CN101182059A - Acid bath waste liquor recovery utilizing method for production of functional viscose fiber - Google Patents
Acid bath waste liquor recovery utilizing method for production of functional viscose fiber Download PDFInfo
- Publication number
- CN101182059A CN101182059A CNA2007101140466A CN200710114046A CN101182059A CN 101182059 A CN101182059 A CN 101182059A CN A2007101140466 A CNA2007101140466 A CN A2007101140466A CN 200710114046 A CN200710114046 A CN 200710114046A CN 101182059 A CN101182059 A CN 101182059A
- Authority
- CN
- China
- Prior art keywords
- acid bath
- waste liquid
- bath waste
- viscose fiber
- functional
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000002253 acid Substances 0.000 title claims abstract description 63
- 239000000835 fiber Substances 0.000 title claims abstract description 37
- 239000002699 waste material Substances 0.000 title claims abstract description 28
- 229920000297 Rayon Polymers 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- 238000011084 recovery Methods 0.000 title 1
- 239000007788 liquid Substances 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 20
- 238000009987 spinning Methods 0.000 claims abstract description 13
- 239000006228 supernatant Substances 0.000 claims abstract description 10
- 238000004064 recycling Methods 0.000 claims abstract description 6
- 238000002425 crystallisation Methods 0.000 claims description 5
- 230000008025 crystallization Effects 0.000 claims description 5
- 238000007872 degassing Methods 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 229940037003 alum Drugs 0.000 claims description 4
- 238000000247 postprecipitation Methods 0.000 claims description 3
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 abstract description 8
- 239000007863 gel particle Substances 0.000 abstract description 4
- 239000000047 product Substances 0.000 abstract description 2
- 239000013049 sediment Substances 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 239000000499 gel Substances 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 6
- 239000005083 Zinc sulfide Substances 0.000 description 6
- 239000000084 colloidal system Substances 0.000 description 6
- 239000005077 polysulfide Substances 0.000 description 6
- 229920001021 polysulfide Polymers 0.000 description 6
- 150000008117 polysulfides Polymers 0.000 description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 description 6
- 235000011152 sodium sulphate Nutrition 0.000 description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 6
- 229960001763 zinc sulfate Drugs 0.000 description 6
- 229910000368 zinc sulfate Inorganic materials 0.000 description 6
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 6
- -1 aluminum ions Chemical class 0.000 description 5
- 239000006210 lotion Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000009970 fire resistant effect Effects 0.000 description 2
- 238000005189 flocculation Methods 0.000 description 2
- 230000016615 flocculation Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear
Abstract
The invention discloses an acid bath waste liquid recycling method of producing the functional viscose fibers. The method is to evenly mix the acid bath waste liquid of producing the functional viscose fibers containing residual functional aids after being added with aluminum sulfate solution, the volume and the concentration of which are respectively 1-40 percent of the acid bath waste liquid and 20-200g/l. Then through 15-18 hours of standing and sediment, supernatant is filtered and prepared to be used in the acid bath circulation of the viscose fiber spinning production. The invention is the acid bath waste liquid recycling method of producing the functional viscose fibers, which can effectively remove gel particles in the acid bath waste liquid to ensure the recycling of the acid bath and improve the fiber product quality.
Description
Technical field
The present invention relates to the treatment process that a kind of trade effluent is recycled, especially relate to a kind of acid bath waste liquid recoverying and utilizing method of producing functional viscose fiber.
Background technology
The production of functional viscose fiber at present mainly contains two kinds of methods: a kind of is additive process (blending method), is that functional aid is added to before spinning in the spinning solution, makes the viscose fiber with specific function through spinning again; Another kind is a coating, generally is to make back or (when fiber is in gel state) in process of production at fiber, functional aid is coated to fiber surface, thereby gives specific function of fiber and purposes.Because additive process is easy and simple to handle, and give fiber nonvolatil specific function, thereby use more in the reality.Owing to be added with this new component of functional aid in the spinning solution, as the flame retardant aid when producing fire-retardant fibre or produce the fungi-proofing auxiliary agent etc. of health fiber, when fiber is shaped in acid bath, these functional aids are constantly mutual diffusion mutually in spinning solution and acid bath two phase systems, finally can make part of auxiliary diffuse into acid bath, they combine with colloid sulphur, polysulfide, zinc sulphide, sour mud etc. in the acid bath and form a lot of short grained gels.These short grained gels make that suspended substance increases in the acid bath, the acid bath transparency descends, the influence of having brought not only for the solidification forming of fiber, cause the strand broken end to increase, original stability of acid bath system and balance have also been changed, brought great influence for the circulation allotment use of acid bath, the method that present people are adopted just adopts and will contain and auxiliary agent bonded colloid sulphur, polysulfide, zinc sulphide, the acid bath waste liquid of small-particle gels such as acid mud filters the back allotment to be reused for the mode of production, but the acid bath waste liquid inner gel particle removal after adopting this kind mode to handle is unclean, the composition instability, the circulation allotment that has influenced acid bath is used, and this all affects greatly for serialization production and the final product quality that spins out fiber.
Summary of the invention
Technical problem to be solved by this invention has provided a kind of recycle that can effectively remove the interior gel particle of acid bath waste liquid with the assurance acid bath, thereby guarantees the serialization of production and the acid bath waste liquid recoverying and utilizing method of the production functional viscose fiber of raising fibrous finished product quality.
The acid bath waste liquid recoverying and utilizing method of this production functional viscose fiber, for mixing at the alum liquor that in the acid bath waste liquid of the production functional viscose fiber that contains residual functional aid, adds to acid bath waste liquid volume 1-40%, Tai-Ace S 150 is as flocculation agent, aluminum ions throwing out by aluminum sulfate hydrolysis, with in the acid bath with auxiliary agent bonded colloid sulphur, polysulfide, zinc sulphide, the big gel particles of the coalescent formation of small-particle gel such as acid mud, leave standstill through 15-18h then, post precipitation, with supernatant liquid filtering after allotment be fit to be produced promptly can be used for after the required standard going in the acid bath circulation of viscose fiber spinning in producing.In order to improve filter effect, can adopt diatomite or polypropylene tow filter that the supernatant liquor of post precipitation is carried out high efficiency filter.
Alum liquor concentration 20-200g/L wherein.
And in order further to improve the treatment effect of acid bath waste liquid, supernatant liquor after filtration through the degassing, evaporation, crystallization, allocate, refilter, heat and be used further in the acid bath circulation that viscose fiber produces, remove waste gas and the redundant moisture that contains by the degassing and evaporation, and remove the unnecessary vitriol that generates because of reaction by crystallization, by heating to adapt to the production temperature requirement of acid bath.
Because each composition is to the influence of the solidification forming of fiber in the viscose fiber spinning acid bath, and to the by product colloid sulphur in functional aid and the acid bath in the acid bath waste liquid, polysulfide, zinc sulphide, the influence of the small-particle gel throwing out that acid mud forms, the present invention adopted the Tai-Ace S 150 less to fiber-forming influence, because the influence that aluminum ion is shaped to rayon spinning is far smaller than sodium ion and zine ion in the acid bath, so remove the by product colloid sulphur in the functional aid and acid bath in the acid bath waste liquid as flocculation agent adopting an amount of Tai-Ace S 150, polysulfide, zinc sulphide, under the situation of the small-particle gel that acid mud forms, influence to acid bath is minimum, and the throwing out that aluminum ion is extremely strong, also make the by product colloid sulphur in the functional aid and acid bath in the acid bath waste liquid, polysulfide, zinc sulphide, the small-particle gel that acid mud forms is condensed into the shallow lake layering rapidly and is easy to remove, and effective ingredient then continues to participate in circulation through filtering the back again, use.This method not only has characteristics easy and simple to handle, that add-on is few, and it is few also to have a new component of bringing into, makes every indexs such as transparency of acid bath excellent more, stable, is of value to the raising and the continual and steady round-robin advantage of acid bath of fiber interior quality.Under normal situation, the transparency of handling through this method that contains the functional aid acid bath can be by the 20-200cm before handling, and reaches the 400-600cm after the processing, the recycling that has effectively guaranteed to produce the acid bath waste liquid of functional viscose fiber.
Embodiment
Embodiment one
Get and contain the residual acid bath waste liquid 600mL that flame retardant is arranged after the production Fire resistant viscose fiber, it contains sulfuric acid 126.38g/L, zinc sulfate 15.36g/L, sodium sulfate 334g/L, body lotion transparency 30cm, add the Tai-Ace S 150 20mL of 50g/L, make it to mix and then leave standstill 17h, solution natural sedimentation layering, getting supernatant liquid filters at diatomaceous earth filter, get body lotion sulfur acid 120.35g/L, zinc sulfate 14.43g/L, sodium sulfate 321.16g/L, proportion 1.264,30 ℃ of temperature, transparency 440cm allocates obtaining qualified spinning acid bath afterwards again.
Embodiment two
Get and contain the residual acid bath waste liquid 1500mL that flame retardant is arranged after the production Fire resistant viscose fiber, it contains sulfuric acid 107.42g/L, zinc sulfate 31.19g/L, sodium sulfate 342.15g/L, body lotion transparency 86cm, the Tai-Ace S 150 60mL that adds 100g/L, make it to mix and then leave standstill 15h, solution natural sedimentation layering is got supernatant liquid and is filtered at the diatomite high efficiency filter, remove the bottom precipitation, each component concentration of assay body lotion: sulfuric acid 104.34g/L, zinc sulfate 28.34g/L, sodium sulfate 313.08g/L, transparency 535cm allocates afterwards again, the degassing, evaporation, crystallization, filter, heating obtains qualified spinning acid bath.
Embodiment three
Get to contain and produce the residual acid bath waste liquid 1200mL that fungi-proofing auxiliary agent is arranged behind the health care viscose fiber, it contains sulfuric acid 113.75g/L, zinc sulfate 16.42g/L, sodium sulfate 310.21g/L, body lotion transparency 180cm, the Tai-Ace S 150 50mL that adds 180g/L, make it to mix and then leave standstill 18h, solution natural sedimentation layering is got supernatant liquid and is filtered at the polypropylene tow filter, remove the bottom precipitation, filter back supernatant liquor sulfur acid 105.38g/L, zinc sulfate 31.68g/L, sodium sulfate 338.16g/L, transparency 600cm is through the degassing, evaporation, crystallization, allotment, refilter, heating obtains qualified spinning acid bath.
Claims (3)
1. produce the method for the acid bath waste liquid recycling of functional viscose fiber, it is characterized in that: the alum liquor that adds acid bath waste liquid volume 1-40% in this acid bath waste liquid mixes, process 15-18h leaves standstill, post precipitation, with supernatant liquid filtering, after allotment, promptly can be used for the viscose fiber spinning then and produce.
2. the method that the acid bath waste liquid of production functional viscose fiber as claimed in claim 1 is recycled is characterized in that: described alum liquor concentration 20-200g/L.
3. the method that the acid bath waste liquid of production functional viscose fiber as claimed in claim 1 or 2 is recycled is characterized in that: behind the described supernatant liquid filtering through the degassing, evaporation, crystallization, allocate, refilter and heat after be used further to the production of viscose fiber.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710114046A CN100575576C (en) | 2007-11-08 | 2007-11-08 | Produce the method for the acid bath waste liquid recycling of functional viscose fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710114046A CN100575576C (en) | 2007-11-08 | 2007-11-08 | Produce the method for the acid bath waste liquid recycling of functional viscose fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101182059A true CN101182059A (en) | 2008-05-21 |
| CN100575576C CN100575576C (en) | 2009-12-30 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710114046A Active CN100575576C (en) | 2007-11-08 | 2007-11-08 | Produce the method for the acid bath waste liquid recycling of functional viscose fiber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100575576C (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102380252A (en) * | 2011-08-02 | 2012-03-21 | 山东雅美科技有限公司 | Backwashing water discharge reduction method of tow filter |
| CN102409434A (en) * | 2011-09-26 | 2012-04-11 | 宜宾海丝特纤维有限责任公司 | Method for treating secondary waste viscose |
| CN102586954A (en) * | 2012-01-09 | 2012-07-18 | 成都丽雅纤维股份有限公司 | Process for recovering waste rubber in viscose production |
| CN104086011A (en) * | 2014-07-07 | 2014-10-08 | 成都丽雅纤维股份有限公司 | Zero discharge process suitable for waste water of viscose fiber industrial acid station |
| CN104445447A (en) * | 2014-10-20 | 2015-03-25 | 宜宾丝丽雅股份有限公司 | Treatment device for acid sewage generated in viscose staple fibre treatment |
| CN107740207A (en) * | 2017-09-27 | 2018-02-27 | 唐山三友集团兴达化纤有限公司 | A kind of preprocess method of viscose rayon acid waste water |
| CN110127962A (en) * | 2019-06-28 | 2019-08-16 | 南通大恒环境工程有限公司 | A kind of processing method of the waste water containing glue |
-
2007
- 2007-11-08 CN CN200710114046A patent/CN100575576C/en active Active
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102380252A (en) * | 2011-08-02 | 2012-03-21 | 山东雅美科技有限公司 | Backwashing water discharge reduction method of tow filter |
| CN102380252B (en) * | 2011-08-02 | 2013-11-27 | 山东雅美科技有限公司 | Backwashing water discharge reduction method of tow filter |
| CN102409434A (en) * | 2011-09-26 | 2012-04-11 | 宜宾海丝特纤维有限责任公司 | Method for treating secondary waste viscose |
| CN102409434B (en) * | 2011-09-26 | 2013-09-25 | 宜宾海丝特纤维有限责任公司 | Method for treating secondary waste viscose |
| CN102586954A (en) * | 2012-01-09 | 2012-07-18 | 成都丽雅纤维股份有限公司 | Process for recovering waste rubber in viscose production |
| CN102586954B (en) * | 2012-01-09 | 2014-06-11 | 成都丽雅纤维股份有限公司 | Process for recovering waste rubber in viscose production |
| CN104086011A (en) * | 2014-07-07 | 2014-10-08 | 成都丽雅纤维股份有限公司 | Zero discharge process suitable for waste water of viscose fiber industrial acid station |
| CN104086011B (en) * | 2014-07-07 | 2016-02-10 | 成都丽雅纤维股份有限公司 | Be applicable to the technique of zero discharge of viscose fibre industry acid station waste water |
| CN104445447A (en) * | 2014-10-20 | 2015-03-25 | 宜宾丝丽雅股份有限公司 | Treatment device for acid sewage generated in viscose staple fibre treatment |
| CN104445447B (en) * | 2014-10-20 | 2016-08-24 | 宜宾丝丽雅股份有限公司 | A kind of short rayon fiber sour water processing means |
| CN107740207A (en) * | 2017-09-27 | 2018-02-27 | 唐山三友集团兴达化纤有限公司 | A kind of preprocess method of viscose rayon acid waste water |
| CN110127962A (en) * | 2019-06-28 | 2019-08-16 | 南通大恒环境工程有限公司 | A kind of processing method of the waste water containing glue |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100575576C (en) | 2009-12-30 |
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Effective date of registration: 20151225 Address after: Dragon Road, 261100 Shandong city of Weifang province Hanting District No. 1825 Building No. 89 Patentee after: Constant day dragon (Weifang) new material Co., Ltd. Address before: Dragon Road, 261100 Shandong city of Weifang province Hanting District No. 555 Patentee before: Shandong Hailong Co., Ltd. |
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Effective date of registration: 20211229 Address after: 261106 north of Xinsha Road, Guti street, Hanting District, Weifang City, Shandong Province Patentee after: Weifang Xinlong biomaterials Co.,Ltd. Address before: 261100 building 89, 1825 Hailong Road, Hanting District, Weifang City, Shandong Province Patentee before: HENGTIAN HAILONG (WEIFANG) NEW MATERIALS CO.,LTD. |