CN101096440B - SEBS thermoplastic elastomer floor and manufacturing method thereof - Google Patents
SEBS thermoplastic elastomer floor and manufacturing method thereof Download PDFInfo
- Publication number
- CN101096440B CN101096440B CN2007100745279A CN200710074527A CN101096440B CN 101096440 B CN101096440 B CN 101096440B CN 2007100745279 A CN2007100745279 A CN 2007100745279A CN 200710074527 A CN200710074527 A CN 200710074527A CN 101096440 B CN101096440 B CN 101096440B
- Authority
- CN
- China
- Prior art keywords
- sebs
- floor
- thermoplastic elastomer
- forcing machine
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Floor Finish (AREA)
Abstract
The invention discloses a SEBS thermoplastic elastic floor, which comprises the following parts: 100wt% SEBS resin and modifier, 75-125wt% rubber filling oil, 20-60wt% polypropylene, 200-400wt% mineral filler, 0.8-1.2wt% lubricant and 0.45-0.70% aging retarder. The making method comprises the following steps: weighing raw material; blending; graining; squeezing; moulding; obtaining the product with anti-slip, abrasion-proof, noise reduction and weather resistant property; fitting for paving basic ground to replace plastic or rubber floor material.
Description
Technical field
The present invention relates to a kind of thermoplastic elastomer floor material and manufacture method thereof, particularly relate to a kind of SEBS thermoplastic elastomer floor and manufacture method thereof.
Background technology
Ground paver commonly used mainly contains timber floor, marble, ceramic tile, carpet and high molecular weight plastic floor; Wherein, the high molecular weight plastic floor with the foot sense of excellence, wear-resisting, sound-absorbing, anti-skidding, moistureproof, protect performances such as dim, and assortment are many, long service life, cost is moderate, installation and maintenance are simple, can increase the advantage of function such as fire-retardant, antistatic, antibiotic on demand, be subject to people's attention more and more.The high molecular weight plastic floor is widely used in following several respects:
1, particular safety place: school, kindergarten, nursery, Senior Citizen Activity Center, the home for the aged, hospital etc.;
2, need noise reduction, sound damping place: meeting room, office, laboratory, museum, Library, broadcasting studio, office building, corridor and large-scale exhibition center, product introduction center etc.;
3, sport and body-building place: stadium, training place, gymnasium, arena, court, playground, natatorium etc.;
4, the vehicles and traffic system: subway/lightrailvehicle, train, automobile, boats and ships and drome, subway station, the customs entry and exit Room, station, harbour etc.;
5, production place: production plant such as pharmacy, biology, chemistry, electronics and test cabinet, watch-keeping cubicle, machine room etc.;
6, commerce and household place: shopping center, brand shop, boutique, performing art centre, teahouse, cafe, reception room, living room, stair, kitchen, toilet etc.
At present, the high molecular weight plastic floor mainly contains PVC plastic floor, rubber floor covering and polyurethane elastomer floor three classes.
Wherein, there is bad phenomenon such as feel like jelly summer, harden winter in the PVC plastic floor, under high-temperature condition, also can produce release and have a strong impact on the able-bodied softening agent of people, vinyl chloride monomer and organotin (comprising dibutyl tin, tributyl tin etc.) etc., will be eliminated gradually.
Rubber floor covering is made by natural rubber or synthetic rubber.Its subject matter is the multiple operation of its production process (need high temperature vulcanized), with high investment, high energy consumption and poor efficiency, simultaneously, and the recovery on waste rubber floor (comprising the scrap stock that produce in the production process) and to handle also be a serious environmental problem.
At present, range of application polyurethane elastomer floor more and more widely, need cast on-site and curing molding, be far from suitable for the overwhelming majority occasion that the crowd is dense needs often to change the floor, also exist simultaneously reaction not exclusively, the isocyanic ester left over and solidifying agent be (as 3,3 '-two chloro-4,4 '-diaminodiphenyl-methane) problem such as volatile.
Thermoplastic elastomer (Thermoplastic elastomer, be called for short TPE) is meant and shows caoutchouc elasticity at normal temperatures, again can plasticizing forming under the high temperature, have the type material of plastics and rubber characteristics concurrently.Have advantages such as easy to process, reusable, easy recovery, performance near or surpass some rubber, development in recent decades is rapidly.It partly replaces flexible PVC and traditional rubber, in fields such as daily necessities, stationery sports goods, automobile, household electrical appliances, medical treatment, toys, has obtained widespread use; But up to the present, the application aspect the floor is also rare, and the application of SEBS thermoplastic elastomer aspect the floor do not appear in the newspapers.
Summary of the invention
Technical problem to be solved by this invention is: a kind of SEBS thermoplastic elastomer floor is provided, and it has, and foot sense is excellent, wear-resisting, sound-absorbing, anti-skidding, moistureproof, characteristics such as the guarantor is dim, flexible for installation.
The further technical problem to be solved of the present invention is: a kind of manufacture method of SEBS thermoplastic elastomer floor is provided, and its production process advanced technology, method are simply, investment is little, energy consumption is low, efficient is high and safety and environmental protection.
For solving the problems of the technologies described above, the present invention adopts following technical scheme: a kind of SEBS thermoplastic elastomer floor is characterized in that it comprises each component of following weight part content:
100 parts of SEBS resin and modifiers thereof;
75～125 parts of rubber filling oils;
20～60 parts of polypropylene;
200～400 parts of mineral fillers;
0.8～1.2 part of lubricant;
0.45～0.70 part of protective agent.
Preferably, this SEBS resin and modifier thereof are the mixture of a kind of in the following material or at least two kinds: high molecular SEBS, lower molecular weight SEBS, maleic anhydride graft SEBS, acrylic ester grafted SEBS.
Preferably, this rubber filling oil is the mixture of a kind of in the following material or two kinds: naphthenic rubber oil, paraffinic base rubber oil.
Preferably, this polypropylene is one or both the mixture in the following material: homopolymerization type polypropylene, copolymerized type propene polymer.
Preferably, this mineral filler is the mixture of a kind of in the following material or at least two kinds: lime carbonate, talcum powder, wollastonite.
Preferably, this lubricant is the mixture of a kind of in the following material or at least two kinds: ethylene bis stearic amide, the two amine hydroxybenzenes of ethylene, Zinic stearas, calcium stearate, polyethylene wax, silicone resin.
Preferably, this protective agent is the mixture of a kind of in the following material or at least two kinds: β (3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) [3-(3 for propionic acid octadecyl ester, four, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] tetramethylolmethane, tricresyl phosphite (2,4-di-t-butyl carbobenzoxy), Tyox B, Octabenzone, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-the 5-chlorinated benzotriazole.
On the other hand, the present invention also proposes following technical scheme: a kind of manufacture method of SEBS thermoplastic elastomer floor, and it may further comprise the steps:
Take by weighing raw material stage, take by weighing each raw material: SEBS resin and modifier 100 weight parts thereof, rubber filling oil 75～125 weight parts according to promptly fixed consumption, polypropylene 20～60 weight parts, 200～400 parts of mineral fillers, lubricant 0.8～1.2 weight part, protective agent 0.45～0.70 weight part;
Mix and granulation step, make SEBS resin and modifier thereof absorb rubber filling oil fully after, again with other materials add stirrer for mixing evenly after, then with twin screw extruder extrude, granulation;
Extrusion moulding sheet material step, in the sheet material forcing machine, the extrusion moulding floor in extrusion moulding sheet material, is optionally carried out calendering and embossing and is handled, last rolling with the SEBS blend after the granulation.
Preferably, this each section of twin screw extruder temperature begins from charging opening, is followed successively by 190～210 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～210 ℃ of head temperatures.
Preferably, the sheet material forcing machine is individual layer forcing machine or two-layer compound forcing machine, and forcing machine host machine part temperature is 190～210 ℃, and the head section temperature is 195～215 ℃; And described sheet material forcing machine is when being the two-layer compound forcing machine, and the upper strata on the floor of its moulding is brand-new material, and lower floor is with material lower cost materials or reclaimed materials, and the thickness of the lower floor on the floor of two-layer compound extrusion moulding is 30～70% of floor total thickness.
The present invention has following beneficial effect: SEBS thermoplastic elastomer floor of the present invention, make full use of the advantage of thermoplastic elastomer, have excellent anti-skidding, wear-resisting, noise reduction, performance such as weather-proof, be adapted at laying on the basic unit ground such as cement, marble, ceramic tile, reinforcement plate, plank, quartz, stone-plastic plate, its laid processes is simple and convenient, lays the no remaining objectionable impurities in back and discharges; In use can not produce the phenomenon of deliquescing in summer, hardening in winter; Waste after it uses can be recycled, and is the emerging floor of a kind of environment-friendly type.
It can replace plastics or rubber floor covering, mat formation in the ground that takes the lead in being used for the vehicles (rolling stock, railcar, light rail vehicle, automobile, steamer etc.) and public place (power supply administration, hospital, stadiums, hotel, restaurant, station, harbour etc.), through rough Statistics, the two year demand floor total amount 8,000 ten thousand square meters, close nearly 500,000 tons of SEBS thermoplastic elastomer floor material;
The SEBS thermoplastic elastomer floor is guaranteeing also can to utilize its characteristic to give some specific function, to realize multi-functional and many kinds of product, the enhancing market adaptability outside its fundamental characteristics as pavement (anti-skidding, wear-resisting, weather-proof etc.).Such as: utilize its excellent electrical insulating property, use on the insulation floor that can be used as machine room, power station; Utilize its nontoxic, tasteless, pollution-free characteristic, be aided with nano anti-biotic material again, then can be used as the senior health shop compress material of hospital, health care institute, sanatorium; Utilize characteristics such as its good springiness, high abrasion, can be used as the material in agonistic sports place.In addition, also can be made into panel material functionally such as fire prevention or anti-electrostatic.
Manufacture method of the present invention, production technology advanced person, work simplification do not need high temperature vulcanized process, and save energy is invested for a short time, and operation is few, and potential safety hazard is few, the production efficiency height, the scrap stock in the production process can be recycled fully, safety and environmental protection.
Description of drawings
Fig. 1 is preparation method's of the present invention process flow sheet.
Below in conjunction with accompanying drawing the present invention is described further.
Embodiment
The invention provides a kind of SEBS thermoplastic elastomer floor, it comprises each component of following weight part content:
100 parts of SEBS resin and modifiers thereof;
75～125 parts of rubber filling oils;
20～60 parts of polypropylene;
200～400 parts of mineral fillers;
0.8～1.2 part of lubricant;
0.45～0.70 part of protective agent.
Wherein, described SEBS resin and modifier thereof are the mixture of a kind of in the following material or at least two kinds: high molecular SEBS, lower molecular weight SEBS, maleic anhydride graft SEBS, acrylic ester grafted SEBS.
Described rubber filling oil is the mixture of a kind of in the following material or two kinds: naphthenic rubber oil, paraffinic base rubber oil.
Described polypropylene is the mixture of a kind of in the following material or two kinds: homopolymerization type polypropylene, copolymerized type propene polymer.
Described mineral filler is the mixture of a kind of in the following material or at least two kinds: lime carbonate, talcum powder, wollastonite.
Described lubricant is the mixture of a kind of of following material or at least two kinds: ethylene bis stearic amide, the two amine hydroxybenzenes of ethylene, Zinic stearas, calcium stearate, polyethylene wax, silicone resin.
Described protective agent is the mixture of a kind of of following each material or at least two kinds: β (3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) [3-(3 for propionic acid octadecyl ester, four, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] tetramethylolmethane, tricresyl phosphite (2,4-di-t-butyl carbobenzoxy), Tyox B, Octabenzone, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-the 5-chlorinated benzotriazole.
On the other hand, as shown in Figure 1, the present invention also provides a kind of manufacture method of SEBS thermoplastic elastomer floor, may further comprise the steps:
Take by weighing raw material stage, take by weighing each raw material: SEBS resin and modifier 100 weight parts thereof, rubber filling oil 75～125 weight parts according to promptly fixed consumption, polypropylene 20～60 weight parts, 200～400 parts of mineral fillers, lubricant 0.8～1.2 weight part, protective agent 0.45～0.70 weight part;
Mix and granulation step, make SEBS resin and modifier thereof absorb rubber filling oil fully, again with other raw materials add stirrer for mixing evenly after, use the twin screw extruder granulation, this each section of twin screw extruder temperature begins from charging opening, be followed successively by 190～210 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～210 ℃ of head temperatures;
Extrusion moulding sheet material step, being extruded into thickness with the sheet material forcing machine is that 3～12mm, width are the sheet material of 610～1800mm, described sheet material forcing machine can adopt individual layer forcing machine or two-layer compound forcing machine, forcing machine host machine part temperature is 190～210 ℃, the head section temperature is 195～215 ℃, and when adopting the two-layer compound forcing machine, the upper strata of the sheet material of its moulding is brand-new material, lower floor is with material lower cost materials or reclaimed materials, and the thickness of lower floor is preferably 30～70% of sheet material total thickness.
In addition, when extrusion moulding sheet material, can increase operations such as calendering, embossing, baling more at last as required.
Be described in detail SEBS thermoplastic elastomer floor of the present invention and manufacture method thereof below in conjunction with 4 examples.
Example 1
Take by weighing raw material stage, take by weighing raw material according to following composition and weight part: high molecular SEBS resin 100 weight parts, paraffinic base rubber filling oil 100 weight parts, homopolymerization type polypropylene 50 weight parts, 250 parts in lime carbonate, ethylene bis stearic amide 0.50 weight part, Zinic stearas 0.30 weight part, polyethylene wax 0.20 weight part, four [3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] tetramethylolmethane 0.3 weight part, tricresyl phosphite (2,4-di-t-butyl carbobenzoxy) 0.15 weight part, Octabenzone 0.10 weight part, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chlorinated benzotriazole 0.05 weight part;
Its technological process makes the SEBS resin absorb rubber filling oil fully, again with other materials add stirrer for mixing evenly after, use the twin screw extruder granulation; Be extruded into sheet material with the sheet material forcing machine again.
Wherein, when using the twin screw extruder granulation, each section of twin screw extruder temperature begins from charging opening, is followed successively by 190～210 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～210 ℃ of head temperatures.
Described sheet material forcing machine can adopt individual layer forcing machine or two-layer compound forcing machine, and forcing machine host machine part temperature is controlled at 190～210 ℃, and the head section temperature then is controlled at 195～215 ℃.
Example 2
Take by weighing raw material stage, take by weighing raw material according to following composition and weight part: high molecular SEBS resin 10 (weight parts, naphthenic rubber extending oil 75 weight parts, copolymerized type propene polymer 20 weight parts, 200 parts of wollastonites, two amine hydroxybenzene 0.40 weight parts of ethylene, calcium stearate 0.20 weight part, polyethylene wax 0.20 weight part, β (3 ', 5 ' di-t-butyl-4 '-hydroxy phenyl) propionic acid octadecyl ester 0.20 weight part, tricresyl phosphite (2,4-di-t-butyl carbobenzoxy) 0.10 weight part, Octabenzone 0.10 weight part, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chlorinated benzotriazole 0.05 weight part;
Its technological process makes the SEBS resin absorb rubber filling oil fully, again with other materials add stirrer for mixing evenly after, use the twin screw extruder granulation; Be extruded into sheet material with the sheet material forcing machine again.
Wherein, each section of twin screw extruder temperature begins from charging opening, is followed successively by 190～210 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～210 ℃ of head temperatures.
Described sheet material forcing machine can adopt individual layer forcing machine or two-layer compound forcing machine, and forcing machine host machine part temperature is controlled at 190～210 ℃, and the head section temperature is controlled at 195～215 ℃.
Example 3
Take by weighing raw material stage, take by weighing raw material according to following composition and weight part: lower molecular weight SEBS resin 80 weight parts, maleic anhydride graft SEBS20 weight part, paraffinic base rubber filling oil 125 weight parts, homopolymerization type polypropylene 20 weight parts, copolymerized type propene polymer 40 weight parts, wollastonite 200 weight parts, talcum powder 200 weight parts, two amine hydroxybenzene 0.50 weight parts of ethylene, calcium stearate 0.40 weight part, polyethylene wax 0.30 weight part, four [3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] tetramethylolmethane 0.30 weight part, tricresyl phosphite (2,4-di-t-butyl carbobenzoxy) 0.15 weight part, Tyox B 0.10 weight part, Octabenzone 0.10 weight part, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chlorinated benzotriazole 0.05 weight part;
Its technological process makes SEBS resin and grafting SEBS absorb rubber filling oil fully, again with other materials add stirrer for mixing evenly after, use the twin screw extruder granulation; Be extruded into sheet material with the sheet material forcing machine again.
Wherein, each section of twin screw extruder temperature begins from charging opening, is followed successively by 190～210 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～210 ℃ of head temperatures.
Described sheet material forcing machine can be individual layer forcing machine or two-layer compound forcing machine, and forcing machine host machine part temperature is controlled at 190～210 ℃, and the head section temperature is controlled at 195～215 ℃.
Example 4
Take by weighing raw material stage, take by weighing raw material according to following composition and weight part: lower molecular weight SEBS resin 85 weight parts, acrylic ester grafted SEBS15 weight part, paraffinic base rubber filling oil 60 weight parts, naphthenic rubber extending oil 60 weight parts, copolymerized type propene polymer 40 weight parts, talcum powder 300 weight parts, ethylene bis stearic acid amide 0.50 weight part, calcium stearate 0.25 weight part, polyethylene wax 0.25 weight part, four [3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] tetramethylolmethane 0.20 weight part, tricresyl phosphite (2,4-di-t-butyl carbobenzoxy) 0.10 weight part and tricresyl phosphite (2,4-di-t-butyl carbobenzoxy) 0.10 weight part, Octabenzone 0.10 weight part, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chlorinated benzotriazole 0.05 weight part;
Its technological process makes SEBS resin and grafting SEBS absorb rubber filling oil fully, again with other materials add stirrer for mixing evenly after, use the twin screw extruder granulation; Be extruded into sheet material with the sheet material forcing machine again.
Wherein, each section of twin screw extruder temperature begins from charging opening, is followed successively by 190～210 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～210 ℃ of head temperatures.
Described sheet material forcing machine can be individual layer forcing machine or two-layer compound forcing machine, and forcing machine host machine part temperature is controlled at 190～210 ℃, and the head section temperature is controlled at 195～215 ℃.
Through test, the SEBS thermoplastic elastomer floor of above-mentioned each example manufacturing and the main performance index of existing rubber floor covering are recited in table 1
The SEBS thermoplastic elastomer floor that each example of table 1 the present invention is made and the main performance index of existing rubber floor covering are relatively
As can be seen from Table 1, with rubber floor covering commonly used relatively, SEBS thermoplastic elastomer floor of the present invention has higher mechanical property, rebound resilience is good, wearability is strong, electrical property excellence, and add and need not sulfuration man-hour.
Claims (10)
1. a SEBS thermoplastic elastomer floor is characterized in that, it comprises each component of following weight part content:
100 parts of SEBS resin and modifiers thereof;
75～125 parts of rubber filling oils;
20～60 parts of polypropylene;
200～400 parts of mineral fillers;
0.8～1.2 part of lubricant;
0.45～0.70 part of protective agent.
2. SEBS thermoplastic elastomer floor according to claim 1 is characterized in that: this SEBS resin and modifier thereof are the mixture of a kind of in the following material or at least two kinds: high molecular SEBS, lower molecular weight SEBS, maleic anhydride graft SEBS, acrylic ester grafted SEBS.
3. SEBS thermoplastic elastomer floor according to claim 1 is characterized in that: this rubber filling oil is the mixture of a kind of in the following material or two kinds: naphthenic rubber oil, paraffinic base rubber oil.
4. SEBS thermoplastic elastomer floor according to claim 1 is characterized in that: this polypropylene is one or both the mixture in the following material: homopolymerization type polypropylene, copolymerized type propene polymer.
5. SEBS thermoplastic elastomer floor according to claim 1 is characterized in that: this mineral filler is the mixture of a kind of in the following material or at least two kinds: lime carbonate, talcum powder, wollastonite.
6. SEBS thermoplastic elastomer floor according to claim 1 is characterized in that: this lubricant is the mixture of a kind of in the following material or at least two kinds: ethylene bis stearic amide, the two amine hydroxybenzenes of ethylene, Zinic stearas, calcium stearate, polyethylene wax, silicone resin.
7. SEBS thermoplastic elastomer floor according to claim 1, it is characterized in that: this protective agent is the mixture of a kind of in the following material or at least two kinds: β (3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) [3-(3 for propionic acid octadecyl ester, four, the 5-di-tert-butyl-hydroxy phenyl) propionic acid] tetramethylolmethane, tricresyl phosphite (2,4-di-t-butyl carbobenzoxy), Tyox B, Octabenzone, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-the 5-chlorinated benzotriazole.
8. the manufacture method of a SEBS thermoplastic elastomer floor as claimed in claim 1 is characterized in that, it may further comprise the steps:
Take by weighing raw material stage, take by weighing each raw material: SEBS resin and modifier 100 weight parts thereof, rubber filling oil 75～125 weight parts according to promptly fixed consumption, polypropylene 20～60 weight parts, 200～400 parts of mineral fillers, lubricant 0.8～1.2 weight part, protective agent 0.45～0.70 weight part;
Mix and granulation step, make SEBS resin and modifier thereof absorb rubber filling oil fully after, again with other materials add stirrer for mixing evenly after, then with twin screw extruder extrude, granulation;
Extrusion moulding sheet material step, in the sheet material forcing machine, the extrusion moulding floor in extrusion moulding sheet material, is optionally carried out calendering and embossing and is handled, last rolling with the SEBS blend after the granulation.
9. the manufacture method of SEBS thermoplastic elastomer floor according to claim 8, it is characterized in that: this each section of twin screw extruder temperature begins from charging opening, be followed successively by 190～210 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～215 ℃, 195～210 ℃ of head temperatures.
10. according to Claim 8 or the manufacture method of 9 described SEBS thermoplastic elastomer floors, it is characterized in that: the sheet material forcing machine is individual layer forcing machine or two-layer compound forcing machine, forcing machine host machine part temperature is 190～210 ℃, and the head section temperature is 195～215 ℃; And described sheet material forcing machine is when being the two-layer compound forcing machine, and the upper strata on the floor of its moulding is brand-new material, and lower floor is with material lower cost materials or reclaimed materials, and the thickness of the lower floor on the floor of two-layer compound extrusion moulding is 30～70% of floor total thickness.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100745279A CN101096440B (en) | 2007-05-22 | 2007-05-22 | SEBS thermoplastic elastomer floor and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100745279A CN101096440B (en) | 2007-05-22 | 2007-05-22 | SEBS thermoplastic elastomer floor and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101096440A CN101096440A (en) | 2008-01-02 |
| CN101096440B true CN101096440B (en) | 2010-06-09 |
Family
ID=39010536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100745279A Expired - Fee Related CN101096440B (en) | 2007-05-22 | 2007-05-22 | SEBS thermoplastic elastomer floor and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101096440B (en) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101676327B (en) * | 2008-09-17 | 2011-11-30 | 东莞市卡帝德塑化科技有限公司 | Thermoplastic elastomer for sucking with polypropylene material |
| CN101913281B (en) * | 2010-08-12 | 2012-12-26 | 山东英科环保再生资源股份有限公司 | Polystyrene dual-layer coextrusion section with soft surface and manufacturing method thereof |
| CN101983984B (en) * | 2010-10-15 | 2012-07-18 | 金发科技股份有限公司 | Elastic body material for refrigerator sealing strips and preparation method thereof |
| CN102532778A (en) * | 2010-12-31 | 2012-07-04 | 海尔集团公司 | Thermoplastic polyurethane elastomer (TPE) door seal for refrigerator and freezer and preparation method thereof |
| CN102604312B (en) * | 2012-01-13 | 2014-05-28 | 深圳市盛嘉伦橡塑工业有限公司 | Thermoplastic elastomer sealing strip material and preparation method thereof |
| CN102719049B (en) * | 2012-05-28 | 2014-06-25 | 深圳市盛嘉伦橡塑工业有限公司 | Non-flame-retardant thermoplastic elastomer material and preparation method thereof |
| CN102964692A (en) * | 2012-12-24 | 2013-03-13 | 烟台百特塑化制品有限公司 | Preparation method of SEBS (styrene-ethylene-butadiene-styrene) nano SiO2 vermin-proof PE (polyethylene) grain storage bag |
| CN103410296B (en) * | 2013-07-10 | 2016-01-20 | 东莞美哲塑胶制品有限公司 | Non-skid floor |
| CN105400150B (en) * | 2014-09-15 | 2017-07-25 | 株洲时代新材料科技股份有限公司 | A kind of thermoplastic polyester elastomer floor and its manufacture method |
| CN104276785B (en) * | 2014-09-29 | 2016-01-06 | 广东萨提亚新型建材科技有限公司 | A kind of stone-plastic plate material and preparation method thereof |
| PL3031998T4 (en) * | 2014-12-08 | 2022-01-24 | I4F Licensing Nv | Panel with a hook-like locking system |
| CN104945771A (en) * | 2015-06-11 | 2015-09-30 | 安徽瑞升电气科技集团有限公司 | Fireproof filling material used for special cable and preparation method thereof |
| WO2017015789A1 (en) * | 2015-07-24 | 2017-02-02 | 新明（芦台）科技有限公司 | Environmentally-friendly light polypropylene composite floorboard and manufacturing method therefor |
| CN105019256B (en) * | 2015-08-13 | 2017-03-08 | 长沙五犇新材料科技有限公司 | A kind of anti-skidding engineered floor leather of flame-proof abrasion-resistant and its manufacturing process and application |
| CN105602272A (en) * | 2015-11-10 | 2016-05-25 | 龙海市奥一体育用品有限公司 | Novel environment-friendly TPR plastic flooring material, and preparation method thereof |
| NL2016223B1 (en) * | 2016-02-04 | 2017-08-14 | Champion Link Int Corp | Panel suitable for constructing a waterproof floor or wall covering, process for producing a panel, panel obtainable by said process. |
| CN106147109B (en) * | 2016-06-30 | 2019-05-24 | 中广核高新核材集团（东莞）祈富新材料有限公司 | A kind of softness dry-touch type thermoplastic elastic material and its preparation method |
| CN107973538B (en) * | 2016-10-25 | 2021-01-01 | 中国石油化工股份有限公司 | High-temperature oil well cement stone elastic material and preparation method thereof |
| CN106832731B (en) * | 2017-01-05 | 2019-12-10 | 上海力茵地面弹性材料有限公司 | elastic floor, rubber particle mixture thereof, construction method thereof and method for manufacturing round thermoplastic polyolefin particles |
| WO2019045833A1 (en) * | 2017-08-30 | 2019-03-07 | Dow Global Technologies Llc | Thermoplastic polyolefin for non-carpeted flooring |
| WO2019086977A1 (en) * | 2017-11-03 | 2019-05-09 | American Biltrite (Canada) Ltd. | Resilient surface coverings and methods of making and using thereof |
| CN107974024B (en) * | 2017-12-20 | 2020-03-17 | 石家庄英利体育用品有限公司 | Thermoplastic elastomer composition, and preparation method and application thereof |
| CN110079100A (en) * | 2019-05-13 | 2019-08-02 | 浙江佳洁塑胶有限公司 | A kind of antibacterial and mouldproof pure air non-slip mat and its production technology |
| CN110092982A (en) * | 2019-05-30 | 2019-08-06 | 湖南优尔康悬浮拼装地板有限公司 | A kind of suspension assembled floor-board having adsorption function |
| CN110643134A (en) * | 2019-10-30 | 2020-01-03 | 广州狮魄秀工艺设计有限公司 | Novel TPE8 plastic particle and production process thereof |
| CN113667259B (en) * | 2021-08-19 | 2024-02-23 | 江门市佳信达模具科技有限公司 | Thermoplastic elastomer and preparation method and application thereof |
| CN113715450B (en) * | 2021-08-19 | 2023-08-22 | 江门市佳信达模具科技有限公司 | Assembled floor with double-layer structure and preparation method thereof |
| CN113943457A (en) * | 2021-11-12 | 2022-01-18 | 阿姆斯壮地面材料（中国）有限公司 | Preparation process of environment-friendly homogeneous permeable floor |
| CN117621582B (en) * | 2023-12-07 | 2024-06-11 | 河北英利奥体育用品有限公司 | Layered composite material and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054392A (en) * | 1990-02-06 | 1991-09-11 | 希蒙特公司 | The method of repairing plastic coatings on metal tubing |
| CN1290720A (en) * | 2000-10-01 | 2001-04-11 | 新疆兴盛实业有限公司 | Formula and production process of filling modified reinformed PE/PP/PS composite material |
| US20050281986A1 (en) * | 2004-06-22 | 2005-12-22 | Seung-Baik Nam | Flooring having surface layer of synthetic resin and wood-based board |
-
2007
- 2007-05-22 CN CN2007100745279A patent/CN101096440B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054392A (en) * | 1990-02-06 | 1991-09-11 | 希蒙特公司 | The method of repairing plastic coatings on metal tubing |
| CN1290720A (en) * | 2000-10-01 | 2001-04-11 | 新疆兴盛实业有限公司 | Formula and production process of filling modified reinformed PE/PP/PS composite material |
| US20050281986A1 (en) * | 2004-06-22 | 2005-12-22 | Seung-Baik Nam | Flooring having surface layer of synthetic resin and wood-based board |
Non-Patent Citations (6)
| Title |
|---|
| 张小林、程金星、林锋、肖望东、徐令军.填料改性充油SEBS力学性能的研究.弹性体17 1.2007,17(1),53-55. |
| 张小林、程金星、林锋、肖望东、徐令军.填料改性充油SEBS力学性能的研究.弹性体17 1.2007,17(1),53-55. * |
| 张小林、程金星、陶影、漆剑.新型热塑性弹性体SEBS及其改性的研究进展.弹性体15 6.2005,15(6),72-76. |
| 张小林、程金星、陶影、漆剑.新型热塑性弹性体SEBS及其改性的研究进展.弹性体15 6.2005,15(6),72-76. * |
| 林锋、程金星、肖望东、徐令军、陶影.充油SEBS力学性能的研究.塑料工业34 6.2006,34(6),43-45. |
| 林锋、程金星、肖望东、徐令军、陶影.充油SEBS力学性能的研究.塑料工业34 6.2006,34(6),43-45. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101096440A (en) | 2008-01-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101096440B (en) | SEBS thermoplastic elastomer floor and manufacturing method thereof | |
| CN109651827B (en) | Fully-recyclable environment-friendly thermoplastic prefabricated plastic track and preparation method thereof | |
| CN1219942C (en) | Pavement material for pedestrian walk and manufacture thereof | |
| AU2010283885B2 (en) | A nonmetal material modified thermoplastic resin composite | |
| CN101955614A (en) | Novel wood plastic composite decorative building material and manufacturing method thereof | |
| EP2788188B1 (en) | Multilayered product for joint utilization of smc, bmc and pet waste | |
| CN101417459A (en) | Utilize straw and waste or used plastics to make the method and the material thereof of wood plastic composite | |
| CN106977872A (en) | Thermoplastic elastomer (TPE) and its preparation method and the Wood-plastic floor containing the thermoplastic elastomer (TPE) | |
| CN102501506A (en) | PVC (Poly Vinyl Chloride) wood-plastic foaming composite and preparation method thereof | |
| CN108250524A (en) | Environment-friendly rubber Prefabricated runway coiled material and preparation method thereof | |
| CN102898770A (en) | Hollow thermoplastic rubber filling particle for artificial turf filling and preparation method of hollow thermoplastic rubber filling particle | |
| GB2476576A (en) | Composition for use in components requiring a surface appearance of cast iron | |
| CN210712429U (en) | Section bar containing E-TPU foaming particles, and TPU floor tiles and runways using section bar | |
| CN107163442A (en) | A kind of manufacture craft of environmentally friendly stone plastic floor | |
| JP3722093B2 (en) | Pavement material for walking path and method for manufacturing the same | |
| CN105492517A (en) | Recycable synthetic flooring | |
| CN110467763B (en) | Luminous prefabricated sports surface layer, paving material and preparation method thereof | |
| CN2780891Y (en) | Color rubber floor tile | |
| CN107141703A (en) | A kind of environmental protection flame retardant elastic ground pavement material and preparation method thereof | |
| CN105400150B (en) | A kind of thermoplastic polyester elastomer floor and its manufacture method | |
| CN110540688A (en) | Method for preparing rubber brick by regenerating environment-friendly water glue and waste rubber | |
| KR20110103811A (en) | Floating flooring material including polylacticacid resin and method for fabricating the same | |
| CN215254255U (en) | Vinyl polymer composite floor | |
| KR102652203B1 (en) | In order to realize carbon neutrality, artificial turf filler composition and manufacturing method using only pure waste materials, and artificial turf filler with excellent impact absorption manufactured by that method | |
| KR100434574B1 (en) | Duplication footway block |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| PB01 | Publication | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20071116 Address after: Guangdong city of Shenzhen province Nanshan District Xili Lake Applicant after: Shenzhen Polytechnic Co-applicant after: Shenzhen Sungallon Rubber & Plastic Industry Co., Ltd. Address before: Guangdong city of Shenzhen province Nanshan District Xili Lake Applicant before: Shenzhen Polytechnic |
|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100609 Termination date: 20190522 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |