CN101176444B - Material for joss stick - Google Patents
Material for joss stick Download PDFInfo
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- CN101176444B CN101176444B CN200710136045.1A CN200710136045A CN101176444B CN 101176444 B CN101176444 B CN 101176444B CN 200710136045 A CN200710136045 A CN 200710136045A CN 101176444 B CN101176444 B CN 101176444B
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- Prior art keywords
- joss stick
- tea
- powder
- line spices
- slag
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- 239000000463 material Substances 0.000 title claims description 40
- 244000269722 Thea sinensis Species 0.000 claims abstract description 64
- 239000000843 powder Substances 0.000 claims abstract description 50
- 235000013616 tea Nutrition 0.000 claims abstract description 43
- 239000002893 slag Substances 0.000 claims abstract description 42
- 239000000077 insect repellent Substances 0.000 claims abstract description 23
- 235000009569 green tea Nutrition 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 235000013599 spices Nutrition 0.000 claims description 48
- 238000000605 extraction Methods 0.000 claims description 24
- 240000006313 Alternanthera bettzickiana Species 0.000 claims description 13
- 235000014138 Caesalpinia decapetala Nutrition 0.000 claims description 13
- 239000002023 wood Substances 0.000 abstract description 15
- 238000000855 fermentation Methods 0.000 abstract description 9
- 239000002728 pyrethroid Substances 0.000 abstract description 7
- 230000000749 insecticidal effect Effects 0.000 abstract description 5
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 abstract description 5
- 241000255925 Diptera Species 0.000 abstract description 4
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- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 abstract description 2
- 229940070846 pyrethrins Drugs 0.000 abstract description 2
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- 230000002940 repellent Effects 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract 4
- 230000000391 smoking effect Effects 0.000 abstract 2
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- 230000000694 effects Effects 0.000 description 19
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- 238000002485 combustion reaction Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- -1 methoxy benzyl Flumethrin Chemical compound 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000010298 pulverizing process Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical class C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 3
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 description 3
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- FDZZZRQASAIRJF-UHFFFAOYSA-M malachite green Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](C)C)C=C1 FDZZZRQASAIRJF-UHFFFAOYSA-M 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 235000020333 oolong tea Nutrition 0.000 description 3
- SMKRKQBMYOFFMU-UHFFFAOYSA-N prallethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OC1C(C)=C(CC#C)C(=O)C1 SMKRKQBMYOFFMU-UHFFFAOYSA-N 0.000 description 3
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 3
- 238000011160 research Methods 0.000 description 3
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- SFHVXKNMCGSLAR-UHFFFAOYSA-N 2,2,3,3-tetramethylcyclopropanecarboxylic acid Chemical compound CC1(C)C(C(O)=O)C1(C)C SFHVXKNMCGSLAR-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 240000008375 Hymenaea courbaril Species 0.000 description 2
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- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 240000004460 Tanacetum coccineum Species 0.000 description 2
- 244000299461 Theobroma cacao Species 0.000 description 2
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- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
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- 238000005516 engineering process Methods 0.000 description 2
- 235000019225 fermented tea Nutrition 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- BGOFCVIGEYGEOF-UJPOAAIJSA-N helicin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=CC=CC=C1C=O BGOFCVIGEYGEOF-UJPOAAIJSA-N 0.000 description 2
- 239000010903 husk Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 229940015367 pyrethrum Drugs 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 2
- LZHCVNIARUXHAL-UHFFFAOYSA-N 2-tert-butyl-4-ethylphenol Chemical compound CCC1=CC=C(O)C(C(C)(C)C)=C1 LZHCVNIARUXHAL-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- 241000256118 Aedes aegypti Species 0.000 description 1
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- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000256135 Chironomus thummi Species 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000633318 Culex pipiens molestus Species 0.000 description 1
- 241000256057 Culex quinquefasciatus Species 0.000 description 1
- 241000256060 Culex tritaeniorhynchus Species 0.000 description 1
- 244000050510 Cunninghamia lanceolata Species 0.000 description 1
- 244000301850 Cupressus sempervirens Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- FSYXMFXBRJFYBS-UHFFFAOYSA-N Furamethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=CC=C(CC#C)O1 FSYXMFXBRJFYBS-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 241000257162 Lucilia <blowfly> Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000304160 Sarcophaga carnaria Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000255632 Tabanus atratus Species 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- KVIZNNVXXNFLMU-AIIUZBJTSA-N [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl (1r,3r)-2,2-dimethyl-3-[(e)-prop-1-enyl]cyclopropane-1-carboxylate Chemical compound FC1=C(F)C(COC)=C(F)C(F)=C1COC(=O)[C@H]1C(C)(C)[C@@H]1\C=C\C KVIZNNVXXNFLMU-AIIUZBJTSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
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- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
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- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 235000020688 green tea extract Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
- Seasonings (AREA)
Abstract
The invention aims to provide a useful substrate for joss stick, which is provided with stable supply and economical performance and good mechanical forming applicability, has the physical properties when smoking to improve the volatilization rate of the pyrethroids which is used as the insecticidal components, has no stimulation, peculiar smell and others when smoking, has the conditions as substrate for joss stick, and can be used to extract slag powder and wood powder instead of pyrethrins. The invention obtains the powder through drying and grinding the extracting slag which contains green tea or/and half-fermentation tea and belongs to one part of the raw materials, and supplies a substrate for joss stick which can solve the above subject and supplies mosquito repellent joss stick or flies repellent joss stick and other joss sticks adopting the above substrate.
Description
Technical field
The present invention relates to the improvement of material for joss stick.
Background technology
Mosquito repellent line spices, as the insecticide of the adult for driving away mosquito, were just looked at by the parent of people institute in the past as far back as 100 years, were to use match to keep spatial manipulation for a long time until after-flame, and effect is stable, very rational desinsection form.In 1902, day the present invention screw type mosquito repellent line spices, its raw material is the powder (60～80%) that contains dry pyrethrum flower and the mixed powder as the powder (20～40%) of the leaf of the Nan Shu (タ Block) of binding agent, add wherein water to mix, make helical form, be dried and manufacture.This line spices are used by people as the necessity of malaria countermeasure in World War II thereafter.
On the other hand, by the chemical constitution of the insecticidal constituent (pyrethrin) that contains in clear and definite dry pyrethrum flower, developed the synthetic pyrethroid with similar structures.Wherein, at the allethrin of nineteen forty-seven invention, there is the chemical constitution being similar to very much with pyrethrin, at nineteen fifty-three, this allethrin, in Japan and the U.S., realize industrialization, be used as the active ingredient of mosquito repellent line spices.
As the base material of mosquito repellent line spices, all the time, wood powder, Dalmatian chrysanthemum extraction slag etc. occupies its major part.Dalmatian chrysanthemum is extracted ground-slag end in when burning, stimulate, peculiar smell is few, in addition, mediating, extrude, stamping procedure has mechanical-moulded adaptability, is the raw material as material for joss stick excellence.But, Dalmatian chrysanthemum extract (extracts) need to turn to synthetic pyrethroid, therefore the output of ground-slag also significantly reduces, and considers stable supplying aspect, when a large amount of mosquito repellent line spices of producing stabilizing qualities, its usage amount is limited.
On the other hand, about the wood powder of pine, China fir, Japan cypress etc., that secondary raw wood chip, fragment when the lumbering of timber are pulverized to the powder forming, therefore cheap, but along with the difference of the position of the kind of raw material timber, the place of production, the age of tree, tree, manufacturing procedure etc., the character of its powder produces various variations, is therefore not easy to obtain the product of stabilizing quality.Find in addition, if only modulate line spices with the raw material of wood powder and binding agent, the physical behavior of line spices becomes fine and close, and the volatility of active ingredient reduces, and in desinsection effect, is wanting in.And then, the in the situation that of a large amount of use wood powder, in the time of may appearing at burning, produce stimulation, peculiar smell, or the too much problem of the amount of being fuming.
Therefore, people attempt exploring Dalmatian chrysanthemum and extract slag, wood powder mosquito repellent material for joss stick in addition, in addition, as mosquito repellent material for joss stick, need to meet following each condition.
(1) bring into play to greatest extent active ingredient effect,
(2) cheapness and stably supply,
(3) mediating, extrude, stamping procedure has excellent mechanical-moulded adaptability,
(4) line spices of manufacturing when burning can not have after-flame just to extinguish and can be easily adjusted into burning time about 7 hours,
(5) when fumigation, do not stimulate and do not produce peculiar smell.
For example, in examined patent publication 46-27839 communique (patent documentation 1), the lupulus (hop) that has proposed to use ale to brewage middle use is squeezed disintegrating slag, in examined patent publication 61-11921 communique (patent documentation 2), propose to coordinate the fermentation residue powder of sweet potato, and then in examined patent publication 61-23762 communique (patent documentation 3), proposed to use the dried powder etc. of the leaf of locust tree.But present situation is that any all can not fully meet above-mentioned condition, allows to practicality, also can only coordinate a small amount of.
In addition, in recent years, although fly in city, occur reducing, in fishing village, the periphery of Yu Jie class processing factory, destructor plant, animal house, hen house etc., than more serious in the past situation increase.As its countermeasure, the Shoofly joss stick that spatial manipulation is used need increase, be not only mosquito repellent line spices, including Shoofly joss stick, also require research base material.
But, for the application in the online perfume base material of cormophytes of tea etc., for example, in patent documentation 2, recorded it and can be used as combustion adjuvant.But, very high for the cost of the comminuted powder of the tealeaves self of tea-bag purposes at that time, there is special peculiar smell, even therefore as line spices base material, also can only coordinate on a small quantity, the kind based on tea, proterties etc. are not carried out research especially to its applicability.In recent years, as tea beverage, the use of tea-bag reduces, and is filled in PET bottle and with the extraction tea that automatic vending machine is sold and is popularized, and accompanies therewith, and the extraction slag of tea can obtain at an easy rate as trade waste.The present inventors, in view of this present situation, are conceived to effective utilization of the extraction slag of tea, and research is applied to material for joss stick.
[patent documentation 1] examined patent publication 46-27839 communique
[patent documentation 2] examined patent publication 61-11921 communique
[patent documentation 3] examined patent publication 61-23762 communique
Summary of the invention
The object of the present invention is to provide a kind of following condition as material for joss stick that possesses,, stable supplying, economy and mechanical-moulded applicability excellence, do not produce stimulation, peculiar smell etc. can improve while possessing fumigation as the physical behavior of the volatility of the pyrethroid of insecticidal constituent and fumigation time, can replace Dalmatian chrysanthemum to extract the useful material for joss stick of slag, wood powder.
That is,, in order to solve above-mentioned problem, the present invention adopts following formation.
(1) material for joss stick, as a part for raw material, contains the extraction slag of green tea and/or semi-fermented tea is dry, pulverizing obtains powder.
(2) material for joss stick of recording as (1), 5～50 quality % that the use level of above-mentioned powder is whole raw materials.
(3) material for joss stick of recording as (1), above-mentioned powder is the powder that extraction slag is dry, pulverizing obtains of green tea and semi-fermented tea, the powder that contains more than 10% semi-fermented tea.
(4) line spices, the material for joss stick described in contain in a part for raw material (the 1)～any one of (3).
(5) line spices of recording as (4), is characterized in that, line spices are mosquito repellent line spices or Shoofly joss stick.
Embodiment
Above-mentioned (1) of the present invention has following feature: select the extraction slag of green tea and/or semi-fermented tea to be dried, to pulverize obtained powder as material for joss stick.
Tea is broadly divided into green tea (azymic tea), semi-fermented tea and fermented tea 3 kinds, and the degree of carrying out according to the oxidative fermentation of the catechu acids of the last stage manufacturing, tealeaves is classified.
Green tea (azymic tea) is that the method by steaming, fry, boil tealeaves etc. is processed in the initial oxidasic effect that suppresses leaf, according to the difference in processing method, the place of production etc., is divided into and simmers tea, is preced with tea, beautiful dew, kind tea etc.
In addition, when semi-fermented tea is few by first tea shoot being shone under sunshine, raising tealeaves temperature, the amount of the fragrance ingredient containing increase tea shoot under the effect of leaf endoenzyme in, then completes with pan-roasting tea bud, is used straight fire or heated-air drying to manufacture.In semi-fermented tea, have the Paochung tea of the catechu acids mild oxidation fermentation of tealeaves and extremely moderate Oolong tea of oxidative fermentation.The former Paochung tea has advantages of and sends high fragrance, mainly in Taiwan, manufactures, and on the other hand, the latter's Oolong tea is poorer than the former aspect aromaticity, but flavour is dense, is China's Mainland and Taiwan main product.
The present inventors find first, the extraction slag of green tea and semi-fermented tea can obtain at an easy rate, characteristic taste than the comminuted powder of tealeaves itself is few, and then with the raw material ratio of only having wood powder, can modulate the more line spices of porous, therefore be conducive to the raising of the volatility of active ingredient etc., meet the condition as above-mentioned material for joss stick, thereby completed the present invention.Can be the extraction slag of green tea and semi-fermented tea to be dried, to pulverize the mixing that the powder of acquisition is obtained by mixing extract ground-slag (below, by as described above by extract slag be dried, pulverize acquisition powder referred to as " extraction ground-slag "), by containing more than 10% semi-fermented tea powder, also can play the stimulation of the base material that reduces other kind, the effect of peculiar smell, therefore the use form of above-mentioned (2) is preferred.
The use level of the extraction ground-slag of green tea and/or semi-fermented tea in line spices, can consider kind, the purposes of line spices, the state of supply of raw material etc., in the scope of 5～50 quality %, suitably determines.
In addition, fermented tea (black tea) is tealeaves complete fermentation, when kneading, carries out dry tea, can confirm, it extracts ground-slag and does not resemble the extraction ground-slag of green tea and/or semi-fermented tea and be suitable as line spices base material.Its clear and definite reason is not clear, but can think that this is relevant to the catechu acids complete oxidation fermentation of tealeaves.
Consider desinsection effect to target pest, economy etc., coordinated mosquito repellent line spices, the Shoofly joss stick of material for joss stick of the present invention, the active ingredient that contains 0.01～0.5 quality % left and right.As this active ingredient, with allethrin, prallethrin (prallethrin), pyrethrin, PH (furamethrin), transfluthrin (transfluthrin), methoxy benzyl Flumethrin (Metofluthrin), Prallethrin, 2,2,3,3-tetramethyl cyclopropane-carboxylic acid 4-methoxy-2,3,5, the various pyrethroid insecticidal constituents of 6-ptfe benzyl ester (being called compd A below) etc. or their isomer are arbitrarily advisable, but are not limited to this.
In addition, above-mentioned line spices are preferred, as synergist, with respect to active ingredient amount, coordinate that 0.1 times of amount is above, preferred 2.0 times of N-(2-ethylhexyl)-dicyclos [2 more than amount, 2,1]-heptan-5-alkene-2,3-dicarboximide (being called synergist A below).This be because, in the situation that synergist A and active ingredient are used in combination in right amount, active ingredient is carried out a kind of steam distillation together with the water containing in line spices, synergist A, the most effectively volatilize, increase diffusion, mutually auxiliary with the effect enhancing effect of Entomological Physiology, bring into play significant synergy.
As the material coordinating together with material for joss stick of the present invention, there are binding agent and other combustion adjuvant, the former binding agent can list nanmu tree powder (タ Block powder), starch, methylcellulose, carboxymethyl cellulose etc.In addition, as other combustion adjuvant of the latter, can illustrate Dalmatian chrysanthemum and extract the inorganic powder etc. of the vegetalitas powder of the dried powder of the leaf of the epidermis powder of ground-slag, wood powder, citrus, locust tree, cocoa husk powder etc. and diatomite, zeolite, furnace lining (brasque) etc.
In above-mentioned line spices, as required, can contain pigment, preservative, stabilizing agent etc.As pigment, can list the organic dyestuff such as such as malachite green, as preservative, representational is for example the acid of sorbic acid, dehydroactic acid and P-hydroxybenzoic acid etc. or their salt etc.In addition, as stabilizing agent, can list 2,6-di-tert-butyl-4-methy phenol (BHT), 2,2 '-methylene two (4-ethyl-6-tert-butyl phenol) etc., but be not limited to these.
And then, only otherwise overslaugh action effect of the present invention, also can mixed bactericide, antibacterial agent, repellent or aromatic, deodorant etc., obtain many objects composition of effect excellence.
When the line spices of material for joss stick of the present invention have been used in modulation, without any need for special technology, can adopt known manufacture method.For example, the line spices base material of pre-mix powder (active ingredient, synergist etc. are included in a part for combustion adjuvant) and surplus is mixed, add water to carry out mixing, then, utilize extruder, stamping machine to carry out after moulding, dry, make mosquito repellent line spices or Shoofly joss stick.In addition, also can only use line spices base material to carry out after moulding, spray wherein or aqua that coating contains active ingredient etc.
The line spices of material for joss stick of the present invention have been used, the fly class of mosquito class to Culex pipiens pallens, Culex tritaeniorhynchus (Culextritaeniorhyncus), Culex quinquefasciatus, Aedes aegypti, malarial mosquito, Culex molestus etc., housefly, lucilia, flesh fly, moth fly, fruit bat etc. shows remarkable effect, certainly, also effective to cockroach, the within doors sanitary insect pest of dirt mite class etc. or the various pests of midge, horsefly etc., its practicality is very high.
Embodiment 1
By dl, d-T80-allethrin (0.3 part) and synergist A (0.6 part) evenly mix with 99.1 parts of line spices base materials (green tea extracts 10 parts of ground-slags, Oolong tea extracts the mixed powder that the binding agents such as 10 parts of ground-slags, 25 parts of ground-slags of Dalmatian chrysanthemum extraction, 32 parts of wood powders and nanmu tree powder, starch form), then add the water that contains colouring agent and preservative, use known method, obtain mosquito repellent line spices of the present invention.
Embodiment 2
By compd A (0.15 part) and synergist A (0.3 part) and 2,0.1 part of 6-di-tert-butyl-4-methy phenol is evenly mixed into 99.45 parts (Paochung tea extracts the mixed powders of the compositions such as 25 parts of ground-slags, 20 parts, cocoa husk powder, 30 parts of wood powders, nanmu tree powder, starch) evenly mix after, add the water that contains preservative, use known method, obtain Shoofly joss stick of the present invention.
Embodiment 3
According to embodiment 1, the mosquito repellent line spices of prescription shown in modulomenter 1.
That is, at line spices except malachite green, with in 100 parts of mixed powders, add 100 parts, the water of the malachite green that contains colouring agent and preservative, fully mediate, then by known method, obtain spiral helicine mosquito repellent line spices.
[table 1]
Each mosquito repellent line spices of manufacturing according to table 1, the measurement result of each characteristic is shown in table 2.
In addition, the desinsection effect of mosquito repellent line spices and fumigation time are evaluated according to following benchmark.
[at 25m
3room in practical effect test]
The 25m closing
3room in put into 100 female Culex pipiens pallens adults, then the central authorities in room place lighted for examination mosquito repellent line spices (modulating according to embodiment 1 or embodiment 2).Expose 2 hours, number go out through time fall and face upward the female Culex pipiens pallens turning over and become borer population, obtain KT
50value.
During [fumigation time]: > 7 hours 30 minutes, note is done length; In the time of 6 hours 30 minutes～7 hours 30 minutes, note is done standard; During < 6 hours 30 minutes, note is done short.
[table 2]
The result of each test shows, the mosquito repellent line spices of the powder that extraction slag is dry, pulverizing obtains of green tea and/or semi-fermented tea in material for joss stick, have been used, compared with comparative example, desinsection effect, mechanical-moulded applicability, the characteristic of fumigation time on an equal basis or more excellent, also do not stimulate during fumigation, the problem of characteristic taste.In addition, the present invention 4 line spices, by coordinating synergist A, can confirm that significant desinsection effect strengthens.Therefore, the extraction ground-slag of green tea and/or semi-fermented tea, can be as there being the Dalmatian chrysanthemum of worry to extract the substitute of ground-slag aspect the stable supplying of raw material.
On the other hand, as shown in comparative example 1, if want to replace Dalmatian chrysanthemum to extract ground-slag with wood powder etc., can not avoid increasing the amount of binding agent, it is fine and close that line spices become, and active ingredient volatility reduces, and causes desinsection effect to reduce.In addition, as the extraction ground-slag of the black tea of complete fermentation tea, as shown in comparative example 2, there is characteristic taste, as material for joss stick, do not there is the such applicability of extraction ground-slag of green tea and/or semi-fermented tea.In addition, green tea comminuted powder, can, for beverage, therefore as material for joss stick, be wanting in economy, is difficult to practical.
Embodiment 4
According to embodiment 2, the Shoofly joss stick of the prescription shown in modulomenter 3.
That is, to line spices, with adding 100 parts, the water that contains preservative in 100 parts of mixed powders, after fully mediating, obtain spiral helicine Shoofly joss stick by known method.
[table 3]
*compd A: 2,2,3,3-tetramethyl cyclopropane-carboxylic acid 4-methoxy-2,3,5,6-ptfe benzyl ester
Each Shoofly joss stick of manufacturing according to table 3, the measurement result of each characteristic is as shown in table 4.In addition, the benchmark of fumigation time is same with mosquito repellent line spices.
[at 25m
3room in practical effect test]
The 25m closing
3room in put into 100 female adult houseflies, then the central authorities in room place lighted for examination Shoofly joss stick (modulating according to embodiment 2).Expose 3 hours, number go out through time fall and face upward the female adult housefly number turning over, obtain KT
50value.
[table 4]
The result of each test shows, in material for joss stick, used the Shoofly joss stick of the powder that extraction slag is dry, pulverizing obtains of green tea and/or semi-fermented tea, compared with comparative example, desinsection effect, mechanical-moulded applicability, the characteristic of fumigation time on an equal basis or more excellent, also do not stimulate during fumigation, the problem of characteristic taste.Therefore, the extraction ground-slag of green tea and/or semi-fermented tea, can be as there being the Dalmatian chrysanthemum of worry to extract the substitute of ground-slag aspect the stable supplying of raw material.
On the other hand, the same with the situation of the mosquito repellent line spices of embodiment 3, as shown in comparative example 1, if want to replace Dalmatian chrysanthemum to extract ground-slag with wood powder etc., can not avoid increasing the amount of binding agent, it is fine and close that line spices become, active ingredient volatility reduces, and causes desinsection effect to reduce.In addition, as the extraction ground-slag of the black tea of complete fermentation tea, as shown in comparative example 2, there is characteristic taste, as material for joss stick, do not there is the such applicability of extraction ground-slag of green tea and/or semi-fermented tea.
Material for joss stick of the present invention, stable supplying, economy and mechanical-moulded applicability excellence and can improve the physical behavior as the volatility of the pyrethroid of insecticidal constituent while possessing fumigation, and when fumigation, do not stimulate, peculiar smell etc., possesses the condition as material for joss stick, can replace pyrethrins to extract slag, wood powder, therefore its practicality is very high.
Industry utilizability
The present invention, in the manufacture realm of sale of mosquito repellent line spices, Shoofly joss stick, just can apply soon.
Claims (5)
1. a material for joss stick, is characterized in that, the extraction slag of green tea and/or semi-fermented tea is dried, pulverizes 5～50 quality % that the use level of obtained powder is whole raw materials.
2. material for joss stick according to claim 1, is characterized in that, the extraction slag of green tea or semi-fermented tea is dried, pulverizes 20～50 quality % that the use level of obtained powder is whole raw materials.
3. material for joss stick according to claim 1, is characterized in that, the extraction slag of green tea and semi-fermented tea is dried, pulverizes 5～25 quality % that the use level of obtained powder is whole raw materials.
4. line spices, is characterized in that, contain the material for joss stick described in any one of claim 1～3 in a part for raw material.
5. line spices according to claim 4, is characterized in that, line spices are mosquito repellent line spices or Shoofly joss stick.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006302688 | 2006-11-08 | ||
| JP302688/2006 | 2006-11-08 | ||
| JP120666/2007 | 2007-05-01 | ||
| JP2007120666A JP4368904B2 (en) | 2006-11-08 | 2007-05-01 | Incense base material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101176444A CN101176444A (en) | 2008-05-14 |
| CN101176444B true CN101176444B (en) | 2014-05-07 |
Family
ID=39402990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710136045.1A Expired - Fee Related CN101176444B (en) | 2006-11-08 | 2007-07-13 | Material for joss stick |
Country Status (3)
| Country | Link |
|---|---|
| JP (2) | JP4368904B2 (en) |
| CN (1) | CN101176444B (en) |
| HK (1) | HK1119525A1 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5753387B2 (en) * | 2011-01-12 | 2015-07-22 | 大日本除蟲菊株式会社 | Mosquito coils and pest control method using the same |
| CN103654253B (en) * | 2012-09-21 | 2015-10-28 | 林国隆 | Nanju peel can be reduced or remitted stick the component prescription of the perfume (or spice) of powder consumption and manufacture the method for this perfume (or spice) |
| CN104430320A (en) * | 2014-12-17 | 2015-03-25 | 杭州家得好日用品有限公司 | Mosquito-repellent incense and production method thereof |
| CN106618128A (en) * | 2016-12-02 | 2017-05-10 | 江凯 | Green environmental protection joss stick and its preparation method thereof |
| CN117099796A (en) * | 2019-07-01 | 2023-11-24 | 大日本除虫菊株式会社 | Continuous mosquito coil |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5620508A (en) * | 1979-07-28 | 1981-02-26 | Lion Corp | Incense stick |
| JP3036949B2 (en) * | 1992-01-31 | 2000-04-24 | 日本デルモンテ株式会社 | Production method of tea extract |
| JPH11139917A (en) * | 1997-10-31 | 1999-05-25 | Nippon Doubutsu Yakuhin Kk | Mosquito-repellent incense for animal |
| AU2000273123A1 (en) * | 2000-09-13 | 2002-03-26 | Seiko Sato | Composition for manufacturing formed article comprising starch, pulverized plantfiber or organic fertilizer obtained by treating garbage as main material, meth od for producing the same, method for manufacturing formed article using the same, and formed article and method for use |
| JP4043194B2 (en) * | 2001-02-15 | 2008-02-06 | 株式会社大貴 | Nonwoven fabric and method for producing the nonwoven fabric |
-
2007
- 2007-05-01 JP JP2007120666A patent/JP4368904B2/en not_active Expired - Fee Related
- 2007-07-13 CN CN200710136045.1A patent/CN101176444B/en not_active Expired - Fee Related
-
2008
- 2008-10-28 HK HK08111824.1A patent/HK1119525A1/en not_active IP Right Cessation
-
2009
- 2009-07-16 JP JP2009167912A patent/JP4488535B2/en active Active
Non-Patent Citations (3)
| Title |
|---|
| 杜向荣等.线香烟花及其制造技术.《火工品》.1994,(第02期), * |
| 胡桂芳.一种非洲线香香型评辨及仿制.《香料香精化妆品》.2001,(第04期), * |
| 高会东.烟雾剂浅析.《邯郸农业高等专科学校学报》.1997,(第01期), * |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4368904B2 (en) | 2009-11-18 |
| JP4488535B2 (en) | 2010-06-23 |
| JP2008137987A (en) | 2008-06-19 |
| HK1119525A1 (en) | 2009-03-13 |
| CN101176444A (en) | 2008-05-14 |
| JP2009242429A (en) | 2009-10-22 |
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