CN101153226A - High-speed diesel engine fuel emulsified by leavings and heavy oil, and process for producing the same - Google Patents

High-speed diesel engine fuel emulsified by leavings and heavy oil, and process for producing the same Download PDF

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Publication number
CN101153226A
CN101153226A CNA2006101164998A CN200610116499A CN101153226A CN 101153226 A CN101153226 A CN 101153226A CN A2006101164998 A CNA2006101164998 A CN A2006101164998A CN 200610116499 A CN200610116499 A CN 200610116499A CN 101153226 A CN101153226 A CN 101153226A
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oil
portions
speed diesel
parts
diesel fuel
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CNA2006101164998A
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Chinese (zh)
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周卫国
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Individual
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Individual
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Priority to CNA2006101164998A priority Critical patent/CN101153226A/en
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Abstract

The present invention discloses a high speed diesel engine fuel obtained by emulsifying residual oil as well as heavy oil and the preparation method thereof. The raw material ratio and the method are that: the preparation of A component is that: 0-5 portions of triethanolamine, 10-18 portions of ammonia water, 12-20 portions of sorbitan monooleate 80, 1-5 portions of tween 80, 20-35 portions of naphthenate, 8-20 portions of methanol, 15-28 portions of solvent naphtha and 0-5 portions of turpentine oil are stirred and mixed, and the A component is obtained; 20-35 portions of residual oil or heavy oil, 35-50 portions of diesel oil, 5-12 portions of solvent naphtha, 3-8 portions of methanol, 8-15 portions of water and 1-10 portions of the A component are taken to be stirred for 5-15 minutes under normal temperature and pressure and then cut for 10-15 minutes by high-speed shearer, thus the high speed diesel engine fuel of the present invention is obtained. The present invention has the advantages of simple preparation method, low cost, good product stability, environmental protecting, etc.

Description

A kind of high-speed diesel fuel that becomes by residual oil and heavy oil emulsive and preparation method thereof
Technical field
The present invention relates to the power new energy field, be specifically related to a kind of residual oil and heavy oil emulsive of utilizing and become high-speed diesel fuel and this fuel preparation method.
Background technology
Mixed emulsion fuel with different methods and prepared has all obtained application in various degree at present, but domestic and international low-grade oil is emulsified in technical existing problems, low as the diesel oil-saving rate, generally be no more than 10%, use range is narrow, unstable (oily water separation) etc., can not be used for high-speed diesel engine, in the process of refining of petroleum, often, the residual oil of decompression line generation is because product viscosity is big, gum level is too high, can't be applied to oil engine, can only be used in industries such as power plant's thermal power generation, Industrial Stoves, as external combustion fuel; Add lighter hydrocarbons in addition in residual oil, its viscosity is reduced, become heavy oil, during heavy oil can be used for, act as a fuel in the slow speed diesel engine and use, but its index can't reach the needed standard of high-speed diesel fuel, therefore can't be used for high-speed diesel engine.
Summary of the invention
At the deficiency that prior art exists, the object of the present invention is to provide a kind of high-speed diesel fuel that becomes by residual oil and heavy oil emulsive;
Another object of the present invention is to put forward the preparation method of this high-speed diesel fuel.
Goal of the invention of the present invention is achieved by the following technical solution:
A kind of high-speed diesel fuel that becomes by residual oil and heavy oil emulsive, the composition of its raw material and fill a prescription as follows:
Residual oil or heavy oil 20-35 part
Diesel oil 35-50 part
Solvent oil 5-12 part
Methyl alcohol 3-8 part
Water 8-15 part
A component 1-10 part
The composition of wherein said A component and fill a prescription as follows:
Trolamine 0-5 part
Ammoniacal liquor 10-18 part
Anhydrous sorbitol list olein Span-80 12-20 part
Anhydrous sorbitol polyoxyethylene list olein Twen-80 1-5 part
Naphthenate 20-35 part
Methyl alcohol 8-20 part
Solvent oil 15-28 part
Turps 0-5 part
Above-described umber is parts by weight.
Wherein said solvent oil is 200 #Or 260 #Solvent oil.
Wherein said naphthenate is a kind of in cyclic potassium naphthenate, sodium napthionate or the calcium naphthenate.
The preparation method of this high-speed diesel fuel is: take by weighing residual oil or heavy oil, diesel oil, solvent oil, methyl alcohol, water and A component earlier by above-mentioned prescription, stirred 5-10 minute at normal temperature and pressure, sheared 10-15 minute with high-speed shearing machine again, get high-speed diesel fuel of the present invention, described velocity of shear is more than 4000 rev/mins.
Among the present invention, naphthenate and ammoniacal liquor reaction generate emulsifying agent naphthenic acid ammonia, methyl alcohol plays the effect of thinner, solvent oil is main solvent, diesel oil is solubility promoter, sorbester p17 (anhydrous sorbitol list olein Span-80) is 5 with the value of the H.L.B that tween 80 (anhydrous sorbitol polyoxyethylene list olein Twen-80) cooperates, plays oleophylic, emulsive effect.
The purpose that adds trolamine in addition is to make itself and naphthenate reaction generate a kind of tensio-active agent flow measurement, can play and remove the intravital carbon distribution of cylinder; Adding terebinthine purpose is to make the dosimetric effect of emulsification further stable, makes the products storage time that processes longer.
High-speed diesel fuel that the present invention makes and preparation method thereof, do not need in the preparation process to heat, need not draw oil during use can directly start on diesel engine, and it is long that oil product is stablized the shelf-time, also can mix mutually and use with finished diesel fuel, diesel oil-saving rate height, so advantages such as the present invention has that the preparation method is simple, cost is low, product stability can be good, environmental protection.
Embodiment
How further specify the present invention below in conjunction with specific embodiment realizes:
Embodiment 1
The preparation of A component
Take by weighing 2 parts of trolamines, 10 parts of ammoniacal liquor, sorbester p17: 13 parts, tween 80: 3 parts, 21 parts of sodium napthionates, 12 parts of methyl alcohol, 260 #15 parts of solvent oils, 2 parts in turps gets the A component after mixing.
Take by weighing 21 parts in residual oil, 35 parts of diesel oil, 200 #10 parts of solvent oils, 4 parts of methyl alcohol, 10 parts in water, 3 parts of above-mentioned A components stirred 12 minutes at normal temperature and pressure, sheared 13 minutes with high-speed shearing machine again, got high-speed diesel fuel of the present invention.
Embodiment 2
The preparation of A component
Take by weighing 5 parts of trolamines, 15 parts of ammoniacal liquor, sorbester p17: 15 parts, tween 80: 2 parts, 25 parts of cyclic potassium naphthenates, 15 parts of methyl alcohol, 260 #20 parts of solvent oils, 3 parts in turps gets the A component after mixing.
Take by weighing 25 parts in heavy oil, 40 parts of diesel oil, 260 #12 parts of solvent oils, 6 parts of methyl alcohol, 13 parts in water, 5 parts of above-mentioned A components stirred 15 minutes at normal temperature and pressure, sheared 15 minutes with high-speed shearing machine again, got high-speed diesel fuel of the present invention.
Embodiment 3
The preparation of A component
Take by weighing 4 parts of trolamines, 18 parts of ammoniacal liquor, sorbester p17: 20 parts, tween 80: 5 parts, 30 parts of sodium napthionates, 20 parts of methyl alcohol, 260 #25 parts of solvent oils, 5 parts in turps gets the A component after mixing.
Take by weighing 30 parts in heavy oil, 48 parts of diesel oil, 200 #10 parts of solvent oils, 7 parts of methyl alcohol, 15 parts in water, 8 parts of above-mentioned A components stirred 12 minutes at normal temperature and pressure, sheared 13 minutes with high-speed shearing machine again, got high-speed diesel fuel of the present invention.
Embodiment 4
The preparation of A component
Take by weighing 18 parts of ammoniacal liquor, sorbester p17: 20 parts, tween 80: 5 parts, 35 parts of sodium napthionates, 20 parts of methyl alcohol, 200 #25 parts of solvent oils get the A component after mixing.
Take by weighing 35 parts in residual oil, 48 parts of diesel oil, 240 #10 parts of solvent oils, 7 parts of methyl alcohol, 15 parts in water, 8 parts of above-mentioned A components stirred 12 minutes at normal temperature and pressure, sheared 13 minutes with high-speed shearing machine again, got high-speed diesel fuel of the present invention.

Claims (6)

1. high-speed diesel fuel that becomes by residual oil and heavy oil emulsive, the composition of its raw material and fill a prescription as follows:
Residual oil or heavy oil 20-35 part
Diesel oil 35-50 part
Solvent oil 5-12 part
Methyl alcohol 3-8 part
Water 8-15 part
A component 1-10 part
The composition of wherein said A component and fill a prescription as follows:
Trolamine 0-5 part
Ammoniacal liquor 10-18 part
Anhydrous sorbitol list olein S-80 12-20 part
Anhydrous sorbitol polyoxyethylene list olein T-80 1-5 part
Naphthenate 20-35 part
Methyl alcohol 8-20 part
Solvent oil 15-28 part
Turps 0-5 part
Above-described umber is parts by weight.
2. a kind of high-speed diesel fuel that is become by residual oil and heavy oil emulsive according to claim 1, it is characterized in that: described solvent oil is 200 #Or 260 #Solvent oil.
3. a kind of high-speed diesel fuel that is become by residual oil and heavy oil emulsive according to claim 1 is characterized in that: described naphthenate is a kind of in cyclic potassium naphthenate, sodium napthionate or the calcium naphthenate.
4. the preparation method of the described high-speed diesel fuel of claim 1-3 is: take by weighing residual oil or heavy oil, diesel oil, solvent oil, methyl alcohol, water and A component earlier by described prescription, stir at normal temperature and pressure, shear with high-speed shearing machine again, get high-speed diesel fuel of the present invention.
5. the preparation method of high-speed diesel fuel according to claim 4 is characterized in that: stirred 5-10 minute under the described normal temperature and pressure.
6. the preparation method of high-speed diesel fuel according to claim 4, it is characterized in that: described velocity of shear is more than 4000 rev/mins, shear time is 10-15 minute.
CNA2006101164998A 2006-09-26 2006-09-26 High-speed diesel engine fuel emulsified by leavings and heavy oil, and process for producing the same Pending CN101153226A (en)

Priority Applications (1)

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CNA2006101164998A CN101153226A (en) 2006-09-26 2006-09-26 High-speed diesel engine fuel emulsified by leavings and heavy oil, and process for producing the same

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Application Number Priority Date Filing Date Title
CNA2006101164998A CN101153226A (en) 2006-09-26 2006-09-26 High-speed diesel engine fuel emulsified by leavings and heavy oil, and process for producing the same

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CN101153226A true CN101153226A (en) 2008-04-02

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181312A (en) * 2011-03-29 2011-09-14 汪青 Microemulsion diesel oil and preparation method thereof
CN108659896A (en) * 2017-04-01 2018-10-16 深圳华联世纪生物工程股份有限公司 A kind of raising biological alcohol-based fuel value formula and new method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102181312A (en) * 2011-03-29 2011-09-14 汪青 Microemulsion diesel oil and preparation method thereof
CN102181312B (en) * 2011-03-29 2013-06-05 汪青 Microemulsion diesel oil and preparation method thereof
CN108659896A (en) * 2017-04-01 2018-10-16 深圳华联世纪生物工程股份有限公司 A kind of raising biological alcohol-based fuel value formula and new method

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Open date: 20080402