CN101130717A - Agent for cleaning dacron and blending dyeing material - Google Patents
Agent for cleaning dacron and blending dyeing material Download PDFInfo
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- CN101130717A CN101130717A CNA2006100302399A CN200610030239A CN101130717A CN 101130717 A CN101130717 A CN 101130717A CN A2006100302399 A CNA2006100302399 A CN A2006100302399A CN 200610030239 A CN200610030239 A CN 200610030239A CN 101130717 A CN101130717 A CN 101130717A
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- terylene
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- detergent
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- blending dyeing
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Abstract
The invention discloses a polyester fibre and blended dye cleaner and application, which comprises the following parts: castor oil oxirane condensate, isomeric tridecaliphatic alcohol polyoxyethylene ether, Na2SiO3, polycarboxylate derivative, PVP and citrate. The invention can realize one-bath dyeing, detergent and washing to save manufacturing time, water, energy, steam and adjuvant, which improves the thermal transition washing staining fastness by 1-2 grade to improve the product quality.
Description
Technical field
The present invention relates to a kind of detergent, relate in particular to terylene and blending dyeing thing detergent thereof.
Background technology
The dispersed dye that terylene and blended fabric dyeing thereof use BLENDED FABRIC (cotton, nylon, spandex) contamination and dyestuff elevated temperature heat transport phenomena often occur in the printing and dyeing treating processes, washing fastness occurs and obviously descend, a difficult problem that very perplexs for dyeing and finishing circle.
The dyeing of traditional T/C BLENDED FABRIC is: dispersion/reactive dyestuffs two one bath two-step method technologies.Promptly earlier under solutions of weak acidity, dye terylene with dispersed dye, dyed and washed back caustic soda/vat powder reduction clearing, destroy and wash the loose colour and the dispersed dye of contamination on cotton component of PET fiber surface, improve washing fastness, then with in the acetic acid with caustic soda, with Dyeing of Cotton Fabric with Reactive Dyes, wash, soap, wash, oven dry etc.Two traditional one bath two-step method technique process complexity are various, and the process time is long, water consumption, electricity, coal equal energy source, and auxiliary agent cost height, more important is to dye caustic soda/vat powder that the R/C reduction clearing technology after washing is used, non-environmental protection, and totally unfavorable to wastewater treatment.Vat powder has following shortcoming specifically: (1) vat powder can spontaneous combustion, especially heats up naturally after moisture absorption and burns, and has the warehouse of putting vat powder that burning and formation fire take place repeatedly, brings serious potential safety hazard to factory; (2) vat powder can discharge a large amount of sulfur dioxide gas in the use of R/C reduction clearing, causes workshop condition to pollute, the infringement workers ' health, the factory that has expressly provide dyeing workshop work at the most 3 years in order to avoid cause into occupational illness; And sulfur dioxide gas also may form " wind seal " to Vinyl-Sulfone Type isoreactivity dyestuff, increases the fraction defective and the rate of returning something for repairs, and additionally increases the cost that returns something for repairs of dye-works; (3) vat powder is at high temperature extremely unstable, and temperature is high slightly, can decompose too soon to lose efficacy; (4) stability in storage of vat powder is very poor, in air and meet water and can decompose, causes effective ingredient constantly to descend.Therefore, people are striving to find the chemical of replacement vat powder to overcome above-mentioned shortcoming and to realize work simplification always.
If use general detergent based on tensio-active agent, it has solublization to hydrophobic dispersed dye, it not only acts on fiber surface and makes loose colour and stain solubilising in washing lotion, it can also act on the dispersed dye of polyster fibre inside, make it constantly migrate to fiber surface, cause new loose colour and contamination, so loose colour and contamination be difficult to clean, the washing fastness of terylene and blending dyeing thing thereof just can not improve yet.
Summary of the invention
The technical issues that need to address of the present invention are to disclose a kind of terylene and blending dyeing thing detergent thereof, to overcome the above-mentioned defective that prior art exists, satisfy the needs of dyeing.
Terylene of the present invention and blending dyeing thing detergent thereof, its component and parts by weight comprise:
Viscotrol C ethylene oxide condensate 15-40 part
Isomery 13 carbon fatty alcohol Soxylat A 25-7 15-13 parts
Na
2SiO
35-10 part
Poly carboxylic acid derivative 10-30 part
PVP 3-15 part
Citrate trianion 5-10 part
Said Viscotrol C ethylene oxide condensate can adopt the commercially available prod, and the trade mark of producing as the auxiliary reagent factory, Shanghai is the product of EL-40;
Said isomery 13 carbon fatty alcohol Soxylat A 25-7s can adopt the commercially available prod, are the product of L26 as the Shanghai trade mark that refined company limited produces of recording;
Said poly carboxylic acid derivative is selected from a kind of in sodium polyacrylate, sodium polymethacrylate, polymaleic acid or the polymaleic anhydride, can adopt the commercially available prod, and the trade mark of producing as BASF AG is the product of SNS;
Said Citrate trianion is selected from trisodium citrate, disodium citrate, sodium dihydrogen citrate, citric acid tri potassium, citric acid dipotassium, monobasic potassium citrate or ammonium citrate;
The chemical name of PVP is a polyvinylpyrrolidone;
The preparation method of terylene of the present invention and blending dyeing thing detergent thereof is the simple physics blending means, various raw material stirring is mixed getting final product.
Terylene of the present invention and blending dyeing thing detergent thereof can be used for the washing of terylene and blending dyeing thing thereof, and the washing method comprises the steps:
With the said terylene and blending dyeing thing detergent preparation the becoming aqueous solution that concentration is 0.5～2.0g/L thereof;
(1) the above-mentioned terylene and the blending dyeing thing detergent aqueous solution thereof are added in the dye bath, bath raio is 1: 15, and 70～85 ℃ turned round 8～15 minutes, washed then 8～15 minutes;
(2) add the above-mentioned terylene and the blending dyeing thing detergent aqueous solution thereof again, bath raio is 1: 15, and 85～95 ℃ turned round 8～15 minutes, washed then 8～15 minutes;
(3) add the above-mentioned terylene and the blending dyeing thing detergent aqueous solution thereof again, bath raio is 1: 15, and 70～85 ℃ turned round 8～15 minutes, washes typing then 8～15 minutes.
Adopt terylene of the present invention and blending dyeing thing detergent thereof, can realize one-bath dyeing, washing and washing, can save production time, water, electricity, steam equal energy source and auxiliary agent cost greatly, and can improve thermophoresis washing staining fastness 1-2 level, promote product quality greatly.
Embodiment
Embodiment 1
Material: pure polyester knitting cloth, wash/cotton (65/35) looped fabric prescription (weight part):
15 parts of Viscotrol C ethylene oxide condensates (EL-40), 15 parts of isomery 13 carbon fatty alcohol Soxylat A 25-7s, Na
2SiO
35 parts, 30 parts of sodium polyacrylates (molecular weight 5000), PVP3 part, 5 parts of trisodium citrates
Various raw material stirring are mixed, promptly obtain terylene and blending dyeing thing detergent thereof.
The washing method:
(1) the above-mentioned terylene and the blending dyeing thing detergent aqueous solution thereof are added in the dye bath, bath raio is 1: 15, and 80 ℃ turned round 15 minutes, washed then 15 minutes;
(2) add the above-mentioned terylene and the blending dyeing thing detergent aqueous solution thereof again, bath raio is 1: 15, and 90 ℃ turned round 15 minutes, washed then 15 minutes;
(3) add the above-mentioned terylene and the blending dyeing thing detergent aqueous solution thereof again, bath raio is 1: 15, and 80 ℃ turned round 15 minutes, washes typing then 15 minutes.
Soaping fastness is tested by GB GB/T 3921-1997; The processing look becomes, soaping fastness is faded grades with gray scale with GB 250-1995 evaluation variable color; Soaping fastness staining is graded with the GB251-1995 grey scale for assessing staining of colour.
Result such as following table:
(1) other soaping agents are soaped and are referred to general cotton and use detergent;
(2) total color difference is dyeing after boil washing oven dry sample with ash card variable color reference
(3) baking temperature is 160 ℃, 3min
From table as can be seen, soap through detergent of the present invention and wash black entirely, wash bright red entirely and polyester-cotton blend black, the bright red total color difference DE of polyester-cotton blend with other soaping agent is soaped
*All less than 1.0, the variable color of ash card is the 4.5-5 level, and numerical value is more or less the same, and coloured light, color and luster depth basically identical illustrate that detergent of the present invention compares with traditional soaping agent, to wash entirely, polyester-cotton blend dyes thing and soaps, and do not influence the coloured light and the color and luster depth.From soaping fastness, through detergent of the present invention soap to wash the staining fastness of washing that dyes thing entirely be the 3.5-4.0 level, and through other soaping agents soap to wash the staining fastness of washing that dyes thing entirely be 2.5 grades; The cotton staining fastness that the polyester-cotton blend of soaping through detergent of the present invention dyes thing is 3.0 grades, and washing staining fastness is 3.5 grades, and is 2.0 grades through the cotton staining fastness that the polyester-cotton blend that other soaping agent is soaped dyes thing, and washing staining fastness is 2.5 grades; Therefore, dye thing with polyester-cotton blend and soap to wash entirely with polyester-cotton blend than with other soaping agent and dye thing entirely soap to wash with detergent of the present invention, soaping fastness (no matter being that cotton is stained with or washs and be stained with) all can improve more than 1 grade.
Embodiment 2
Prescription (weight part):
40 parts of Viscotrol C ethylene oxide condensates (EL-40), 13 parts of isomery 13 carbon fatty alcohol Soxylat A 25-7s, Na
2SiO
35 parts, 10 parts of sodium polyacrylates (molecular weight 5000), PVP15 part, 10 parts of trisodium citrates.
The washing method is with embodiment 1, and detected result is as follows:
Result such as following table:
Claims (5)
1. terylene and blending dyeing thing detergent thereof is characterized in that component and parts by weight comprise:
Viscotrol C ethylene oxide condensate 15-40 part
Isomery 13 carbon fatty alcohol Soxylat A 25-7 15-13 parts
Na
2SiO
35-10 part
Poly carboxylic acid derivative 10-30 part
PVP 3-15 part
Citric acid 5-10 part.
2. terylene according to claim 1 and blending dyeing thing detergent thereof is characterized in that, said poly carboxylic acid derivative is selected from a kind of in sodium polyacrylate, sodium polymethacrylate, polymaleic acid or the polymaleic anhydride.
3. terylene according to claim 1 and blending dyeing thing detergent thereof is characterized in that said Citrate trianion is selected from trisodium citrate, disodium citrate, sodium dihydrogen citrate, citric acid tri potassium, citric acid dipotassium, monobasic potassium citrate or ammonium citrate.
4. according to the application of claim 1,2 or 3 described terylene and blending dyeing thing detergent thereof, it is characterized in that, be used for the washing of terylene and blending dyeing thing thereof.
5. application according to claim 4 is characterized in that the washing method comprises the steps:
With the said terylene and blending dyeing thing detergent preparation the becoming aqueous solution that concentration is 0.5～2.0g/L thereof;
(1) the above-mentioned terylene and the blending dyeing thing detergent aqueous solution thereof are added in the dye bath, bath raio is 1: 15, and 70～85 ℃ turned round 8～15 minutes, washed then 8～15 minutes;
(2) add the above-mentioned terylene and the blending dyeing thing detergent aqueous solution thereof again, bath raio is 1: 15, and 85～95 ℃ turned round 8～15 minutes, washed then 8～15 minutes;
(3) add the above-mentioned terylene and the blending dyeing thing detergent aqueous solution thereof again, bath raio is 1: 15, and 70～85 ℃ turned round 8～15 minutes, washes typing then 8～15 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610030239A CN101130717B (en) | 2006-08-21 | 2006-08-21 | Agent for cleaning dacron and blending dyeing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610030239A CN101130717B (en) | 2006-08-21 | 2006-08-21 | Agent for cleaning dacron and blending dyeing material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101130717A true CN101130717A (en) | 2008-02-27 |
| CN101130717B CN101130717B (en) | 2010-05-12 |
Family
ID=39128123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610030239A Expired - Fee Related CN101130717B (en) | 2006-08-21 | 2006-08-21 | Agent for cleaning dacron and blending dyeing material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101130717B (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134530A (en) * | 2010-01-25 | 2011-07-27 | 罗门哈斯公司 | Laundry detergent bar composition |
| CN102535164A (en) * | 2011-12-28 | 2012-07-04 | 浙江台华新材料股份有限公司 | Three-proofing finishing method of terylene fabric with high soaping-proof color fastness and high sublimation fastness, finishing agent and preparation method of finishing agent |
| CN102586038A (en) * | 2011-12-28 | 2012-07-18 | 浙江台华新材料股份有限公司 | Fabric reductive cleaning agent with high soaping-resistant color fastness and high sublimation fastness, preparation method thereof and polyester fabric treatment method |
| CN102876500A (en) * | 2012-10-25 | 2013-01-16 | 南京大地冷冻食品有限公司 | Preparation method of acidic dye printing anti-staining detergent |
| CN102876498A (en) * | 2012-10-25 | 2013-01-16 | 南京大地冷冻食品有限公司 | Preparation method of novel reactive dye low-temperature high-efficiency soaping agent |
| CN104059783A (en) * | 2014-06-10 | 2014-09-24 | 深圳市新纶科技股份有限公司 | Preparation method of surfactant for detergents and detergent composition |
| CN106554861A (en) * | 2016-10-14 | 2017-04-05 | 无锡市华诚印染剂厂 | Polyester cotton detergent |
| CN106592284A (en) * | 2016-11-24 | 2017-04-26 | 张家港市德宝化工有限公司 | Reduction clearing method used for synthetic fiber |
| CN107828534A (en) * | 2017-11-14 | 2018-03-23 | 广州先盈生物科技有限公司 | A kind of efficient resist printing detergent for garment wash and preparation method thereof |
| CN108779602A (en) * | 2016-01-04 | 2018-11-09 | 尼克瓦格斯有限公司 | improved method for removing textile dyes |
| CN109610206A (en) * | 2018-11-15 | 2019-04-12 | 纳派化学(上海)有限公司 | A kind of preparation method of novel dispersion dyeing efficient cleaner |
| CN112726236A (en) * | 2020-12-28 | 2021-04-30 | 绍兴海成化工有限公司 | Neutralization soaping agent |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2295623A (en) * | 1994-12-01 | 1996-06-05 | Procter & Gamble | Detergent Compositions |
| JPH08176590A (en) * | 1994-12-22 | 1996-07-09 | Kao Corp | Powder cleaner composition |
| CN1311295A (en) * | 2001-02-28 | 2001-09-05 | 陈胜利 | Anti-static dust-proof sterilizing broad spectrum detergent and preparing method |
-
2006
- 2006-08-21 CN CN200610030239A patent/CN101130717B/en not_active Expired - Fee Related
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134530A (en) * | 2010-01-25 | 2011-07-27 | 罗门哈斯公司 | Laundry detergent bar composition |
| CN102535164A (en) * | 2011-12-28 | 2012-07-04 | 浙江台华新材料股份有限公司 | Three-proofing finishing method of terylene fabric with high soaping-proof color fastness and high sublimation fastness, finishing agent and preparation method of finishing agent |
| CN102586038A (en) * | 2011-12-28 | 2012-07-18 | 浙江台华新材料股份有限公司 | Fabric reductive cleaning agent with high soaping-resistant color fastness and high sublimation fastness, preparation method thereof and polyester fabric treatment method |
| CN102586038B (en) * | 2011-12-28 | 2013-08-21 | 浙江台华新材料股份有限公司 | Fabric reductive cleaning agent with high soaping-resistant color fastness and high sublimation fastness, preparation method thereof and polyester fabric treatment method |
| CN102535164B (en) * | 2011-12-28 | 2014-09-03 | 浙江台华新材料股份有限公司 | Three-proofing finishing method of terylene fabric with high soaping-proof color fastness and high sublimation fastness, finishing agent and preparation method of finishing agent |
| CN102876500A (en) * | 2012-10-25 | 2013-01-16 | 南京大地冷冻食品有限公司 | Preparation method of acidic dye printing anti-staining detergent |
| CN102876498A (en) * | 2012-10-25 | 2013-01-16 | 南京大地冷冻食品有限公司 | Preparation method of novel reactive dye low-temperature high-efficiency soaping agent |
| CN104059783B (en) * | 2014-06-10 | 2017-10-03 | 深圳市新纶科技股份有限公司 | A kind of preparation method of detergent use surfactant |
| CN104059783A (en) * | 2014-06-10 | 2014-09-24 | 深圳市新纶科技股份有限公司 | Preparation method of surfactant for detergents and detergent composition |
| CN108779602A (en) * | 2016-01-04 | 2018-11-09 | 尼克瓦格斯有限公司 | improved method for removing textile dyes |
| CN106554861A (en) * | 2016-10-14 | 2017-04-05 | 无锡市华诚印染剂厂 | Polyester cotton detergent |
| CN106592284A (en) * | 2016-11-24 | 2017-04-26 | 张家港市德宝化工有限公司 | Reduction clearing method used for synthetic fiber |
| CN107828534A (en) * | 2017-11-14 | 2018-03-23 | 广州先盈生物科技有限公司 | A kind of efficient resist printing detergent for garment wash and preparation method thereof |
| CN109610206A (en) * | 2018-11-15 | 2019-04-12 | 纳派化学(上海)有限公司 | A kind of preparation method of novel dispersion dyeing efficient cleaner |
| CN112726236A (en) * | 2020-12-28 | 2021-04-30 | 绍兴海成化工有限公司 | Neutralization soaping agent |
| CN112726236B (en) * | 2020-12-28 | 2022-06-17 | 绍兴海成化工有限公司 | Neutralization soaping agent |
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| Publication number | Publication date |
|---|---|
| CN101130717B (en) | 2010-05-12 |
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