CN101093048A - Color frosted plastic-steel section bar, and manufacturing method - Google Patents
Color frosted plastic-steel section bar, and manufacturing method Download PDFInfo
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- CN101093048A CN101093048A CN 200710141395 CN200710141395A CN101093048A CN 101093048 A CN101093048 A CN 101093048A CN 200710141395 CN200710141395 CN 200710141395 CN 200710141395 A CN200710141395 A CN 200710141395A CN 101093048 A CN101093048 A CN 101093048A
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Abstract
This invention relates to color matte plastic steel profiles, in which at least one surface includes backing of a plastic steel profile, ultraviolet solidified color coat and a protection film orderly from inside characterizing in blasting sand on the surface of the backing to form a sandblasting layer, then coating a solidified color dope layer on the sandblasting surface. This invention also relates to a manufacturing method for the color matte plastic steel profiles.
Description
Technical field
The present invention relates to a kind of surface by the color frosted plastic-steel section bar of frosted application colour-wash production and the manufacture method of this colour plastics-steel shaped material.
Background technique
The plastics-steel shaped material that construction industry adopted is generally PVC (U-PVC), and traditional white plastics-steel shaped material (as shown in Figure 1) is owing to be exposed to the open air for a long time, be positioned at the window sectional material surface jaundice easily of outdoor, suffer erosion, shorten working life greatly.And along with the raising of people's living standard, color solid sense plastics-steel shaped material is subjected to Consumer's favor.
Present colour section bar has the entire body colouring, promptly adds colorant in the PVC raw material.Such section bar after the extruding and moulding, because the dispersion inequality of colorant can cause aberration between different batches, in addition, this plastics-steel shaped material is easy to fade after long-time the use, weatherability is poor.
Also have the bicolor co-extrusion method, promptly by auxiliary extruder and mould, with PMMA, the ASA of colour or PVC fusion co-extrusion to the plastics-steel shaped material surface.My company discloses a kind of synthetic-resin window sectional materials and manufacturing mechanism with multi-colour and three-dimensional line surface in Chinese patent CN200510014744X, PMMA and ASA have good weatherability, but such section bar production need be purchased auxiliary extruder, mould in the past also needs to improve, and investment is big.In addition, colored PMMA and ASA color category are less, and expense of raw materials is also higher.
In addition, the external coating method is promptly at plastics-steel shaped material surface spraying one deck colour-wash.This method biggest advantage is exactly the variation of color kind, and production scale, mode are flexible.A kind of common known product for example shown in Figure 3, it comprises PVC plastic-steel base material 2, conventional chromatic spray painting layer 3 and protective film 4.The colored plastics-steel shaped material that a kind of surface produces by the application colour-wash is disclosed among the China utility model patent ZL200520001953.6 (notification number CN2767149Y, day for announcing 2006.03.29).It is to be coated with at the plastics-steel shaped material matrix surface one deck ultraviolet cured colored paint is housed, at ultraviolet cured colored paint surface coated with protective film; Or be coated with at the plastics-steel shaped material matrix surface and one deck ultraviolet cured colored paint be housed or from dryness colored paint coating, be coated with at ultraviolet cured colored paint or from dryness colored paint coating surface one deck ultraviolet light polymerization varnish is housed; At ultraviolet light polymerization varnish surface coated with protective film.The colored plastics-steel shaped material of this model utility has rich color, and paint film is plentiful, and resistance to marring is good, and wear-resisting, corrosion-resistant, ageing-resistant, colour-fast, nonflammable advantage has better decorative effect and protection effect than the plastics-steel shaped material that generally uses at present.The making method of plastics-steel shaped material described in the utility model has that required production site is little, and equipment investment is low, manufacturing efficiency height, less energy consumption, free of contamination advantage.But for this colored plastics-steel shaped material, owing to will carry out complicated soda acid washing agent surface treatment to plastics-steel shaped material before the spraying, after the spraying, coating will carry out levelling and drying, complex manufacturing, and manufacturing efficiency is low, the energy consumption height, and also the surface three-dimensional sense is relatively poor.Therefore, provide a kind of ornamental strong, weatherability good, the chromatograph adhesion-tight, technology is simple, the production continuity is strong, manufacturing efficiency and raw material availability height, less energy consumption, free of contamination colored plastics-steel shaped material, is that related domain has problem to be solved.
Summary of the invention
In order to address the above problem, the present invention passes through at the plastics-steel shaped material matrix surface through sand blast, application one deck contains the ultraviolet curing chromatic coating of acryl particulate, directly carry out ultraviolet light polymerization, thereby improved the ornamental and weatherability of plastics-steel shaped material, and the manufacturing efficiency of whole process flow.
According to a kind of color frosted plastic-steel section bar of the present invention; its at least one surface comprises plastics-steel shaped material base material, ultraviolet curing chromatic coating and protective film from inside to outside successively; it is characterized in that; carry out sandblast at described plastics-steel shaped material substrate surface; form the sandblast layer, again at this sandblast laminar surface coating ultraviolet light curing color coating layer.
Disclosed a kind of color frosted plastic-steel section bar more than according to the present invention; in other words; its at least one surface at described plastics-steel shaped material comprises plastics-steel shaped material base material, ultraviolet curing chromatic coating and protective film from inside to outside successively, it is characterized in that: wherein comprise the above-mentioned sandblast layer that forms by blasting craft between described plastics-steel shaped material substrate surface and ultraviolet curing chromatic coating.
According to a kind of color frosted plastic-steel section bar of the present invention, the employed particle of wherein said sandblast layer is resin sand.
According to a kind of color frosted plastic-steel section bar of the present invention, the particle diameter of wherein said resin sand is 40~100 orders.
According to a kind of color frosted plastic-steel section bar of the present invention, the employed coating lacquer of wherein said ultraviolet curing chromatic coating can be selected from ultraviolet light polymerization solid-shade paint, ultraviolet light polymerization metal flash paint, ultraviolet curing pearl lacquer.
According to a kind of color frosted plastic-steel section bar of the present invention, comprise the acryl particulate in the wherein said ultraviolet curing chromatic coating.
According to a kind of color frosted plastic-steel section bar of the present invention, the particle diameter of wherein said acryl particulate is 5~20 μ m.
According to a kind of color frosted plastic-steel section bar of the present invention, wherein between described sandblast layer and ultraviolet curing chromatic coating, also comprise the ultraviolet cured primer coating.
According to a kind of color frosted plastic-steel section bar of the present invention, wherein include the surface that forms by the ultraviolet curing chromatic coating that contains the acryl particulate with color frosted texture at least one surface of described plastics-steel shaped material.
The thickness of described ultraviolet curing chromatic paint coatings is 15~25 μ m, and the thickness sum of ultraviolet light polymerization layer of varnish and ultraviolet curing chromatic paint coatings is 15~25 μ m.
Materials such as above-mentioned resin sand, the employed coating lacquer of ultraviolet curing chromatic coating, acryl, ultraviolet light polymerization varnish, protective film are related domain materials commonly used.
On the other hand, the present invention also provides the manufacture method of above-mentioned color frosted plastic-steel section bar, it is characterized in that may further comprise the steps:
(a) carry out sand blast at the plastics-steel shaped material matrix surface,
(b) application one deck contains the ultraviolet curing chromatic coating of acryl particulate, directly carries out ultraviolet light polymerization,
(c) at ultraviolet curing chromatic coating surface coated with protective film.
According to above-mentioned manufacture method of the present invention, it is characterized in that between described step (a) and step (b), also comprising application one deck ultraviolet light polymerization varnish.
Color frosted plastic-steel section bar of the present invention is that the section bar surface after sand blast forms the microcosmic convex and concave feature, increased surface adhesion force greatly, need not any other operation, directly the section bar external coating one deck after processing contains the ultraviolet curing chromatic coating of acryl particulate, after the ultraviolet light polymerization program, the protective film that polypropylene or polyethylene etc. are used to protect body surface is posted on the surface after curing; Or the elder generation of the plastics-steel shaped material matrix surface after sand blast application one deck ultraviolet cured primer; make further increasing surface adhesion force; application one deck contains the ultraviolet curing chromatic coating of acryl particulate subsequently, and the protective film that polypropylene or polyethylene etc. are used to protect body surface is posted on the surface after curing.
Choose wantonly, color frosted plastic-steel section bar of the present invention can be made by the following method:
PVC plastics-steel shaped material surface sand-blasting is handled:
Section bar is put on the automatic sand-blasting machine line belt, regulates nozzle angle, adjust air pressure, adjust the distance on nozzle and section bar surface, select suitable transfer rate, load the resin sand that is exclusively used in rigid plastic surface, carry out sand blast.Section bar specific surface area after the processing increases, and has improved the adhesion of section bar to the ultraviolet colour-wash.
Application ultraviolet curing chromatic coating:
The application mode can adopt general application mode, also can adopt the mode of spraying, and coating can be recycled directly.The ultraviolet curing chromatic coating that contains the acryl particulate comprises ultraviolet light polymerization solid-shade paint or ultraviolet light polymerization metal flash paint or ultraviolet curing pearl lacquer.Choose wantonly, can also application one deck ultraviolet light polymerization varnish before the above ultraviolet curing chromatic coating of application.
Photocuring:
Can directly be cured after spraying finishes, not need to carry out levelling or oven dry.Photocuring adopts ultraviolet light polymerization.Because it is thorough with coating curing that the color of colored ultraviolet coating and coating thickness have determined that single vitalight lamp is difficult to, this process using characteristic wavelength be optimized combination at high pressure mercury lamp and the 420nm metal halid lamp of 360nm, guaranteed that the coating of different colours can both thoroughly solidify.Vitalight lamp quantity: high pressure mercury lamp 3-6 props up, power 5-8Kw, and metal halid lamp 2-4 props up, power 4-6Kw, curing rate 1-30m/min.
Pasting protective film:
Plastics-steel shaped material through being up to the standards sticks polypropylene or polyethylene protective film at sprayed surface, avoids section bar to scratch in carrying and work progress.
Employed ultraviolet curing chromatic coating, ultraviolet priming paint are coating commonly used in related domain among the present invention.
Described plastics-steel shaped material is various PVC (PVC) section bar commonly used in related domain, can be used for making various plastic-steel door and windows or other ornament material.
Plastics-steel shaped material of the present invention; the surface after treatment; have that rich color, weatherability are good, firm adhesion, paint film is plentiful, scratch resistant is strong, corrosion-resistant, colour-fast; advantage such as nonflammable; can also realize the frosted texture on section bar surface, have excellent decorative effect and protection effect.
It is simple that plastics-steel shaped material manufacture method of the present invention has preparation process, can produce continuously, manufacturing efficiency height, raw material availability height, less energy consumption, pollution-free, advantage such as save space.
Description of drawings
Fig. 1 is traditional white plastics-steel shaped material perspective view.
Fig. 2 is a color frosted plastic-steel section bar perspective view provided by the invention.
Fig. 3 is traditional colored plastics-steel shaped material structural representation.
Fig. 4 is a kind of structural representation of color frosted plastic-steel section bar provided by the invention.
Fig. 5 is the another kind of structural representation of color frosted plastic-steel section bar provided by the invention.
Wherein, main reference character is as follows:
1, color frosted venner 4, protective film
2, PVC plastic-steel base material 5, chromatic spray painting layer
3, conventional chromatic spray painting layer 6, ultraviolet varnish coat
7, sandblast layer
Embodiment
See also Fig. 2, it is a color frosted plastic-steel section bar perspective view of the present invention.Comprise color frosted venner 1 and PVC plastic-steel base material 2 among the figure, color frosted venner 1 wherein occupies a surface at least on PVC plastic-steel base material 2, and preferably the surface that is occupied by this color frosted venner 1 is the outer surface at PVC plastic-steel base material 2.
See also Fig. 4 again, it is the color frosted plastic-steel section bar structural representation of first embodiment of the invention.It comprises PVC plastic-steel base material 2 laterally successively by plastic-steel base material inboard, at the sandblast layers 7 of this PVC plastic-steel base material 2 surface sprayings, and the chromatic spray painting layer 5 of spraying on this sandblast layer 7, and the protective film 4 that covers at chromatic spray painting layer 5 outer surface.Wherein chromatic spray painting layer 5 is by forming by the colour-wash spraying of ultraviolet light polymerization.
See also Fig. 5 again, it is the color frosted plastic-steel section bar structural representation of second embodiment of the invention.It comprises PVC plastic-steel base material 2 laterally successively by plastic-steel base material inboard; sandblast layer 7 in these PVC plastic-steel base material 2 surface sprayings; the ultraviolet varnish coat 6 of spraying on this sandblast layer 7; the chromatic spray painting layer 5 of spraying on this ultraviolet varnish coat 6, and the protective film 4 that covers at chromatic spray painting layer 5 outer surface.Wherein ultraviolet varnish coat 6 is to form by spraying by the varnish paint of ultraviolet light solid, and chromatic spray painting layer 5 is by forming by the colour-wash spraying of ultraviolet light polymerization.
Embodiment 1: the faint yellow plastics-steel shaped material of frosted
Please refer to Fig. 4.Prepare qualified PVC base material, be placed on the production line, prepare to produce.Adjust sandblast transmission speed, spraying transmission speed, solidify transmission speed, hauling speed all at 20m/min.Enter into spraying equipment after the substrate passed sand blast, with mass fraction is 3-8wt%, the yellow ultraviolet solidifying coating that contains acryl particulate (2-8wt%) sprays (coating should constantly stir, and keeps 50 ℃~60 ℃ temperature), then enters curing apparatus.In the curing apparatus, 3 of high pressure mercury lamps, power 4.7kw, 3 of metal halid lamps, power 3Kw.Curing finishes, and behind tractor, checks whether section bar qualified, reach criterion of acceptability after, paste PE (polyethylene) protective film.
Embodiment 2: the coffee-like plastics-steel shaped material of frosted
Prepare qualified PVC base material, be placed on the production line, prepare to produce.The acryl particulate that with mass fraction is 3-8wt% mixes mutually with coffee-like ultraviolet photocureable coating, stirs and be heated to 50-60 ℃.Adjust sandblast transmission speed, spraying transmission speed, solidify transmission speed, hauling speed all at 18m/min.Begin to produce, through entering curing apparatus, 6 of high pressure mercury lamps, power 7.8Kw, 3 of metal halid lamps, power 3Kw after surface sand-blasting processing, the coating spraying.After the curing, reach criterion of acceptability, paste PE (polyethylene) protective film through test rating, get final product the coffee-like plastics-steel shaped material of frosted.
Embodiment 3: the green plastics-steel shaped material of frosted
Prepare qualified PVC base material, be placed on the production line, prepare to produce.Adjust sandblast transmission speed, spraying transmission speed, solidify transmission speed, hauling speed all at 18m/min.Enter into spraying equipment after the substrate passed sand blast, adopt the green ultraviolet solidifying coating that contains acryl particulate (3-8wt%) to spray (coating should constantly stir, and keeps the temperature about 52 ℃), then enter curing apparatus.In the curing apparatus, 3 of high pressure mercury lamps, power 4.7kw, 3 of metal halid lamps, power 3Kw.Curing finishes, and behind tractor, checks whether section bar qualified, reach criterion of acceptability after, paste PE (polyethylene) protective film.
Embodiment 4: mute light silver grey frosted plastic-steel section bar
Prepare qualified PVC base material, be placed on the production line, prepare to produce.Adjust sandblast transmission speed, spraying transmission speed, solidify transmission speed, hauling speed all at 25m/min.Beginning to produce, behind surface sand-blasting processing, application ultraviolet photocureable priming coat, is 0.5-2wt% with mass fraction, and the aluminum paste that contains acryl particulate (3-8wt%) mixes with colourless ultraviolet photocureable coating mutually with auxiliary agent, stirs and be heated to 50-60 ℃.Enter curing apparatus, 6 of high pressure mercury lamps, power 7.8Kw, 3 of metal halid lamps, power 3Kw after the coating spraying.After the curing, reach criterion of acceptability, paste PE (polyethylene) protective film through test rating, get final product mute light silver grey plastics-steel shaped material.
Embodiment 5: silvery white pearly-lustre color and luster frosted plastic-steel section bar
Prepare qualified PVC base material, be placed on the production line, prepare to produce.With mass fraction is after silvery white pearl essence, 3-8wt% acryl particulate and the auxiliary agent of 3-10wt% mixes, to mix mutually with colourless ultraviolet photocureable coating, stirs and be heated to 50-60 ℃.Adjust sandblast transmission speed, spraying transmission speed, solidify transmission speed, hauling speed all at 28m/min.Begin to produce, through entering curing apparatus, 6 of high pressure mercury lamps, power 7.8Kw, 3 of metal halid lamps, power 3Kw after surface sand-blasting processing, the coating spraying.After the curing, reach criterion of acceptability, paste PE (polyethylene) protective film through test rating, get final product silvery white pearly-lustre color and luster frosted plastic-steel section bar.
Reference examples:
Earlier wipe the greasy dirt on plastics-steel shaped material surface, remove the dust on plastics-steel shaped material surface again with dusting apparatus with ethanol.Then at the green lacquer of the golden yellow ultraviolet light polymerization of surface treated plastics-steel shaped material surface spraying; levelling is 5 minutes under the infrared rays of 40 ℃ of temperature; enter then 8 3Kw ultraviolet lamps (high pressure mercury lamp) are housed; transmission speed is 12 meters/minute a photo solidification machine; after the curing; spray ultraviolet light cured burnished varnish at green coating surface again; levelling is 3 minutes under the infrared rays of 50 ℃ of temperature; enter 4 5Kw ultraviolet lamps (high pressure mercury lamp) are housed; transmission speed is 25 meters/minute a photo solidification machine, after the curing, and the section bar through being up to the standards; paste the polypropylene protective film, can obtain the golden yellow plastics-steel shaped material finished product of highlight type.
The test example:
With reference to relevant criterion, the product of above embodiment and reference examples manufacturing is detected, the results are shown in Table 1.
As seen the result compares with the product that commonsense method in the reference examples is produced from table, and product performance of the present invention obviously improve.
Table 1, section bar The performance test results
Test event | Embodiment 1 | |
|
|
|
Reference examples | Test method |
Curing time (s) | 3.5 | 6 | 4 | 4.5 | 4.5 | 16 | Company standard |
Adhesion (level) | 0 | 0 | 0 | 0 | 0 | 1 | GB9286-98 |
The low temperature drop impact | Qualified | Qualified | Qualified | Qualified | Qualified | Qualified | GB/T8814- 2004 |
Fillet weld strength (Mpa) | 54.49 | 56.79 | 54.49 | 58.91 | 59.24 | 44.18 | GB/T8814- 2004 |
Hardness (H) | 5 | 5 | 4 | 4 | 4 | 3 | |
Weatherability | By 6000h test Δ E≤3 Δ b≤2 | By 6000h test Δ E≤3 Δ b≤2 | By 6000h test Δ E≤3 Δ b≤2 | By 6000h test Δ E≤3 Δ b≤2 | By 6000h test Δ E≤3 Δ b≤2 | Not by 6000h test, Δ E=5.65 | GB/T8814- 2004 |
Claims (10)
1, a kind of color frosted plastic-steel section bar; its at least one surface comprises plastics-steel shaped material base material, ultraviolet curing chromatic coating and protective film from inside to outside successively; it is characterized in that; carry out sandblast at described plastics-steel shaped material substrate surface; form the sandblast layer, again at this sandblast laminar surface coating ultraviolet light curing color coating layer.
2, color frosted plastic-steel section bar according to claim 1 is characterized in that, the employed particle of described sandblast layer is resin sand.
3, color frosted plastic-steel section bar according to claim 1 and 2 is characterized in that, the particle diameter of described resin sand is 40~100 orders.
4, color frosted plastic-steel section bar according to claim 1 is characterized in that, the employed coating lacquer of described ultraviolet curing chromatic coating is selected from ultraviolet light polymerization solid-shade paint, ultraviolet light polymerization metal flash paint, ultraviolet curing pearl lacquer.
5, color frosted plastic-steel section bar according to claim 1 is characterized in that, comprises the acryl particulate in the described ultraviolet curing chromatic coating.
6, color frosted plastic-steel section bar according to claim 5 is characterized in that, the particle diameter of described acryl particulate is 5~20 μ m.
7, according to any described color frosted plastic-steel section bar of claim 1~6, it is characterized in that, between described sandblast layer and ultraviolet curing chromatic coating, also comprise the ultraviolet light polymerization varnish coat.
8, color frosted plastic-steel section bar according to claim 7, it is characterized in that, the thickness of described ultraviolet curing chromatic paint coatings is 15~25 μ m, and the thickness sum of described ultraviolet light polymerization layer of varnish and ultraviolet curing chromatic paint coatings is 15~25 μ m.
9, make the method for any described color frosted plastic-steel section bar of claim 1~6, it is characterized in that may further comprise the steps:
(a) carry out sand blast at the plastics-steel shaped material matrix surface,
(b) application one deck contains the ultraviolet curing chromatic coating of acryl particulate, directly carries out ultraviolet light polymerization,
(c) at ultraviolet curing chromatic coating layer surface pasting protective film.
10, method according to claim 9 is characterized in that, also comprises application one deck ultraviolet light polymerization varnish between described step (a) and step (b).
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102133570A (en) * | 2010-01-26 | 2011-07-27 | 深圳市昌盛辉精密五金有限公司 | Coloring and painting process for surface of hardware |
CN102617967A (en) * | 2012-03-09 | 2012-08-01 | 武汉正浩塑胶有限公司 | Plastic profile with surface matte effect and production method thereof |
CN109079445A (en) * | 2018-09-06 | 2018-12-25 | 黄石鑫华轮毂有限公司 | A kind of aluminium alloy wheel hub of vehicle surface frosted coating process |
CN111816810A (en) * | 2020-07-17 | 2020-10-23 | 东莞市中泰精密科技有限公司 | Flash sand process for composite plate of mobile phone battery cover |
CN114101004A (en) * | 2021-11-23 | 2022-03-01 | 浙江德裕科技有限公司 | Intermediate layer coating structure coated on surface of window rail and forming process thereof |
-
2007
- 2007-08-09 CN CN 200710141395 patent/CN101093048A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102133570A (en) * | 2010-01-26 | 2011-07-27 | 深圳市昌盛辉精密五金有限公司 | Coloring and painting process for surface of hardware |
CN102617967A (en) * | 2012-03-09 | 2012-08-01 | 武汉正浩塑胶有限公司 | Plastic profile with surface matte effect and production method thereof |
CN102617967B (en) * | 2012-03-09 | 2014-06-04 | 武汉正浩环保新材料科技有限公司 | Plastic profile with surface matte effect and production method thereof |
CN109079445A (en) * | 2018-09-06 | 2018-12-25 | 黄石鑫华轮毂有限公司 | A kind of aluminium alloy wheel hub of vehicle surface frosted coating process |
CN111816810A (en) * | 2020-07-17 | 2020-10-23 | 东莞市中泰精密科技有限公司 | Flash sand process for composite plate of mobile phone battery cover |
CN114101004A (en) * | 2021-11-23 | 2022-03-01 | 浙江德裕科技有限公司 | Intermediate layer coating structure coated on surface of window rail and forming process thereof |
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Open date: 20071226 |