CN101215178B - Production of fireproof door filling material by using industrial waste material of metal door production and preparation method thereof - Google Patents
Production of fireproof door filling material by using industrial waste material of metal door production and preparation method thereof Download PDFInfo
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- CN101215178B CN101215178B CN2007103069920A CN200710306992A CN101215178B CN 101215178 B CN101215178 B CN 101215178B CN 2007103069920 A CN2007103069920 A CN 2007103069920A CN 200710306992 A CN200710306992 A CN 200710306992A CN 101215178 B CN101215178 B CN 101215178B
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Abstract
The invention discloses a fire door filling material produced by the industrial waste material for producing metal door and a process for preparation, which includes magnesium oxide, magnesium sulfate, the depositing waste slag of the metal after bonderite process, transfer waste paper, water proofing agent, water reducing agent and foaming agent, the volume weight is between 200-500kg/m3, the proportionings of each component according to weight percentage respectively are that the magnesium oxide takes 40-65, the magnesium sulfate takes 20-30, the depositing waste slag of the metal after bonderite process takes 8-13, the transfer waste paper takes 5-10, the water proofing agent takes 2-6, the water reducing agent takes 1.5-6 and the foaming agent takes 0.1-0.5. Employing the technical scheme, the product has the advantages of high mechanical strength, light weight, high grade of fire resistance, good effect of sound absorption and acoustic insulation, strong anti-weatherability, heat insulation, heat preservation and energy conservation, easy production and no poison, on hazard and no radiation and the like. The product can be widely used in metal door industry, architectural materials industry and the related industries.
Description
Technical field
The present invention relates to a kind of lightweight foam material, particularly a kind of fireproof filling material and preparation method who utilizes the phosphatization waste residue, waste water and the transfer printing waste paper that produce in the metal door production processes such as antitheft door, fire door, steel entering house door to produce fire door as raw material.
Background technology
At present, in the technological process of production of producing metal door such as antitheft door, fire door, steel entering house door, get rusty and make paint have a better adsorptive power for preventing the metallic surface, all must carry out pickling degreasing phosphatization processing of rust removing, in this process, all have the phosphatization waste residue of metal-conditioning treatment postprecipitation and waste water to discharge metal door.Because the chemical feedstocks that adds in the phosphatization aqueous solution is more, so just contain multiple harmful Chemical Composition in waste residue that emits and the waste water, mainly contain Vanadium Pentoxide in FLAKES in the waste residue, secondary calcium phosphate, monocalcium phosphate, ferric oxide, multiple components such as polymer alumina, polyacrylamide mainly contain a large amount of phosphorus in the waste water.For qualified discharge, manufacturing enterprise need drop into substantial contribution, environmental protection equipment, personnel and water treatment agent waste residue and waste water are handled, and treated waste water can reach the urban sewage discharge standard basically, but still contains phosphorus in a small amount in the sewage of discharging; To the waste residue that precipitates in the water treatment procedure, manufacturing enterprise generally transports to the brick field and adds in the yellow mud, and the filling raw material as brickmaking carries out burning disposal with waste in the process of baking bricks.But bad enterprise is also arranged,, directly phosphorized waste water is outwards discharged without this procedure of water treatment.Owing to contain a large amount of phosphorus in the phosphorized waste water, outwards the phosphorized waste water of discharging is to subterranean percdation, the polluted underground water resource.
In the technological process of production of producing metal door such as antitheft door, fire door, steel entering house door, can produce transfer printing waste paper after the shop front pattern transfer, because this waste paper can not recycling, therefore how to handle and also become burden, have enterprise to burn, and the enterprise that has end up with nothing definite with regard to directly pouring the refuse tip into through after drying.The problems referred to above not only cause the wasting of resources, do not meet the policy of national energy-saving and emission-reduction, comprehensive utilization, and contaminate environment.
And metal door such as the antitheft door of producing at present, fire door, steel entering house door generally to select honeycomb paper and Calucium Silicate powder plate holder aluminium silicate wool for use be stopping composition.The weak point that honeycomb paper exists is: meeting fire can burn, and does not have fire resistance, and sound absorption sound insulation and heat preservation and insulation are poor, and moisture-sensitive is met water and can be softened, and the waterproof water resistance is poor.The weak point that Calucium Silicate powder plate holder aluminium silicate wool exists is: fire resistance rating is low, meet high temperature and can produce fusing, do not have anti-fire action, the production cost height, asbestos needle-holding hand, dust suck the human body infringement big, and State Environmental Protection Administration just clearly stipulated in 2005 for this reason, must not contain asbestos in the household article, tackiness agent must not contain objectionable impuritiess such as formaldehyde, benzene.Metal door such as antitheft door, fire door, steel entering house door press for a kind of fire-protection rating height, physical strength is good, production is easy for installation, cost is low type gate inner filling material.
For this reason, many scientific research institutions, manufacturer and knowledgeable people have constantly carried out R and D at the problems referred to above that exist, and do not improve way preferably but have as yet so far.
Summary of the invention
My company drops into a large amount of man power and materials for solving the problem of above-mentioned existence, and development research has been carried out in the comprehensive utilization of the phosphatization waste residue, waste water and the transfer printing waste paper that produce in the production metal door process.Through effort more than a year, my company develops and a kind of phosphatization waste residue, waste water and waste paper is fully utilized stopping composition and the preparation method who produces novel fire door, for my company on the road of having walked out a light aspect energy-saving and emission-reduction, environment protection treating, the comprehensive utilization.The objective of the invention is to utilize the phosphatization waste residue, waste water and the transfer printing waste paper that produce in the metal door production process as raw material, produce a kind of unit weight at 200～500kg/m
3Between the fire door light filler, these goods have physical strength height, in light weight, advantages such as fire resistance rating is high, good, the weathering resistance of sound absorption soundproof effect is strong, heat insulation heat preservation energy-saving, production are easy, nontoxic no radiation.These goods can be widely used in metal door industry, building material industry and relevant industries.
The technical solution adopted for the present invention to solve the technical problems, raw material comprise waste residue, transfer printing waste paper, water-resisting agent, water reducer and the whipping agent of magnesium oxide, sal epsom, metal-conditioning treatment postprecipitation, and unit weight is at 200～500kg/m
3Between, each composition components by weight percentage is respectively:
Magnesium oxide 40～65;
Sal epsom 20～30;
The waste residue 8～13 of metal-conditioning treatment postprecipitation;
Transfer printing waste paper 5～10;
Water-resisting agent 2～6;
Water reducer 1.5～6;
Whipping agent 0.1～0.5.
Described magnesian content 85%, its active oxidation Mg content 65% has not been cooked or heated long enough and burns till part≤2%, overdoes and burns till part≤3%, free calcium oxide content≤2%, ferric oxide≤1.5%, loss on ignition≤15%.
The waste residue of described metal-conditioning treatment postprecipitation contains Vanadium Pentoxide in FLAKES, secondary calcium phosphate, monocalcium phosphate, ferric oxide, polymer alumina, polyacrylamide multiple components, and fineness is more than 120; Have and fire-resistantly do not fire, toughness reinforcing insulation, magnesium oxide had good retarded water-resistant performance and anti-water modifying function, but consumption is crossed product strength is descended.
Described transfer printing waste paper is the transfer printing waster paper slag after the machine pulverization process, and it contains a large amount of fibers, can overcome the fragility of product, increases its snappiness, also can reduce the density of product, mainly when the fiber use.
Described water-resisting agent mainly plays the gap of sealing pore, reduces water-intake rate.
Described water reducer adopts modified polycarboxylic acid salt high efficiency water reducing agent, and main effect is the transparent performance that stops up pore, improves pore structure, improves water resisting property.
Described sal epsom mainly plays solidification, the hole that reduces the goods hardenite is arranged, to returning halogen and returning the modifying function of frost, increases waterproof and water resistance, avoids the corrosion of iron sheet, plays the rust protection effect.
Described whipping agent is an animal proteinum type efficient foam whipping agent, and the concentration of its aqueous solution is 0.1～0.5%, its foamy diameter≤1mm, and gas production rate is big, and production low density goods are had an unexpected effect.
The preparation method of described stopping composition, it comprises the steps:
(1), the waste residue of magnesium oxide, metal-conditioning treatment postprecipitation, water-resisting agent, water reducer, sal epsom, transfer printing waste paper are added stirrer and mixes, and to add the bonderizing wastewater dilution be thick shape base-material slurry by above-mentioned part by weight and order; Simultaneously whipping agent is made the foam slurry;
(2), with foam slurry by volume 4～15 times ratio join in the thick shape base-material slurry, carry out the foaming slip that secondary stirring becomes even matter again;
(3), with curing molding in the slip casting progressive die tool;
(4), after the demoulding, natural curing at normal temperatures and pressures was finished product in 3～10 days.
Contain phosphate radical in the described bonderizing waste water, because phosphate radical has good delayed coagulation, can be to play the pore of gelling and obstruction stopping composition in the fire door with stopping composition, improve the structure of pore, can reduce goods and return halogen and scum, improving magnesian rapid hardening has good retarded water-resistant performance and anti-water modifying function.Can increase the later strength of goods in addition, improve the water resistance of product.
After adopting above-mentioned technical scheme, the present invention has following advantage:
1, the present invention's mechanical-physical foaming method, mix in the process that stirs with thick shape base-material slurry at the foam slurry, by the effect of foamy surfactivity, introduce a large amount of evenly micro bubbles of sealing, make in the foaming slip and contain air in certain amount, slip to be foamed is poured in the mould behind the curing molding, foam is along with vesicular structure is died away in the evaporation of moisture, last inside stays the pore of many sealings, externally form the concavo-convex surface of blister, thereby make material of the present invention have adiabatic heat-insulation, the sound absorption sound insulation, the performance of obvious energy conservation, it is easy and simple to handle, less investment, cost is low;
2, the present invention can prevent damp suction surface halide accumulation, craze and transfiguration;
3, the present invention with the waste residue of metal-conditioning treatment postprecipitation, transfer printing waste paper as one of raw material of stopping composition, with the bonderizing wastewater dilution is thick shape base-material slurry, turn waste into wealth, light weight is inexpensive, gather materials on the spot, not only solved the waste residue, transfer printing waste paper of metal-conditioning treatment postprecipitation problem because of the bulk deposition land occupation, and solved the phosphorized waste water problem of environment pollution caused simultaneously, can play energy-saving and emission-reduction, reduce less environmental contamination, can also reduce the products production cost, improve the performance of enterprises and social benefit, meet national industrial policies;
4, goods of the present invention are vesicular structure, and by adjusting the size that void content size and base-material consumption change unit weight and intensity, setting range is big, and unit weight can be at 200～500kg/m
3Between select for use arbitrarily according to purposes so that satisfy the requirement of different functions of use;
5, the present invention uses animal proteinum type efficient foam whipping agent, surface tension, foam degree, cost value etc. all are better than existing whipping agent, its major cause is that its gas production rate is big, have an unexpected effect to producing low-density goods, surface tension is big, and bubble stability is strong, help controlling the size of void content, the void content maximum is up to 98%, and minimum is 0, thereby can make unit weight at 200～500kg/m
3Between adjust arbitrarily, can widen Application Areas of the present invention greatly like this; Also improve freeze thawing intensity simultaneously, done wet tenacity, softening intensity and corrosion resistant ability, waterproof water resistance and energy-saving effect.
6, goods of the present invention are substitutes of honeycomb paper, calcium silicate board and aluminium silicate wool, and its cost is than calcium silicate board and aluminium silicate wool low about 60%; Can reduce the usage quantity of honeycomb paper, very big potentiality also be arranged saving forest resourceies; Can change honeycomb paper, calcium silicate board and aluminium silicate wool and fill that difficulty is big, the backwardness of complex manufacturing, raise labour productivity, shorten the production cycle, be once great technological change to the production of metal door; The present invention is used for building material industry, and consumption is very huge.
Embodiment
Further specify the present invention below in conjunction with specific embodiments, raw material comprises waste residue, transfer printing waste paper, water-resisting agent, water reducer and the whipping agent of magnesium oxide, sal epsom, metal-conditioning treatment postprecipitation, and unit weight is at 200～500kg/m
3Between, each composition mixture ratio by weight percent is respectively:
Magnesium oxide 40～65;
Sal epsom 20～30;
The waste residue 8～13 of metal-conditioning treatment postprecipitation;
Transfer printing waste paper 5～10;
Water-resisting agent 2～6;
Water reducer 1.5～6;
Whipping agent 0.1～0.5.
Described magnesian content 〉=85%, its active oxidation Mg content 65% has not been cooked or heated long enough and burns till part≤2%, overdoes and burns till part≤3%, free calcium oxide content≤2%, ferric oxide≤1.5%, loss on ignition≤15%.
The waste residue of described metal-conditioning treatment postprecipitation contains Vanadium Pentoxide in FLAKES, secondary calcium phosphate, and monocalcium phosphate, ferric oxide, polymer alumina, polyacrylamide multiple components, fineness is more than 120 orders.
Described transfer printing waste paper is the transfer printing waster paper slag after the machine pulverization process.
Described whipping agent is an animal proteinum type efficient foam whipping agent, and the concentration of its aqueous solution is 0.1～0.5%, its foamy diameter 1mm.
The preparation method of described fire-retardant material, it comprises the steps:
(1), the waste residue of magnesium oxide, metal-conditioning treatment postprecipitation, water-resisting agent, water reducer, sal epsom, transfer printing waste paper are added stirrer and mixes, and to add the bonderizing wastewater dilution be thick shape base-material slurry by above-mentioned part by weight and order; Simultaneously whipping agent is made the foam slurry;
(2), with foam slurry by volume 4～15 times ratio join in the thick shape base-material slurry, carry out the foaming slip that secondary stirring becomes even matter again;
(3), with curing molding in the slip casting progressive die tool;
(4), after the demoulding, natural curing at normal temperatures and pressures was finished product in 3～10 days.
Contain phosphate radical in the described bonderizing waste water.
Embodiment 1: present embodiment is 200kg/m by unit weight
3Prepare, magnesium oxide 100kg wherein, anhydrous magnesium sulfate 50kg, the waste residue 23kg of metal-conditioning treatment postprecipitation, transfer printing waste paper 15kg, water-resisting agent 5.5kg, water reducer 6kg, whipping agent 0.5kg adds bonderizing waste water 80kg dilution by above-mentioned described preparation method and is thick shape base-material slurry, adding foam diameter≤1mm, consumption then is 13～15 times foam slurry secondary stirring of thick shape base-material slurry, makes the sheet material of 1970mm * 780mm * 50mm.Ultimate compression strength 1.40Mpa, folding strength 0.87Mpa.
Embodiment 2: present embodiment is 300kg/m by unit weight
3Prepare, magnesium oxide 150kg wherein, anhydrous magnesium sulfate 75kg, the waste residue 34.5kg of metal-conditioning treatment postprecipitation, transfer printing waste paper 22.5kg, water-resisting agent 8.6kg, water reducer 9kg, whipping agent 0.4kg adds bonderizing waste water 120kg dilution by above-mentioned described preparation method and is thick shape base-material slurry, adding foam diameter≤1mm, consumption then is 9～11 times foam slurry secondary stirring of thick shape base-material slurry, makes the sheet material of 1970mm * 780mm * 50mm.Ultimate compression strength 1.84Mpa, folding strength 1.20Mpa.
Embodiment 3: present embodiment is 400kg/m by unit weight
3Prepare, magnesium oxide 200kg wherein, anhydrous magnesium sulfate 100kg, the waste residue 46kg of metal-conditioning treatment postprecipitation, transfer printing waste paper 30kg, water-resisting agent 11.7kg, water reducer 12kg, whipping agent 0.3kg adds bonderizing waste water 160kg dilution by above-mentioned described preparation method and is thick shape base-material slurry, adding foam diameter≤1mm, consumption then is 6～7 times foam slurry secondary stirring of thick shape base-material slurry, makes the sheet material of 1970mm * 780mm * 50mm.Ultimate compression strength 2.70Mpa, folding strength 1.53Mpa.
Embodiment 4: present embodiment is 500kg/m by unit weight
3Prepare, magnesium oxide 250kg wherein, anhydrous magnesium sulfate 125kg, the waste residue 57.5kg of metal-conditioning treatment postprecipitation, transfer printing waste paper 37.5kg, water-resisting agent 14.8kg, water reducer 15kg, whipping agent 0.2kg adds bonderizing waste water 180kg dilution by above-mentioned described preparation method and is thick shape base-material slurry, adding foam diameter 1mm, consumption then is 4～5 times foam slurry secondary stirring of thick shape base-material slurry, makes the sheet material of 1970mm * 780mm * 50mm.Ultimate compression strength 3.30Mpa, folding strength 2.10Mpa.
Can draw from the foregoing description: unit weight is light-and intensity difference, unit weight weight-intensity are good.By unit weight is 350kg/m
3The Fire Resistance Steel Door of sheet material processing, check through national fire-proof construction material quality supervision and test center: its check conclusion is that fire performance is 72 minutes, first class fire resistance period requirement up to specification, all the other every technical indicators are all qualified, press the GB12955-91 synthetic determination, this quality product is qualified.This fire door stopping composition is checked through the Zhejiang Academy of Medical Sciences: its check conclusion is a rat acute per os toxicity: according to the acute oral toxicity grade scale of " industrial chemical toxicity is identified standard and experimental technique ", the female male rat acute per os toxicity of this fire door stopping composition all belongs to low toxicity level.This fire door stopping composition is checked through Zhejiang Province's building material product quality monitoring testing station: its check conclusion is for meeting the requirement of construction main body material in GB6566-2001 " the radioactive material nucleic is limited the quantity of " standard.
Claims (7)
1. fire door stopping composition that the industrial waste that utilizes the production metal door is produced, it is characterized in that: raw material comprises waste residue, transfer printing waste paper, water-resisting agent, water reducer and the whipping agent of magnesium oxide, sal epsom, metal-conditioning treatment postprecipitation, and unit weight is at 200～500kg/m
3Between, each composition components by weight percentage is respectively:
Magnesium oxide 40～65;
Sal epsom 20～30;
The waste residue 8～13 of metal-conditioning treatment postprecipitation;
Transfer printing waste paper 5～10;
Water-resisting agent 2～6;
Water reducer 1.5～6;
Whipping agent 0.1～0.5.
2. the fire door stopping composition that utilizes the industrial waste production of production metal door according to claim 1, it is characterized in that: described magnesian content 〉=85%, its active oxidation Mg content 65%, have not been cooked or heated long enough and burn till part≤2%, overdo and burn till part≤3%, free calcium oxide content≤2%, ferric oxide≤1.5%, loss on ignition≤15%.
3. the fire door stopping composition that utilizes the industrial waste production of production metal door according to claim 1, it is characterized in that: the waste residue of described metal-conditioning treatment postprecipitation contains Vanadium Pentoxide in FLAKES, secondary calcium phosphate, monocalcium phosphate, ferric oxide, polymer alumina, polyacrylamide multiple components, and fineness is more than 120 orders.
4. the fire door stopping composition that utilizes the industrial waste production of production metal door according to claim 1, it is characterized in that: described transfer printing waste paper is the transfer printing waster paper slag after the machine pulverization process.
5. the fire door stopping composition that utilizes the industrial waste production of production metal door according to claim 1, it is characterized in that: described whipping agent is an animal proteinum type efficient foam whipping agent, and the concentration of its aqueous solution is 0.1～0.5%, its foamy diameter≤1mm.
6. according to the preparation method of each described fire door stopping composition of claim 15, it is characterized in that: it comprises the steps:
(1), the waste residue of magnesium oxide, metal-conditioning treatment postprecipitation, water-resisting agent, water reducer, sal epsom, transfer printing waste paper are added stirrer and mixes, and to add the bonderizing wastewater dilution be thick shape base-material slurry by above-mentioned part by weight and order; Simultaneously whipping agent is made the foam slurry;
(2), with foam slurry by volume 4～15 times ratio join in the thick shape base-material slurry, carry out the foaming slip that secondary stirring becomes even matter again;
(3), with curing molding in the slip casting progressive die tool;
(4), after the demoulding, natural curing at normal temperatures and pressures was finished product in 3～10 days.
7. according to the preparation method of the described fire door stopping composition of claim 6, it is characterized in that: contain phosphate radical in the described bonderizing waste water.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007103069920A CN101215178B (en) | 2007-12-29 | 2007-12-29 | Production of fireproof door filling material by using industrial waste material of metal door production and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2007103069920A CN101215178B (en) | 2007-12-29 | 2007-12-29 | Production of fireproof door filling material by using industrial waste material of metal door production and preparation method thereof |
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| CN101215178A CN101215178A (en) | 2008-07-09 |
| CN101215178B true CN101215178B (en) | 2011-06-15 |
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| CN103936388A (en) * | 2014-04-18 | 2014-07-23 | 张家港市盛港绿色防火建材有限公司 | Sulfur-oxygen-magnesium door core board and production method thereof |
| CN106044812B (en) * | 2016-07-21 | 2024-03-29 | 浙江天乙环保科技股份有限公司 | Fireproof door filler production and recovery integrated system device |
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| CN1800557A (en) * | 2005-12-23 | 2006-07-12 | 邢思银 | Multifunctional light energy-saving wall board and its quick production method |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1800557A (en) * | 2005-12-23 | 2006-07-12 | 邢思银 | Multifunctional light energy-saving wall board and its quick production method |
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