mentioned target.
Table 2 is to the resistor part, and the ceramic matrix, lead-in wire, electrode cap, the various piece that promptly form carbon film are not carried out above-mentioned heat treatment, have checked gas componant and generating capacity under the condition identical with the analysis in the table 1.
The gas generating capacity of (table 2) resistor each several part
And above analysis 400 ℃ of heating down, but under the situation of heating about 100 ℃, does not find that what gas takes place.That is to say that as can be seen, for example, when utilizing the heat treatment method in past of above-mentioned patent documentation 1, be arranged in the resistor in the glass tube of mercury vapor lamp, the degassing is handled insufficient.
From each table, investigated thoroughly the main component of the gas that takes place.And, as can be seen from Table 1, CO 2Generating capacity big.As can be seen from Table 2, the gas that takes place from the electrode cap is many.Can think that these gas componants are to be included in the electrodeposited coating unavoidable composition owing to the operation of the punch process of electrode cap with to the electroplating work procedure of electrode cap and lead-in wire.And, the generating capacity of every kind of composition (for example, the H that has nothing in common with each other in table 1 and table 2 2In finished product, reduce Co 2In finished product, increase).This shows that wire bonds etc. are attended by the operation of heating, to having a significant impact adhering to of gas.
The ceramic matrix, lead-in wire, the electrode cap that have formed conductive membrane have gas to take place respectively.So, it is assembled, make before the finished product, in each part stage, heat-treat also separately or together and produce effect.And as can be seen from Table 2, especially the gas generating capacity of electrode cap is up to 2.10 * 10 -3HPaL, so, only the electrode cap is carried out heat treated and also produce effect.Moreover, to ceramic matrix, lead-in wire and electrode cap whole or a certain heat-treat in advance after, it is assembled, make finished product, again this finished product is heat-treated, help to reduce gas generating capacity as the resistor of the band lead-in wire of finished product.Here said heat treated condition can adopt the condition identical with above-mentioned condition.
Following with reference to Fig. 3, describe the manufacture method of the resistor of the band lead-in wire relate to an embodiment of the present invention in detail.
<operation 1〉conductive membrane formation
In the high-temperature vacuum furnace of the ceramic matrix of packing into, make the hydrocarbon thermal decomposition, on the surface of ceramic matrix, separate out carbon film.
<operation 2〉assembling
On the two ends of ceramic matrix, be pressed into the electrode cap.The electrode cap is cleaned.
operation 3〉by the resistance value sorting
In this stage, the resistance value difference of each product is very big.So, adjust the efficient of operation in order to improve following one resistance, product is divided into several classes by resistance.
operation 4〉the resistance adjustment
One side measured resistance value, with cutter on ceramic matrix surface cut into spiral grooves on one side, remove the part carbon film, carry out the resistance adjustment, also can cut groove with the laser trimming machine.
<operation 5〉clean
To being pressed into the electrode cap, the ceramic matrix of the resistance that is through with adjustment cleans, and washes off be attached to residue on the resistor surface etc. on preceding operation.
<operation 6〉wire bonds
Utilize welding that lead-in wire is soldered to electrode cap and cover, so-called resistance melting welding (flow into big electric current in welded-joint, utilize the resistance heat in this generation to heat, plus-pressure engages it) is suitable.
<operation 7〉heat treatment (degassing is handled)
In the blanket of nitrogen stove, heat.Heat treatment is heated in the blanket of nitrogen atmosphere in 350 ℃~500 ℃ the scope, keeps 40 minutes~5 hours, utilizes this operation to remove the gas that comprises in the overall electrical resistance device.
<operation 8〉the voltage processing
Add the potential pulse of about 5 times of rated voltages, make the resistance stabilisation.
<operation 9〉inspection, tape wrap, packing
Finish the resistor of the band lead-in wire of the processing that outgases by above-mentioned operation.This resistor is arranged in the glass tube of mercury vapor lamp, exposes to the open air also to produce gas hardly under about 400 ℃ high temperature, so as mentioned above, helps to improve the reliability of mercury vapor lamp.
And, the example of carbon film resistor more than has been described.But having the resistor of the band lead-in wire of other conductive membranes, metal film resistor and metal-oxide film resistor etc. also can use the present invention equally.
One embodiment of the present invention more than has been described, but the present invention is not limited in above-mentioned execution mode, self-evident, in its technological thought scope, can utilize various mode to implement.

Claims (8)

1. manufacture method with the resistor of lead-in wire, it is characterized in that: on the surface of ceramic matrix, form conductive membrane, the electrode cap is embedded on the two ends of above-mentioned ceramic matrix, and be conducted with above-mentioned conductive membrane, cover welding lead at above-mentioned electrode cap, thereby the formation resistor heats above-mentioned resistor in 350 ℃~500 ℃ scope, and keeps 40 minutes~5 hours.
2. the manufacture method of the resistor of band lead-in wire as claimed in claim 1 is characterized in that: the operation that above-mentioned resistor heats is carried out in inert atmosphere.
3. the manufacture method of the resistor of band lead-in wire as claimed in claim 1 is characterized in that: in the resistor of above-mentioned band lead-in wire, above-mentioned conductive membrane exposes.
4. the manufacture method of the resistor of band lead-in wire as claimed in claim 1, it is characterized in that: above-mentioned conductive membrane is a carbon film.
5. the manufacture method of the resistor of band as claimed in claim 1 lead-in wire is characterized in that: above-mentioned electrode cap is to have formed the electrode cap that plated copper film and nickel plated film form on the surface of the iron that is processed into the cap shape.
6. the manufacture method of the resistor of band lead-in wire as claimed in claim 1, it is characterized in that: above-mentioned lead-in wire is to have formed the lead-in wire that plated copper film forms on the wire rod that is made of iron.
7. resistor with lead-in wire, have: formed from the teeth outwards conductive membrane ceramic matrix, be embedded on the two ends of above-mentioned ceramic matrix and the electrode cap that is conducted with above-mentioned conductive membrane and the two ends that are welded on above-mentioned electrode cap on lead-in wire, it is characterized in that:
The state that is heated to 400 ℃ of temperature being kept the gas generating capacity under 1 hour the situation is 1 * 10 -3Below the hPaL.
8. the resistor of band lead-in wire as claimed in claim 7 is characterized in that: in the resistor of above-mentioned band lead-in wire, above-mentioned conductive membrane exposes.
CN2007100016245A 2007-01-09 2007-01-09 Electric resistor with lead wire and manufacturing method thereof Expired - Fee Related CN101221844B (en)

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CN101221844B true CN101221844B (en) 2011-07-27

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5918629B2 (en) * 2011-09-29 2016-05-18 Koa株式会社 Ceramic resistor
WO2013086676A1 (en) * 2011-12-12 2013-06-20 第一电阻电容器股份有限公司 Film ceramic resistor
CN108055727A (en) * 2017-12-26 2018-05-18 海宁市鑫诚电子有限公司 A kind of LED illuminator based on MBL driving circuits
CN110047635B (en) * 2019-05-05 2021-01-05 西北核技术研究所 Solid-state flexible resistor for gas-insulated pulsed power source
CN110349722B (en) * 2019-07-12 2021-04-30 南京萨特科技发展有限公司 Heat treatment method of alloy resistor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5252943A (en) * 1990-09-13 1993-10-12 Ngk Insulators, Ltd. Resistor element whose electrically resistive layer has extension into openings in cylindrical ceramic support
CN1104801A (en) * 1993-12-16 1995-07-05 清川电镀工业株式会社 Method for producing a metal film resistor
CN1595554A (en) * 2003-09-12 2005-03-16 兴亚株式会社 Resistor with cable port and its manufacturing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5252943A (en) * 1990-09-13 1993-10-12 Ngk Insulators, Ltd. Resistor element whose electrically resistive layer has extension into openings in cylindrical ceramic support
CN1104801A (en) * 1993-12-16 1995-07-05 清川电镀工业株式会社 Method for producing a metal film resistor
CN1595554A (en) * 2003-09-12 2005-03-16 兴亚株式会社 Resistor with cable port and its manufacturing method

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