CN101182187A - Foaming ceramic for treatment of automobile exhaust as well as making method and special mold therefor - Google Patents

Foaming ceramic for treatment of automobile exhaust as well as making method and special mold therefor Download PDF

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Publication number
CN101182187A
CN101182187A CNA2007101684802A CN200710168480A CN101182187A CN 101182187 A CN101182187 A CN 101182187A CN A2007101684802 A CNA2007101684802 A CN A2007101684802A CN 200710168480 A CN200710168480 A CN 200710168480A CN 101182187 A CN101182187 A CN 101182187A
Authority
CN
China
Prior art keywords
tourmalinite
clay
foamed ceramics
organic
vehicle exhaust
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2007101684802A
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Chinese (zh)
Inventor
朱运彬
陈朝晖
黄新
吴世雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GANZHOU TOURMALINE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Original Assignee
GANZHOU TOURMALINE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GANZHOU TOURMALINE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd filed Critical GANZHOU TOURMALINE ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Priority to CNA2007101684802A priority Critical patent/CN101182187A/en
Publication of CN101182187A publication Critical patent/CN101182187A/en
Pending legal-status Critical Current

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Abstract

The invention provides a foam ceramic used for the automotive exhaust treatment, a preparation method and a special die. The foam ceramic is made from burned organic silicone or organic metallic salts, tourmaline, clay and foam stabilizer. The technological process is: evenly mixing the tourmaline, the clay and the foam stabilizer of 300-2000 order, adding the organic silicone or the organic metallic salts to prepare uniform tourmaline slurry; adding the uniformly prepared tourmaline slurry in a die, which is put in a kiln and burned at 300-750 DEG C. The special die is conical structured, and a lifting rod is arranged in the die. Under the low temperature without destroying the structure of the tourmaline, the invention makes use of the organic silicone (or the organic metallic salts) to solidify and sinter the powder body of the tourmaline. Blistered foam ceramics are formed, which increase the contact surface with exhaust. And the tourmaline generates negative oxygen ions with higher activity to purify harmful substrates in the automotive exhaust.

Description

Be used for foamed ceramics and making method and particular manufacturing craft that vehicle exhaust is handled
Affiliated technical field
The present invention relates to a kind of foamed ceramics and making method and particular manufacturing craft that vehicle exhaust is handled that be used for.
Background technology
Along with improving constantly of living standards of the people, motor vehicle quantity also sharply increases, and has also brought the serious environmental pollution when bringing convenience to people's life, and human beings'health has been caused huge threat.The atmospheric pollution of the U.S. has 60% approximately for transport facility causes according to statistics, causes that by automobile the situation of China also allows of no optimist in Japan about 85%.Current automobile exhaust gas has become city primary pollution source.Automobile start with driving process in the pollutent of discharging mainly contain carbon monoxide (CO), oxynitride (NOX), hydrocarbon polymer (HC), aldehyde (RHCO), plumbous particulate matter etc.At present, handling vehicle exhaust has numerous methods, still is blank but utilize tourmalinite to carry out the vehicle exhaust processing.
Summary of the invention
The object of the present invention is to provide a kind of foamed ceramics and making method and particular manufacturing craft that vehicle exhaust is handled that be used for, this mode utilizes the fluctuation of heat of vehicle exhaust bigger, and the characteristic that contains a large amount of water vapors in the tail gas, make tourmalinite produce negative oxygen ion, with objectionable impurities (CO, the NO in the tail gas with greater activity X, HC, RHCO etc.) be oxidized to the little or avirulent material of toxicity, thereby reach the effect of purifying automobile tail gas.
The technical solution adopted for the present invention to solve the technical problems is:
Described foamed ceramics is fired by organosilicon, tourmalinite, clay and suds-stabilizing agent and is formed.
Described foamed ceramics is fired by organic metal salt, tourmalinite, clay and suds-stabilizing agent and is formed.
Described foamed ceramics manufacture craft flow process is: A, 300-2000 purpose tourmalinite, clay and suds-stabilizing agent are mixed, add organosilicon and be modulated to uniform tourmalinite slurry; To modulate uniform tourmalinite slurry and add in the mould, put into kiln, fire 3-5h at 300-750 ℃.
Described foamed ceramics manufacture craft flow process is: A, 300-2000 purpose tourmalinite, clay and suds-stabilizing agent are mixed, add organic metal salt and be modulated to uniform tourmalinite slurry; B, will modulate uniform tourmalinite slurry and add in the mould, put into kiln, fire 3-5h at 300-750 ℃.
Described particular manufacturing craft is a tapered structure, is provided with motion bar in the mould.
Described organosilicon, tourmalinite, clay and suds-stabilizing agent are followed successively by by weight percentage; 10-50%, 10-25%, 35-70%, surplus
Described organic metal salt, tourmalinite, clay and suds-stabilizing agent are followed successively by by weight percentage: 20-50%, 20-40%, 25-55%, surplus.
Described organic metal salt is be selected from organic zinc, organic-magnesium, organic iron, organoaluminum, organic titanium at least a.
Described tourmalinite is a 300-2000 purpose powder.
The invention has the beneficial effects as follows: characteristics of the present invention are not for destroying in lower temperature (300-750 ℃) with organosilicon (or organic metal salt) under the case conditions of structure of tourmalinite, realization is to the curing nodulizing of tourmaline powder, form the foamed ceramics of many pores, increase contact area with tail gas.Make tourmalinite produce the negative oxygen ion with greater activity, the objectionable impurities in the purifying automobile tail gas rapidly.
The present invention is further described below in conjunction with embodiment.
Embodiment 1: by wt%, get 35% tourmalinite, 20% organosilicon, 40% clay respectively, surplus is a suds-stabilizing agent.
Embodiment 2: by wt%, get 25% tourmalinite, 25% organic metal salt, 45% clay respectively, surplus is a suds-stabilizing agent.
Embodiment 3: by wt%, get 10% tourmalinite, 10% organosilicon, 70% clay respectively, surplus is a suds-stabilizing agent.
Embodiment 4: by wt%, get 10% tourmalinite, 50% organosilicon, 35% clay respectively, surplus is a suds-stabilizing agent.
Embodiment 5: by wt%, get 25% tourmalinite, 10% organosilicon, 35% clay respectively, surplus is a suds-stabilizing agent.
Embodiment 6: by wt%, get 20% tourmalinite, 20% organic metal salt, 55% clay respectively, surplus is a suds-stabilizing agent.
Embodiment 7: by wt%, get 20% tourmalinite, 50% organic metal salt, 25% clay respectively, surplus is a suds-stabilizing agent.
Embodiment 8: by wt%, get 40% tourmalinite, 20% organic metal salt, 25% clay respectively, surplus is a suds-stabilizing agent.
Embodiment 2, and the organic metal salt among the embodiment 6-8 is be selected from organic zinc, organic-magnesium, organic iron, organoaluminum, organic titanium at least a
Proportioning by embodiment 1-8 mixes 300-2000 purpose tourmalinite, clay and suds-stabilizing agent, and the organosilicon or the organic metal salt that add corresponding proportion again are modulated to uniform tourmalinite slurry; To modulate uniform tourmalinite slurry and add in the mould, put into kiln, fire 3-5h, under the effect of suds-stabilizing agent, promptly form foamed ceramics by the thermolysis of organosilicon (or organic metal salt) and a large amount of gas of process generation of oxidation at 300-750 ℃.
Particular manufacturing craft is made tapered structure, helps the demoulding; As required, can carry out the size of adjustment hole and the size of tapering, the quantity that the quantity by regulating the mould king-rod can the free adjustment hole; Tapered structure also helps the cleaning in duct.

Claims (9)

1. one kind is used for the foamed ceramics that vehicle exhaust is handled, and it is characterized in that: described foamed ceramics is fired by organosilicon, tourmalinite, clay and suds-stabilizing agent and formed.
2. one kind is used for the foamed ceramics that vehicle exhaust is handled, and it is characterized in that: described foamed ceramics is fired by organic metal salt, tourmalinite, clay and suds-stabilizing agent and formed.
3. making method that is used for the foamed ceramics that vehicle exhaust handles, it is characterized in that: described foamed ceramics manufacture craft flow process is:
A, 300-2000 purpose tourmalinite, clay and suds-stabilizing agent are mixed, add organosilicon and be modulated to uniform tourmalinite slurry;
B, will modulate uniform tourmalinite slurry and add in the mould, put into kiln, fire 3-5h at 300-750 ℃.
4. making method that is used for the foamed ceramics that vehicle exhaust handles, it is characterized in that: described foamed ceramics manufacture craft flow process is:
A, 300-2000 purpose tourmalinite, clay and suds-stabilizing agent are mixed, add organic metal salt and be modulated to uniform tourmalinite slurry;
B, will modulate uniform tourmalinite slurry and add in the mould, put into kiln, fire 3-5h at 300-750 ℃.
5. a production is used for the particular manufacturing craft of the foamed ceramics that vehicle exhaust handles, and it is characterized in that: described particular manufacturing craft is a tapered structure, is provided with motion bar in the mould.
6. the foamed ceramics that is used for the vehicle exhaust processing according to claim 1, it is characterized in that: described organosilicon, tourmalinite, clay and suds-stabilizing agent are followed successively by by weight percentage: 10-50%, 10-25%, 35-70%, surplus.
7. the foamed ceramics that is used for the vehicle exhaust processing according to claim 2, it is characterized in that: described organic metal salt, tourmalinite, clay and suds-stabilizing agent are followed successively by by weight percentage: 20-50%, 20-40%, 25-55%, surplus.
8. describedly be used for the foamed ceramicses that vehicle exhaust is handled according to claim 2,7, it is characterized in that: described organic metal salt is be selected from organic zinc, organic-magnesium, organic iron, organoaluminum, organic titanium at least a.
9. according to claim 1,2,6, the 7 described foamed ceramicses that are used for the vehicle exhaust processing, it is characterized in that: described tourmalinite is a 300-2000 purpose powder.
CNA2007101684802A 2007-11-19 2007-11-19 Foaming ceramic for treatment of automobile exhaust as well as making method and special mold therefor Pending CN101182187A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2007101684802A CN101182187A (en) 2007-11-19 2007-11-19 Foaming ceramic for treatment of automobile exhaust as well as making method and special mold therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2007101684802A CN101182187A (en) 2007-11-19 2007-11-19 Foaming ceramic for treatment of automobile exhaust as well as making method and special mold therefor

Publications (1)

Publication Number Publication Date
CN101182187A true CN101182187A (en) 2008-05-21

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CN (1) CN101182187A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103936402A (en) * 2014-04-08 2014-07-23 安徽省亚欧陶瓷有限责任公司 Ceramic tile capable of releasing negative oxygen ions and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103936402A (en) * 2014-04-08 2014-07-23 安徽省亚欧陶瓷有限责任公司 Ceramic tile capable of releasing negative oxygen ions and preparation method thereof
CN103936402B (en) * 2014-04-08 2016-05-25 安徽省亚欧陶瓷有限责任公司 A kind of Ceramic Tiles that can releasing negative oxygen ion and preparation method thereof

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Open date: 20080521