CN101144119A - Auxiliary agent for reducing low temperature reduction index of sintering ore - Google Patents
Auxiliary agent for reducing low temperature reduction index of sintering ore Download PDFInfo
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- CN101144119A CN101144119A CNA2007101134253A CN200710113425A CN101144119A CN 101144119 A CN101144119 A CN 101144119A CN A2007101134253 A CNA2007101134253 A CN A2007101134253A CN 200710113425 A CN200710113425 A CN 200710113425A CN 101144119 A CN101144119 A CN 101144119A
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- auxiliary agent
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Abstract
The present invention relates to the manufacture and an application method for auxiliary agent which can reduces the low temperature reducibility index of sintered ore. With the weight percentage ratio, the auxiliary agent has the chemical formula that boric acid is 3-5 percent, calcium chloride is 30-40 percent, calcium nitrate is 30-40 percent, magnesium sulfate is 25-30 percent, and fatty alcohol polyoxyethylene ether is 1-10 percent; the chemical agent with suitable content and granularity is evenly mixed, and is packed and sealed into bags with 25 kg per bag. The prepared auxiliary agent is completely dissolved with water of 3 percent content, and the prepared solution is sprayed to the sintered ore with 3.4 kg/ton content. The present invention provides the preparation and the application method of the chemical agent suitable for reducing the low temperature reduction and the pulverization of the sintered ore with simple formula, remarkable effect, low cost, and simple application method, and by adopting the auxiliary agent, the low temperature reduction and pulverization indexes of the sintered ore can be effectively reduced by about RDI <SUB> + 3.15 mm </SUB> 10 percent.
Description
Technical field
The present invention relates to metallurgical technology field, belong to the sintering class.Be a kind of be used to reduce preparation of agglomerate cryogenic reducting powder index auxiliary agent and using method thereof.
Background technology
The agglomerate cryogenic reducting powder index is reflection iron-smelting furnace charge metallurgical performance index of cracked degree in the low-temperature reduction process of middle part on blast furnace, is to influence one of blast furnace production important factor.Low temperature reduction index is too high, and permeability of stock column worsens in the blast furnace, and output reduces, and coke ratio rises.So it is very great to blast furnace volume increase consumption reduction meaning to reduce the agglomerate cryogenic reducting powder index.The calcium chloride of the finishing room of steel industry sprinkling now sintering aid reduces the agglomerate cryogenic reducting powder index, in view of effect, have certain effect, can effectively improve about agglomerate cryogenic reducting powder index RDI+3.15mm5% from the check and analysis result and (represent cryogenic reducting powder index) with the residual content after sieving.But spray that calcium chloride brings thus than burden, because chloride ion content is higher in the calcium chloride, the subsequent handling blast furnace gas is had stronger corrodibility, produce the cryogenic reducting powder index that needs the lower more effective reduction agglomerate of auxiliary agent energy of a kind of chloride ion content.
CN1827801 discloses a kind of chemical additive for sintering iron ore fine, is Powdered composite mixture, granularity 〉=50 orders, and its set of dispense is oxygenation agent 20-45% than (wt%); Radical initiator 5-15%; Fusing assistant 20-45%; Reinforcer 2-15%; Catalyzer 2-15%; Nucleus agent 5-20%.The present invention does not contain smelting iron elements such as deleterious K, Na, is characterized in utilizing radical initiator to improve permeability of sintering material bed; Utilize combination and crystallization between the solid liquid phase of rare earth element acceleration of sintering; Utilize the nucleus agent to suppress the natural efflorescence and the low temperature reduction degradation of agglomerate.The consumption of this kind additive is the 0.1-0.3 ‰ of sinter mixture total amount, can improve agglomerate output 5%, improve barrate strength 3.4%, improve compound needle-like calcium ferrite (SFCA) content 15%, improve reduction degree (RI) 7.83%, improve cryogenic reducting powder index (RDI+315) 8.2%, reduce sintering solid burnup 8%.The mixing that replants additive using method complexity and agglomerate is poor, and the use cost height is not remarkable to the cryogenic reducting powder index effect.
Summary of the invention
The present invention mainly solves corrosion and the lower problem of effect that original sprinkling calcium chloride brings.A kind of preparation and using method that reduces agglomerate low-temperature reduction differentiation index auxiliary agent than low chlorine ion content, better effects if that have is provided.
The invention provides a kind of auxiliary agent that reduces low temperature reduction index of sintering ore, chemical ingredients and weight percent content are:
Boric acid 3～5%
Calcium chloride 30～40%
Nitrocalcite 30～40%
Sal epsom 25～30%
Fatty alcohol-polyoxyethylene ether 0.1～1%.
The granularity of above-mentioned chemical ingredients is 80～120 orders.Preferably, the auxiliary agent of described reduction low temperature reduction index of sintering ore, chemical ingredients and weight percent content are:
Boric acid 5%
Calcium chloride 40%
Nitrocalcite 30%
Sal epsom 25%
Fatty alcohol-polyoxyethylene ether 0.1%.
The mechanism of action of additive is: after spraying auxiliary agent on the agglomerate, because of agglomerate has certain temperature, moisture is evaporated in the auxiliary agent of spraying, and the solute in the auxiliary agent crystallizes into crystal and is adsorbed in agglomerate surface and the agglomerate micropore, forms thin film.Because agglomerate is a kind of cell texture, its surface porosity is a lot, these pores just are that reducing gas enters agglomerate inside and reduces the wherein passage of Fe2O3, the film that sticks to agglomerate surface has hindered contacting of reducing gas and agglomerate surface on the one hand, thereby has suppressed the reduction of agglomerate surface; The passage that reducing gas enters agglomerate has been filled in film gambling on the other hand, has hindered the continuation reduction of agglomerate inside, has slowed down the reduction rate of agglomerate, thereby has reduced reduction and pulverization ratio.
The preparation method of the auxiliary agent of described reduction low temperature reduction index of sintering ore is: with granularity is 80 purpose boric acid 3～5%, calcium chloride 30～40%, nitrocalcite 30～40%, sal epsom 25～30%, fatty alcohol-polyoxyethylene ether 1～10% (weight percent), mix, pack for every bag by 25kg.
Want the strict prevention moisture absorption and the situation of drenching with rain to take place in transportation and the use.
The using method of the auxiliary agent of described reduction low temperature reduction index of sintering ore: get above-mentioned auxiliary agent 3 weight parts, add 97 weight parts waters, be dissolved into the clear solution of 3 weight %; Clear solution adds the material spray jar, sprays by 3.4kg solution/ton agglomerate.
The characteristics of technical solution of the present invention:
1, chloride ion content is lower in the auxiliary agent, has only 17～23%.
2, result of use is remarkable, can effectively reduce agglomerate cryogenic reducting powder index about 10%.
3, use simply.
Embodiment
Following examples are to further specify of the present invention, but the present invention is not limited thereto.
Embodiment 1
Reduce the auxiliary agent of low temperature reduction index of sintering ore, chemical ingredients and weight percent content are: boric acid 4%, calcium chloride 40%, nitrocalcite 30%, sal epsom 25%, fatty alcohol-polyoxyethylene ether 1%.
Embodiment 2
Reduce the auxiliary agent of low temperature reduction index of sintering ore, chemical ingredients and weight percent content are: boric acid 4.9%, calcium chloride 30%, nitrocalcite 40%, sal epsom 25%, fatty alcohol-polyoxyethylene ether 0.1%.
Embodiment 3
Reduce the auxiliary agent of low temperature reduction index of sintering ore, chemical ingredients and weight percent content are: boric acid 4.5%, calcium chloride 40%, nitrocalcite 35%, sal epsom 25%, fatty alcohol-polyoxyethylene ether 0.5%.
Embodiment 4
Reduce the auxiliary agent of low temperature reduction index of sintering ore, chemical ingredients and weight percent content are: boric acid 4%, calcium chloride 34%, nitrocalcite 36%, sal epsom 35%, fatty alcohol-polyoxyethylene ether 1%.
Embodiment 5
With the auxiliary agent of embodiment of the invention 1-4, carry out weighing by the formulation content of determining after, mix with mixer, water is dissolved into 3% clear solution, adds the material spray jar, carries situation according to agglomerate, sprays by 3.4kg solution/ton agglomerate.Comparative Examples adopts calcium chloride.Experimental result sees the following form:
| Embodiment | Additive amount | RDI +6.3(％) | RDI +3.15(％) | RDL 0.5(％) |
| 1 | 100g/ ton agglomerate | 38.50 | 68.43 | 9.45 |
| 2 | 100g/ ton agglomerate | 43.42 | 70.97 | 8.92 |
| 3 | 100g/ ton agglomerate | 40.63 | 69.85 | 9.12 |
| 4 | 100g/ ton agglomerate | 37.86 | 65.59 | 10.40 |
| Calcium chloride | 150g/ ton agglomerate | 38.49 | 65.95 | 9.79 |
Claims (5)
1. auxiliary agent that reduces low temperature reduction index of sintering ore, chemical ingredients and weight percent content are:
Boric acid 3～5%
Calcium chloride 30～40%
Nitrocalcite 30～40%
Sal epsom 25～30%
Fatty alcohol-polyoxyethylene ether 0.1～1%.
2. the auxiliary agent of reduction low temperature reduction index of sintering ore as claimed in claim 1 is characterized in that, the granularity of above-mentioned chemical ingredients is 80～120 orders.
3. the auxiliary agent of reduction low temperature reduction index of sintering ore as claimed in claim 1 is characterized in that, the auxiliary agent of described reduction low temperature reduction index of sintering ore, and chemical ingredients and weight percent content are:
Boric acid 5%
Calcium chloride 40%
Nitrocalcite 30%
Sal epsom 25%
Fatty alcohol-polyoxyethylene ether 0.1%.
4. the preparation method of the auxiliary agent of reduction low temperature reduction index of sintering ore as claimed in claim 1 is: with granularity is 80 purpose boric acid 3～5%, calcium chloride 30～40%, nitrocalcite 30～40%, sal epsom 25～30%, fatty alcohol-polyoxyethylene ether 1～10% (weight percent), mix, pack for every bag by 25kg.
5. reduce the using method of the auxiliary agent of low temperature reduction index of sintering ore according to claim 1: get above-mentioned auxiliary agent 3 weight parts, add 97 weight parts waters, be dissolved into the clear solution of 3 (weight) %; Clear solution adds the material spray jar, sprays by 3.4kg solution/ton agglomerate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007101134253A CN100560753C (en) | 2007-10-15 | 2007-10-15 | A kind of auxiliary agent that reduces low temperature reduction index of sintering ore |
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| CNB2007101134253A CN100560753C (en) | 2007-10-15 | 2007-10-15 | A kind of auxiliary agent that reduces low temperature reduction index of sintering ore |
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| CN101144119A true CN101144119A (en) | 2008-03-19 |
| CN100560753C CN100560753C (en) | 2009-11-18 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102234718A (en) * | 2010-04-23 | 2011-11-09 | 宝山钢铁股份有限公司 | Accessory ingredient for reducing low-temperature reduction degradation index of lump ore and use method thereof |
| CN102409167A (en) * | 2010-09-26 | 2012-04-11 | 鞍钢股份有限公司 | Sintered ore pulverization inhibitor and adding method thereof |
| CN102605176A (en) * | 2012-04-09 | 2012-07-25 | 通化耐博新材料股份有限公司 | Low-temperature pulverization inhibitor for sintered ore |
| CN102899429A (en) * | 2012-09-19 | 2013-01-30 | 秦皇岛赛文冶金科技有限公司 | Blast furnace smelting raw material modifier |
| CN108531721A (en) * | 2018-05-24 | 2018-09-14 | 西安建筑科技大学 | A kind of additive and iron ore sinter inhibiting iron ore sinter low temperature reduction degradation |
| JP2019173051A (en) * | 2018-03-27 | 2019-10-10 | 日本製鉄株式会社 | Reduction degradation control device, reduction degradation control program, and reduction degradation control method |
| CN112095001A (en) * | 2019-06-18 | 2020-12-18 | 美匡冶金技术研究院(苏州)有限公司 | Pretreatment method of mixed water for sintering production |
-
2007
- 2007-10-15 CN CNB2007101134253A patent/CN100560753C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102234718A (en) * | 2010-04-23 | 2011-11-09 | 宝山钢铁股份有限公司 | Accessory ingredient for reducing low-temperature reduction degradation index of lump ore and use method thereof |
| CN102234718B (en) * | 2010-04-23 | 2012-09-19 | 宝山钢铁股份有限公司 | Accessory ingredient for reducing low-temperature reduction powdering index of lump ore and use method thereof |
| CN102409167A (en) * | 2010-09-26 | 2012-04-11 | 鞍钢股份有限公司 | Sintered ore pulverization inhibitor and adding method thereof |
| CN102605176A (en) * | 2012-04-09 | 2012-07-25 | 通化耐博新材料股份有限公司 | Low-temperature pulverization inhibitor for sintered ore |
| CN102899429A (en) * | 2012-09-19 | 2013-01-30 | 秦皇岛赛文冶金科技有限公司 | Blast furnace smelting raw material modifier |
| JP2019173051A (en) * | 2018-03-27 | 2019-10-10 | 日本製鉄株式会社 | Reduction degradation control device, reduction degradation control program, and reduction degradation control method |
| JP7003782B2 (en) | 2018-03-27 | 2022-02-04 | 日本製鉄株式会社 | Reduced pulverization property management device, reduced pulverization property management program, and reduced pulverization property management method |
| CN108531721A (en) * | 2018-05-24 | 2018-09-14 | 西安建筑科技大学 | A kind of additive and iron ore sinter inhibiting iron ore sinter low temperature reduction degradation |
| CN112095001A (en) * | 2019-06-18 | 2020-12-18 | 美匡冶金技术研究院(苏州)有限公司 | Pretreatment method of mixed water for sintering production |
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| Publication number | Publication date |
|---|---|
| CN100560753C (en) | 2009-11-18 |
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