CN101130940B - Moisture-proof flame-retardant liquid specially adapted to corrugated paper box - Google Patents
Moisture-proof flame-retardant liquid specially adapted to corrugated paper box Download PDFInfo
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- CN101130940B CN101130940B CN2007102014189A CN200710201418A CN101130940B CN 101130940 B CN101130940 B CN 101130940B CN 2007102014189 A CN2007102014189 A CN 2007102014189A CN 200710201418 A CN200710201418 A CN 200710201418A CN 101130940 B CN101130940 B CN 101130940B
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- proof flame
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Abstract
The present invention relates to a moisture-proof fire-resisting liquor for corrugated sheet box. Said moisture-proofying fire-resisting liquor contains zinc borate, hydrochloric acid, water, ammonia water, moisture-proofing agent, epoxy resin and epoxy resin solidifying agent. Its preparation method includes the following steps: diluting zinc borate by using hydrochloric acid, using ammonia water as buffer solution, then adding penetrating agent, moisture-proofing agent, epoxy resin and epoxy resin solidifying agent, stirring and filtering to obtain the invented water-base fire-resisting liquor.
Description
Technical field
The present invention relates to a kind of fire resistant fluid, relate in particular to a kind of moisture-proof flame-retardant liquid that is specially adapted to corrugated case, this fire resistant fluid also is applicable to other fire-retardant fireproof fields.
Background technology
At present, in the middle of the corrugated case that fire resistance also do not occur both at home and abroad having is applied to produce, and corrugated case is existing great potential safety hazard aspect the packing inflammable thing.Nearly in the world 80% goods is with after watt distracted packed in cases, through transfer, shipping, storage, shop, forwards at last in client's hand.In a single day a lot of products in these goods belong to inflammable articles, and corrugated case made of paper is generally all very easily lighted by fire, so run into flare, are not only the problem of lighting a chest, but the beginning of a disaster.If we do not solve with regard to this problem, what cause is not only threat to client's property safety, also is to social harm.Two aspects of main both at home and abroad research aspect the fire-retarded corrugated paper plate, first flame retardant effect is as the afterflame time of cardboard, continuously burn time, char length and all will be up to state standards; Its two be carton humidity resistance with flame retardant effect to reach be fit to produce, application facet.Show that according to data at home and abroad Many researchers has solved first problem, the fire resistant fluid of good flame retardation effect has a lot, can both good flame, for example U.S. PYROBREAK EX18, Taiwan FI-202, the spark chemical material KY-FW-001 of company of Hefei section; But demonstrations such as experiment and data, they all can not satisfy the condition of second aspect, the performance of taking these products to be applied to all can to appear at (more than 70%) cardboard under the high humility on the corrugated board is very big has been subjected to influence, the phenomenon that the serious moisture absorption occurred, the almost available hand of the moisture that is sucked is extruded, and does not meet China's climate characteristic; And price is too high.Therefore a kind of have fire-retardant and humidity resistance has concurrently and cost is reasonable, and the flame retardant type corrugated case that is suitable for producing will become following focus.
Summary of the invention
The objective of the invention is at the deficiencies in the prior art, a kind of moisture-proof flame-retardant liquid is provided, make the object that flooded behind this fire resistant fluid can reach fire-retardant purpose, have humidity resistance well again.
For achieving the above object, the present invention adopts a kind of moisture-proof flame-retardant liquid that is specially adapted to corrugated case, and said composition is composed of the following components by weight percentage:
Firebrake ZB 15%～20%
Hydrochloric acid 5%～10%
Water 71.25%～50.75%
Ammoniacal liquor 5%～10%
Anti-blushing agent 2%～3%
Epoxy resin 1%～5%
Epoxy curing agent 0.25%～1.25%
In above-mentioned moisture retardant fluid composition, Firebrake ZB has good flame-retardant effect; Hydrochloric acid is used for dilute solution; Water is the usefulness of decentralized medium; Ammoniacal liquor is used for cushioning liquid; Characteristics such as anti-blushing agent has good cementability, and has good heat resistance, and shrinkage factor is low, and water absorption rate is little are applicable to the protection against the tide of cardboard; Epoxy resin and epoxy curing agent are more endured by paper, improve paper board strength.The above-mentioned percentage range of these components and each component is determined by a large amount of tests.
Anti-blushing agent among the present invention selects white organosilicon macromolecule compound, PS polymer, inorganic aluminate, polyvinyl formal acetal, alkene monomer emulsion polymer, wherein organosilicon macromolecule compound preferably.
Epoxy resin in the moisture-proof flame-retardant liquid among the present invention selects white bisphenol A-type, bisphenol S type, Bisphenol F type, wherein bisphenol A-type preferably.
Epoxy curing agent among the present invention selects white fat polyamine, aromatic amine, polyamide-based, wherein preferably belongs to the ethylenediamine type of fat polyamine.
Moisture-proof flame-retardant liquid preparation of compositions process of the present invention is: Firebrake ZB is diluted with hydrochloric acid, then with 10% ammoniacal liquor as buffer solvent, add bleeding agent, anti-blushing agent, epoxy resin and epoxy curing agent then and get the aqua type fire resistant fluid through agitation and filtration, this moisture-proof flame-retardant liquid contains Firebrake ZB and has good flame-retardant effect, and anti-blushing agent wherein has moisture resistance, epoxy resin and epoxy curing agent can make and allow paper more endure, and improve paper board strength.Moisture retardant fluid composition of the present invention adopts conventional brushing and spraying method to apply, but adopts the dipping method effect to be only best to being used thing.For example, to flood with this fire resistant fluid with the corrugated case that special adhesive is produced, this is because dipping can make cardboard absorb fire resistant fluid better, the flame retardant effect of oven dry back cardboard is better than brushes and sprays prepared cardboard, corrugated case behind the dipping had both had flame retardant effect, had humidity resistance well again.Moisture-proof flame-retardant liquid of the present invention is specially adapted to the corrugated case field, also goes for the field that other can answer water type fire resistant fluid, such as, the fire prevention field of wooden ancient building.
The specific embodiment
Effect contrast below by three embodiment and after being applied to corrugated board further specifies the present invention.
Embodiment one: prepare 1000g by mass percentage, prepare by the compositional range of giving in the prescription, composition is: Firebrake ZB 150g, hydrochloric acid 50g, water 700g, ammoniacal liquor 50g, fragrant alkyl sulfonic acid bleeding agent 5g, organosilicon macromolecule compound anti-blushing agent 20g, bisphenol A type epoxy resin 20g, ethylenediamine type epoxy curing agent 5g.This fire resistant fluid is applied to corrugated case: soak cardboard with this fire resistant fluid and drain about 4 minutes, dry under 80 degrees centigrade to take out less than 14% o'clock to the cardboard moisture and promptly get the fire-retarded corrugated paper plate.
The characteristics of this embodiment are:
1. flame retardant effect is obvious, and the test result through relevant inspection center all is up to state standards, and wherein afterflame time is 0 second, continues the 4 seconds time, 48 millimeters of carbonization length burned.
2. humidity resistance is good, and the limit pressure under relative humidity 85% state is learned the common cardboard of strength ratio and improved about 17%.
Embodiment two: prepare 1000g by mass percentage, prepare by the compositional range of giving in the prescription, composition is: Firebrake ZB 160g, hydrochloric acid 50g, water 690g, ammoniacal liquor 50g, sulfosuccinic acid dihexyl sodium salt bleeding agent 5g, alkene monomer emulsion polymer anti-blushing agent 20g, bisphenol-s epoxy resin 20g, m-phenylene diamine (MPD) type epoxy curing agent 5g.This fire resistant fluid is applied to corrugated case: soak cardboard with this fire resistant fluid and drain about 4 minutes, dry under 80 degrees centigrade to take out less than 14% o'clock to the cardboard moisture and promptly get the fire-retarded corrugated paper plate.
The characteristics of this embodiment are:
Flame retardant effect also clearly, the test result through relevant inspection center all is up to state standards, wherein afterflame time is 2 seconds, continuous burns 5 seconds time, 50 millimeters of carbonization length.
2. humidity resistance is good, and the limit pressure under relative humidity 85% state is learned the common cardboard of strength ratio and improved about 14%.
Embodiment three: prepare 1000g by mass percentage, prepare by the compositional range of giving in the prescription, composition is: Firebrake ZB 200g, hydrochloric acid 100g, water 525g, ammoniacal liquor 100g, ester based quaternary ammonium salt bleeding agent 5g, inorganic aluminate anti-blushing agent 20g, bisphenol f type epoxy resin 40g, polyamide type epoxy curing agent 10g.This fire resistant fluid is applied to corrugated case: soak cardboard with this fire resistant fluid and drain about 4 minutes, dry under 80 degrees centigrade to take out less than 14% o'clock to the cardboard moisture and promptly get the fire-retarded corrugated paper plate.
The characteristics of this embodiment are:
Flame retardant effect also clearly, the test result through relevant inspection center all is up to state standards, wherein afterflame time is 5 seconds, continuous burns 15 seconds time, 70 millimeters of carbonization length.
2. humidity resistance is general, and the limit pressure under relative humidity 85% state is learned the common cardboard of strength ratio and improved about 8%.
More than three embodiment all under normal temperature, normality, carry out, by being applied to the effect contrast behind the corrugated board, the present invention adopts each constituent content of prescription of embodiment 1 as can be known, the fire-retardant and moisture effect that reaches is best.
Claims (7)
1. moisture-proof flame-retardant liquid that is specially adapted to corrugated case, said composition is composed of the following components by weight percentage:
Firebrake ZB 15%～20%
Hydrochloric acid 5%～10%
Water 71.25%～50.75%
Ammoniacal liquor 5%～10%
Anti-blushing agent 2%～3%
Epoxy resin 1%～5%
Epoxy curing agent 0.25%～1.25%.
2. the moisture-proof flame-retardant liquid that is specially adapted to corrugated case according to claim 1 is characterized in that: anti-blushing agent wherein is selected from organosilicon macromolecule compound, PS polymer, inorganic aluminate, polyvinyl formal acetal, alkene monomer emulsion polymer.
3. the moisture-proof flame-retardant liquid that is specially adapted to corrugated case according to claim 1 is characterized in that: epoxy resin wherein is selected from bisphenol A-type, bisphenol S type, Bisphenol F type.
4. the moisture-proof flame-retardant liquid that is specially adapted to corrugated case according to claim 1 is characterized in that: epoxy curing agent wherein is selected from fat polyamine, aromatic amine, polyamide.
5. the moisture-proof flame-retardant liquid that is specially adapted to corrugated case according to claim 2 is characterized in that: anti-blushing agent wherein is the organosilicon macromolecule compound.
6. the moisture-proof flame-retardant liquid that is specially adapted to corrugated case according to claim 3 is characterized in that: epoxy resin wherein is bisphenol A-type.
7. the moisture-proof flame-retardant liquid that is specially adapted to corrugated case according to claim 4 is characterized in that: epoxy curing agent wherein is the ethylenediamine type that belongs to fat polyamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007102014189A CN101130940B (en) | 2007-08-21 | 2007-08-21 | Moisture-proof flame-retardant liquid specially adapted to corrugated paper box |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007102014189A CN101130940B (en) | 2007-08-21 | 2007-08-21 | Moisture-proof flame-retardant liquid specially adapted to corrugated paper box |
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| Publication Number | Publication Date |
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| CN101130940A CN101130940A (en) | 2008-02-27 |
| CN101130940B true CN101130940B (en) | 2010-11-10 |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104404822A (en) * | 2014-11-06 | 2015-03-11 | 合肥东彩印刷科技有限公司 | Waterproof flame-retardant paint for cartons |
| CN104963244A (en) * | 2015-05-21 | 2015-10-07 | 芜湖蒲草电子商务有限公司 | Fireproof mould-proof corrugated carton and preparation method thereof |
| CN104893435A (en) * | 2015-05-21 | 2015-09-09 | 芜湖蒲草电子商务有限公司 | Wear-resistant fireproof paint for corrugated cartons and preparation method thereof |
| CN105178105A (en) * | 2015-08-31 | 2015-12-23 | 福建省龙创工业设计有限公司 | Flame-retardant corrugated paperboard |
| CN107527606A (en) * | 2016-06-21 | 2017-12-29 | 天津普朗多乐器有限公司 | A kind of drum barrel and its processing method |
| CN106120452B (en) * | 2016-06-23 | 2019-04-02 | 力嘉包装（东莞）有限公司 | Fire retardant, fire-retarded corrugated paper plate and preparation method thereof and Preparation equipment |
| CN106882467A (en) * | 2017-04-10 | 2017-06-23 | 滁州卷烟材料厂 | A kind of fire-type corrugated case |
| CN109518535A (en) * | 2017-09-16 | 2019-03-26 | 南京志超汽车零部件有限公司 | A kind of preparation method of moisture retardant corrugated case |
| CN107905035A (en) * | 2017-10-29 | 2018-04-13 | 贵州铜仁华毅新型材料科技有限公司 | A kind of waterproof honeycomb refill and preparation method thereof |
| CN107932664A (en) * | 2017-11-03 | 2018-04-20 | 苏州梅香雅筑工艺品有限公司 | A kind of manufacture craft of fire-retardant ribs of the fan |
| CN110284262A (en) * | 2019-07-25 | 2019-09-27 | 常熟市嘉淀纺织有限公司 | A kind of fire-retardant sound-absorbing polyester fiber board and preparation method thereof |
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| US3723379A (en) * | 1970-06-08 | 1973-03-27 | M & T Chemicals Inc | Vinyl dispersion textured coating |
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Address after: 325000, No. 1, east longitude Road, Li Ao section, 104 National Road, Zhejiang, Wenzhou Patentee after: DONGJING HOLDING Co.,Ltd. Address before: 325000, No. 1, east longitude Road, Li Ao section, 104 National Road, Zhejiang, Wenzhou Patentee before: Dongjing Holding Group Co.,Ltd. |
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Effective date of registration: 20151229 Address after: Ouhai Li Ao Kawamura 325000 Zhejiang city of Wenzhou province (104 National Highway) Patentee after: DONGJING PAPER PRODUCTS (WENZHOU) Co.,Ltd. Address before: 325000, No. 1, east longitude Road, Li Ao section, 104 National Road, Zhejiang, Wenzhou Patentee before: Dongjing Holding Co.,Ltd. |
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Address after: Ouhai Li Ao Kawamura 325000 Zhejiang city of Wenzhou province (104 National Highway) Patentee after: ZHEJIANG DONGJING TECHNOLOGY CO.,LTD. Address before: Ouhai Li Ao Kawamura 325000 Zhejiang city of Wenzhou province (104 National Highway) Patentee before: DONGJING PAPER PRODUCTS (WENZHOU) Co.,Ltd. |