CN105602272A - Novel environment-friendly TPR plastic flooring material, and preparation method thereof - Google Patents
Novel environment-friendly TPR plastic flooring material, and preparation method thereof Download PDFInfo
- Publication number
- CN105602272A CN105602272A CN201510757101.8A CN201510757101A CN105602272A CN 105602272 A CN105602272 A CN 105602272A CN 201510757101 A CN201510757101 A CN 201510757101A CN 105602272 A CN105602272 A CN 105602272A
- Authority
- CN
- China
- Prior art keywords
- tpr
- novel environment
- environment friendly
- mixture
- floor material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention relates to a novel environment-friendly TPR plastic flooring material, and a preparation method thereof. The preparation method comprises following steps: high temperature melting of plastic TPR is carried out; a preplasticizing mixture is mixed with high temperature molten plastic TPR particles, and a fire retardant so as to obtain a mixture A; and the mixture A is subjected to melting extrusion using a double-screw extruder. The novel environment-friendly TPR plastic flooring material can be applied to floors in gymnasiums, and possesses environment protection effect.
Description
Technical field
The present invention relates to the athletic floor of sports buildings, be specifically related to a kind of novel environment friendly TPRPlastic floor material and preparation method thereof.
Background technology
The preparation of polyvinyl chloride resin blend alloy is this kind of method simple practical conventionally, respond well,To be widely adopted and the most rising method of modifying. The plasticized modifier of PVC is a lot,Substantially can be divided into elastic body toughening modifier and Toughening By Non-elastomers modifier, effect has preferablyEVA, NBR, TPU, SBR, ABS, MBS, ACR, CPE, AS, PS etc.
Compatibility and inclusive ranges are its main standard. Compatibility is too poor, the bonding force of two-phaseDeficiency, is prone to the phenomenons such as delamination splitting in use procedure, cause blend hydraulic performance decline orUnstable; When compatibility has been crossed, decentralized photo phase size is very little, is even difficult to form homogeneous phase bodySystem, the toughening effect that also can not produce. US4880862, US3965214,CN101497735, CN101704983A, CN1962751, CN1765985 all adopt Sb2O3And halogen flame. But halogenated flame retardant, more specifically, is halogen-antimony flame retardant systems,When burning or hot tearing, be certain to produce the corrosivity such as dioxanes, dioxin and noxious material, can be rightEnvironment and human health cause very large harm. CN1616545 disclose phosphate, polyphenylene oxide,The composite flame retardant system of epoxy resin, but phosphoric acid ester fire retardant fusing point is low, and stickiness is large, processingProperty is poor. CN1908062 select magnesium salt whisker and acicular wollastonite whisker fire-retardant. Inorganic combustion inhibitor,Although in fire-retardant process, can not discharge toxic gas, for ABS, addition mistakeMany, grievous injury the mechanical property of ABS, greatly affected the range of application of ABS.Expanding fire retardant is a kind of halogen-free environment-friendly flame-proof agent of recently studying, and it belongs in essenceThe composite inorganic system of N-P, wide material sources. Traditional expansion type flame retardant is to ABS flame retarding efficiencyNot high, addition is more, poor with the compatibility of ABS system, bad dispersibility, and hygroscopicity is strong.Above-mentioned several halogen-free flame retardants all destroys larger to the impact property of ABS resin, greatly limitMake the range of application of ABS.
In sum, and other materials also more or less there are the problems referred to above.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, exploitation provides a kind of Novel ringThe preparation method who protects TPR plastic floor material, comprises the following steps: 1) taking filler is SiO2With modified kaolin totally 10 weight portions, plasticizer triisooctyl trimellitate 3 weight portions, profitLubrication prescription polytetrafluoroethylene (PTFE) 4 weight portions; Raw material is placed in to high-speed mixer and mixes, thenPreplasticizing obtains preplasticizing mixture; 2) take TPR80 weight portion, high temperature melting plastics TPR,Obtain high temperature melting plastics TPR; 3) take fire retardant 10 weight portions, fire retardant is phosphinatesWith the mixture of melamine salt, wherein, the quality percentage composition of phosphinates is 68%; 4)Preplasticizing mixture mixes with high temperature melting plastics TPR particle, fire retardant, obtains mixture A;5) described mixture A is placed in to double screw extruder melt extrudes, tie rod, cooling,Pelletizing, wherein, the draw ratio of screw rod is 30: 90: 1, the temperature melt extruding is 200-290℃。
The temperature that preferred molten is extruded is 200-280 DEG C, and the temperature melt extruding is 200-260DEG C, the temperature melt extruding is 200-250 DEG C, the temperature melt extruding be 200 DEG C, 250 DEG C,270℃。
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further described in detail.
Embodiment 1
A preparation method for novel environment friendly TPR plastic floor material, comprises the following steps:1) taking filler is SiO2With modified kaolin totally 10 weight portions, plasticizer tri trimellitate is differentMonooctyl ester 3 weight portions, lubricant polytetrafluoroethylene (PTFE) 4 weight portions; Raw material is placed in to high-speed mixerIn mix, then preplasticizing obtains preplasticizing mixture; 2) take TPR80 weight portion,High temperature melting plastics TPR, obtains high temperature melting plastics TPR; 3) take fire retardant 10 weightPart, fire retardant is the mixture of phosphinates and melamine salt, wherein, and the matter of phosphinatesAmount percentage composition is 68%; 4) preplasticizing mixture and high temperature melting plastics TPR particle, resistanceCombustion agent mixes, and obtains mixture A; 5) described mixture A is placed in to double screw extruderIn melt extrude, tie rod, cooling, pelletizing, wherein, the draw ratio of screw rod is 30: 90: 1,The temperature melt extruding is 250 DEG C.
Embodiment 2
A preparation method for novel environment friendly TPR plastic floor material, comprises the following steps:1) taking filler is SiO2With modified kaolin totally 10 weight portions, plasticizer tri trimellitate is differentMonooctyl ester 3 weight portions, lubricant polytetrafluoroethylene (PTFE) 4 weight portions; Raw material is placed in to high-speed mixerIn mix, then preplasticizing obtains preplasticizing mixture; 2) take TPR80 weight portion,High temperature melting plastics TPR, obtains high temperature melting plastics TPR; 3) take fire retardant 10 weightPart, fire retardant is the mixture of phosphinates and melamine salt, wherein, and the matter of phosphinatesAmount percentage composition is 68%; 4) preplasticizing mixture and high temperature melting plastics TPR particle, resistanceCombustion agent mixes, and obtains mixture A; 5) described mixture A is placed in to double screw extruderIn melt extrude, tie rod, cooling, pelletizing, wherein, the draw ratio of screw rod is 30: 90: 1,The temperature melt extruding is 200 DEG C.
Claims (6)
1. a preparation method for novel environment friendly TPR plastic floor material, is characterized in that,Comprise the following steps:
1) taking filler is SiO2With modified kaolin totally 10 weight portions, plasticizer trimellitic acidThree different monooctyl ester 3 weight portions, lubricant polytetrafluoroethylene (PTFE) 4 weight portions; Raw material is placed in mixed at a high speedClose in machine and mix, then preplasticizing obtains preplasticizing mixture;
2) take TPR80 weight portion, high temperature melting plastics TPR, obtains high temperature melting plasticsTPR；
3) take fire retardant 10 weight portions, fire retardant is the mixed of phosphinates and melamine saltCompound, wherein, the quality percentage composition of phosphinates is 68%;
4) preplasticizing mixture mixes with high temperature melting plastics TPR particle, fire retardant, obtainsMixture A;
5) described mixture A is placed in to double screw extruder melt extrudes, tie rod, coldBut, pelletizing, wherein, the draw ratio of screw rod is 30: 90: 1, the temperature melt extruding is 200-290℃。
2. the system of a kind of novel environment friendly TPR plastic floor material according to claim 1Preparation Method, is characterized in that, the temperature melt extruding is 270 DEG C.
3. the system of a kind of novel environment friendly TPR plastic floor material according to claim 1Preparation Method, is characterized in that, the temperature melt extruding is 250 DEG C.
4. the system of a kind of novel environment friendly TPR plastic floor material according to claim 1Preparation Method, is characterized in that, the temperature melt extruding is 200 DEG C.
5. the novel environment friendly TPR making according to the method described in claim 1-4 any one mouldsAdhesive floor material, is characterized in that, the tension that described flooring material has 100-1500MPa is strongDegree.
6. novel environment friendly TPR plastic floor material according to claim 5 is at sports groundApplication in shop, is characterized in that, this flooring material is for the floor of all kinds of arenas.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510757101.8A CN105602272A (en) | 2015-11-10 | 2015-11-10 | Novel environment-friendly TPR plastic flooring material, and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510757101.8A CN105602272A (en) | 2015-11-10 | 2015-11-10 | Novel environment-friendly TPR plastic flooring material, and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105602272A true CN105602272A (en) | 2016-05-25 |
Family
ID=55982647
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510757101.8A Pending CN105602272A (en) | 2015-11-10 | 2015-11-10 | Novel environment-friendly TPR plastic flooring material, and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105602272A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107901575A (en) * | 2017-12-26 | 2018-04-13 | 巨野县明皓塑胶有限公司 | A kind of manufacture craft of TPE plastic floors |
| CN108795016A (en) * | 2018-05-17 | 2018-11-13 | 株洲时代新材料科技股份有限公司 | A kind of modified thermoplastic material and preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2100435U (en) * | 1991-08-15 | 1992-04-01 | 戴聪俊 | Shock-proof honeycomb floor |
| CN1844226A (en) * | 2006-04-11 | 2006-10-11 | 侯盼领 | Color plastic floor made of waste PVC and manufacturing method thereof |
| CN101096440A (en) * | 2007-05-22 | 2008-01-02 | 深圳职业技术学院 | SEBS thermoplastic elastomer floor and manufacturing method thereof |
| CN102796341A (en) * | 2012-07-24 | 2012-11-28 | 金发科技股份有限公司 | Halogen-free flame-retardant elastomer composition |
-
2015
- 2015-11-10 CN CN201510757101.8A patent/CN105602272A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2100435U (en) * | 1991-08-15 | 1992-04-01 | 戴聪俊 | Shock-proof honeycomb floor |
| CN1844226A (en) * | 2006-04-11 | 2006-10-11 | 侯盼领 | Color plastic floor made of waste PVC and manufacturing method thereof |
| CN101096440A (en) * | 2007-05-22 | 2008-01-02 | 深圳职业技术学院 | SEBS thermoplastic elastomer floor and manufacturing method thereof |
| CN102796341A (en) * | 2012-07-24 | 2012-11-28 | 金发科技股份有限公司 | Halogen-free flame-retardant elastomer composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107901575A (en) * | 2017-12-26 | 2018-04-13 | 巨野县明皓塑胶有限公司 | A kind of manufacture craft of TPE plastic floors |
| CN108795016A (en) * | 2018-05-17 | 2018-11-13 | 株洲时代新材料科技股份有限公司 | A kind of modified thermoplastic material and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102617915B (en) | Anti-mildew halogen-free flame-retardant smoke-suppression wood-plastic composite material and preparation method thereof | |
| CN106751183A (en) | A kind of energy-conserving and environment-protective material and preparation method thereof | |
| CN105061887B (en) | Halogen-free anti-flaming polypropylene material and preparation method thereof | |
| CN109705462A (en) | A kind of dedicated V0 grade halogen-free flame-retardant polypropylene material of extrusion plastic uptake and preparation method thereof | |
| WO2008135529A3 (en) | Process for making polyolefin compositions | |
| CN1807500A (en) | Combustion-proof composite foaming granule material for producing wood plastic product | |
| CN105504482A (en) | Halogen-free flame-retardant linear low density polyethylene(LLDPE) material | |
| CN105131551A (en) | High-performance halogen-free flame-retardant PC/ASA alloy and preparation method thereof | |
| CN103509263B (en) | A kind of environmental protection addition type polyethylene anti-flaming master batch and preparation method thereof | |
| CN104356546A (en) | Antidrip flame-retardant PVC-U (unplasticized polyvinyl chloride) pipe and preparation method thereof | |
| CN105602272A (en) | Novel environment-friendly TPR plastic flooring material, and preparation method thereof | |
| CN104693760A (en) | Blended alloy of polycarbonate and polybutylene terephthalate | |
| CN105504594A (en) | Polyvinyl chloride plastic and preparation method thereof | |
| CN106188975B (en) | A kind of soft high transparent and fire-retardant heat-resistant polyvinyl chloride material of spy and preparation method thereof | |
| CN104086942A (en) | Special material composition with low metal cohesiveness for automobile tail fins | |
| CN105440564B (en) | A kind of halogen-free flame-retardant ABS composite material and preparation method thereof | |
| CN106883485A (en) | One kind can porcelain wood plastic composite | |
| CN105754259A (en) | Low-temperature-resistant PVC (polyvinyl chloride) pipe and manufacturing method thereof | |
| CN106398086A (en) | Degradable and thermoplastic shoe sole containing polycarbonate alloy, and preparation method thereof | |
| CN102649863A (en) | ABS (Acrylonitrile Butadiene Styrene) environment-friendly inflaming retarding compound material and preparation method thereof | |
| CN102850712A (en) | Anti-dropping flame-retardant ABS material and preparation method thereof | |
| CN103802427A (en) | Polyetherimide/ethylene-vinyl acetate (PET/EVA) flame retardant composite film for electronic encapsulation application and preparation method thereof | |
| CN105131415A (en) | Thermoplastic low-smoke halogen-free flame-retardant polyolefin composite material for data cable and preparation method of polyolefin composite material | |
| CN1939970B (en) | PC/ABS disposable recovering composition and its use | |
| CN113956564A (en) | Anti-dripping low-smoke halogen-free flame-retardant polyolefin oxygen-insulating material easy to process and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160525 |
|
| RJ01 | Rejection of invention patent application after publication |