CN101096308A - Seawater erosion abrasion and biologic defiling resistant composite ceramic powder for hot spraying and preparation therefor - Google Patents
Seawater erosion abrasion and biologic defiling resistant composite ceramic powder for hot spraying and preparation therefor Download PDFInfo
- Publication number
- CN101096308A CN101096308A CNA2007100523184A CN200710052318A CN101096308A CN 101096308 A CN101096308 A CN 101096308A CN A2007100523184 A CNA2007100523184 A CN A2007100523184A CN 200710052318 A CN200710052318 A CN 200710052318A CN 101096308 A CN101096308 A CN 101096308A
- Authority
- CN
- China
- Prior art keywords
- powder
- composite ceramic
- composition
- biofouling
- oxide ceramics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention discloses a hot spraying composite ceramic power of sea water corrosive wear resistant and biological defilement resistant and the preparing method. The composite ceramic power comprises 95%-98% material power and 2%-5% binder; the material power comprises 80%-95% reference-phase structure which comprises oxide ceramic principal phase component and close structure accessory component and 5-20% biological defilement resistant component; the oxide ceramic reference-phase structure comprises 80%-90% Cr2O3 and 10%-20% TiO2 or TiO2+Al2O3. The composite ceramic power comprises the following steps: proportioning; drying with atomise; high-sintering; screening. The invention is provided with the simple process, safety and the low cost.
Description
Technical field
The present invention relates to a kind of material that is used for the Surface Engineering of thermospray, particularly relate to the Conglobation type anti-seawater corrosion wearing and tearing that are used for hot-spraying techniques and the composite ceramic and the preparation method of biodeterioration.
Background technology
In 21 century, along with people to the energy development of marine field and the expansion of scope of activity, increasing reciprocating part begins to be applied under the ocean environment, but the corrodibility of seawater, microorganism are stained etc. the device under the seawater Working environment is all produced a very large impact.The use heat spraying technology sprays one deck composite ceramic coat on metallic matrix, both overcome metal resistance to corrosion seawater difference and the big shortcoming of brittleness of ceramics, can give full play to the rigidity of metal and the good anti-corrosion wear of pottery again.The high rigidity of ceramic coating, high rigidity, high elastic coefficient make ceramic coating have excellent performances such as wear-resistant, corrosion-resistant, anti-cavitation erosion; Can prepare fine and close ceramic coating by improving raw material and process for refining, reduce porosity, be more suitable in briny environment, working; Oxide-based stupalith can reduce the frictional coefficient of to-and-fro movement device greatly owing to the easy adsorbed film of water of polarized action; A spot of hole in the ceramic coating is good containment structures, can keep the continuity of water lubricating film to exist in to-and-fro movement.
But ceramic coating is applied to need in the briny environment to solve emphatically following problem:
1. bonding strength.Because reciprocating part not only bears very high contact stress, also can bear vibratory impulse to a certain degree, if bonding strength is low, coating shedding often occurs or peel off.
2. the suitability of body material and coated material.Whether the linear expansivity and the thermal conductivity that mainly are pairing material be close, differs when too greatly then the working in reciprocating mode part is subjected to thermal shocking and can produce thermal stresses on bonding interface.
3. compactness.Plasma spraying is that the ceramic powder that will be the fine droplet shape under molten state impacts on the matrix surface with high speed, become the pancake shape, accumulate synergetic process layer by layer, therefore produce many small pores in the coating forming procedure, when coating is thin, often there is the passage from the coatingsurface to the bonding surface in the passage that the interconnection formation of many pores is tiny inevitably, the corrosion of interfacial layer in having corrosive water, occurs, weaken bonding strength even cause that the part peels off.
4. the control of various tissue defects in the coating, as be mingled with micro-crack etc.
5. make the adaptability difficult problem of medium with water conservancy project.The water particularly corrodibility of seawater is strong, has comprised a large amount of organism, microorganism, metal and nonmetallic ion in the seawater, and chloride ion content is big, and seawater is natural ionogen.
There is data to show SiC, Si
3N
4, Sialon, Al
2O
3Be suitable for doing to-and-fro movement material under the briny environment Deng all, still because SiC, Si
3N
4In Plasma Spraying Process Using, have serious oxidation, can not guarantee the composition of coating, so and be not suitable for thermospray; can only consider vapour deposition or laser remolten; if adopt other prepared ceramic coating of non-thermospray, production cost is significantly improved, can't mass-producing use.Sialon is Si
3N
4The middle Al that adds
2O
3, Al in sintering process
2O
3Solid solution is in Si
3N
4Form, can only consider to manufacture integral member, adopt single ceramic material reciprocating part can't overcome the stupalith inherent defect.Japan DSRV sea-water pump cylinder bore lined ceramics Al
2O
3Plasma spraying; The plunger of Kawasaki Heavy Industries sea water plunger pump is the molten pottery of annotating of stainless steel surface; Domestic research unit such as Zhejiang University's fluid transmission and control National Key Laboratory adopt Al
2O
3+ 13%TiO
2Preparation ceramic coating working element, though reach requirement substantially at dynamic performance, the stained and anti-seawater corrosion polishing machine of microorganism requires barely satisfactoryly in anti-sealing, its weather resistance that is applied to real work is still waiting perfect.Domestic and international ceramic coating working element multiselect oxide ceramic powder under the briny environment, but its ceramic powder select for use and composite ceramic between the ratio of each component inclined to one side mistake is arranged more, do not add any stained composition of microorganism in the sealing of effectively preventing simultaneously; Even part has been added the anti-biofouling composition, but the fouling resistance composition of its interpolation may contaminate environment.Use new problem and the task of having proposed therefore for the research of the preparation raw material of the ceramic coating reciprocating part in the briny environment.By on the basis of choose reasonable anti-seawater corrosion wearing and tearing raw material, the trace interpolation addresses the above problem the component that environment does not have the anti-biofouling of harm this patent just.
Summary of the invention
Technical problem to be solved by this invention is: composite ceramic and preparation method that a kind of used for hot spraying anti-seawater corrosion wearing and tearing and biodeterioration are provided, this composite ceramic is a kind of ceramic powder that preparation traditional ceramics coating is used that is different from, performance with the wearing and tearing of significant anti-biofouling and seawater corrosion resistance, be suitable for plasma spraying or flame plating technology, this composite ceramics powder preparation technique is simple simultaneously, cost is low and be beneficial to suitability for industrialized production.
The present invention is the composite ceramic powder of developing voluntarily, is a kind of with Cr
2O
3For the principal phase composition and contain TiO
2Or TiO
2+ Al
2O
3The parafacies composition forms oxide ceramics base phase constitution, adds different antibionts again and adheres to pollution components, forms the composite ceramic powder of multicomponent system.
Cr
2O
3Ceramic coating hardness height, thermal expansivity is low, and the thermal stresses that produces in the friction process is smaller, and the suitability of coating and base material is good.Coating is not easy to take place serious fracture, and abrasion resistance properties is superior, is widely used in improving the performance of metallic surface because of having excellent characteristic such as wear-resisting, anti-corrosion.And it has excellent gasproof erosion performance, and chemical property is very stable, is insoluble to acid, alkali, salt and all kinds of SOLVENTS, and to atmosphere, fresh water and seawater and auroral poles are for stable.While Cr
2O
3Coating has the good hydrophilicity energy, can be at Cr
2O
3Laminar surface forms the layer of even moisture film.Because TiO
2, Al
2O
3Fusing point hangs down and easily produce deformation when thermal-flame sprays, and can be filled in Cr
2O
3Between the hole of skeleton, reduce porosity, raising intensity, the strengthen toughness and the wear resistance of coating; The bonding force that improves ceramic coating and matrix is strong, and coating is fine and close more, improves the remarkable and powder deposition efficiency of seawater corrosion resistance polishing machine.
The anti-biofouling material that adds can be Cu, CuO or Cu
2O, it mainly acts on and is:
The one, composite ceramic (first kind of composite ceramic of interpolation Cu powder, in the raw material based on 80～95% oxide ceramics base phase powder, the anti-biofouling composition that adds is 5～20%Cu powder) be prepared into coating after, burning causes partial oxidation to form in ceramic coating to contain CuO or Cu the Cu powder through plasma flame flow
2O composition tissue reaches the anti-biofouling effect, and unoxidized Cu component is also oxidation gradually in coating use subsequently, and the Cu disperse also can be played the enhanced tissue structure in coating, improves the effect of coating self bonding strength.
The 2nd, composite ceramic (second kind of composite ceramic powder of interpolation CuO powder, in the raw material based on 80～95% oxide ceramics base phase powder, the anti-biofouling composition that adds is 5～20%CuO powder) be prepared into coating after, burning causes the part oxygen loss to form in ceramic coating to contain or Cu the CuO powder through plasma flame flow
2O composition tissue reaches the anti-biofouling effect.
The 3rd, add Cu
2The composite ceramic of O powder (feature of the third composite ceramic powder be in the raw material based on 80～95% oxide ceramics base phase powder, the anti-biofouling composition of interpolation is 5～20%Cu
2The O powder) be prepared into coating after, Cu
2The disperse of O powder is distributed in the ceramic coating.Along with coating state of wear in use, Cu is arranged constantly
2The O composition is organized in coatingsurface and occurs, and makes coating play the anti-biofouling effect from start to finish in whole process.
The composite ceramic of anti-seawater corrosion wearing and tearing provided by the invention and biodeterioration, its composition is: by mass percentage, composite ceramic is made up of starting powder 95～98% and caking agent 2～5%; By mass percentage, parafacies composition by principal phase composition interpolation dense structure in the described starting powder forms oxide ceramics base phase constitution, adding different anti-biofouling components again forms, wherein, oxide ceramics base phase constitution accounts for 80～95% of starting powder weight, 5～20% of anti-biofouling ingredients constitute original weight; Oxide ceramics base phase constitution contains principal phase composition 80～90%Cr
2O
3, parafacies composition 10～20%TiO
2Or TiO
2+ Al
2O
3Described caking agent is a kind of in dextrin, polyvinyl alcohol, carboxymethyl cellulose, the polystyrene, or two or more mixtures.
The composite ceramic of above-mentioned anti-seawater corrosion wearing and tearing provided by the invention and biodeterioration, the parafacies composition that is added dense structure by the principal phase composition forms oxide ceramics base phase constitution, add the anti-biofouling component again and form, it prepares the method that may further comprise the steps that adopts:
(1) batching: by mass percentage, get raw material powder 95～98%, caking agent 2～5%, it is mixed the water purification that the back adds 1～1.3 times of compound weight, be deployed into slip;
Contain 80～95% oxide ceramics base phase constitution material in the above-mentioned raw materials powder, also contain 5～20%Cu of anti-biofouling and enhanced tissue structure function, perhaps 5～20%CuO of anti-biofouling effect or Cu
2O; Oxide ceramics base phase constitution material contains principal phase composition 80～90%Cr
2O
3, parafacies composition 10～20%TiO
2Or TiO
2+ Al
2O
3
(2) atomization drying: with resulting slip atomization drying in spray-drying tower, the drying tower temperature is controlled in 110～300 ℃ of scopes, makes reunion powder.
(3) high temperature sintering: resulting reunion powder is placed the sintering oven sintering, and temperature is 1100～1300 ℃, and temperature rise rate is 5 ℃/min, and soaking time is 30～60 minutes, makes composite ceramic powder.
(4) screening:,, obtain antibiont and adhere to composite ceramic with anti-seawater corrosion after sieve with resulting composite ceramic powder furnace cooling.
The present invention compared with prior art has following main advantage:
One. the composite ceramic that provides is the material with remarkable anti-biofouling, and fouling resistance component wherein has the characteristics of environmental protection, is the good raw material of preparation to-and-fro movement device under the seawater working conditions.
They are two years old. by thermospray composite ceramic of the present invention, can make that the ceramic coating of preparation has that bonding strength height, compactness are big, good toughness, tissue defects are few, rub resistance wearing and tearing and excellent corrosion-resistant function and the matching good with matrix.
They are three years old. added caking agent in the spray drying granulation process, in follow-up granulation process, will all burn or vapor away below 300 ℃, and can not become the impurity in the hot spray coating.
They are four years old. and the whole preparation process flow process is few, and equipment is simple, and processing parameter is easy to control, is fit to serialization scale operation.
They are five years old. and preparation reunion powder cost is relatively low, is easy to promote.
They are six years old. and can on same production line, adjust the solid and hollow bead shape of reunion powder flexibly according to product requirement, and guarantee high purity, high-specific surface area and certain surfactivity of aggregate powder of AI/Yt.
In a word, composite ceramic provided by the invention passes through in the metal base surface thermospray, can prepare and have the good seawater corrosion resistance wearing and tearing and the ceramic coating of remarkable anti-biofouling, the advantage that its preparation technology is simple, be suitable for serialization scale operation, and difference as requested, can be prepared into solid and the reunion powder hollow bead shape.
Embodiment
One. the composite ceramic of anti-seawater corrosion wearing and tearing and biodeterioration
By mass percentage, composite ceramic is made up of starting powder 95～98% and caking agent 2～5%.The particle diameter of described starting powder is 1～10 μ m, its composition is: by mass percentage, parafacies composition by principal phase composition interpolation dense structure in the described starting powder forms oxide ceramics base phase constitution, adding different anti-biofouling components again forms, wherein, oxide ceramics base phase constitution accounts for 80～95% of starting powder weight, 5～20% of anti-biofouling ingredients constitute starting powder weight; Oxide ceramics base phase constitution contains principal phase composition 80～90%Cr
2O
3, parafacies composition 10～20%TiO
2Or TiO
2+ Al
2O
3Described caking agent is a kind of in dextrin, polyvinyl alcohol, carboxymethyl cellulose, the polystyrene, or two or more mixtures.
Two. the preparation method of the composite ceramic of anti-seawater corrosion wearing and tearing and biodeterioration
Described composite ceramics powder material forms oxide ceramics base phase constitution by the parafacies composition that the principal phase composition adds dense structure, adds the anti-biofouling component again and forms, and it prepares the method that may further comprise the steps that adopts:
(1) batching: by mass percentage, get starting powder 95～98%, caking agent 2～5%, it is mixed the water purification that the back adds 1～1.3 times of compound weight, be deployed into slip.
Contain oxide ceramics base phase constitution in the above-mentioned starting powder and account for 80～95% of ceramics powder weight, 5～20% of anti-biofouling ingredients constitute ceramics powder weight; Oxide ceramics base phase constitution contains principal phase composition 80～90%Cr
2O
3, parafacies composition 10～20%TiO
2Or TiO
2+ Al
2O
3Principal phase composition Cr
2O
3Granularity be 1～10 μ m, its content accounts for 80～90wt% of oxide ceramics base phase constitution material weight.Parafacies composition TiO
2Or TiO
2+ Al
2O
3Granularity be 1～10 μ m, its content accounts for 10%～20wt% of oxide ceramics base phase constitution material weight.
Described caking agent is a kind of in dextrin, polyvinyl alcohol, carboxymethyl cellulose, the polystyrene, or two or more mixtures.
(2) atomization drying: with resulting slip dried compressed air is carrier, adopts two streaming nozzles or centrifugal atomizing nozzle that slurry is sprayed into atomization drying in the spray-drying tower.The drying tower temperature is controlled in 110～300 ℃ of scopes, makes reunion powder.
(3) high temperature sintering: resulting reunion powder is placed the sintering oven sintering, and temperature is 1100～1300 ℃, and temperature rise rate is 5 ℃/min, and soaking time is 30～60 minutes, makes the Conglobation type composite ceramic powder;
(4) screening: with resulting composite ceramic powder furnace cooling, after sieve, get between-180～+ 325 mesh sieves and two grades of dense powders of-325 mesh sieves, they are that the antibiont of two kinds of different granularities of purposes adheres to the composite ceramic product with anti-seawater corrosion.Wherein: the composite ceramic between-180～+ 325 mesh sieves should prepare thick coating (thickness 〉=0.5mm), and the composite ceramic of-325 mesh sieves should prepare fine and close shallow layer (thickness≤0.5mm).
Below in conjunction with specific embodiment preparation method of the present invention is described further, but does not limit the present invention.
Embodiment 1:
Batching: get the ceramic powder material of 9.8 kilogram of 1～10 μ m particle diameter, wherein contain 64%Cr
2O
3, 10%TiO
2, 6%Al
2O
3, 20%Cu, add 0.2 kilogram polyvinyl alcohol caking agent then, behind the thorough mixing, adding 10 kilograms water purification again, to stir into the slip that homodisperse suspends stand-by.
Atomization drying: carry gas with dry purified pressurized air, gaseous tension is controlled at 0.8Mpa, take two streaming nozzles that slip is sprayed in the drying tower, the slip of atomizing relies on the surface tension of self to be shrunk to the reunion hollow ball shape, dry in hot blast, the Heating temperature of drying tower well heater is 110～300 ℃, and the height of temperature is regulated and exceeded with the powder thorough drying.To collect in the exsiccant reunion powder suction cyclonic separator by vacuum fan subsequently.
High temperature sintering and screening: with the reunion powder that the makes crucible of packing into, van-type heat treatment furnace internal heating to 1100～1300 ℃, be incubated after 30～60 minutes, then with the composite ceramic furnace cooling that sinters after sieve, get composite ceramic between-180～+ 325 mesh sieves and should prepare thick coating (thickness 〉=0.5mm), and the composite ceramic of-325 mesh sieves should prepare fine and close shallow layer (thickness≤0.5mm).Powder content of effective behind the sintering is greater than 99.9%, and remaining additive foreign matter content is less than 0.1%.With the loose density and the flowability of Hall under meter mensuration powder, scanning electron microscope is measured the pattern of powder, and X ray powder crystal diffraction is measured the crystalline structure of powder, measures the specific surface area of powder with the BET method.The test result of the composite ceramic that this example obtains is listed in table 1.
Embodiment 2:
Batching: get the ceramic powder material of 9.5 kilogram of 1～10 μ m particle diameter, wherein contain 85.5%Cr
2O
3, 9.5%TiO
2, 5%CuO, add to add each 0.2 kilogram of 0.1 kilogram in dextrin, polystyrene and polyvinyl alcohol caking agent then, behind the thorough mixing, adding 12 kilograms water purification again, to stir into the slip that homodisperse suspends stand-by.
Atomization drying: slip is sprayed in the drying tower with the centrifugal atomizing nozzle, the rotating speed of centrifugal atomizer is 18000～20000r/min, the slip particulate of atomizing relies on the surface tension of self to be shrunk to the solid sphere of reuniting, dry in hot blast, the Heating temperature of drying tower well heater is 110～300 ℃, and the height of temperature is regulated and exceeded with the powder thorough drying.To collect in the exsiccant reunion powder suction cyclonic separator by vacuum fan subsequently.
High temperature sintering and screening: with embodiment 1.The test result of the composite ceramic that this example obtains is listed in table 2.
Embodiment 3:
Batching: get the ceramic powder material of 9.8 kilogram of 1～10 μ m particle diameter, wherein contain 64%Cr
2O
3, 16%TiO
2, 20%Cu
2O adds each 0.1 kilogram of carboxymethyl cellulose and polystyrene caking agent then, and behind the thorough mixing, adding 13 kilograms water purification again, to stir into the slip that homodisperse suspends stand-by.
Atomization drying: with embodiment 1.
High temperature sintering and screening: with embodiment 1.The test result of the composite ceramic that this example obtains is listed in table 3.
Embodiment 4:
Batching: get the ceramic powder material of 9.6 kilogram of 1～10 μ m particle diameter, wherein contain 76.5%Cr
2O
3, 13.5%TiO
2, 10%Cu, add 0.4 kilogram of polystyrene caking agent then, behind the thorough mixing, adding 11 kilograms water purification again, to stir into the slip that homodisperse suspends stand-by.
Atomization drying: with embodiment 2.
High temperature sintering and screening: with embodiment 1.The test result of the composite ceramic that this example obtains is listed in table 4.
Embodiment 5:
Batching: get the ceramic powder material of 9.7 kilogram of 1～10 μ m particle diameter, wherein contain 68%Cr
2O
3, 12%TiO
2, 5%Al
2O
3, 15%CuO, add 0.3 kilogram of carboxymethyl cellulose caking agent then, behind the thorough mixing, adding 13 kilograms water purification again, to stir into the slip that homodisperse suspends stand-by.
Atomization drying: with embodiment 1.
High temperature sintering and screening: with embodiment 1.The test result of the composite ceramic that this example obtains is listed in table 5.
Embodiment 6:
Batching: get the ceramic powder material of 9.5 kilogram of 1～10 μ m particle diameter, wherein contain 76%Cr
2O
3, 13%TiO
2, 6%Al
2O
3, 5%Cu
2O adds each 0.2 kilogram of 0.1 kilogram of polyvinyl alcohol, polystyrene and dextrin caking agent then, and behind the thorough mixing, adding 12 kilograms water purification again, to stir into the slip that homodisperse suspends stand-by.
Atomization drying: with embodiment 2.
High temperature sintering and screening: with embodiment 1.The test result of the composite ceramic that this example obtains is listed in table 6.
Subordinate list
The test data of the composite ceramic that table 1 embodiment 1 obtains
| Granularity | Powder morphology | Loose density g/cm 3 | Mobile S/50g | Specific surface area (BET) m 2/g |
| -180～+ 325 orders | Loose hollow ball shape | 2.14 | 68 | 6.32 |
| -325 orders | Loose hollow ball shape | 1.92 | 94 | 7.85 |
The test data of the composite ceramic that table 2 embodiment 2 obtains
| Granularity | Powder morphology | Loose density g/cm 3 | Mobile S/50g | Specific surface area (BET) m 2/g |
| -180～+ 325 orders | Fine and close solid sphere | 1.38 | 98 | 6.87 |
| -325 orders | Fine and close solid sphere | 1.24 | 117 | 6.93 |
The test data of the composite ceramic that table 3 embodiment 3 obtains
| Granularity | Powder morphology | Loose density g/cm 3 | Mobile S/50g | Specific surface area (BET) m 2/g |
| -180～+ 325 orders | Fine and close hollow ball shape | 1.58 | 81 | 8.19 |
| -325 orders | Fine and close hollow ball shape | 1.29 | 112 | 8.78 |
The test data of the composite ceramic that table 4 embodiment 4 obtains
| Granularity | Powder morphology | Loose density g/cm 3 | Mobile S/50g | Specific surface area (BET) m 2/g |
| -180～+ 325 orders | Fine and close solid sphere | 1.84 | 75 | 8.09 |
| -325 orders | Fine and close solid sphere | 1.72 | 102 | 8.91 |
The test data of the composite ceramic that table 5 embodiment 5 obtains
| Granularity | Powder morphology | Loose density g/cm 3 | Mobile S/50g | Specific surface area (BET) m 2/g |
| -180～+ 325 orders | Fine and close hollow ball shape | 1.28 | 88 | 9.12 |
| -325 orders | Fine and close hollow ball shape | 1.17 | 118 | 10.21 |
The test data of the composite ceramic that table 6 embodiment 6 obtains
| Granularity | Powder morphology | Loose density g/cm 3 | Mobile S/50g | Specific surface area (BET) m 2/g |
| -180～+ 325 orders | Fine and close solid sphere | 1.29 | 87 | 9.34 |
| -325 orders | Fine and close solid sphere | 1.13 | 113 | 10.35 |
Claims (8)
1. the composite ceramic of used for hot spraying anti-seawater corrosion wearing and tearing and biodeterioration is characterized in that by mass percentage composite ceramic is made up of raw material powder 95～98% and caking agent 2～5%; By mass percentage, parafacies composition by oxide ceramics principal phase composition interpolation dense structure in the described raw material powder forms basic phase constitution, adding different anti-biofouling components again forms, wherein, oxide ceramics base phase constitution accounts for 80～95% of raw material powder weight, 5～20% of anti-biofouling ingredients constitute ceramics powder weight; Oxide ceramics base phase constitution contains principal phase composition 80～90%Cr
2O
3, parafacies composition 10～20%TiO
2Or TiO
2+ Al
2O
3Described caking agent is a kind of in dextrin, polyvinyl alcohol, carboxymethyl cellulose, the polystyrene, or two or more mixtures.
2. composite ceramic according to claim 1, the particle diameter that it is characterized in that raw material powder are 1～10 μ m.
3. composite ceramic according to claim 1, the feature of its first kind of composite ceramic powder is based on 80～95% oxide ceramics base phase powder in the raw material, the anti-biofouling composition that adds is 5～20%Cu powder, is prepared into the Cu oxidation of coating rear section at plasma spraying and forms Cu
2O, unoxidized Cu also plays certain strengthening effect to weave construction.
4. composite ceramic according to claim 1, the feature of its second kind of composite ceramic powder is based on 80～95% oxide ceramics base phase powder in the raw material, the anti-biofouling composition that adds is 5～20%CuO powder, is prepared into coating rear section CuO reduction at plasma spraying and forms Cu
2O.
5. composite ceramic according to claim 1, the feature of its third composite ceramic powder be in the raw material based on 80～95% oxide ceramics base phase powder, the anti-biofouling composition of interpolation is 5～20%Cu
2The O powder.
6. the preparation method of the composite ceramic of used for hot spraying anti-seawater corrosion wearing and tearing and biodeterioration, it is characterized in that described composite ceramics powder material forms basic phase constitution by the parafacies composition that oxide ceramics principal phase composition adds dense structure, add the anti-biofouling component again and form, it prepares the method that may further comprise the steps that adopts:
(1) batching: by mass percentage, get raw material powder 95～98%, caking agent 2～5%, it is mixed the water purification that the back adds 1～1.3 times of compound weight, be deployed into slip;
Contain 80～95% oxide ceramics base phase constitution material in the above-mentioned raw materials powder, also contain 5～20%Cu of anti-biofouling and enhanced tissue structure function, perhaps 5～20%Cu of anti-biofouling effect or Cu
2O; Oxide ceramics base phase constitution material contains principal phase composition 80～90%Cr
2O
3, parafacies composition 10～20%TiO
2Or TiO
2+ Al
2O
3
(2) atomization drying: with resulting slip atomization drying in spray-drying tower, the drying tower temperature is controlled in 110～300 ℃ of scopes, makes reunion powder;
(3) high temperature sintering: resulting reunion powder is placed the sintering kiln roasting, and temperature is 1100～1300 ℃, and temperature rise rate is 5 ℃/min, and soaking time is 30～60 minutes, makes the composite ceramic powder of typing;
(4) screening:,, obtain antibiont and adhere to composite ceramic product with anti-seawater corrosion after sieve with the composite ceramic powder furnace cooling of resultant typing.
7. the preparation method of composite ceramic according to claim 6, when it is characterized in that sieving in the step 4, get between-180～+ 325 mesh sieves and two grades of powder of-325 mesh sieves, they are that the antibiont of two kinds of different granularities of purposes adheres to the composite ceramic product with anti-seawater corrosion.
8. the preparation method of composite ceramic according to claim 6 is characterized in that described atomization drying is is carrier with dried compressed air, adopts two streaming nozzles or centrifugal atomizing nozzle that slurry is sprayed into atomization drying in the spray-drying tower.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100523184A CN100506743C (en) | 2007-05-29 | 2007-05-29 | Seawater erosion abrasion and biologic defiling resistant composite ceramic powder for hot spraying and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100523184A CN100506743C (en) | 2007-05-29 | 2007-05-29 | Seawater erosion abrasion and biologic defiling resistant composite ceramic powder for hot spraying and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101096308A true CN101096308A (en) | 2008-01-02 |
| CN100506743C CN100506743C (en) | 2009-07-01 |
Family
ID=39010421
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100523184A Expired - Fee Related CN100506743C (en) | 2007-05-29 | 2007-05-29 | Seawater erosion abrasion and biologic defiling resistant composite ceramic powder for hot spraying and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100506743C (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101723650B (en) * | 2009-11-04 | 2012-06-06 | 哈尔滨工业大学 | Oxide ceramic/BaxSrl-xSO4 ceramic composite material and preparation method thereof |
| CN101736279B (en) * | 2008-11-05 | 2012-07-18 | 沈阳黎明航空发动机(集团)有限责任公司 | Hypersonic flame spraying process for self-lubricating wear-resistant coating |
| CN103086700A (en) * | 2013-02-26 | 2013-05-08 | 江苏立达高科特种材料有限公司 | Preparation method of nano oxide ceramic hollow sphere used for thermal spraying |
| CN105297032A (en) * | 2015-12-01 | 2016-02-03 | 西北有色金属研究院 | Method preventing marine organisms from adhering to surface of titanium or titanium alloy |
| WO2019057002A1 (en) * | 2017-09-19 | 2019-03-28 | 同济大学 | Thermal spray graphene enamel and use thereof |
| CN114085562A (en) * | 2021-12-17 | 2022-02-25 | 武汉苏泊尔炊具有限公司 | Corrosion-resistant material, method for producing same, and corrosion-resistant coating formed therefrom |
| CN117142841A (en) * | 2023-09-06 | 2023-12-01 | 青岛永钊新材料科技有限公司 | Nano ceramic composite coating for resisting marine biofouling and preparation method thereof |
-
2007
- 2007-05-29 CN CNB2007100523184A patent/CN100506743C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101736279B (en) * | 2008-11-05 | 2012-07-18 | 沈阳黎明航空发动机(集团)有限责任公司 | Hypersonic flame spraying process for self-lubricating wear-resistant coating |
| CN101723650B (en) * | 2009-11-04 | 2012-06-06 | 哈尔滨工业大学 | Oxide ceramic/BaxSrl-xSO4 ceramic composite material and preparation method thereof |
| CN103086700A (en) * | 2013-02-26 | 2013-05-08 | 江苏立达高科特种材料有限公司 | Preparation method of nano oxide ceramic hollow sphere used for thermal spraying |
| CN105297032A (en) * | 2015-12-01 | 2016-02-03 | 西北有色金属研究院 | Method preventing marine organisms from adhering to surface of titanium or titanium alloy |
| WO2019057002A1 (en) * | 2017-09-19 | 2019-03-28 | 同济大学 | Thermal spray graphene enamel and use thereof |
| CN114085562A (en) * | 2021-12-17 | 2022-02-25 | 武汉苏泊尔炊具有限公司 | Corrosion-resistant material, method for producing same, and corrosion-resistant coating formed therefrom |
| CN117142841A (en) * | 2023-09-06 | 2023-12-01 | 青岛永钊新材料科技有限公司 | Nano ceramic composite coating for resisting marine biofouling and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100506743C (en) | 2009-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100506743C (en) | Seawater erosion abrasion and biologic defiling resistant composite ceramic powder for hot spraying and preparation thereof | |
| CN1296314C (en) | Nickel-picotite type infrared radiation ceramic powdered material for thermal spraying and preparation method | |
| JP7341582B2 (en) | NiCrBSi-ZrB2 cermet powder for high temperature protection, composite coating and manufacturing method thereof | |
| CN110396687A (en) | A kind of Ti2AlC MAX phase ceramics coating and its cold spraying preparation method | |
| CN102181815A (en) | Marine organism corrosion resistant ceramic coating and preparation method thereof | |
| CN105603352A (en) | Al2O3/YAG amorphous/eutectic composite ceramic coating and preparation method thereof | |
| CN113564512B (en) | Method for preparing whisker toughened plasma sprayed ceramic-based seal coating | |
| CN102363877A (en) | Method for preparing TiB2-Co coating by supersonic-speed flame spraying | |
| CN1202043C (en) | Prepn of large grain spherical submicron/nano composite fiber-ceramic powder | |
| CN105967658A (en) | Wear-resistant composite coating material | |
| US7799716B2 (en) | Partially-alloyed zirconia powder | |
| CN105967683A (en) | Weather-resistant ceramic coating material | |
| CN115121789A (en) | Thermal shock resistance high wear-resistant coating material and preparation method thereof | |
| CN104498858A (en) | Nano-ceramic thermal barrier coating and preparation method thereof | |
| CN106756729B (en) | A kind of FeB/Co liquid zinc corrosion resistants wear-proof metal ceramic coating and preparation method | |
| CN101927586B (en) | Metallic matrix surface composite coating and preparation method thereof | |
| CN105967693A (en) | Ceramic coating material for exhaust equipment | |
| CN101774019B (en) | Metal/nanometer zirconia composite spherical powder material used for gradient coating and preparation method thereof | |
| CN113862599B (en) | Al 2 O 3 -GdAlO 3 Amorphous oxide ceramic coating and method for preparing same | |
| CN108517482B (en) | Wear-resistant corrosion-resistant coating for boiler tube wall and preparation method thereof | |
| CN101580380B (en) | Anticorrosion abrasion-resistant coating material for hot-dip galvanizing device | |
| CN111809133B (en) | High-hardness nickel-based titanium carbide powder and preparation method thereof | |
| CN1762901A (en) | Nanostructured yttrium stable zirconium oxide agglomerate type powder and its production method | |
| CN111875416A (en) | Ceramic-based abradable seal material, coating, composite coating and preparation method | |
| CN108707897B (en) | Ceramic coating of exhaust pipe and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090701 Termination date: 20130529 |