KR930019800A - Chemiluminescent composition and method for producing same - Google Patents

Chemiluminescent composition and method for producing same Download PDF

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Publication number
KR930019800A
KR930019800A KR1019920004541A KR920004541A KR930019800A KR 930019800 A KR930019800 A KR 930019800A KR 1019920004541 A KR1019920004541 A KR 1019920004541A KR 920004541 A KR920004541 A KR 920004541A KR 930019800 A KR930019800 A KR 930019800A
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KR
South Korea
Prior art keywords
oxalate
chemiluminescent composition
bis
trichlorophenyl
chemiluminescent
Prior art date
Application number
KR1019920004541A
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Korean (ko)
Inventor
진동일
유성덕
김홍선
Original Assignee
김영선
진동일
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Application filed by 김영선, 진동일 filed Critical 김영선
Priority to KR1019920004541A priority Critical patent/KR930019800A/en
Publication of KR930019800A publication Critical patent/KR930019800A/en

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Abstract

본 발명은 조도와 발광지속 시간이 향상된 옥살레이트계화합물, 형광제, 산화제로 구성되는 화학발광 조성물 및 그 제조방법에 관한 것이다.The present invention relates to a chemiluminescent composition composed of an oxalate compound, an fluorescent agent, and an oxidant having improved illuminance and emission duration, and a method of manufacturing the same.

본 발명은 발광 에너지원으로 비스(2,4,6-트리클로로페닐)옥살레이트 또는 이것과 비스(2,4-디니트로페닐)옥살레이트의 혼합물을 사용하고, 산화제로 농도 60% 이상의 과산화 수소를 2.5×10-2~3.2×10-2M/L 첨가하는 것을 특징으로 한다.The present invention uses bis (2,4,6-trichlorophenyl) oxalate or a mixture of bis (2,4-dinitrophenyl) oxalate as a luminescent energy source, and has a concentration of 60% or more hydrogen peroxide as an oxidant. To 2.5 × 10 −2 to 3.2 × 10 −2 M / L.

이와같이 제조된 화학발광 조성물은 발광 지속시간이 길고, 발광강도가 높을 뿐만 아니라, 제조원가가 저렴하고 공정이 간단하므로 상업화에 적합하다.The chemiluminescent composition thus prepared is suitable for commercialization because it has a long emission duration, high luminous intensity, low manufacturing cost and simple process.

Description

화학발광 조성물 및 그 제조방법.Chemiluminescent composition and its manufacturing method.

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (14)

옥살레이트계 화합물과, 형광제와 산화제로 구성되는 화학발광 조성물에 있어서, 상기 옥살레이트계 화합물이 비스(2,4,6-트리클로로페닐)옥살레이트 또는 이것과 비스(2,4-디니트로페닐)옥살레이트의 혼합물인 것을 특징으로 하는 화학 발광 조성물.In a chemiluminescent composition comprising an oxalate compound and a fluorescent agent and an oxidizing agent, the oxalate compound may be bis (2,4,6-trichlorophenyl) oxalate or bis (2,4-dinitro). Phenyl) oxalate, a chemiluminescent composition. 제1항에 있어서, 비스(2,4,6-트리클로로페닐) 옥살레이트 단독사용의 경우 비스(246-트리클로로페닐)옥살레티트의 농도가 2.5×10-2~5.0×10-2M/L인 것을 특징으로 하는 화학발광 조성물.The concentration of bis (246-trichlorophenyl) oxalate according to claim 1, wherein bis (2,4,6-trichlorophenyl) oxalate alone is used at a concentration of 2.5 × 10 −2 to 5.0 × 10 −2 M Chemiluminescent composition, characterized in that / L. 제1항에 있어서, 혼합사용의 경우 비스(2,4,6-트리클로로페닐)옥살레이트 : 비스(2,4-디니트로페닐)옥살레이트의 혼합비율이 1.00×10-2~2.25×10-2: 2.0×10-2~2.5×10-2M/L인 것을 특징으로 하는 화학발광 조성물.The mixing ratio of bis (2,4,6-trichlorophenyl) oxalate to bis (2,4-dinitrophenyl) oxalate according to claim 1, wherein the mixing ratio of bis (2,4,6-trichlorophenyl) oxalate is 1.00 × 10 -2 to 2.25 × 10 -2 : The chemiluminescent composition, characterized in that 2.0 × 10 -2 ~ 2.5 × 10 -2 M / L. 제1항에 있어서, 산화제로 60% 이상의 과산화 수소를 2.5×10-2~3.5×10-2M/L첨가하는 것을 특징으로 하는 화학발광 조성물.The chemiluminescent composition according to claim 1, wherein at least 60% of hydrogen peroxide is added at 2.5 × 10 −2 to 3.5 × 10 −2 M / L as an oxidizing agent. 제4항에 있어서, 과산화수소 안정제로 소디움 디포스페이트를 첨가하는 것을 특징으로 하는 화학발광 조성물.5. The chemiluminescent composition of claim 4, wherein sodium diphosphate is added as a hydrogen peroxide stabilizer. 제5항에 있어서, 소디움 디포스페이트의 첨가량이 5.0×10-3~9.0×10-3M/L인 것을 특징으로 하는 화학발광 조성물.The chemiluminescent composition according to claim 5, wherein the amount of sodium diphosphate added is 5.0 × 10 −3 to 9.0 × 10 −3 M / L. 제1항에 있어서, 반응촉매로 3,5,6-트리클로로살리실산을 사용하는 것을 특징으로 하는 화학발광 조성물.The chemiluminescent composition according to claim 1, wherein 3,5,6-trichlorosalicylic acid is used as the reaction catalyst. 제7항에 있어서, 3,5,6-트리클로로살리실산의 첨가량이 3.0×10-3~6.0×10-3M/L인 것을 특징으로 하는 화학발광 조성물.The chemiluminescent composition according to claim 7, wherein the amount of 3,5,6-trichlorosalicylic acid added is 3.0 × 10 −3 to 6.0 × 10 −3 M / L. 제1항 기재의 화학발광 조성물을 제조하는 방법에 있어서, 하기 조성비를 갖는 조성비를 갖는 용매를 사용하는 것을 특징으로 하는 화학발광 조성물의 제조방법.A method for producing a chemiluminescent composition according to claim 1, wherein a solvent having a composition ratio having the following composition ratio is used. A)디부틸프탈레이트 43-68부피%A) 43-68% by volume dibutyl phthalate B)디메틸프탈레이트 25-50부피%B) Dimethylphthalate 25-50% by volume C)4-메틸-2-펜타놀 15-2.0부피%C) 4-Methyl-2-pentanol 15-2.0% by volume D)t-부틸알콜 5.0-5.5부피%D) t-butyl alcohol 5.0-5.5% by volume ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920004541A 1992-03-19 1992-03-19 Chemiluminescent composition and method for producing same KR930019800A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100369785B1 (en) * 2000-07-06 2003-02-05 주식회사 알지비케미컬 Chemiluminescent composition comprising carbazole-containing compound or a mixture of carbazole-containing compound and fluorene-containing compound as fluorophores

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100369785B1 (en) * 2000-07-06 2003-02-05 주식회사 알지비케미컬 Chemiluminescent composition comprising carbazole-containing compound or a mixture of carbazole-containing compound and fluorene-containing compound as fluorophores

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