CN101108361A - Manufacturing method of faujasite coated phosphorus heteropoly tungstic acid catalyzer - Google Patents
Manufacturing method of faujasite coated phosphorus heteropoly tungstic acid catalyzer Download PDFInfo
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- CN101108361A CN101108361A CNA2007100698600A CN200710069860A CN101108361A CN 101108361 A CN101108361 A CN 101108361A CN A2007100698600 A CNA2007100698600 A CN A2007100698600A CN 200710069860 A CN200710069860 A CN 200710069860A CN 101108361 A CN101108361 A CN 101108361A
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Abstract
The invention relates to a preparation method of faujasite covered phospho-tungstic heteropoly acid catalyst. Tungstate and phosphate are taken as raw materials, faujasite is the generatrix for covering phospho-tungstic heteropoly acid. A making-ship-in-a-bottle method is adopted to synthesize the catalyst by in-situ reaction in a microwave reactor. The invention has the advantages of the short synthesizing time and the high synthesizing efficiency; and the crystallographic structure of the faujasite maintains integral in the acidification synthesis process.
Description
Technical field
The present invention relates to a kind of novelty, novel solid acid---the preparation method of faujasite coated phosphorus heteropoly tungstic acid efficiently.
Background technology
Solid acid (for example: molecular sieve, oxide, mixed oxide and phosphate etc.) is the crucial catalyst of a class in the production process of petrochemical industry and many chemicals.Up to the present, nearly more than 180 industrial process have used above-mentioned solid acid catalyst.But, still have many acid catalyzed reactions (for example: esterification, hydrolysis and hydration reaction etc.) need be at a large amount of inorganic acids (sulfuric acid, hydrochloric acid etc.) or AlCl
3Carry out under the effect, these courses of reaction are accompanied by a series of problems such as serious toxicity, corrosivity, product separation and liquid waste processing difficulty.Thereby adopt safety, the solid acid that do not have corrosion and an easily separated recovery substitutes liquid acid and has great importance for environmental protection as catalyst.
Many organic reactions (for example: hydrolysis, hydration reaction, esterification and Prins reaction etc. always have water to exist in) raw material or the product, because the water electrode in the reaction system easily makes the activated centre of solid acid catalyst (as molecular sieve etc.) poison and inactivation, have only only a few solid acid (as heteropoly acid) to have to a certain degree active and stable.
Heteropoly acid has the characteristic of many excellences, as: component is simple, and structure determines to have the architectural feature of general complex and metal oxide; It is the polyelectron oxidant, is again strong protonic acid, and its oxidisability and acidity can be carried out modulation by changing its composition mode; Its soluble in water and polar organic solvent, its solution is generally more stable; The heteropoly acid that wherein has the Keggin structure has by force and the characteristic of the Br nsted acid of homogeneous etc.These character can make heteropoly acid be used as homogeneous phase and heterogeneous oxidation type catalyst and acid catalyst.Heteropoly acid is widely used in ester decomposition reaction, alkylated reaction, epoxides ring-opening reaction, condensation reaction and etherification reaction etc. as a kind of novel acid catalyst.
But it is little (less than 10m that heteropoly acid also exists specific area
2/ g), heat endurance is low, be difficult for defectives such as recoverys, water-soluble easy loss, thereby therefore usually the employing infusion process loaded by heteropoly acid is improved its specific area, heat endurance, catalytic activity and repeat performance on carrier.People are with various carriers in recent years, as: active carbon, amorphous silica, molecular sieve wait the carried heteropoly acid compound.But because heteropolyanion shifts to carrier generation electronics easily, the acidity of heteropoly acid reduces after the load; Simultaneously in the application of reality, problem such as still exist easy solution-off of heteropoly acid and loss, target product selectivity is low in complex reaction.
Meanwhile, the solid acid catalyst----molecular sieve that an other class is commonly used because its back bone network defective is few, acidity a little less than, for the reaction of need strong acid catalysis, catalytic activity is low.But have uniform duct in the molecular sieve structure, when the molecular size of reactant, product and intracrystalline aperture were close, the selectivity of reaction often depended on the relative size in molecule and aperture, often has very high target product selectivity when mating mutually.Therefore, if with the highly acid of heteropoly acid combine with the duct characteristic of molecular sieve may produce not only have stronger acidity, but also new solid acid catalyst with higher selectivity of product.Because the duct of Y zeolite is generally 0.74 * 0.78 nanometer, and therefore the diameter of the phosphorus heteropoly tungstic acid of Keggin structure is difficult to by traditional impregnation technology heteropoly acid is introduced directly in the duct of molecular sieve greatly about about the 1.0-1.2 nanometer.But, Y zeolite has the supercage structure, and the size in its inner spherical hole is 1.3 nanometers, is incorporated in the molecular sieve supercage if will synthesize the raw material of phosphorus heteropoly tungstic acid in advance, adopt " shipbuilding in the bottle " method original position synthetic then, the heteropoly acid that finally obtains will be fixed on Y zeolite inside.Zhi Bei faujasite coated phosphorus heteropoly tungstic acid catalyzer by this method, the acidity that can regulate catalyst by the load capacity of regulating heteropoly acid remedies the more weak shortcoming of acidic zeolite on the one hand, improves its catalytic performance; Also can increase the shape selectivity energy of product on the other hand by the duct characteristic of molecular sieve.Because limit in the duct of molecular sieve, can effectively overcome the problems such as loss of heteropoly acid in the use simultaneously.
People such as B.Sulikowski are synthetic phosphorus heteropoly tungstic acid in the supercage that proposed first at Y zeolite in 1996, and they will be in advance through H
4The Y zeolite of EDTA dealuminzation is as fertile material, the catalyst that makes through infrared and
31The P-nuclear magnetic resonance characterizes phosphorus heteropoly tungstic acid and forms in the supercage of Y zeolite, and is applied to the disproportionated reaction of meta-xylene.(CatalysisLetters 1996,39,27)
People such as B.Sulikowski are synthetic phosphorus heteropoly tungstic acid in the supercage that proposed first at Y zeolite in 1996, and they will be in advance through H
4The Y zeolite of EDTA dealuminzation is as fertile material, the catalyst that makes through infrared and
31The P-nuclear magnetic resonance characterizes phosphorus heteropoly tungstic acid and forms in the supercage of Y zeolite, but combined coefficient is very low.(Catalysis Letters 1996,39,27)
In the work afterwards, they carry out the cesium ion exchange to the synthetic phosphato-molybdic heteropolyacid of original position in the Y zeolite supercage again, to increase the stability of phosphato-molybdic heteropolyacid.The reservation amount of phosphato-molybdic heteropolyacid in supercage through the part exchange that found that increases, but because the reduction of exchange back heteropoly acid acid amount, its catalytic effect descends on the contrary in esterification.(Reaction Kineticsand Catalysis Letters 2000,69,253)
In addition, they have also studied in the molecular sieve parent silica alumina ratio to the influence of combined coefficient, find medium aluminium content to synthetic be favourable.The raw material of synthetic phosphato-molybdic heteropolyacid can at first be exchanged with the aluminium atom by the aluminium inducing atom, thereby promotes synthetic.But too much aluminium content has influenced the acid amount of phosphato-molybdic heteropolyacid on the contrary.(Chemical Engineering Science 2001,56,799)
What above bibliographical information adopted all is high-temperature water hot acid metallization processes, synthetic medium acidity higher (pH=1.5-2), solution temperature height (95 degrees centigrade), generated time long (0.5-3 hour), very easily cause caving in of parent molecule sieve structure, be difficult to obtain the intact catalyst of faujasite crystal formation.
In order to eliminate these top adverse effects, people such as S.R.Mukai attempted to adopt the ion-exchange membrane technology to realize effective coating to heteropoly acid in 2003.Yet they studies show that, though adopt electrode reaction to help the synthetic of phosphato-molybdic heteropolyacid, be fixed in the molecular sieve supercage amount but seldom.Therefore, they have still adopted traditional hydro-thermal method to synthesize, and stablize phosphomolybdic acid by adopting interpolation four butanols, have obtained coating the catalyst of heteropoly acid under 60-150 degree centigrade of different temperatures.(Applied Catalysis A:General 2003,256,107)。
Skeleton according to molecular sieve under the method condition of above-mentioned bibliographical information subsides in building-up process, and obtaining is the heteropoly tungstic acid of unbodied coated with silica phosphorus.Therefore, traditional hydration becomes technology to be difficult to successfully synthetic this new solid acid catalyst material, needs to explore and develop new synthesis technique.
Summary of the invention
The purpose of this invention is to provide a kind of problem that both can overcome aspects such as the synthetic medium acidity that exists in the technology of bibliographical information is higher, temperature is high, generated time is long, need not add stabilizing agent again; Can obtain simultaneously the synthesis technique of the intact phosphorus heteropoly tungstic acid catalyzer of faujasite crystal formation.
The preparation method who the invention provides the faujasite coated phosphorus heteropoly tungstic acid catalyzer mainly contains: with tungstates and phosphate is raw material, faujasite is the parent of coated phosphorus heteropoly tungstic acid, adopt " shipbuilding in the bottle " method, the reaction original position is synthetic in microwave reactor, and preparation process is as follows in detail:
1, be 5-15 by tungstates and phosphate weight ratio: 1, two kinds of salt are dissolved in the deionized water fully, make tungstates and phosphatic mixed solution, wherein the w/v of tungstates and deionized water is 1: 5-10;
2, the faujasite parent is placed vacuum reactor, by outer wall heating steam and other desorbing gas to help to adhere in the molecular sieve pore passage;
3, by faujasite parent and tungstates weight ratio be: 1: 1-2, in the faujasite parent, drip tungstates and the phosphatic mixed solution that step 1 obtains, make it to soak into fully, tungstate ion and phosphate anion are entered in the supercage of molecular sieve, after solution dropwises, suspension is transferred to beaker stirred 12-24 hour;
4, in the suspension of step 3 gained, drip acidulant to pH=1, be transferred to rapidly in the round-bottomed flask then, put into microwave reactor and react, 3-10 minute microwave reaction time, 650 watts of power.After question response finished, cooling was filtered, and with the complete wash-out of the phosphotungstic acid on molecular sieve surface, again with the catalyst oven dry, 250 degrees centigrade of roastings 2 hours can obtain catalyst of the present invention with hot water.
The synthesis technique of novel faujasite coated phosphorus heteropoly tungstic acid catalyzer provided by the invention is with the parent of faujasite as coated phosphorus heteropoly tungstic acid.
The phosphatic raw materials of preparation phosphotungstic acid is sodium hydrogen phosphate, sodium dihydrogen phosphate, sodium phosphate, dipotassium hydrogen phosphate, potassium dihydrogen phosphate and potassium phosphate in the faujasite coated phosphorus heteropoly tungstic acid catalyzer of the present invention, and the tungstates raw material is sodium tungstate, potassium tungstate and ammonium tungstate.The raw material of preferred synthetic phosphotungstic acid is sodium tungstate and sodium hydrogen phosphate.Acidulant is selected concentrated hydrochloric acid or phosphoric acid for use, is preferably concentrated hydrochloric acid.
The heating using microwave that the present invention adopts is to utilize microwave to quicken to be heated the internal motion of material and to generate heat, owing to do not need the process heat transfer process, material inside promptly can reach heating-up temperature in moment.Compare with conventional heating means, heating using microwave have reaction system be heated evenly, can promote between reaction molecular collision probability, shorten the reaction time, improve characteristics such as reaction yield.Therefore in the process that adopts " shipbuilding in the bottle " method synthetic faujasites coated phosphorus heteropoly tungstic acid new catalyst, the auxiliary original position of heating using microwave is synthesized, and can shorten the ruined possibility of time, minimizing faujasite self structure in building-up process of synthetic reaction.
Synthesis technique provided by the invention all can obtain complete faujasite crystalline structure when suitable in the microwave assisted reaction time.The acid strength of the catalyst that obtains by this technology is suitable with the catalyst that directly adopts equi-volume impregnating to obtain with the acid amount, and phosphotungstic acid can not run off in reaction.
The specific embodiment
Embodiment 1
Sodium tungstate 15 grams and sodium hydrogen phosphate 1.5 grams are dissolved in 50 ml deionized water simultaneously, add faujasite 10 grams, fully stirred 24 hours.Suspension is put into 95 degrees centigrade of hot water, slowly drips concentrated hydrochloric acid under stirring, and stops when being controlled to pH=1 with acidometer adding, and continues to react half an hour, makes it to generate phosphotungstic acid.Cooling back suction filtration repeatedly washs with 100 milliliters 80 degrees centigrade deionized water at every turn, will be attached to the complete wash-out of the phosphotungstic acid on molecular sieve surface, and collection filtrate is detected filtrate with ultraviolet spectra, to judge whether the complete wash-out of the phosphotungstic acid that will adhere to.After treating the complete wash-out of phosphotungstic acid on molecular sieve surface, with catalyst oven dry, 250 degrees centigrade of roastings 2 hours.He Cheng sample mark PW@USY (hydro-thermal method) in this way.Above-mentioned structures of samples adopts means such as X-ray diffraction, nitrogen adsorption and ammonia temperature programmed desorption to detect, and the results are shown in Table 1 and 2.
Embodiment 2
Be dissolved in 50 ml deionized water sodium tungstate 15 grams and sodium hydrogen phosphate 1.5 grams standby fully.Place round-bottomed flask to vacuumize 10 gram faujasites, at outer wall heating steam and other desorbing gas to help to adhere in the molecular sieve pore passage.In faujasite, drip the mixed solution of sodium tungstate and sodium hydrogen phosphate then, make it to soak into fully, enter in the supercage of molecular sieve to help tungstate ion and phosphoric acid hydrogen radical ion.After solution dropwises, suspension is transferred to beaker stirred 12 hours, at room temperature drip concentrated hydrochloric acid again, it is transferred to rapidly in the round-bottomed flask, put into microwave reactor and react to pH=1.From 3 to 9 minutes microwave reaction time, power is 650 watts.After question response finished, cooling was filtered, with hot water with the complete wash-out of the phosphotungstic acid on molecular sieve surface, again with the catalyst oven dry, 250 degrees centigrade of roastings 2 hours.He Cheng sample mark PW@USY (X minute) (X represents the microwave reaction time) in this way.Above-mentioned structures of samples adopts means such as X-ray diffraction, nitrogen adsorption and ammonia temperature programmed desorption to detect, and the results are shown in Table 1 and 2.
Embodiment 3
10 gram faujasites are joined in the aqueous solution that is dissolved with 4 gram phosphorus heteropoly tungstic acids carry out incipient impregnation, room temperature is placed after 24 hours the catalyst oven dry, 250 degrees centigrade of roastings 2 hours.He Cheng sample mark PW/USY in this way.Above-mentioned structures of samples adopts means such as X-ray diffraction, nitrogen adsorption and ammonia temperature programmed desorption to detect, and the results are shown in Table 1 and 2.
Embodiment 4
Be dissolved in 50 ml deionized water sodium tungstate 15 grams and sodium phosphate 1.7 grams standby fully.Place round-bottomed flask to vacuumize 10 gram faujasites, at outer wall heating steam and other desorbing gas to help to adhere in the molecular sieve pore passage.In faujasite, drip the mixed solution of sodium tungstate and sodium phosphate then, make it to soak into fully, enter in the supercage of molecular sieve to help tungstate ion and phosphate anion.After solution dropwises, suspension is transferred to beaker stirred 12 hours, at room temperature drip concentrated hydrochloric acid again, it is transferred to rapidly in the round-bottomed flask, put into microwave reactor and react to pH=1.The microwave reaction time is 7 minutes, and power is 650 watts.After question response finished, cooling was filtered, with hot water with the complete wash-out of the phosphotungstic acid on molecular sieve surface, again with the catalyst oven dry, 250 degrees centigrade of roastings 2 hours.He Cheng sample mark PW@USY (sodium phosphate) in this way.Above-mentioned structures of samples adopts means such as X-ray diffraction, nitrogen adsorption and ammonia temperature programmed desorption to detect, and the results are shown in Table 1.
Embodiment 5
Be dissolved in 50 ml deionized water sodium tungstate 15 grams and sodium dihydrogen phosphate 1.2 grams standby fully.Place round-bottomed flask to vacuumize 10 gram faujasites, at outer wall heating steam and other desorbing gas to help to adhere in the molecular sieve pore passage.In faujasite, drip the mixed solution of sodium tungstate and sodium dihydrogen phosphate then, make it to soak into fully, enter in the supercage of molecular sieve to help tungstate ion and dihydrogen phosphate ions.After solution dropwises, suspension is transferred to beaker stirred 12 hours, at room temperature drip concentrated hydrochloric acid again, it is transferred to rapidly in the round-bottomed flask, put into microwave reactor and react to pH=1.The microwave reaction time is 7 minutes, and power is 650 watts.After question response finished, cooling was filtered, with hot water with the complete wash-out of the phosphotungstic acid on molecular sieve surface, again with the catalyst oven dry, 250 degrees centigrade of roastings 2 hours.He Cheng sample mark PW@USY (sodium dihydrogen phosphate) in this way.Above-mentioned structures of samples adopts means such as X-ray diffraction, nitrogen adsorption and ammonia temperature programmed desorption to detect, and the results are shown in Table 1.
Embodiment 6
Be dissolved in 50 ml deionized water potassium tungstate 15 grams and sodium hydrogen phosphate 1.5 grams standby fully.Place round-bottomed flask to vacuumize 10 gram faujasites, at outer wall heating steam and other desorbing gas to help to adhere in the molecular sieve pore passage.In faujasite, drip the mixed solution of potassium tungstate and sodium hydrogen phosphate then, make it to soak into fully, enter in the supercage of molecular sieve to help tungstate ion and phosphoric acid hydrogen radical ion.After solution dropwises, suspension is transferred to beaker stirred 12 hours, at room temperature drip concentrated hydrochloric acid again, it is transferred to rapidly in the round-bottomed flask, put into microwave reactor and react to pH=1.The microwave reaction time is 7 minutes, and power is 650 watts.After question response finished, cooling was filtered, with hot water with the complete wash-out of the phosphotungstic acid on molecular sieve surface, again with the catalyst oven dry, 250 degrees centigrade of roastings 2 hours.He Cheng sample mark PW@USY (potassium tungstate) in this way.Above-mentioned structures of samples adopts means such as X-ray diffraction, nitrogen adsorption and ammonia temperature programmed desorption to detect, and the results are shown in Table 1.
Embodiment 7
Be dissolved in 50 ml deionized water ammonium tungstate 13 grams and sodium hydrogen phosphate 1.5 grams standby fully.Place round-bottomed flask to vacuumize 10 gram faujasites, at outer wall heating steam and other desorbing gas to help to adhere in the molecular sieve pore passage.In faujasite, drip the mixed solution of ammonium tungstate and sodium hydrogen phosphate then, make it to soak into fully, enter in the supercage of molecular sieve to help tungstate ion and phosphoric acid hydrogen radical ion.After solution dropwises, suspension is transferred to beaker stirred 12 hours, at room temperature drip concentrated hydrochloric acid again, it is transferred to rapidly in the round-bottomed flask, put into microwave reactor and react to pH=1.The microwave reaction time is 7 minutes, and power is 650 watts.After question response finished, cooling was filtered, with hot water with the complete wash-out of the phosphotungstic acid on molecular sieve surface, again with the catalyst oven dry, 250 degrees centigrade of roastings 2 hours.He Cheng sample mark PW@USY (ammonium tungstate) in this way.Above-mentioned structures of samples adopts means such as X-ray diffraction, nitrogen adsorption and ammonia temperature programmed desorption to detect, and the results are shown in Table 1.
Embodiment 8
Be dissolved in 50 ml deionized water sodium tungstate 15 grams standby fully.Place round-bottomed flask to vacuumize 10 gram faujasites, at outer wall heating steam and other desorbing gas to help to adhere in the molecular sieve pore passage.In faujasite, drip sodium tungstate solution then, make it to soak into fully, enter in the supercage of molecular sieve to help tungstate ion.After solution dropwises, suspension is transferred to beaker stirred 12 hours, at room temperature drip phosphoric acid again, it is transferred to rapidly in the round-bottomed flask, put into microwave reactor and react to pH=1.The microwave reaction time is 7 minutes, and power is 650 watts.After question response finished, cooling was filtered, with hot water with the complete wash-out of the phosphotungstic acid on molecular sieve surface, again with the catalyst oven dry, 250 degrees centigrade of roastings 2 hours.He Cheng sample mark PW@USY (phosphoric acid) in this way.Above-mentioned structures of samples adopts means such as X-ray diffraction, nitrogen adsorption and ammonia temperature programmed desorption to detect, and the results are shown in Table 1.
Table 1, different synthetic method gained structures of samples
Catalyst | Specific area (meters squared per gram) | Supercage pore volume (milliliter/gram) | The catalyst crystal formation |
USY | 693.6 | 0.25 | Faujasite |
PW@USY (hydro-thermal method) | 171.1 | 0.07 | Amorphous silica |
PW@USY (9 minutes) | 331.4 | 0.10 | Amorphous silica |
PW@USY (7 minutes) | 324.5 | 0.11 | Faujasite |
PW@USY (5 minutes) | 383.3 | 0.13 | Faujasite |
PW@USY (3 minutes) | 542.8 | 0.22 | Faujasite |
PW/USY | 476.7 | 0.21 | Faujasite |
PW@USY (sodium phosphate) | 351.3 | 0.12 | Faujasite |
PW@USY (sodium dihydrogen phosphate) | 362.4 | 0.11 | Faujasite |
PW@USY (potassium tungstate) | 321.2 | 0.12 | Faujasite |
PW@USY (ammonium tungstate) | 341.3 | 0.11 | Faujasite |
PW@USY (phosphoric acid) | 375.3 | 0.14 | Faujasite |
Table 2: the acid matter of different synthetic method gained samples
Catalyst | Total acid content (mM/gram) | Acid amount (mM/gram) | ||
Weak acid acid amount | Strong acid acid amount | |||
A | B | |||
USY hydro-thermal method PW@USY (9 minutes) PW@USY (7 minutes) PW/USY | 2.64 2.37 2.89 2.40 2.38 | 1.05 0.14 0.20 0.51 0.51 | 1.59 0.21 0.30 0.77 0.77 | 0 2.02 2.39 1.12 1.10 |
A: the strong acid acid amount B that faujasite produces: the strong acid acid amount that phosphotungstic acid produces.
Claims (8)
1. the preparation method of a faujasite coated phosphorus heteropoly tungstic acid catalyzer is a raw material with tungstates and phosphate, and faujasite is the parent of coated phosphorus heteropoly tungstic acid, adopts " shipbuilding in the bottle " method, and the reaction original position is synthetic in microwave reactor, and preparation process is as follows:
1) be 5-15 by tungstates and phosphate weight ratio: 1, two kinds of salt are dissolved in the deionized water fully, make tungstates and phosphatic mixed solution, wherein the w/v of tungstates and deionized water is 1: 5-10;
2) place reactor to vacuumize the faujasite parent, at outer wall heating steam and other desorbing gas to help to adhere in the molecular sieve pore passage;
3) by faujasite parent and tungstates weight ratio be: 1: 1-2, in the faujasite parent, drip tungstates and the phosphatic mixed solution that step 1 obtains, make it to soak into fully, tungstate ion and phosphoric acid hydrogen radical ion are entered in the supercage of molecular sieve, after treating that solution dropwises, suspension is transferred to beaker stirred 12-24 hour;
4) in the suspension of step 3 gained, drip acidulant to pH=1, be transferred to rapidly in the round-bottomed flask then, put into microwave reactor and react, 3-9 minute microwave reaction time, 650 watts of power, after reaction finished, cooling was filtered, water is with the complete wash-out of the phosphotungstic acid on molecular sieve surface, again with catalyst oven dry, 250 degrees centigrade of roastings 2 hours can obtain the faujasite coated phosphorus heteropoly tungstic acid catalyzer.
2. the preparation method of faujasite coated phosphorus heteropoly tungstic acid catalyzer according to claim 1 is characterized in that adopting microwave reactor, reaction time 3-9 minute.
3. the preparation method of faujasite coated phosphorus heteropoly tungstic acid catalyzer according to claim 1 is characterized in that described raw material tungstates is a kind of in sodium tungstate, potassium tungstate and the ammonium tungstate.
4. the preparation method of faujasite coated phosphorus heteropoly tungstic acid catalyzer according to claim 1 is characterized in that described raw material phosphate is a kind of in sodium hydrogen phosphate, sodium dihydrogen phosphate, sodium phosphate, dipotassium hydrogen phosphate, potassium dihydrogen phosphate and the potassium phosphate.
5. the preparation method of faujasite coated phosphorus heteropoly tungstic acid catalyzer according to claim 1 is characterized in that described tungstates and phosphatic raw materials are sodium tungstate and sodium hydrogen phosphate.
6. the preparation method of faujasite coated phosphorus heteropoly tungstic acid catalyzer according to claim 1 is characterized in that described tungstates and phosphate weight ratio are 5-15: 1.
7. the preparation method of faujasite coated phosphorus heteropoly tungstic acid catalyzer according to claim 6 is characterized in that described tungstates and phosphate weight ratio are 8-12: 1.
8. the preparation method of faujasite coated phosphorus heteropoly tungstic acid catalyzer according to claim 1 is characterized in that described acidulant selects concentrated hydrochloric acid or phosphoric acid for use.
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