CN101135432A - Steam can used for containing and cooling down forming gas - Google Patents

Steam can used for containing and cooling down forming gas Download PDF

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Publication number
CN101135432A
CN101135432A CNA2006101375113A CN200610137511A CN101135432A CN 101135432 A CN101135432 A CN 101135432A CN A2006101375113 A CNA2006101375113 A CN A2006101375113A CN 200610137511 A CN200610137511 A CN 200610137511A CN 101135432 A CN101135432 A CN 101135432A
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China
Prior art keywords
syngas cooler
forming gas
flue
fluid cooling
cooler
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Granted
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CNA2006101375113A
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CN101135432B (en
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基普林·C·亚历山大
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Babcock and Wilcox Co
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Babcock and Wilcox Co
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

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  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Abstract

This invention relates to a steam generator for storage and cooling of the synthetic gas in the gasification process of coal with the radiant and convective surface and an integrated gasification device. It realizes the compact design of low cost via a special device.

Description

Be used to hold steam generator with cooling down forming gas
Technical field
The present invention relates generally to the coal gasification field, relates to the steam generator that is used to hold and cool off the forming gas that coal gasifying process produces especially.
Background technology
Usually costly and operation possibility and reliability are low compared with competitive solid coal combustion technology such as pulverized coal friring rankine cycle in the integrated gasification combined cycle plants of buring solid fuel (IGCC) power plant.For making IGCC more competitive, the critical piece that haves much room for improvement comprises non-gasifier and radiation and convection current syngas cooler.Owing to the pressure vessel containment and with the economy of its shipping to the on-site size restrictions in most of power plants, the design of radiation syngas cooler has the actual limit of an overall outer dimensions.In the restriction to container diameter, the radiant heat exchange steam generation surface that needs to be used for refrigerating gas is tightened to greatest extent, thereby makes the whole height minimum of radiation syngas cooler.
The U.S. Patent No. 4,768,470 of authorizing Ziegler adopts the coaxial flue that is made of the steam generation wall to shorten whole cooler height.This flue that is designed to separate provides independently water loop that thereby lifting, cleaning and the inspection of independently inner and outside flue are provided.Another kind of by Babcock ﹠amp; Thereby surface (" aileron ") takes place with the additional steam that hangs on the flue inboard makes the surface area maximum shorten the cooler height simultaneously in an independent flue of the employing steam generation wall of improving one's methods that Wilcox Company ca. proposed in 1992.Other company adopts identical design as GHH Mann.
Existing solution does not drop to competitive level with the cost of these parts yet.Adopting the power plant of maximum commercial gas turbine to be used for the height of single radiant coolers of cooling down forming gas can be above 150 foot high.Two coolers have been adopted in the design in some power plants, have reduced whole height like this and have but further increased cost.In addition, too much gasifier, radiant coolers and convection cooler are included in the power plant design to improve the operation possibility in power plant with quite high cost.
Have the parts that are independent of radiant coolers of solution needs that are used for the convection current syngas cooler now, and connect this two parts with a cooling stack.The convection cooler design comprises the design (water or steam are in pipe, and gas is outside pipe) (Shell Oil Company) of water and steam pipe and the design (gas is in pipe, and water is outside pipe) (Steinmueller and other companies) of fire tube.These two kinds of designs all need to be independent of the pressure vessel enclosure and the water/vapour system of radiant coolers.The turbulent flow that produces with the convection cooler porch in gas stack has caused the stained source of reluctant fuel ash successively.
The existing solution that is used for gasifier comprises the refractory outer cover of non-cooling and cooling.Non-cooled enclosure (General Electric, Conoco and other companies) has experienced early stage failure and has constantly substituted.Making these designs have high feasibility needs a standby gasifier train usually, and/or lights gas turbine with very high cost with oil or gas in the gasifier maintenance process.The number of times of the slow heating and cooling of the non-Cooling Design of thick refractory material has prolonged to maintenance or has changed the time that refractory material is shut down.Water with refractory coating that existing gasifier design (Shell Oil Company, future source of energy company) employing separates or steam generation loop are to pack into and to store gasifying gas.Some system in these systems adopts low pressure, forced circulation cooling water system, the heat outside the isolated power plant steam/water system of this system, thus reduced efficient.Be used for the environment facies on this employing and cooling circuit all-in-one-piece steam generation surface, downstream with the burning situation prior art that stores the thermosetting attitude fuel gas that has molten slag comprise Cyclone TMPoint hot pot stove (Babcock; Wilcox company).
Therefore obviously, developing a kind of economy, compactness, reliable and solid syngas cooler will be vital to the future with commercial-scale IGCC system.
Summary of the invention
Therefore, an aspect of of the present present invention relates to a kind of syngas cooler that is used for extracting from the forming gas that gasification produces heat.This syngas cooler comprises the housing with entrance and exit; Be contained in the fluid cooling inner flue that is used to receive forming gas in the housing; Be contained in the fluid cooling external flue that is used in the housing receive from the forming gas of inner flue; Be positioned at the radiant heat exchange surface that inner flue is used for cooling down forming gas; With the device that forming gas is carried to the exit from external flue.
Another aspect of the present invention relates to a kind of aforesaid syngas cooler that disposes the Convective Heating surface, and it is positioned at external flue, is used for further cooling down forming gas.
Of the present inventionly also relate in one aspect to a kind of syngas cooler that not only in same shell, adopts radiation and Convective Heating surface but also be combined as the integrated gasification device.
The various novel features that the present invention had at length point out and form the part of the disclosure content in appended claims.For a better understanding of the present invention, its service advantages and use in the particular advantage that obtains, be elaborated with reference to the accompanying drawings and to the preferred embodiment of the present invention.
Description of drawings
In the accompanying drawings:
Fig. 1 is the side generalized section of first embodiment of radiation syngas cooler of the present invention;
Fig. 2 be the direction along the arrow 2-2 of Fig. 1 obtain cutaway view;
Fig. 3 is the side generalized section of second embodiment of radiation syngas cooler of the present invention, wherein illustrates the layout on Convective Heating surface; With
Fig. 4 is the side generalized section of the 3rd embodiment of radiation syngas cooler of the present invention, wherein illustrates the layout of integrated gasification device.
The specific embodiment
Total referring to accompanying drawing, wherein identical identical or intimate parts of symbolic representation in institute's drawings attached especially referring to Fig. 1, wherein show the side generalized section of first embodiment of the invention, it relates to a radiation syngas cooler, represents with 10 usually.This syngas cooler 10 is a hydrostatic column typically, its longitudinal axis vertical orientation.In this embodiment, the thermal synthesis gas of supplying with from gasifier (not shown) for cooler 10 from the inlet 14 that is positioned at cooler 10 tops 12.Gas 12 enters the inner flue that is positioned at cooler 10 inside or goes along with sb. to guard him zone 16.Inner flue is defined by interior enclosure wall 18, is preferably cylindrically, and typically comprises the fluid cooling tube.Working fluid can be water, steam or its mixture in the pipe.Except the fluid cooling tube of enclosure wall 18 in forming, inner flue 16 also has a large amount of fluid-cooled ailerons surface 20, these surfaces are and hang on cooler 10 inside integratedly and make a large portion of aileron 20 be exposed to the forming gas 12 of introducing, the working fluid of aileron 20 thereby heating is flowed through (still water, steam or its mixture).Aileron 20 is configured to the flat tube group structure that adjoins each other usually, and have be used to distribute or aggregate flow through the entrance and exit house steward or the collector 22 of the working fluid of aileron 20.The quantity of set aileron 20 and layout will be by heat exchange and the decisions of other factors.Therefore, although Fig. 2 shows the structure of arranging six (6) ailerons 20 around the vertical axes of cooler 10, the aileron 20 that also can adopt more or less quantity is to adapt to concrete heat exchange and cooling requirement.When the forming gas 12 of heat is flowed through inner flue 16 downwards, it is touched mouth by interior enclosure wall 18 and aileron 20, simultaneously upwards turn round roughly 180 degree by being positioned at the one or more openings 26 on the enclosure wall 18, and then enter the external flue that the exterior enclosure wall 30 by interior enclosure wall 18 and same structure defines or go along with sb. to guard him regional 28 at bottom section 24 forming gas 12 of inner flue 16.External flue 28 just has the shape of general toroidal like this.If desired, house steward or collector 32 can be set so that the formation of opening 26 is easier.Subsequently, upwards carry forming gas 12,, leave cooler 10 by forming gas outlet 36 then by one or more openings 34 by external flue 28.
Distance between interior enclosure wall 18 and the exterior enclosure wall 30, and the distance between the shell 38 of exterior enclosure wall 30 and formation cooler 10 all will be enough big, thus when not working, cooler 10 can not enter and check.In forming and the enclosure wall 18,30 of external flue 16,28 all will preferably be set to have independently stream separately so that other lifting, cleaning and inspection to be provided.All water/steam generation surface will be arranged to carry out Natural Circulation, avoid the demand to the forced circulation system with circulating pump.The entrained solid thing tends to leave forming gas 12 at bottom section 24 in the thermal synthesis gas 12 that flows downward along inner flue 16, and here forming gas 12 turns round upwards roughly that 180 degree enter external flue 28.Solids falls into the water-bath portion 38 that is positioned at cooler 10 bottoms, thereby makes the solids cooling and pass through 40 discharges of solids outlet.Avoid the obstruction that caused by the solids that gathers if desired, can soot blower 42 be set at opening 26 places of bottom section 24, wherein forming gas 12 180 degree that turn round in this zone enter external flue 30.
In and external flue 16,28 and the combination that is positioned at the aileron 20 of inner flue 16 make the whole height of cooler 10 significantly be lower than any independent structure.In inner flue 16, hold in aileron house steward 22 and the other jockey (not shown), in independently and external flue 16,28 be provided for the space that promotes and clear up, with a kind of new inner flue 16 designs of needs, particularly in the bottom of inner flue 16.
Perhaps, heat based on the forming gas 12 of supplying with cooler 10 needs the other area of heating surface, is used to realize that the second embodiment of the present invention of this target is shown in Figure 3.As it may occur to persons skilled in the art that second embodiment is identical with the first embodiment part technical characterictic shown in Figure 1, and its special character is to have the layout on the Convective Heating surface 50 that is positioned at external flue 28 as shown in the figure.This Convective Heating surface 50 can water-cooled or the steam cooling, and by being arranged to make flow through one or more pipe groups of its outside of forming gas 12 to form.The group on Convective Heating surface 50 can be arranged on any position in the external flue 28 around the periphery of cooler 10.A special feature is in this embodiment, and same stream (a kind of type of cooling of integral body) can be adopted separately with the steam generation surface with interior and exterior enclosure wall 18,30 in Convective Heating surface 50, thereby eliminates the demand to the cooling system that separates.Perhaps, the stream of separation also can be adopted in Convective Heating surface 50.After flowing through Convective Heating surface 50, forming gas 12 leaves external flue 28 via opening 34, leaves cooler via gas vent 36 again.Soot blower 52 can be set clear up Convective Heating surface 50 to avoid obstruction.
The demand to the convection cooler parts that are independent of radiant coolers 10 and separate with radiant coolers 10 has been eliminated on Convective Heating surface 50, and to the other additional tube connector with inflection point, identical pressure vessel containment and in the situation next one of the aforementioned whole type of cooling demand of cooling system independently.The forming gas 12 that is upward through the Convective Heating surface 50 that is positioned at external flue 28 from radiation cooling segment (inner flue 16) is substantially along straight ahead, thereby makes the porch gas turbulence degree minimum of external flue 28.It is minimum that this just makes uncontrolled lime-ash possibility of jamming drop to, and allow soot blower 52 is set so that it is cleaned near Convective Heating surface 50.This design and turbulent flow are compared useful especially with subsidiary uncontrolled blockage problem, above-mentioned blockage problem typically can run at the unexpected inlet of the inlet tube sheet place pipe of fire tube cooler design.
If desired, being applied to the structure of gasification system and the further simplification of equipment can realize by the third embodiment of the present invention, as shown in Figure 4.As shown in the figure, this layout extends upward the pipe group that composition defines the enclosure wall 18 of inner flue 16, so as the upper area of cooler 10 form an integral body, the fluid gasifier goes along with sb. to guard him zone 60.Integrated gasification device 60 is located in cooler 10 inside like this, for inner flue 16 provides forming gas 12.Form gasifier and go along with sb. to guard him the pipe group of the enclosure wall 62 in zone 60 and have refractory coating 64, do not destroyed and the environment temperature that gasifier is gone along with sb. to guard him zone 60 is maintained the temperature of the suitable gasification reaction of enough generations with protection tube group surface by slag.
Go along with sb. to guard him zone 60 according to gasifier of the present invention and overcome the problem that gasifier can run in non-cooling, fire-resistant gasifier and the prior art.The present invention incorporates same fluid cooling circuit that radiant coolers 10 has into to improve previous gasifier design by gasifier being gone along with sb. to guard him zone 60 cooling circuit, has eliminated the demand to the cooling system that separates.This design has also been reclaimed from gasifier and has been gone along with sb. to guard him regional 60 liberated heats, and imports it steam/water system of gasification installation into, thus raise the efficiency and the device life cycle in the appropriateness the fuel savings cost.
The discussion of each among above-mentioned three kinds of embodiment has all been listed the technical advantage of its relative prior art.From the angle of commerce, the design concept of inside/outside flue and aileron combination has been reduced cost significantly by hanging down the overall height of radiation syngas cooler significantly.The cost that the reduction of cost not only comes from external container reduces, and from the reduction of the cost of cost of transportation, fuel channel cost, steel construction cost and construction on site parts.Provide separable in and external flue make the maintenance cost minimum.This is extremely important to the gasifying process cooler, and this cooler stands worse corrosive environment and needs more maintenance time than employed burning gases cooler in traditional powdered coal equipment.
Convective Heating surface and radiation are cooled off and are gone along with sb. to guard him the zone and be combined as a whole and reduced the cost of separating component.At the cost highly significant of this saving,, also have the gas stack of simplification and the reduction of steam/water pipe cost, steel construction cost and construction cost because except that having saved the extra pressure container cost.Owing to reduced or eliminated the convection cooler obstruction, the fund cost of saving the cost that comes all convection coolers in can the ratio device life cycle from the high feasibility of buring solid fuel is more.
Whole, gasifier combination by eliminating to the demand of the pressure vessel that separates and some cooling lines score from the gasifier appropriateness saved cost.Let it be to the greatest extent, and fund cost may be slightly higher than non-gasifier, can believe, adopts solid-fuelled high feasibility will surmount the difference of any fund cost significantly, widely.
From several or all these the three kinds cost savings that combination obtained of allowing the design concept of cancellation replacement part series is significant.In addition, such saving has exceeded the scope of additional components, expands to steel construction around all support equipments and these parts and the construction cost of building it.Can draw like this, important, a basic improvement that is brought by the present invention relates to parts independently is merged into the parts of an integral body so that its compactness, low cost, more reliable and be easier to maintenance.
Although the application of principle in order to demonstrate the invention, have been illustrated and described in detail in specific embodiments of the invention, but it may occur to persons skilled in the art that the present invention can change with the form of the present invention that claim was covered on the basis that does not break away from these principles.In certain embodiments of the present invention, some technical characterictic of the present invention is used to obtain advantage sometimes when not corresponding use other technologies feature.Therefore, all these changes and embodiment fall within the scope of claim fully.

Claims (18)

1. one kind is used for the syngas cooler that the forming gas that produces from gasifying process extracts heat, and it comprises:
Housing with entrance and exit;
Be contained in the fluid cooling inner flue that is used to receive forming gas in the housing;
Be contained in the fluid cooling external flue that is used in the housing receive from the forming gas of inner flue;
Be positioned at the radiant heat exchange surface that inner flue is used for cooling down forming gas; With
The device that forming gas is carried to the exit from external flue.
2. syngas cooler as claimed in claim 1, it is characterized in that this syngas cooler comprises that the bottom that is arranged in syngas cooler is used to receive and cool off the water-bath portion and the solids outlet that is used for discharging from syngas cooler solids of the solids that is entrained in forming gas.
3. syngas cooler as claimed in claim 1 is characterized in that, fluid cooling inner flue is made up of the enclosure wall that fluid cooling tube group is constituted.
4. syngas cooler as claimed in claim 1 is characterized in that, fluid cooling external flue is made up of the enclosure wall that fluid cooling tube group is constituted.
5. syngas cooler as claimed in claim 1, it is characterized in that, the radiant heat exchange surface is by fluid-cooled aileron surface composition, and described aileron surface is and hangs on syngas cooler inside integratedly and make a large portion on aileron surface be exposed in the forming gas of introducing.
6. syngas cooler as claimed in claim 5 is characterized in that, the aileron surface is made up of the flat tube group that adjoins each other.
7. syngas cooler as claimed in claim 1 is characterized in that, forming gas when inner flue is transported to external flue at the bottom section of syngas cooler roughly 180 degree that turn round.
8. syngas cooler as claimed in claim 7 is characterized in that, forming gas is transferred by the one or more openings on the enclosure wall that forms inner flue.
9. syngas cooler as claimed in claim 8 is characterized in that, this syngas cooler comprises near the sootblower arrangement the one or more openings that are arranged on the enclosure wall that forms inner flue.
10. syngas cooler as claimed in claim 4 is characterized in that, is used for carrying the device of forming gas to comprise one or more openings on the enclosure wall that forms external flue from external flue to outlet.
11. syngas cooler as claimed in claim 1 is characterized in that, external flue is basically around inner flue.
12. syngas cooler as claimed in claim 1 is characterized in that, this syngas cooler comprises and is positioned at the Convective Heating surface that external flue is used for cooling down forming gas.
13. syngas cooler as claimed in claim 12 is characterized in that, the Convective Heating surface comprises one or more pipe groups that are configured to make the forming gas flowing pipe outside.
14. syngas cooler as claimed in claim 12 is characterized in that, this syngas cooler comprises and is arranged on the sootblower arrangement that the Convective Heating near surface is used to clear up the Convective Heating surface.
15. syngas cooler as claimed in claim 1 is characterized in that, this syngas cooler comprises that also is contained in the fluid cooling integrated gasification device that enclosure interior is used to produce forming gas, and described integrated gasification device is the inner flue application of syngas.
16. syngas cooler as claimed in claim 15 is characterized in that, the integrated gasification device is positioned at the upper area of syngas cooler and is made up of the enclosure wall that fluid cooling tube group constitutes.
17. syngas cooler as claimed in claim 16 is characterized in that, fluid cooling inner flue is made up of the enclosure wall that the fluid cooling tube constitutes, and the described fluid cooling tube that forms inner flue extends upward to form the enclosure wall of integrated gasification device.
18. syngas cooler as claimed in claim 16 is characterized in that, the fluid cooling tube that forms the enclosure wall of integrated gasification device is coated with refractory coating.
CN2006101375113A 2006-09-01 2006-09-01 Steam can used for containing and cooling down synthetic gas Expired - Fee Related CN101135432B (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101921628A (en) * 2009-04-16 2010-12-22 通用电气公司 Be used for protecting the method and apparatus of the cooling tube of radiation formula syngas cooler
CN102533364A (en) * 2010-10-19 2012-07-04 通用电气公司 System and method of substitute natural gas production
CN102966938A (en) * 2012-12-11 2013-03-13 中国东方电气集团有限公司 Bundle radiation boiler capable of relieving combustion fouling of perbasic coal
CN102977931A (en) * 2012-12-11 2013-03-20 中国东方电气集团有限公司 Integrated rotary radiation preheating mixing type heat recovery device with smoke chilling function
CN103013579A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integrated sarciniform radiation preheating hybrid heat recovery device with flue gas chilling function
CN103013582A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integral bunchy radiation preheating mixing-type energy utilization device with flue gas chilling
CN103013580A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integrated bunch type radiant boiler and preheating boiler mixed heat recovery device
CN103013577A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integral rotational radiation preheating mixing energy utilization device with flue gas chilling
CN103013578A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integrated bunch type radiant boiler and preheating boiler mixed energy utilization device
CN104373925A (en) * 2014-11-25 2015-02-25 中国东方电气集团有限公司 CFB radiation mixed boiler capable of reducing contamination of high-alkalinity coal

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JPS5784986A (en) * 1980-09-19 1982-05-27 Sulzer Ag High temperature gas cooler with pressure vessel
US4377132A (en) * 1981-02-12 1983-03-22 Texaco Development Corp. Synthesis gas cooler and waste heat boiler
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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101921628A (en) * 2009-04-16 2010-12-22 通用电气公司 Be used for protecting the method and apparatus of the cooling tube of radiation formula syngas cooler
CN102533364A (en) * 2010-10-19 2012-07-04 通用电气公司 System and method of substitute natural gas production
CN102533364B (en) * 2010-10-19 2014-11-19 通用电气公司 System and method of substitute natural gas production
CN103013580A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integrated bunch type radiant boiler and preheating boiler mixed heat recovery device
CN103013579A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integrated sarciniform radiation preheating hybrid heat recovery device with flue gas chilling function
CN103013582A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integral bunchy radiation preheating mixing-type energy utilization device with flue gas chilling
CN102977931A (en) * 2012-12-11 2013-03-20 中国东方电气集团有限公司 Integrated rotary radiation preheating mixing type heat recovery device with smoke chilling function
CN103013577A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integral rotational radiation preheating mixing energy utilization device with flue gas chilling
CN103013578A (en) * 2012-12-11 2013-04-03 中国东方电气集团有限公司 Integrated bunch type radiant boiler and preheating boiler mixed energy utilization device
CN103013577B (en) * 2012-12-11 2014-07-02 中国东方电气集团有限公司 Integral rotational radiation preheating mixing energy utilization device with flue gas chilling
CN103013579B (en) * 2012-12-11 2014-08-27 中国东方电气集团有限公司 Integrated sarciniform radiation preheating hybrid heat recovery device with flue gas chilling function
CN103013582B (en) * 2012-12-11 2014-08-27 中国东方电气集团有限公司 Integral bunchy radiation preheating mixing-type energy utilization device with flue gas chilling
CN102966938A (en) * 2012-12-11 2013-03-13 中国东方电气集团有限公司 Bundle radiation boiler capable of relieving combustion fouling of perbasic coal
CN104373925A (en) * 2014-11-25 2015-02-25 中国东方电气集团有限公司 CFB radiation mixed boiler capable of reducing contamination of high-alkalinity coal

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