CN101213282A - Colloidal cleaning system - Google Patents

Abstract

Cleaning formulations, methods, and systems are effective, mild, and non-hazardous. Embodiments of the cleaning formulation comprise a fatty acid, a saponifier, a water conditioner, a solvent, a nonionic surfactant, and an anionic surfactant. Some embodiments also optionally additives. Embodiments are particularly effective for cleaning concrete.

Description

Colloidal cleaning system

The cross reference of related application

[01] the application has required the rights and interests of No. the 60/673rd, 855, the U. S. application that proposes on April 22nd, 2005, and the disclosure of this patent all is incorporated herein by reference.The application has required to be called " colloidal cleaning system (COLLOIDALCLEANING SYSTEM) ", the lawyer's case number right of priority for the United States Patent (USP) of ONLG.002A 11/__ number in the name that on March 22nd, 2006 proposed, and its disclosure all is incorporated herein by reference.

Background technology

Technical field

[02] the application relates generally to cleaning combination, more specifically, but relates to colloidal state cleaning combination, the method and system that is used for concrete and other washing surface.

Association area is described

[03] many sanitising agents of public Ke De, soap, washing agent and cleaning chemical character are acid, and great majority also destroy environment and/or are pernicious to people.

Summary of the invention

[04] cleaning combination, method and system are effective, gentle and safe.The embodiment of cleaning combination comprises lipid acid, saponifying agent, water conditioner, solvent, nonionic surface active agent and aniorfic surfactant.Some embodiments also randomly comprise one or more additives.Embodiment is effective especially to cleaning concrete.

[05] some embodiments comprise cleaning combination, and it comprises: about 25% to about 50% lipid acid; About 15% to about 25% saponifying agent; About water conditioner of 4% to 16%; About 12% to about 24% solvent; About 8% to about 32% nonionic surface active agent; With about 1% to about 6% aniorfic surfactant.In some embodiments, said composition comprises: about 30% to about 40% lipid acid; About 17% to about 20% saponifying agent; About 6% to about 10% water conditioner; About 16% to about 20% solvent; About 14% to about 20% nonionic surface active agent; With about 2% to about 4% aniorfic surfactant.In some embodiments, described lipid acid comprises tall oil fatty acid.Some preferred embodiment in, described tall oil fatty acid comprises high tallol rosin content.In some embodiments, described saponifying agent comprises 2-amino-2-methyl-1-propanol.In some embodiments, described water conditioner comprises cationic cellulose polymer.Some preferred embodiment in, described cationic cellulose polymer comprises the cellulosic materials main chain with polyquaternium-4 (polyquaternium-4) side chain graft.In some embodiments, described ionic surfactant pack is drawn together octylphenol ethoxylate (octylphenol ethoxylate).Anion surfactant comprises alkyl naphthalene sulfonate (alkylnaphthalene sulfonate).Some embodiments also comprise water.Some embodiments comprise that also one or more are selected from the material of lanolin, Oleum Cocois and spices.As used herein, " one (a) " means " at least one " or " one or more ", and described per-cent is described component " at least one " or " one or mores' " summation.

[06] also provide the method that is used for article-cleaning, comprised that at least a portion that makes these article contacts with composition, described composition comprises: about 25% to about 50% lipid acid; About 15% to about 25% saponifying agent; About 4% to about 16% water conditioner; About 12% to about 24% solvent; About 8% to about 32% nonionogenic tenside; With about 1% to about 6% anion surfactant.In some embodiments, cleaning combination dilute with water.Some embodiments also comprise at least a portion of mechanical scrub article.In some embodiments, described article comprise concrete surface.

[07] also provide the system that is used for article-cleaning, it comprises: cleaning combination, and it comprises about 25% to about 50% lipid acid; About 15% to about 25% saponifying agent; About 4% to about 16% water conditioner; About 12% to about 24% solvent; About 8% to about 32% nonionogenic tenside; With about 1% to about 6% anion surfactant; The specification sheets that contacts with described cleaning combination with at least a portion that is used to make these article.Some embodiments also comprise the instrument that is used for cleaning combination is applied at least a portion of these article.Some embodiments comprise that also machinery cleans the instrument of at least a portion of these article.

[08] also provide cleaning combination, it comprises: about 36% lipid acid; About 18%2-amino-2-methyl-1-propyl alcohol; About 8% cationic cellulose polymer; About 18% methyl soyate (methyl soyate); About 16% octylphenol ethoxylate; With about 3% alkyl naphthalene sulfonate.

[09] also provide composition to clean the purposes of part objects at least, wherein said composition comprises: about 25% to about 50% lipid acid; About 15% to about 25% saponifying agent; About 4% to about 16% water conditioner; About 12% to about 24% solvent; About 8% to about 32% nonionogenic tenside; With about 1% to about 6% anion surfactant.

Preferred implementation describes in detail

[10] the application relates to cleaning combination, and uses described method for compositions and system.The embodiment of disclosed composition, under mild conditions, it is effective especially to remove oils and/or soil; And therefore, it is useful using in a lot of cleanings.The preferred implementation of described composition shows the wetting property of raising, and this provides improved cleaning to aperture, crack and/or space.Some embodiments are particularly useful to the compound that cleaning comprises long carbochain, for example the oil of oil and/or biogenetic derivation.Some embodiments are used to clean body fluid, for example blood, urine, lymph liquid, purulence, and analogue, and it for example comprises fat, carbohydrate, protein and other component known in the art.The embodiment of cleaning combination is useful to the concrete that cleans dwelling house and commercial establishment.Embodiment be used to clean natural stone, marble, grouan, saponite, synthetic stone, pottery, watt and/or terrazzo.As following more detailed discussion, the preferred implementation of cleaning combination is alkaline, and therefore can not corrode or dissolve concrete and/or cement.When the embodiment that uses described composition came clean metal and fluorescence fixture, accident spills into polluted on the soil that oil is arranged also proof, and said composition has been dissolved oil wherein, therefore, find its to soil remedy with analogue be helpful.Some embodiments are following one or more: hand cleaner, toughener is cleaned in the laundry, the clean fabric agent, carpet cleaner and/or stain sanitising agent, the smell remover, jewelry sanitising agent (comprise and clean pearl and/or chatoyant), the grease cleaning agent, the baking oven sanitising agent, the tile sanitising agent, the grout sanitising agent, the scum silica frost remover, the lime remover, the doughnut sanitising agent, the engine stain remover, vehicle maintenance is cleaned, glass fibre ship sanitising agent (fiberglass boat cleaner), industrial floor sanitising agent and wax scavenging agent, stain remover, motor vehicle repair and cleaning elements agent, car cleaning, ship/ship sanitising agent, bilge sanitising agent, the diesel engine sanitising agent, oil leakage thing/overspill cleaning, fire retardant, soil-repairing agent, the mold remediation agent, anti-acne skin clean-out system and/or treatment, earwax remover/emulsifying agent, antimicrobial drug and/or sterilant.

[11] embodiment of cleaning combination comprises lipid acid, saponifying agent, water conditioner, solvent and one or more tensio-active agents.Some embodiments also randomly comprise another kind of solvent and/or additive, and for example, negative catalyst is as lanolin and/or Oleum Cocois (cupraol).Some embodiments comprise spices.Some preferred embodiment in, the ratio of these components is provided in the Table I.In some embodiments, lanolin and/or Oleum Cocois account for 0 to about 4% of described composition by weight.The embodiment of described composition has about 9 to about 13 pH, comprises about 10 to about 11.The preferred implementation of described composition does not comprise soap and/or washing agent (detergent).The embodiment of described composition is working aspect dissolving, emulsification and/or dispersion organic soil and the material especially.

Table I

Component	Scope (wt%)	Preferable range (wt%)
			Fatty acid saponification agent water conditioner solvent nonionogenic tenside anion surfactant	About 25% to about 50% about 15% to about 25% about 4% to about 16% about 12% to about 24% about 8% to about 32% about 1% to about 6%	About 30% to about 40% about 17% to about 20% about 6% to about 10% about 16% to about 20% about 14% to about 20% about 2% to about 4%

[12] term " colloid (colloid) " uses with its common implication at this, and it is meant subparticle charged and that repel each other with the random motion that does not stop.Typically, super centrifugal by utilizing, according to its density, colloid is separable.

[13] example of suitable fatty acids is as known in the art, comprises the lipid acid from any suitable source, for example, and plant derivation, animal derived, tall oil fatty acid, tallol sylvic acid, tallol rosin and similar lipid acid.In some embodiments, described lipid acid have about 10 to about 30 carbon atoms, preferably, about 12 to about 20 carbon atoms, and comprise saturated fatty acid, monounsaturated fatty acids and/or polyunsaturated fatty acid.Unsaturated fatty acids has cis-double bonds and/or trans double bond.Some embodiments comprise having triple-linked lipid acid.Preferred lipid acid is tall oil fatty acid, it randomly contains tallol rosin and/or tallol sylvic acid (tall oil rosin acids), and with Sylvatal  and Sylfat  commerce derive from Arizona Chemical (Jacksonville, FL).Tallol typically mainly comprises palmitinic acid, oleic acid and linolic acid.Tallol rosin exists with from about 0% to about 35%.Suitable tall oil fatty acid derives from Arizona Chemical with Sylvatal  D30LR commerce, and (Jacksonville, FL), it comprises the tall oil fatty acid with high tallol rosin content.Mixture also is suitable.Some embodiments of suitable fatty acids, when mixing, noncondensing substantially with the saponifying agent of discussing below.

[14] suitable saponifying agent is as known in the art.Preferred saponifying agent comprises alkamine, for example, 2-amino-1-butanols (AB , Dow Chemical, Midland, MI), 2-amino-2-methyl-1, ammediol (AMPD ^TM, Dow Chemical, Midland, MI), 2-amino-2-methyl-1-propanol (AMP ^TM, AMP ^TM-95, Dow Chemical, Midland, MI), 2-amino-2-ethyl-1, ammediol (AEPD , Dow Chemical, Midland, MI), three (methylol) aminomethane (TRIS AMINO , Dow Chemical, Midland, MI), thanomin and their composition.Some preferred embodiment in, saponifying agent is 2-amino-2-methyl-1-propanol (2-amino-2-methyl-1-propanol (AMP ^TM-95)).

[15] suitable tensio-active agent comprises non-ionic type as known in the art, anionic and/or cationic surfactant.Suitable nonionic surface active agent comprises polyethoxylated, polyethers alcohols (polyether alcohols), the secondary alcohol ethoxyl compound of branching (Tergitol  TMN series, Dow Chemical, Midland, MI), ethylene oxide/propylene oxide multipolymer (Tergitol  L Series, Tergitol  XD, XH, and XJ, Dow Chemical, Midland, MI), nonyl phenol ethoxylate (Tergitol  NP Series, Dow Chemical, Midland, MI), octylphenol ethoxylate (Triton  X Series, Dow Chemical, Midland, MI), secondary alcohol ethoxyl compound (Tergitol  15-S Series, Dow Chemical, Midland, MI), glycol ester, the triglyceride level ethoxylate, alkanolamide, the Isosorbide Dinitrate ethoxylate, the alcohol alkoxylate of line style and branching, fatty alcohol ethoxylate, segmented copolymer product and their combination.Some preferred embodiment in, nonionic surface active agent comprises octylphenol ethoxylate (Triton  X).

[16] suitable aniorfic surfactant comprises organic carboxylate, sulfosuccinate, sulfonate, vitriol and/or phosphonate.Preferred embodiment comprise alkyl naphthalene sulfonate (for example, Petro , Akzo Nobel, Chicago, IL), alkyl benzene sulphonate (ABS) and sulfonated.Some preferred implementations do not comprise phosphorus compound.Some preferred embodiment in, aniorfic surfactant comprises alkyl naphthalene sulfonate (Petro ).

[17] suitable cationic surfactants comprises organic ammonium and pyridine  compound, comprises aliphatic amide, quaternary amines and/or ester amine (ester amines).In some embodiments, described aliphatic amide is primary amine, secondary amine, tertiary amine and/or diamines.Some preferred embodiment in, aliphatic amide is C ₈To about C ₂₂The preferred implementation of described quaternary ammonium is the quaternized form of disclosed aliphatic amide.

[18] suitable solvent is as known in the art, for example, and water-containing solvent, alcoholic solvent, organic solvent and their combination.Preferred solvent comprises organic solvent.Some preferred embodiment in, described solvent is natural organic solvent, for example, the vegetables oil of transesterify.Some preferred embodiment use soy(a)-bean oil fatty acid alkane ester, and they are that transesterify by soybean oil produces.Preferred solvent comprises methyl soyate and/or soybean oil fatty acetoacetic ester.Methyl soyate is that commerce can get, for example with DESOL ^TM(DESOL Inc.San Diego, CA) commerce can get.

[19] suitable water conditioner comprises cationic polymers as known in the art.Example comprises polyquaternium compound, cationic cellulose polymer, cationic guar gum, cationic starch polymkeric substance, cation graft and/or segmented copolymer, its combination and analogue.Suitable polyquaternium compound is poly-(diallyl dimethylammonium) compound, comprises polyquaternium-4, polyquaternium-7, polyquaternium-10 and/or senior polyquaternium compound.Suitable cationic cellulose polymer comprises the compound that contains fiber disposition main chain, described fiber disposition main chain is Mierocrystalline cellulose, Natvosol, hydroxypropylcellulose, hydroxyethylmethyl-cellulose, Vltra tears and analogue for example, the polyquaternium side chain is grafted to (Celquat  on this fiber disposition main chain, National Starch, Bridgewater, NJ).Suitable cationic guar gum comprise guar gum Hydroxyproyl Trimethyl ammonium compound (guar hydroxypropyltrimonium compounds) (AquaCat , Hercules, Wilmington, DE).Some preferred embodiment in, described water conditioner comprises cationic cellulose polymer.It is believed that this water conditioner plays a part tacking agent (tracking agent) and intercalating agent.

[20] some embodiments comprise the additive that one or more are independently selected as known in the art, for example, and spices, negative catalyst, lanolin, Oleum Cocois, dyestuff, pigment, defoamer, viscosity modifier, sanitas, abrasive and analogue.In some embodiments, the component of described composition is selected, makes to take place a large amount of condense or precipitate mixing and/or leave standstill Shi Buhui.

[21] use, described composition is contacted with article to be cleaned.The embodiment of said composition is typically water or another kind of solvent cut before use, although also can use pure composition, for example in difficult especially application of cleaning.The degree of dilution depends on application-specific.In some embodiments, extent of dilution is from about 1: 1 to about 30: 1, preferably, and about 5: 1 to about 20: 1.The dilution of all reports all is by volume, and wherein the volume of composition is second value.Unless otherwise prescribed, thinner is a water.Some preferred embodiment in, composition is with the dilution of temperature and/or hot water, although in other embodiments, frozen water and/or cold water also are useful, for example when finished surface of cleaning thermo-sensitivity and/or article.In some embodiments, described composition utilized instrument known in the art to dilute before using at once, for example, used the device (applicator) with mixing head and/or pipe end mixing tank (hose-end mixer).In some embodiments, composition is sprayed under pressure, for example, uses spraying as known in the art to spread the machine of spilling and/or pressure washer (pressure washer).In some embodiments, make described composition form mist, to handle space or space.In some embodiments, at least a portion with thing to be cleaned immerses in the composition of common dilute with water.Use point to handle or Local treatment in some applications, for example clothing cleans and carpet cleans.Think that the cleaning properties of composition is derived from is moistening, dissolving, dispersion and/or emulsive combination.

[22] some preferred embodiment in, using instrument known in the art---for example to utilize brush, broom, cleaning pad, abrasive material, its combination and analogue---when cleaning combination contacts, article also can be by mechanical cleaning.Specific method will depend on factor as known in the art, for example, and the amount of the characteristic of article to be cleaned, soil to be removed or pollutent and similar factor.It will be understood by those skilled in the art that machine cleaning effect is the lip-deep pollutent of physical removal (one or more), and replace that the surface is gone up or near surface is full of the cleaning combination of pollutent (one or more) with fresh cleaning combination.In some embodiments, mechanical behavior also helps to disperse the pollutent (one or more) in the cleaning combination.Mechanical cleaning can be manual and/or automatic.In some embodiments, mechanical cleaning equipment also is set to cleaning combination is applied to article to be cleaned.In other embodiments, ultrasonic energy is used to help to clean.

[23] under a series of temperature condition, from the zero pour to the boiling point, the embodiment of composition is an available.Composition preferred embodiment is not photoactivation.

[24] after article or surface were cleaned, it was rinsed usually, to remove remaining pollutent and/or cleaning combination.Randomly, by dry these article of method as known in the art, for example, by blow as air, by vacuumize, by heat, by lyophilize, by contact, use rubber brush wiping (squeegeeing), their combination and similar approach with sorbing agent.

[25] undiluted composition is also as lubricant.Because it is nontoxic, so it is particularly suitable for other device of medicine equipment, instruments, food processing machinery and preferred non-toxic substance or lubricating of machinery.

Embodiment 1

[26] preferred implementation of described composition is provided in the following Table II, and is referred to herein as " Like New ".Component 1000 gallons (3,785L) mix in the groove.

Table II

Component	The source	Manufacturers	wt％
				Fatty acid saponification agent water conditioner solvent nonionogenic tenside nonionogenic tenside anion surfactant	Sylvatal D30LR AMP-95 Celquat H-100 DESOL Triton X-45 Triton X-114 Petro 22	Arizona Chemical Dow Chemical National Starch DESOL Inc. Union Carbide Union Carbide Akzo Nobel	36.36％ 18.00％ 8.08％ 18.00％ 8.08％ 8.08％ 3.40％

[27] Celquat  H-100 has cellulosic backbone (Natvosol), and its polyquaternium-4 side chain graft is in polynuclear plane.Triton  X-45 is an octylphenol ethoxylate, and wherein this ethoxylate unit comprises average about 4.5 ethoxylate unit.Triton  X-114 is an octylphenol ethoxylate, and wherein this ethoxylate unit comprises average about 7.5 ethoxylate unit.Petro  22 is a kind of mixtures with exclusive right of sodium alkyl naphthalene sulfonate and nonionogenic tenside.

[28] Like New composition is alkaline, nontoxic, and biodegradable in 7 days, and it has the colloid feature.Said composition comprises 7 kinds of independent chemical, and wherein some have 12.5 or above pH.The prescription of Table II has about 10.5 pH before dilution.

Embodiment 2

[29] water dilutes the prescription (Like New) of embodiment 15: 1, and the fluid reservoir that will be installed on the rotary washing machine is filled washed mixture.This machine has 1.5hp (horsepower) engine, and is equipped with 17, and " (43-cm) the highly abrasion-resistant polycarbonate is brushed (pad) (high-abrasive-polycarbonate brush (pad)).Concrete surface has oil and tire stain.Cleaning combination is applied to concrete surface, and this surface is shampooed, and does not have stain substantially until it.With clean water flushing surface, wipe with rubber brush then, to remove excessive water.With wet/dry vacuum the surface is vacuumized, make its drying then.It is believed that vacuumize remaining composition is removed, this can stop the adhesion of sealing agent, paint etc. from concrete hole.Then the liquid polymers sealing agent is sprayed onto on the clean surface.

Embodiment 3

[30] repeat embodiment 1, until clean step, it forms tight foam.Make lather collapse by water spray.Replace the polycarbonate brush with soft nylon brush, and clean concrete surface once more.With surface washing, wipe, vacuumize and seal, as mentioned above with rubber brush.It is believed that the water that is added has improved the infiltration of composition to concrete hole, and scrub and washed away the hole, thereby improved cleaning is provided.In some cases, sealing face is crossed and is sprayed a concrete layer.

Embodiment 4

[31] result below the physical analysis of the composition (Like New) of embodiment 1 is provided:

Character	The result
		The water-soluble viscosity proportion of outward appearance insolubles color vapour pressure (20 ) pH vapour density (air=1) smell (wt/ gallon) flash-point volatile matter per-cent boiling point surface tension (dyne/cm, 25 ℃) toxicity rate of evaporation (butylacetate=1) arsenic nitrate borate NTA boron petroleum solvent corrosion thing phenol chlorophosphate (PO by volume 4) cresols silicate	Evenly adulterant 0.04% shallow coppery-amber 17.0mm 10.77 0.62 (before the dilution) (scentless) 99.935% 110cps 8.6lb from the gentleness to the pleasant does not have 212  (100 ℃), 29.5 nothings, 0.7 nothing nothing does not have

Character	The result
		Enzyme a. proteolytic ferment b. lipolytic enzyme c. amylolysis (amoylolytic) enzyme vitriol (SO 4) halogen	Do not have

Embodiment 5

Hard water stability

[32] preparation of hard water liquid storage: by with 0.40 ± 0.005g, two water lime acetate (Ca (C ₂H ₃O ₂) ₂2H ₂O, AG) and 0.28 ± 0.005g analytical reagent magnesium sulfate heptahydrate (MgSO ₄7H ₂O, AG) is dissolved in 1 liter the ebullient distilled water, prepares 20 grain hard water liquid storages.

[33] step: the LikeNew aqueous solution that in three clean graduated cylinders of 50-mL, adds 5mL 25%V/V.In each graduated cylinder, add 45mL hard water liquid storage.With every kind of gained solution thorough mixing, and it was left standstill 24 hours at 25 ± 5 ℃ (77 ± 0 ), check the precipitation situation of every kind of solution afterwards.Be inverted graduated cylinder by five times and stir each solution, and use the Orbeco-Hellige turbidometer, utilize test, measure their turbidity about silicon-dioxide.Test result is averaged.

Test 1	Test 2
		＜10ppm	＜10ppm

Embodiment 6

Cold stability

[34] Like-New that will about 50mL pours in the test tube and was cooled to-18 ± 5 ℃ (0 ± 9 ) about 1 hour.Make compound return to room temperature then.Behind 5 inversion test tubes, the homogeneity of inspection group's compound.

Test 1	Test 2
		Return to normal appearance	Return to normal appearance

Embodiment 7

To phosphatic analysis

[34] the following standard phosphoric acid salt that carries out is tested.The sample that the 10.000g embodiment 1 that weighs in porcelain or silicon-dioxide furnace pot fills a prescription.Gentle this sample of burning burns up to most of combustiblematerials on low gas flame, then it is transferred to retort furnace 10-15 minute that is no more than 550 ℃.The gained residue is carbon containing not.The cooling resistates adds the dense HCl of 10mL then, and mixture is transferred in the 400-mL beaker.Water makes liquor capacity reach about 100mL, and contains the excessive dense HCl of 10mL at least.Beaker covers with watch-glass and seethed with excitement 30-60 minute in the presence of glassy phosphate.Solution is cooled to room temperature, is diluted with water to 200mL, and 50%NaOH at first, utilize 0.5 and/or 0.01N NaOH then, be adjusted to pH4.3.In some cases, gained solution is cooled and keeps temperature below 30 ℃.With NaOH solution with this solution titration to the pH8.8 terminal point.Total phosphorus per-cent in P2O5 is (T * N * 7.098)/(example weight), and wherein N is the equivalent concentration of NaOH used in the titration, and T is the volume of NaOH solution used in the titration.

Embodiment 8

Thermostability

[35] sample with 50mL embodiment 1 composition (Like New) is placed in the 50-mL graduated cylinder, and it is plugged then.This graduated cylinder was placed in 60 ± 2 ℃ of (140 ± 3 ) water-baths 6 hours.At least the composition of 30mL is submerged.

Test 1	Test 2
		Do not separate or layering	Do not separate or layering

Embodiment 8

Emulsifying property

[36] aqueous mixture with embodiment 1 composition of 10mL 25% (V/V) is placed in the 50-mL glass-cover measuring cylinder.The sample that adds 30mL cleaning solvent (Mil-P-D-680 type 2).By being inverted graduated cylinder is for 10 times the thermal agitation in 15 seconds then, forms milk sap.Make after this milk sap left standstill 5 minutes, once more 15 seconds of stirred sample.Gained milk sap was left standstill 6 hours.When during 6 hours, finishing, check the profit layering situation of this milk sap.

	Test 1	Test 2	Test 3
				Water oil	1.00mL there is not free oil	0.8mL there is not free oil	0.90mL there is not free oil

Embodiment 9

Inflammableness

[37] sample with embodiment 1 composition (Like New) is placed in the uncovered cup, and makes its boiling.Flame is applied to this boiling liquid.

Test 1	Test 2
		Sparkless	Sparkless

Embodiment 10

Biological degradability

[38] utilize standard method of test (Journal of the Water Pollution ControlFederation), estimate the biological degradability of embodiment 1 composition (Like New), utilize the standardized solution of sodium laurylsulfonate (SDS) to compare.The concentration of two kinds of samples in containing the B.O.D. dilution water of yeast extract is 20ppm, and inoculates with sewage.Flask is cultivated 3 one-week cycles, adapted to these compounds to guarantee organism.

By common methylene blue test, measure the degraded of SDS.As degraded at the Like of mensuration described in Journal of WaterPollution and Control New.

The per-cent of degrading in 7 days

SDS	The composition of embodiment 1
		99.0％	99.0％

Embodiment 11

Surface tension

[39] in 25 ℃, the following surface tension of measuring Like New of 29.5 dyne/cm.The Like New/ tap water of 1/1625 ratio has the surface tension of 36 dyne/cm under 25 ℃, this is definite by the surface tension of the Like New solution of drawing serial dilution.

Embodiment 12

Fresh water or seawater performance

[40] utilize standard U.S. federal test method, estimate fresh water and seawater performance.

[41] first step.In the 200-mL round-bottomed flask, the 10mL sample of mix embodiment 1 composition (Like New) and 10mL proportion are 23 ± 0.5 raw crude oil, and with 10 seconds of mixture thermal agitation.The 150mL seawater sample is placed in first 200-mL graduated cylinder, 150mL fresh tap water sample is placed in second 200-mL graduated cylinder, and Like New and the blends of crudes of 5mL added in each graduated cylinder, then with all graduated cylinders stopper beyond the Great Wall.Mix the inclusion of each graduated cylinder by being inverted 5 times, and graduated cylinder was at room temperature left standstill 1 hour.The free crude oil on visual observations graduated cylinder surface.Utilize the glass stirring rod, any floating former oil particles that gets is flatly spread on 1 * 2 wave carrier piece, then with fresh tap water or this wave carrier piece of seawater rinsing 1 minute.All trace amounts should dissipate in water.Described composition is by this test.

[42] second steps.With trieline (technical grade Fed.Spec.O-T-634) is fully cleaned one 4 " * 6 " thin slice and weighing, each have aluminium alloy (2024, Fed.Spec.QQ-A-250/4) and magnesium alloy (AZ318 or higher, Fed.Spec.QQ-M-44).The one side of each sheet evenly applied 40 weight machinery oil and sooty mixture---it provides the visibility of improvement, and weighs, to measure the oil-contg on each sheet.Each sheet is placed on the horizontal surface, wherein is with pasta up, and spray, up to fully moistening with the Like New of 1 part of dilution and the mixture of 7 parts of tap water.After 5 minutes the residence time, each sheet was immersed in the fresh tap water rinse tank of mild agitation 5 minutes, oven drying is 10 minutes under 150 .Weigh described again, to measure the amount of the oil of being removed, it is represented as per-cent.Basically all oil all are removed.

Embodiment 13

Toxicity

[43] observe no environment toxicity.

[44] oral toxicity.With 18 mean body weights is that the male Long-Evans rat of 268g (scope 256-280g) is divided into three comparative group, every group of 6 animals.Give single dose Like New by stomach tube to 1 group, dosage is every 100g body weight 1mL.Give single dose Like New by stomach tube to 2 groups, dosage is every 100g body weight 0.5mL.Give single dose 1mL normal saline solution by stomach tube to group 3---they are organized in contrast---, dosage is every 100g body weight 1mL.Rat is placed in the independent cage with the sieve shape bottom of lifting, and food (Purina Laboratory Chow) and water arbitrarily are provided.Keep to observe animal 14 days, and afterwards it was weighed and dissect.The weight in average of rat in each group after 14 days feed increases as follows:

1 group 2 groups 3 groups

44.4g 48.6g 47.2g

[45] not significant on the weight increase difference statistics between each group.In giving any rat of LikeNew, do not observe total poisonous or deleterious effect.Internal organs between test animal and the control animal do not have significant difference in appearance.

[46] dermal toxicity.The male New Zealand rabbit (New Zealand White rabbits) that to select 12 mean body weights be 2291g (scope 2134-2416g) is divided into 2 comparative group, every group of 6 animals.On the middle dorsal surface zone of each animal, prune the area of about 2 " * 3 " size.In a group, the skin of pruning in the district is kept intact; In another group, by produce a series of shallow cuts with sharp instrument, skin is worn.Rabbit is placed in the independent metal cage, and arbitrarily provides food and water at duration of test.Every day the pruning district that Like New is applied to two groups is amounted to 4 days then.During using back first hour, observed animal every 10 minutes, afterwards twice observation every day animal.After using first, keep observing one week of animal.In any rabbit, do not observe total deleterious effect.In process of the test, all animals have all increased body weight (average 177g), and look like normal in all fields.

Embodiment 14

The stress crazing of acrylic plastics

[47] three samples of sheet acrylplastics (MIL-P-5425) by annealing in the baking box that is suspended in 90 ± 2 ℃ (194 ± 4 ) in 2 hours.When finishing during annealing, the temperature of sample is reduced to room temperature with maximum 27 ± 5 ℃ of (49 ± 9 ) speed per hour.Then, before use this annealed samples is at room temperature regulated 7 days.Each of three samples is set up as overarm, and is forced into the outer fiber intensity of 3,000 pounds per square foots carefully.After 10 minutes, check sample, to guarantee that not having crazing occurs., about 3/4 square inch cotton is absorbed the cloth sheet be placed on the tension force face of this sample, directly on fulcrum still in the pressurized at sample.Like New is applied to this cotton sheet carefully, and makes the cloth sheet keep moistening by other applying as required.After 24 hours, and still in the pressurized, the cotton sheet is removed, and, reexamined crazing, cracking or other defective with tap water rinsing sample at sample.

Test 1	Test 2
		There are not cracking or crazing	There are not cracking or crazing

Embodiment 15

Colibacillary excitation research (challenge study)

[48] three tests are carried out in the dilutions in 5: 1 of (V/V) in water to embodiment 1 composition (Like New), and estimate at 0 day, 1 day and 3 days.What test simultaneously with product is three kinds of quality control samples (blank product, positive control, negative control).Cultivate excitation organism (intestinal bacteria ATCC 25922) and it is transferred in described 3 product samples (three are repeated sample), the ultimate density of positive control is about 1.0 * 10 ⁶The excitation organism does not add in blank product or the negative control.Representative part is removed by aseptic from each test container, and double repeats to count on the Petrifilm that sample is inoculated into AOAC 99114 for example.These first samples are designated 0 day, and concentration is before cultivated in expression.Carry out this research at ambient temperature, and other part is removed by aseptic afterwards in 24 hours (1 day) and 72 hours (3 days).Before calculating bacterium colony and evaluating data,---intestinal bacteria---grew 48 hours on Petrifilm to make test organism.

[49] data show, in the presence of 5: 1 solution of Like New, do not have the growth of excitation microorganism Escherichia coli to occur.Three duplicate samples at the product of 0 day, 1 day and 3 days test do not show growth, and positive control demonstrates slowly and significant increasing simultaneously.Intestinal bacteria in positive control growth and in blank and negative control, do not grow and confirmed this test.Observation in addition shows that intestinal bacteria excitation organism can not survive after 5: 1 solution that are exposed to Like New 1 hour.

[50] other commerce cleaning product that can get CLR  (Jelmar for example, Skokie, IL), Simple Green  (Sunshine Makers, Inc.Huntington Harbour, CA) and OxiClean  (Orange Glo International, but Littleton CO) has finished some tasks has not covered the myriad applications of disclosure composition preferred implementation.For example, be used to preferred embodiment clean that great majority can be washed the surface and/or for they carry out degreasing.Example comprises the concrete combination, pitch, pitch foundation material (tar foundation material), natural stone, marble, grouan, terrazzo, poultry, eggs, railroad rail and sleeper, water drain/sewer, leather, baking box, stove, watt, grout, woollen blanket, fabric, the fabric stain, laundry item, soil, inside and outside aircraft assembly, coating surface (can soften emulsion paint), the animal fence, plastics, resin glass (Plexiglas ), glass fibre, metal and analogue.Some preferred embodiment also are used for from the vehicles, car, ship and floor-cleaning and remove wax.Some embodiments are used for the storage tank of crude oil and/or refining petroleum product.Some embodiment emulsifications or remove are used for the mastic coatings class of laying floor and/or watt---for example oilcloth, vinyl floor and analogue---.Some embodiments clean dust and/or corrosive metallic surface.

[51] as discussed above, some preferred embodiment in, described composition is dilute with water for example before use.As used herein, term " composition (formulation) " also refers to diluted composition.Dilution only provides as guiding opinion.It will be understood by those skilled in the art that some one or more concentrated solutions of application use, and these solution are also included within the scope of the present disclosure.

[52] some clean the described composition of applications exploiting, in conjunction with other cleaning products as known in the art.For example, the embodiment of described composition uses with chlorine and/or oxygen bleaching as the laundry sanitising agent.Other additive known in the art also is useful in use the laundry, for example, and tenderizer, soap, washing agent, reodorant and analogue.In other embodiments, the embodiment of composition uses as the laundry washing agent separately, and effectively removes stain, soil, body oil, smell and analogue.

[53] some embodiment killing bacterias, promptly airborne bacterium and lip-deep bacterium.Some embodiments be it seems and can be treated acne, comprise adult acne.It is believed that, this kind behavior is responsible for oil removing bonded antibacterial effect to small part.Some embodiments kill mould and/or mould, their spore and/or the rudiment of prevention spore.Have been found that using Like New to handle can kill up to about 50% survival mould spores in 10 seconds of contact, and in 30 minutes, kill and do not have mould-growth after 99%, 60 day.The about 5-10 of some embodiment utilizations of these application: 1 extent of dilution.In some embodiments, spray with diluted composition in infected zone, for example in blast main, and for the bolt hole on the wall.In other embodiments, infected surface is sprayed dilute compositions and/or is soaked into this dilute compositions.

[54] in addition, the embodiment of disclosure composition cleans skin safely, for example removes superfluous oil from skin and pore, for example at about 5-15: under 1 the dilute strength.For example the embodiment of lanolin and/or Oleum Cocois is particularly useful to cleaning skin to contain optional softener, and reason is the humidity-holding effect of these additives.Some embodiments for example are diluted to about 10-15: 1 embodiment, decompose earwax.By for example at about 8-9: wash skin under 1 the dilution, perhaps about 10-12: 1 dilution hair washing is down sent out, and embodiment also is being useful aspect treatment scabies, louse, flea, flat lice and the analogue.This treatment is useful on dog and the cat for example people and other animal.But the embodiment of described composition also resists the analogue of animal, plant and/or lip-deep insect, other arthropods and family, commerce and/or agricultural application aspect on the desinsection effectively.In some embodiments, processed article or surface are soft materials, for example, and fabric, mattress, upholstery and analogue.Example comprises ant, moth (silverfish), aphid, bedbug, louse, scabies, flat lice, flea and analogue.

[55] some embodiments also are safe to domestic animal, pet, hydrobiont and analogue.Therefore, in some applications, need not the protectiveness outer cover.Some embodiments also are used for soil and remedy and/or purify fresh water body, for example lake, pond and/or river.In these embodiments, it also is safe that cleaning combination flows in the waterways.Equally, the disposal of these embodiments does not increase safety issue substantially.

[56] at for example about 5-12: under 1 the dilution, some embodiment neutralizer flavors, for example, pet, cigarette and people's waste smell.The skunk smell is effectively removed in about 5: 1 dilution.

[57] some embodiments are used for airflow cleans (air cleaner).In some embodiments, the about 10-20 of described composition dilute with water: 1, and with this solution atomization in air-flow.In some embodiments, utilize filter or other trap, mist is removed in the downstream.Atomising method also is used for cleaned air conduit, vent-pipe, HVAC system and analogue.Effective neutralizing acid of some embodiments and/or sour gas.Some embodiments effectively suppress fire and prevent to fire again.

[58] preferred implementation do not comprise from the application during the applying date the California safety of California proposal 65 times or 1986 drink with the water law case under classify the composition of hazardous substance as.

[59] Table III provides the exemplary dilution of embodiment 1 composition (Like New) in water, to be used for multiple application.

Table III

Use	Preferred extent of dilution, approximately
		Carpet pet odors mould garage, laundry or the amusement of track corrosion (Tarnish) automotive wheels car engine degreasing household cleaning baking box are removed putty (mastic) hand cleaning agent with the vehicles/ship jewelry floor or concrete and are removed the cleaning of earwax antimicrobial drug oil field	10-16∶1 8-9∶1 5-12∶1 5-10∶1 5-8∶1 10∶1 5-6∶1 5-6∶1 10-12∶1 5∶1 8-10∶1 8∶1 5-10∶1 5∶1 5-15∶1 10-15∶1 5-10∶1 5-8∶1

[60] although described some embodiment, these embodiments only propose as embodiment, and are not intention restriction the scope of the present disclosure.It will be understood by those skilled in the art that composition described herein, method and system can embody with multiple other form.In addition, can carry out the various omissions of the form of composition described herein, method and system, alternative and variation, and not deviate from spirit of the present disclosure.Appending claims and their Equivalent are intended to cover these forms or modification.

Claims (20)

1. cleaning combination comprises:

About 25% to about 50% lipid acid;

About 15% to about 25% saponifying agent;

About 4% to about 16% water conditioner;

About 12% to about 24% solvent;

About 8% to about 32% nonionic surface active agent; With

About 1% to about 6% aniorfic surfactant.

2. claim 1 is described at composition, comprising:

About 30% to about 40% lipid acid;

About 17% to about 20% saponifying agent;

About 6% to about 10% water conditioner;

About 16% to about 20% solvent;

About 14% to about 20% nonionic surface active agent; With

About 2% to about 4% aniorfic surfactant.

3. claim 1 or 2 described compositions, wherein said lipid acid comprises tall oil fatty acid.

4. the described composition of claim 3, wherein said tall oil fatty acid comprises high tallol rosin content.

5. each described composition of claim 1-4, wherein said saponifying agent comprises 2-amino-2-methyl 1-1-propyl alcohol.

6. each described composition of claim 1-5, wherein said water conditioner comprises cationic cellulose polymer.

7. the described composition of claim 6, wherein said cationic cellulose polymer comprise the cellulose skeleton with polyquaternium-4 side chain graft.

8. each described composition of claim 1-7, wherein said nonionic surface active agent comprises octylphenol ethoxylate.

9. each described composition of claim 1-8, wherein said aniorfic surfactant comprises alkyl naphthalene sulfonate.

10. each described composition of claim 1-9 also comprises water.

11. each described composition of claim 1-10 comprises that also one or more are selected from the material of lanolin, Oleum Cocois and spices.

12. each described composition of claim 1-11 comprises:

About 36% lipid acid;

About 18%2-amino-2 methyl isophthalic acids-propyl alcohol;

About 8% cationic fiber acid polymer;

About 18% methyl soyate;

About 16% octylphenol ethoxylate; With

About 3% alkyl naphthalene sulfonate.

13. the method for an article-cleaning comprises each described composition among at least a portion contact claim 1-12 that makes described article.

14. the described method of claim 13, wherein said cleaning combination dilute with water.

15. claim 13 or 14 described methods also comprise at least a portion of the described article of mechanical scrub.

16. each described method of claim 13-15, wherein said article comprise concrete surface.

17. a system that is used for article-cleaning comprises:

Each described cleaning combination of claim 1-12; With

Be used to make at least a portion and the contacted specification sheets of described cleaning combination of described article.

18. the described system of claim 17 also comprises the instrument that described composition is applied at least a portion of described article.

19. claim 17 or 18 described systems also comprise being used for the instrument to small part that machinery cleans described article.

20. each described composition of claim 1-12 is as at least a application in following:

The sanitising agent of following material: comprise the compound of long carbochain, for example, oil and/or biologically-derived oil; Or body fluid, for example, blood, urine, lymph liquid, purulence, and analogue, it for example comprises fat, carbohydrate, protein and other component known in the art; Body oil; Oil leakage thing/overspill; Grease; Dust; Or corrosive metal;

The sanitising agent of following material: can wash the surface; The concrete of dwelling house and commercial establishment; Pitch; The pitch foundation material; Natural stone; Marble; Grouan; Saponite; Synthetic stone; The pottery, watt; Terrazzo; Metal; Plastics; Resin glass (Plexiglas ); Glass fibre; Coating surface; The fluorescence fixture; Fabric; The fabric stain; Laundry item; Carpet and/or stain; Leather; Jewelry; Pearl; Chatoyant; Baking box; Stove; Tile; Grout; Doughnut; The amusement vehicles; The glass fibre ship; Industrial floor; Motor vehicle repair and parts; Automobile; Ship/ship; The bilge; Diesel engine; Railroad rail and sleeper; Inside and outside aircraft assembly; The storage tank that is used for crude oil and/or refining petroleum product; Water drain; Soil; Poultry; Eggs; The animal fence; Hand; Skin; Hair; Air-flow; Air; Blast main; Vent-pipe; Or HVAC system;

Toughener is cleaned in the laundry;

Be used for engine and maybe can wash the stain remover on surface;

Scum silica frost or lime remover;

Fire retardant; Fireproofing agent; Or fire preventive again;

The stripper of following substances: wax; Wax on vehicle, automobile, ship or the floor; Perhaps be used for laying floor and/or watt the putty type, for example, oilcloth, vinyl floor material and analogue;

Remove smell; Or remove skunk, pet, cigarette or people's waste smell;

Anti-acne skin clean-out system and/or treatment;

Earwax scavenging agent/emulsifying agent;

Antiseptic-germicide, airborne and from the teeth outwards; Kill mould and/or mould; Kill mould and/or mould spore; Or prevent spore mould and/or mould rudiment;

Family, commerce and/or agricultural insecticide; Be applied to the sterilant of ant, moth, aphid, bedbug, louse, scabies, flat lice or flea; The sterilant that is used for animal, plant, surface or soft material, described soft material such as fabric, mattress, upholstery and analogue;

Treatment scabies, louse, flea, flat lice; Or

Neutralizing acid and/or sour gas.