CN101113220A - Glossy sheet material and preparation method therefor - Google Patents
Glossy sheet material and preparation method therefor Download PDFInfo
- Publication number
- CN101113220A CN101113220A CNA2007100291986A CN200710029198A CN101113220A CN 101113220 A CN101113220 A CN 101113220A CN A2007100291986 A CNA2007100291986 A CN A2007100291986A CN 200710029198 A CN200710029198 A CN 200710029198A CN 101113220 A CN101113220 A CN 101113220A
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- glossy
- sheet material
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- hips
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Abstract
The invention provides a glossy plank stuff material and a preparation method thereof. The glossy plank stuff material comprises a glossy molding level HIPS base material and accessories of polish-increasing masterbatch and strengthening masterbatch. The concrete preparation method is that: the materials are mixed according to a certain proportion and dried to make the glossy plank stuff level HIPS material which is processed into the glossy plank stuff material through an extruding plate and surface corona, then the plank stuff material can be used as a linear or other components of a chest/a door of a refrigerator/a cabinet through vacuum heat molding process, pressing and cutting, as wall as assembling technique. The invention has low production cost and the linear or other components of the chest/door produced by the material has glossy surface, beautiful appearance, good corrosion resistance and strong antistatic performance, thereby the surface is easy to be cleaned but does not easily absorb dust.
Description
Technical field
The present invention relates to the plastic material technical field, more particularly, relate to a kind of preparation method who is used to make case/door lining or other product of refrigerator/refrigerator with glossy sheet material and this sheet material.
Background technology
In the prior art, case/the door lining of refrigerator/refrigerator or other product often use the ABS PP Pipe Compound of sheet material level or use the HIPS PP Pipe Compound of sheet material level to make, use these two kinds of sheet material level materials all to have following shortcoming: one, the ABS PP Pipe Compound of sheet material level has gloss, but price comparison height, the manufacturing cost height, and its erosion resistance is bad, a little less than the antistatic property; Two, the HIPS PP Pipe Compound of sheet material level is inferior light, glossiness is bad, price comparison is cheap, use the HIPS material of sheet material level, elder generation's extrusion board, just can make case/door lining or other product of refrigerator/refrigerator again by vacuum thermoforming technology, but its outward appearance lacks gloss, and the liner of making or the easy dust suction of other product, difficult cleaning.
Summary of the invention
The purpose of this invention is to provide a kind of glossy sheet material that has, use the case/door lining of refrigerator/refrigerator that this sheet material makes or other product low cost of manufacture, glossy, erosion resistance good, antistatic property is strong.
Another object of the present invention provides above-mentioned preparation method with glossy sheet material.
The technical scheme that the present invention solves the problems of the technologies described above is: a kind of have a glossy sheet material, the auxiliary material that comprises the base-material of band glossy injection grade HIPS and the masterbatch that adds lustre to, enhancing masterbatch, in order to satisfy the needs of different colours, in above-mentioned materials, can also add colour batch.
The parts by weight of above-mentioned each component are: band glossy injection grade HIPS:70～90 parts, masterbatch adds lustre to: 2～10 parts, strengthen masterbatch: 3～20 parts.
The preferred weight umber of above-mentioned each component is: band glossy injection grade HIPS:75～85 parts, masterbatch adds lustre to: 5～10 parts, strengthen masterbatch: 10～18 parts.Specifically, the masterbatch major ingredient that adds lustre to comprises silicone based and the oilness auxiliary agent, and wherein the oilness auxiliary agent is silicone or silicone oil or polyethylene wax or monostearate; Strengthening masterbatch is SBS series elastomerics, shore hardness Shore A=60～85.
Another technical scheme of technical solution problem of the present invention: a kind of preparation method of glossy sheet material may further comprise the steps:
(1) will mix with the base-material of glossy injection grade HIPS, the auxiliary material of add lustre to masterbatch and enhancing masterbatch by suitable parts by weight;
(2) said mixture after carrying out drying, is made 70～90 ℃ of high temperature band glossy sheet material level HIPS pellet;
(3) above-mentioned band glossy sheet material level HIPS pellet is made sheet material by plate squeezing and surface corona processing.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention has the glossy sheet material owing to adopt the base-material of band glossy injection grade HIPS to make with the auxiliary material of the masterbatch that adds lustre to, enhancing masterbatch, have case/door lining or other product that the glossy sheet material is made refrigerator/refrigerator with this, the product surface glossiness is good, good looking appearance is generous, erosion resistance is good, antistatic property is strong, be difficult for dust suction, easy to clean.
Description of drawings
Fig. 1 is the schematic flow sheet that the present invention has glossy sheet material preparation method.
Embodiment
The present invention can be applied to have case/door lining or other product of refrigerator/refrigerator that the glossy sheet material makes, this have the glossy sheet material comprise band glossy injection grade HIPS the base-material and the masterbatch that adds lustre to, strengthen the auxiliary material of masterbatch.
It is base-material that the present invention selects band gloss injection grade HIPS for use, and (mainly be that toughened master batch is an auxiliary material, wherein the parts by weight of each component are: band glossy injection grade HIPS:70～90 parts, preferred 75～85 parts with add lustre to masterbatch and enhancing masterbatch; Masterbatch adds lustre to: 2～10 parts, and preferred 5～10 parts; Strengthen masterbatch: 3～20 parts, preferred 10～18 parts.In order to satisfy the needs that this has glossy sheet material different colours, also need add colour batch usually.
Above-mentioned selected band gloss injection grade HIPS base-material, its concrete physicals is as follows:
| Tensile strength | The socle girder notched Izod impact strength | Melt flow index | Modulus in flexure | Glossiness | |
| Index | ≥30MPa | ≥6KJ/M 2 | 2～6g/10min | ≥3000MPa | ≥80％ |
The above-mentioned selected masterbatch major ingredient that adds lustre to is silicone based and other oilness auxiliary agent, this oilness auxiliary agent is silicone or silicone oil or polyethylene wax or monostearate, its carrier is high light HIPS material, and addition is 2～10%, and glossiness can improve 20～30%.
Above-mentioned selected enhancing masterbatch is a SBS series elastomerics, shore hardness Shore A=60～85, and this enhancing masterbatch can have considerable influence to glossiness.Rubber size is more little, can reduce the reduction of glossiness, but rubber size is little after to a certain degree, and the shock resistance influence of material is increased.
This preparation method with glossy sheet material may further comprise the steps:
(1) will be by suitable parts by weight with the base-material of glossy injection grade HIPS, the auxiliary material of add lustre to masterbatch and enhancing masterbatch mixes;
(2) said mixture after carrying out drying, is made 70～90 ℃ of high temperature band glossy sheet material level HIPS pellet;
(3) above-mentioned band glossy sheet material level HIPS pellet is handled to make by plate squeezing and surface corona have the glossy sheet material.
Above-mentioned have the glossy sheet material and make case/door lining or other product of refrigerator/refrigerator through following procedure of processing:
(1) with above-mentioned sheet material vacuum thermoforming processing;
(2) the sheet material punching that above-mentioned process vacuum thermoforming is processed becomes case/door lining or other product of refrigerator/refrigerator.
Above-mentioned three kinds of materials are in be mixed back plate squeezing and after vacuum thermoforming processing of certainweight ratio, and the performance of gained sheet material is as follows:
| Shock strength | Tensile strength | Elongation | Glossiness | Melt flow index | |
| Vertically | 70～100J/M | 22～30MPa | 30～60％ | 60～85％ | 0.8～1.5g/10min |
| Laterally | 90～120J/M | 23～32MPa | 45～70％ | 60～85％ |
List three kinds of concrete embodiment below:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | ||
| Band gloss injection grade HIPS | 80 | 80 | 85 | |
| Masterbatch adds lustre to | 5 | 8 | 5 | |
| Strengthen masterbatch | 15 | 12 | 10 | |
| Embodiment 1 | Embodiment 2 | Embodiment 3 | ||
| Shock strength | Vertically | 85J/M | 80J/M | 73J/M |
| Laterally | 104J/M | 101J/M | 95J/M | |
| Tensile strength | Vertically | 25MPa | 26.3MPa | 28MPa |
| Laterally | 26MPa | 27.5MPa | 29.6MPa | |
| Elongation | Vertically | 48％ | 45％ | 40％ |
| Laterally | 63.1％ | 60％ | 53％ | |
| Glossiness | Vertically | 62％ | 72％ | 80％ |
| Laterally | 62％ | 72％ | 80％ | |
| Melt flow index | 0.9g/10min | 1.1g/10min | 1.3g/10min | |
What make as stated above has a glossy sheet material, can be widely used on the case/door lining or other product of making refrigerator, refrigerator, low cost of manufacture, and it is strong that case/door lining of making or other product surface have gloss, good looking appearance, erosion resistance reaches antistatic property well, its surface is difficult for dust suction, and is easy to clean.
Claims (8)
1. one kind has the glossy sheet material, it is characterized in that: the auxiliary material that comprises the base-material of band glossy injection grade HIPS, the masterbatch that adds lustre to, enhancing masterbatch.
2. according to claim 1 have a glossy sheet material, and it is characterized in that: the concrete parts by weight of above-mentioned each component are as follows: band glossy injection grade HIPS:70～90 parts, masterbatch adds lustre to: 2～10 parts, strengthen masterbatch: 3～20 parts.
3. according to claim 2 have a glossy sheet material, and it is characterized in that: the preferred weight umber of above-mentioned each component is: band glossy injection grade HIPS:75～85 parts, masterbatch adds lustre to: 5～10 parts, strengthen masterbatch: 10～18 parts.
4. each describedly has a glossy sheet material according to claim 1 to 3, and it is characterized in that: the masterbatch that adds lustre to comprises silicone based and the oilness auxiliary agent.
5. according to claim 4 have a glossy sheet material, and it is characterized in that: above-mentioned oilness auxiliary agent is silicone or silicone oil or polyethylene wax or monostearate.
6. according to claim 5 have a glossy sheet material, it is characterized in that: strengthening masterbatch is SBS series elastomerics.
7. according to claim 1 have a glossy sheet material, it is characterized in that: also comprise colour batch.
8. the preparation method with glossy sheet material according to claim 1 is characterized in that may further comprise the steps:
(1) will be by suitable parts by weight with the base-material of glossy injection grade HIPS, the auxiliary material of add lustre to masterbatch and enhancing masterbatch mixes;
(2) said mixture is made band glossy sheet material level HIPS pellet after carrying out drying at 70～90 ℃;
(3) above-mentioned band glossy sheet material level HIPS pellet is made sheet material by plate squeezing and surface corona processing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100291986A CN101113220B (en) | 2007-07-17 | 2007-07-17 | Glossy sheet material and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100291986A CN101113220B (en) | 2007-07-17 | 2007-07-17 | Glossy sheet material and preparation method therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101113220A true CN101113220A (en) | 2008-01-30 |
| CN101113220B CN101113220B (en) | 2010-09-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100291986A Expired - Fee Related CN101113220B (en) | 2007-07-17 | 2007-07-17 | Glossy sheet material and preparation method therefor |
Country Status (1)
| Country | Link |
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| CN (1) | CN101113220B (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827430A (en) * | 2012-09-11 | 2012-12-19 | 王光华 | Preparation method of special materials for door liners of refrigerator-freezer liners |
| CN102838812A (en) * | 2012-09-11 | 2012-12-26 | 王光华 | Preparation method of liner and door liner materials of refrigerators and freezers |
| CN102838814A (en) * | 2012-09-11 | 2012-12-26 | 王光华 | Preparation method for special inner liner material of refrigerating cabinet |
| CN102838813A (en) * | 2012-09-11 | 2012-12-26 | 王光华 | Preparation method of refrigerator and freezer liner door liner materials |
| CN103509307A (en) * | 2013-09-23 | 2014-01-15 | 海信容声(广东)冰箱有限公司 | High-gloss refrigerator liner |
| CN103692668A (en) * | 2013-12-13 | 2014-04-02 | 东莞市益亨表面处理科技有限公司 | Surface treatment equipment |
| CN104744869A (en) * | 2015-03-23 | 2015-07-01 | 利丰新材料科技（深圳）有限公司 | 3D printed HIPS consumable material and preparation method thereof |
| CN104744868A (en) * | 2013-12-26 | 2015-07-01 | 奇美实业股份有限公司 | Impact-resistant styrene polymer composition for refrigerator plates |
| WO2019021546A1 (en) * | 2017-07-28 | 2019-01-31 | テクノＵｍｇ株式会社 | Sliding resin composition and body molded therefrom |
-
2007
- 2007-07-17 CN CN2007100291986A patent/CN101113220B/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102827430A (en) * | 2012-09-11 | 2012-12-19 | 王光华 | Preparation method of special materials for door liners of refrigerator-freezer liners |
| CN102838812A (en) * | 2012-09-11 | 2012-12-26 | 王光华 | Preparation method of liner and door liner materials of refrigerators and freezers |
| CN102838814A (en) * | 2012-09-11 | 2012-12-26 | 王光华 | Preparation method for special inner liner material of refrigerating cabinet |
| CN102838813A (en) * | 2012-09-11 | 2012-12-26 | 王光华 | Preparation method of refrigerator and freezer liner door liner materials |
| CN103509307A (en) * | 2013-09-23 | 2014-01-15 | 海信容声(广东)冰箱有限公司 | High-gloss refrigerator liner |
| CN103509307B (en) * | 2013-09-23 | 2016-01-27 | 海信容声(广东)冰箱有限公司 | A kind of high gloss type inner container of icebox |
| CN103692668A (en) * | 2013-12-13 | 2014-04-02 | 东莞市益亨表面处理科技有限公司 | Surface treatment equipment |
| CN103692668B (en) * | 2013-12-13 | 2015-12-30 | 东莞市益亨表面处理科技有限公司 | Surface processing equipment |
| CN104744868A (en) * | 2013-12-26 | 2015-07-01 | 奇美实业股份有限公司 | Impact-resistant styrene polymer composition for refrigerator plates |
| CN104744869A (en) * | 2015-03-23 | 2015-07-01 | 利丰新材料科技（深圳）有限公司 | 3D printed HIPS consumable material and preparation method thereof |
| WO2019021546A1 (en) * | 2017-07-28 | 2019-01-31 | テクノＵｍｇ株式会社 | Sliding resin composition and body molded therefrom |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101113220B (en) | 2010-09-01 |
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Granted publication date: 20100901 Termination date: 20110717 |