CN101191051A - Pasty chemical luminous composite with relative high viscosity - Google Patents
Pasty chemical luminous composite with relative high viscosity Download PDFInfo
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- CN101191051A CN101191051A CNA2006101295528A CN200610129552A CN101191051A CN 101191051 A CN101191051 A CN 101191051A CN A2006101295528 A CNA2006101295528 A CN A2006101295528A CN 200610129552 A CN200610129552 A CN 200610129552A CN 101191051 A CN101191051 A CN 101191051A
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Abstract
The invention discloses a paste-shaped chemiluminescence mixture with comparative high viscosity, and is characterized in that: 1. 'an oxalate component' contains 3 - 100 percent of oxalate; 2. 'an activator component' contains 2 - 20 percent of peroxide; the weight ratio of the oxalate component and the activator component is within the range of 1: 50 - 3:1; the rest is added with fluorescent agent, catalysts, solvents and thickener. The invention has advantages that: 1. the viscosity of the chemiluminescence mixture obtained by the invention is above 1000MPa.s; 2. the chemiluminescence mixture can be used in some vessels as the traditional chemiluminescence mixture to produce chemiluminescence and can also be coated on needed object surface without using vessels to produce chemiluminescene; 3. the thickness of the coating layer can be adjusted according to viscosity of a system and need of luminescence; 4. the usability of oxidized chemiluminescence mixture is improved greatly.
Description
(1) technical field:
The present invention relates to the chemical luminous composite field, particularly a kind of have a full-bodied relatively pasty chemical luminous composite.
(2) background technology:
At present, various oxidation chemistry light emitting compositions just are familiar with by people and are utilized, for example the oxidation chemistry light emitting composition described in United States Patent (USP) 3816326,4313843 and 5122306.Traditional oxidation chemistry light emitting composition all typically has 50mPas or littler viscosity, and this has just determined it to use under certain container containing restriction, thereby must make its range of application be subjected to certain limitation.As carrying out area illumination when needs or when needing accurately to indicate object surface shape, all can being subjected to the influence of container itself.
United States Patent (USP) 5043851,5121302 and 6062380 have all described the improvement container containing and have optimized the photodistributed device of emission, but they all are based on chemoluminescence solution or suspension that viscosity is less than or equal to 50mPas, and all still are subject to their container of splendid attire.
(3) summary of the invention:
Purpose of the present invention is to provide a kind of full-bodied relatively pasty chemical luminous composite that has, it be based on a kind of with the barkite be activeconstituents " barkite component " and a kind of be " activator component " of activeconstituents and the chemical luminous composite that is contained in one or more fluorescent agents, catalyzer, solvent and thickening material in described " barkite component " and/or " activator component " with the oxygenant, it has the advantages that not use under the restriction of certain container containing.
Technical scheme of the present invention: a kind of have a full-bodied relatively pasty chemical luminous composite, it is characterized in that it comprises:
1) a kind of " barkite component " that contains 3% to 100% barkite;
2) a kind of " activator component " that contains 2% to 20% superoxide; The weight ratio of barkite component and activator component is 1: 50-3: in 1 the scope;
Surplus adds fluorescent agent, catalyzer, solvent and thickening material; Viscosity is greater than 1000mPas.
Above-mentioned said barkite component can be solid-state, liquid state or paste.
Above-mentioned said activator component can be a paste.
Above-mentioned said fluorescent agent, catalyzer, solvent, thickening material can be included in " barkite component " or " activator component " or be contained in " barkite component " and " activator component " two components in.
The barkite that uses in the above-mentioned barkite component is known as this area people.The example of the barkite that is suitable for comprises two (2,4,5-three chloro-6-carbonyls penta oxygen phenyl) barkite, two (2,4, the 5-trichlorophenyl) barkite, two (2,4, the own oxygen phenyl of 5-three bromo-6-carbonyls) barkite, two (2,-nitrophenyl) barkite, two (2, the 4-dinitrophenyl) barkite, two (2,6-two chloro-4-nitrophenyls) barkite, two (2,4, the 6-trichlorophenyl) barkite, two (3-trifluoromethyl-4-nitrophenyl) barkite, two (1,2-dimethyl-4, the 6-dinitrophenyl) barkite, two (2, the 4-dichlorophenyl) barkite, two (2, the 4-dinitrophenyl) barkite, two (2, the 5-dinitrophenyl) barkite, two (2-formyl-4-nitrophenyl) barkite, two (five chlorophenyl) barkite, two (1,2-dihydro-2-oxo--1-pyridyl) oxalic dialdehyde, two (2,4-dinitrobenzene-6-aminomethyl phenyl) barkite.Described barkite preferably comprises two (2,4,5-three chloro-6-carbonyls penta oxygen phenyl) barkite (being called " CPPO ") or two (2,4, the 5-trichlorophenyl) barkites (being called " TCPO ").The barkite component can be single barkite.
The barkite component also can be barkite and fluorescent agent and/or mixture of catalysts.
The barkite component also can be barkite or barkite and fluorescent agent and/or the catalyzer mixture with non-aqueous solvent.
The barkite component also can be barkite or barkite and the fluorescent agent mixture with non-water hickener.In this mixture, can add also and can not add non-aqueous solvent.
Above-mentioned activator component is solution, suspension, colloid or the emulsion of viscosity greater than 1000mPas.Comprise superoxide, one or more solvents and/or fluorescent agent, catalyzer.The thickening material or the non-water hickener that contain water and water simultaneously in the activator component are so that activator component reaches the viscosity that needs.
Above-mentioned superoxide comprises hydrogen peroxide, sodium peroxide, peroxidation trisodium phosphate, urea peroxide, sodium perborate, peroxidation Histidine, tertbutyl peroxide and peroxidation phenylformic acid.Preferred superoxide is a urea peroxide.When composition is used for hair, skin or other to oxidation-sensitive surperficial, use urea peroxide to make oxygenant, can reduce the oxidisability of composition, so that the composition anergy.
The catalyzer of above-mentioned chemical luminous composite is known in the prior art.Catalyst concentration is generally about 1 * 10 in activator component or the barkite component
-5To the scope of 2M.The catalyzer that is suitable for comprises sodium salicylate, potassium salicylate, lithium salicylate, 5-chloro-salicylic acid sodium, 5-chloro-salicylic acid lithium, sodium trifluoroacetate, Pentachlorophenol potassium, Whitfield's ointment TBuA, phenylformic acid TBuA, TBAP, Sodium dodecylbenzene sulfonate, Sodium palmityl sulfate, trolamine, water glass.Preferred catalyzer is a sodium salicylate.
Above-mentioned fluorescent agent generally has the spectral emissions of 330nm-1000nm scope, and it can be present in barkite component, activator component or the two kinds of components, and general concentration is in the 0.001M-0.05M scope.The fluorescent agent that is suitable for comprises United States Patent (USP) 3729426,3948797, the fluorescent agent described in 4017415 and 5122306, such as 9,10-diphenylanthrancene, 9,10-tolane base anthracene, 1,8-two chloro-9,10-tolane base anthracene, 2-ethyl-9,10-tolane base anthracene, 1,6,7,12-four phenoxy groups-N, N '-two (2,5 diisopropyl phenyl)-3,4,9,10-perylene dicarboximide etc.Preferred fluorescent agent is 9,10-tolane base anthracene and 1,8-two chloro-9,10-tolane base anthracene.
Above-mentioned solvent comprises ethyl acetate, dimethyl phthalate, dibutyl phthalate, butyl benzoate, ethyl benzoate, wintergreen oil, salicylic ether, glycerine, the trimethyl carbinol and water.Preferred solvent is dimethyl phthalate, dibutyl phthalate, butyl benzoate and water.Its general concentration is 0.3%-90%.
Above-mentioned said thickening material can be the thickening material of non-water hickener or water.
Above-mentioned said non-water hickener comprises paraffinic base material and polyoxyethylene glycol.Its general concentration is 30%-95%.
The thickening material of above-mentioned water generally is a water-soluble polymer, and it can mutual group becomes the matrix of activator component with water, and its general concentration is 0.1%-15%.The thickening material of the water that is suitable for comprises W-Gum, Viscogum BE, guar gum, xanthan gum, gelatin, carboxymethyl cellulose, ethyl cellulose, Natvosol, polyacrylic acid, polyacrylic acid derivative, polyoxyethylene glycol and polyvinylpyrrolidone.Preferred thickening is xanthan gum and polyacrylic acid derivative, as carbomer.
Superiority of the present invention is: 1, the present invention obtains the chemical luminous composite of a kind of viscosity greater than 1000mPas; 2, this chemical luminous composite can equally with traditional chemical luminous composite use in certain container, produces chemoluminescence, also can not use container, and it is coated on the body surface that needs, and produces chemoluminescence; 3, Tu Bu thickness can be decided according to the viscosity of system itself and luminous needs; 4, make the use properties of oxidation chemistry light emitting composition that significant improvement take place.
(4) embodiment:
Embodiment 1
Under nitrogen atmosphere, 20 gram polyoxyethylene glycol-400 are heated to 80 ℃, add 5 gram CPPO and 0.2 gram 9,10-tolane base anthracene, stir and add 20 gram polyoxyethylene glycol-4000 after 5 minutes, being stirred to polyoxyethylene glycol-4000 under 80 ℃ all dissolves, be cooled to room temperature under the nitrogen atmosphere, make paste barkite component.
Under agitation 20 gram polyoxyethylene glycol-400 are heated to 60 ℃, add 20 gram polyoxyethylene glycol-4000, lower the temperature after being stirred to fusion, add 0.5 gram sodium salicylate and 6 gram urea peroxides simultaneously, stir and drop to room temperature, make the paste activator component.
Above-mentioned barkite component and activator component are mixed, produce green chemoluminescence.
Viscosity is greater than 1000mPas.
Embodiment 2
20 gram water with 20 gram glycerine mixing, are added 0.3 gram sodium salicylate and 3.5 gram urea peroxides, be stirred to dissolving, slowly add 1 gram xanthan gum, continuing to be stirred to system viscosity no longer increases, and adding 2ml butyl benzoate is even to system under vigorous stirring.Gained is the paste activator component.
With 5 gram CPPO and 0.2 gram 1,8-two chloro-9,10-tolane base anthracene mixes, and gained is solid-state barkite component.
Activator component and barkite component are mixed, send xanchromatic light at once.
Viscosity is greater than 1000mPas.
Embodiment 3
In 35 gram water, add sodium salicylate 0.5 gram and urea peroxide 3.5 grams, be stirred to whole dissolvings.Slowly add 1 gram carbomer, be stirred well to complete swelling, under vigorous stirring, add 1.5ml dimethyl phthalate and 0.2 gram 9 then, 10-tolane base anthracene, it is even to continue to be stirred to system, and gained is the paste activator component.
5 gram CPPO and 0.25 gram Sodium dodecylbenzene sulfonate are mixed, be solid-state barkite component.
Activator component and barkite component are mixed, produce green chemoluminescence.
Viscosity is greater than 1000mPas.
Claims (10)
1. one kind has full-bodied relatively pasty chemical luminous composite, it is characterized in that it comprises:
1) a kind of " barkite component " that contains 3% to 100% barkite;
2) a kind of " activator component " that contains 2% to 20% superoxide; The weight ratio of barkite component and activator component is 1: 50-3: in 1 the scope;
Surplus adds fluorescent agent, catalyzer, solvent and thickening material; Viscosity is greater than 1000mPas.
2. according to the said a kind of full-bodied relatively pasty chemical luminous composite that has of claim 1, it is characterized in that said barkite component can be solid-state, liquid state or paste; Said activator component can be a paste.
3. according to the said a kind of full-bodied relatively pasty chemical luminous composite that has of claim 1, it is characterized in that said fluorescent agent, catalyzer, solvent, thickening material can be included in " barkite component " or " activator component " or be contained in " barkite component " and " activator component " two components in.
4. according to the said a kind of full-bodied relatively pasty chemical luminous composite that has of claim 1, it is characterized in that the barkite that is suitable in the barkite component comprises two (2,4,5-three chloro-6-carbonyls penta oxygen phenyl) barkite, two (2,4, the 5-trichlorophenyl) barkite, two (2,4, the own oxygen phenyl of 5-three bromo-6-carbonyls) barkite, two (2,-nitrophenyl) barkite, two (2, the 4-dinitrophenyl) barkite, two (2,6-two chloro-4-nitrophenyls) barkite, two (2,4, the 6-trichlorophenyl) barkite, two (3-trifluoromethyl-4-nitrophenyl) barkite, two (1,2-dimethyl-4, the 6-dinitrophenyl) barkite, two (2,4 dichloro benzene base) barkite, two (2, the 4-dinitrophenyl) barkite, two (2, the 5-dinitrophenyl) barkite, two (2-formyl-4-nitrophenyl) barkite, two (five chlorophenyl) barkite, two (1,2-dihydro-2-oxo--1-pyridyl) oxalic dialdehyde, two (2,4-dinitrobenzene-6-aminomethyl phenyl) barkite; Described barkite preferably includes two (2,4,5-three chloro-6-carbonyls penta oxygen phenyl) barkite (being called " CPPO ") or two (2,4, the 5-trichlorophenyl) barkites (being called " TCPO "); The barkite component can be single barkite.
5. according to the said a kind of full-bodied relatively pasty chemical luminous composite that has of claim 1, it is characterized in that activator component is solution, suspension, colloid or the emulsion of viscosity greater than 1000mPas, comprises hydrogen peroxide, sodium peroxide, peroxidation trisodium phosphate, urea peroxide, sodium perborate, peroxidation Histidine, tertbutyl peroxide and peroxidation phenylformic acid; Preferred superoxide is a urea peroxide.
6. according to the said a kind of full-bodied relatively pasty chemical luminous composite that has of claim 1, it is characterized in that said catalyst concn is generally about 1 * 10
-5To the scope of 2M; The catalyzer that is suitable for comprises sodium salicylate, potassium salicylate, lithium salicylate, 5-chloro-salicylic acid sodium, 5-chloro-salicylic acid lithium, sodium trifluoroacetate, Pentachlorophenol potassium, Whitfield's ointment TBuA, phenylformic acid TBuA, TBAP, Sodium dodecylbenzene sulfonate, Sodium palmityl sulfate, trolamine, water glass.Preferred catalyzer is a sodium salicylate.
7. according to the said a kind of full-bodied relatively pasty chemical luminous composite that has of claim 1, it is characterized in that said fluorescent agent generally has the spectral emissions of 330nm-1000nm scope, it can be present in barkite component, activator component or the two kinds of components, and general concentration is in the 0.001M-0.05M scope; The fluorescent agent that is suitable for comprises 9,10-diphenylanthrancene, 9,10-tolane base anthracene, 1,8-two chloro-9,10-tolane base anthracene, 2-ethyl-9,10-tolane base anthracene, 1,6,7,12-four phenoxy groups-N, N '-two (2,5 diisopropyl phenyls)-3,4,9,10-perylene dicarboximide etc.; Preferred fluorescent agent is 9,10-tolane base anthracene and 1,8-two chloro-9,10-tolane base anthracene.
8. according to the said a kind of full-bodied relatively pasty chemical luminous composite that has of claim 1, it is characterized in that said solvent comprises ethyl acetate, dimethyl phthalate, dibutyl phthalate, butyl benzoate, ethyl benzoate, wintergreen oil, salicylic ether, glycerine, the trimethyl carbinol and water; Preferred solvent is dimethyl phthalate, dibutyl phthalate, butyl benzoate and water; Its general concentration is 0.3%-90%.
9. according to the said a kind of full-bodied relatively pasty chemical luminous composite that has of claim 1, it is characterized in that said thickening material can be the thickening material of non-water hickener or water.
10. according to the said a kind of full-bodied relatively pasty chemical luminous composite that has of claim 1, it is characterized in that said non-water hickener comprises paraffinic base material and polyoxyethylene glycol, its general concentration is 30%-95%; The thickening material of said water generally is a water-soluble polymer, and it can mutual group becomes the matrix of activator component with water, and its general concentration is 0.1%-15%; The thickening material of the water that is suitable for comprises W-Gum, Viscogum BE, guar gum, xanthan gum, gelatin, carboxymethyl cellulose, ethyl cellulose, Natvosol, polyacrylic acid, polyacrylic acid derivative, polyoxyethylene glycol and polyvinylpyrrolidone; Preferred thickener is xanthan gum and polyacrylic acid derivative, as carbomer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006101295528A CN101191051A (en) | 2006-11-23 | 2006-11-23 | Pasty chemical luminous composite with relative high viscosity |
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| Application Number | Priority Date | Filing Date | Title |
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| CNA2006101295528A CN101191051A (en) | 2006-11-23 | 2006-11-23 | Pasty chemical luminous composite with relative high viscosity |
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| CN101191051A true CN101191051A (en) | 2008-06-04 |
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| CNA2006101295528A Pending CN101191051A (en) | 2006-11-23 | 2006-11-23 | Pasty chemical luminous composite with relative high viscosity |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775984A (en) * | 2011-05-13 | 2012-11-14 | 天津天龙化学发光管有限公司 | Pasty chemiluminescent composition with low oxidizability and high stability |
| CN102775983A (en) * | 2011-05-13 | 2012-11-14 | 天津天龙化学发光管有限公司 | Solid chemiluminescent composition with organic matter as filler |
| CN103013499A (en) * | 2011-09-20 | 2013-04-03 | 金朝阳 | Luminescence composition, preparation method and applications thereof |
-
2006
- 2006-11-23 CN CNA2006101295528A patent/CN101191051A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102775984A (en) * | 2011-05-13 | 2012-11-14 | 天津天龙化学发光管有限公司 | Pasty chemiluminescent composition with low oxidizability and high stability |
| CN102775983A (en) * | 2011-05-13 | 2012-11-14 | 天津天龙化学发光管有限公司 | Solid chemiluminescent composition with organic matter as filler |
| CN103013499A (en) * | 2011-09-20 | 2013-04-03 | 金朝阳 | Luminescence composition, preparation method and applications thereof |
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Application publication date: 20080604 |