CN101085548A - Method for manufacturing exterior wall thermal-insulation water-proof decoration plate - Google Patents
Method for manufacturing exterior wall thermal-insulation water-proof decoration plate Download PDFInfo
- Publication number
- CN101085548A CN101085548A CN 200610014045 CN200610014045A CN101085548A CN 101085548 A CN101085548 A CN 101085548A CN 200610014045 CN200610014045 CN 200610014045 CN 200610014045 A CN200610014045 A CN 200610014045A CN 101085548 A CN101085548 A CN 101085548A
- Authority
- CN
- China
- Prior art keywords
- decorative layer
- fire retardant
- exterior wall
- decorative
- wall thermal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention relates to the making of outside wall insulation and water proof decoration board.The invention relates to the making of a construction part.It can bear the change of all day climate, with isolation, water proof and decorative effect, with the product being able to use for the outside wall with simple construction and short cycle. It features in the making of the decorative layer, mold fabrication, making unpolymered resin, forming under normal pressure in 30-100deg.C. The process for complex isolation layer uses spray gun spraying foam lotion to prevent the flaming on the decoration board, controlling the temperature over 10deg.C, condensing for 20-40s.Applies the adhesive on the back of the decorative back, pouring into foam liquid inside the mold in 65-90deg.C to form complex plate with the decorative layer. It applies the back of the decorative layer with binder to bind it with the EPS plate to form the compound plate. It can build at the same time with the construction of the building.
Description
Technical field
The present invention relates to a kind of preparation method of building element.A kind of preparation method of exterior wall thermal-insulation water-proof decoration plate particularly.
Background technology:
For energy savings, the environment of beautifying city, the exterior wall of building need add the heat preserving and water proof decoration layer.Present exterior wall thermal-insulation water-proof decorations layer mostly is on the exterior wall of building pastes foaming layer as heat-insulation layer with adhesive, the linked network of glassivation fiber on heat-insulation layer then, on linked network, spread the sand ash of making by cement and complexing agent, become watertight composition after the sand ash drying, the decorative paint that sprays exterior wall again is as decorative layer.
Laying of this exterior wall thermal-insulation water-proof decorations layer begins construction and working procedure complexity after must building up at the exterior wall of building, not only prolong the time limit of construction, simultaneously, because exterior wall is bearing round-the-clock variation of temperature, expanding with heat and contract with cold year in and year out makes grey sheet come off or surface checking easily.
Utility application " exterior wall thermal-insulation water-proof decoration plate " provides a kind of exterior wall thermal-insulation water-proof decoration plate.It is a kind of prefabricated component, and it comprises heat-insulation layer and decorative layer; Heat-insulation layer is foaming layer, and decorative layer is a polyester layer.
Should " exterior wall thermal-insulation water-proof decoration plate " must possess insulation, waterproof and decorative effect, and its heat-insulation layer must combine closely with the water-proof decorative layer, after bearing round-the-clock variation of temperature, not fall grey sheet, not chap, and require construction simply, reliable in quality.
Summary of the invention:
The present invention aims to provide a kind of preparation method of exterior wall thermal-insulation water-proof decoration plate.This preparation method is simple, and can bear the variation of round-the-clock temperature, has insulation, waterproof action and decorative effect; When prepared product was used for skin, construction was simple, and the duration is short.
Technical scheme of the present invention
One, the making of decorative layer
1, make mould;
The bottom surface of tabular die is provided with the decoration line.
2, batching:
Is 100 parts with following each component with major ingredient unsaturated-resin 196, and each component is according to following weight ratio, and mixing becomes not polymeric polyester body;
Unsaturated-resin 1,968 100
Fire retardant 2-75
Ultra-violet absorber 0.5-2
Initator 1-2
Promoter 2-6
Wherein:
Unsaturated-resin 196S is unsaturated-resin 1 96S that Tianjin synthetic material factory produces.
Fire retardant can be tri-chlorination two antimony, three (β-chloroethyl) phosphate or aluminium hydroxides;
Ultra-violet absorber can be UV-9 (chemical name is 2-hydroxyl-4-methoxy benzophenone), UV-531 (chemical name is a UV-531).
Initator can be to contain 50% peroxidating, first and second copper solutions;
Promoter can be the styrene solution that contains 6% naphthoic acid cobalt.
3, moulding: after the polymeric polyester body does not soak into toning with glass mat, apply in mould, cover die cover, normal pressure heating down is tabular decorative layer at 30-100 ℃ of temperature compacted under.
Two, composite heat-insulating layer on decorative layer
The process using method 1 of the present invention's composite heat-insulating layer on decorative layer, method 2, method 3;
Wherein:
Method 1, the decoration texture of decorative layer is faced down, use spray gun after fire-retardant Polyurethane expanding foam solution is sprayed at the back side of decorative panel equably, make the decorative panel polymerization of in limited space, foaming, environment temperature is controlled at more than 10 ℃, setting time is controlled at 20-40 between second, and fire-retardant Polyurethane expanding foam solution polymerization forming is with dicing after decorative layer becomes composite plate.
Fire-retardant Polyurethane expanding foam solution is 100 parts with the phosphorous PPG of major ingredient, and each component according to weight ratio is:
Phosphorous PPG 100
Poly isocyanate 218
Ethylenediamine PPG 30-40
Triethylene diamine (33%) 4-10
Catalyst 1-2
Blowing agent 40-50
Stabilizing agent 4-6
Fire retardant 30-40
Wherein:
Catalyst can be an organo-aluminium tin;
Blowing agent can be a F-11;
Stabilizing agent can be an organosilicon;
Fire retardant can be a barium metaborate, tetrabromobisphenol A, three (β-chloroethene is stupid) phosphate.
Method 2, decorative layer is after die for molding, directly the decorative layer back side in mould is coated with adhesive, in mould, water people's fire retardant polystyrene expanding foam solution then, according to the thickness requirement of made heat-insulation layer adjust the loam cake height and fixing after, foaming under 65-90 ℃ of temperature becomes composite plate with decorative layer.
The fire retardant polystyrene expanding foam solution is 100 parts with the major ingredient polystyrene, and each component according to weight ratio is:
Polystyrene (major ingredient) 100
Water 160
Blowing agent 8-12
Dispersant 4-5
Fire retardant 2-3
Antioxidant 0.2-0.6
Feed nitrogen 0.3-0.5MPa;
Wherein:
Blowing agent can be a butane;
Dispersant can be a washing powder;
Fire retardant can be a tetrabromoethane, cumyl peroxide.
Antioxidant can be the antioxidant 264 that the logical generation chemical industry Co., Ltd in Yantai produces;
Method 3 is coated with the back side of decorative layer with adhesive, makes it bonding with the EPS plate, constitutes composite plate;
The EPS plate is a polystyrene self-extinguishing type moulded foam plate, can be the EPS plate that U.S. building material Co., Ltd in sky, Shenyang or the rich peaceful foam in Nanjing Co., Ltd produce.
In the made decorative layer of the present invention, since tri-chlorination two antimony, three (β-chloroethyl) phosphate, and aluminium hydroxide is the self-extinguishment compound, therefore has fire retardation; And the UV9 of adjacent hydroxyl hexichol class (2-hydroxyl-4-methoxy benzophenone) has the ultraviolet ray of absorption, anti-ultraviolet effect with UV531 (UV-531); Glass mat can play the effect that improves intensity and freedom from cracking; Can make the decorative layer typing after the unsaturated-resin polymerization, waterproof also strengthens firmness.With tri-chlorination two antimony, three (β-chloroethyl) phosphate, aluminium hydroxide, adjacent hydroxyl hexichol class is mixed back sized glass fibres felt with unsaturated-resin, after resin was through the toning polymerization forming, prepared decorative layer not only had the Z-Correct bump mapping Z-correct pattern of mould bottom surface setting and the set decorative effect that color produced, after being used for building, can the beautifying city; Have uvioresistant simultaneously, waterproof and fire-retardant performance can adapt to round-the-clock temperature Change and not fall grey sheet, do not chap.
Because the present invention during composite heat-insulating layer, is subjected to set spatial constraints on decorative layer, therefore, the expansive force that produces during foaming is combined into one foaming body and decorative layer, in conjunction with firm, can delamination not fall sheet.
And heat-insulation layer of the present invention is the foaming body formation, and airtight micro-bubble has good insulation effect in this foaming body, therefore has insulation effect; The foaming body that adds fire retardant also has fire-retardant effect on heat preservation effect; And, because the light specific gravity of foaming body, therefore make the weight saving of products made thereby integral body.
Because the prepared product of the present invention is architectural prefab, can make the same period at the building course of building, promptly can adhesive after outside the building wall builds up cohere or hook hangs, saved the duration.
In sum, the present invention is a kind of preparation method of exterior wall thermal-insulation water-proof decoration plate.This preparation method is simple, and can bear the variation of round-the-clock temperature, has insulation, waterproof action and decorative effect; When prepared product was used for skin, construction was simple, and the duration is short.
Embodiment 1
One, the making of decorative layer
1, make mould; With the slate stone material is that mould turns over the system aluminum alloy mould, and aluminum alloy mould is the rectangular channel shape, and the groove inner bottom part is the slaty former, and the wall height is 70 millimeters.Have in the mould and can move up and down loam cake.
2, batching: is 100 parts with following each component with major ingredient unsaturated-resin 196, and each component is according to following weight ratio, and mixing becomes not polymeric polyester body;
Unsaturated-resin 196 100
Antimony oxide 5
Three (β-chloroethyl) phosphate 7
UV9 0.5
Contain 50% peroxidating, first and second copper solutions 2
The styrene solution 4 that contains 6% naphthoic acid cobalt
Green grey acrylic acid coloring agent is an amount of
3, moulding: at first coat releasing agent on mould, brush the above-mentioned not polymeric polyester of last layer body, about 0.5 millimeter of thickness after the primary solidification, does not soak into glass mat and to apply thereon behind the polymeric polyester body; Then, brush not polymeric polyester body of one deck again, apply layer of glass cloth and compacting, cover die cover and push down, normal pressure heating down is tabular decorative layer at 50 ℃ of temperature compacted unders, and thickness is 4mm, and skin is decorated with the slate texture of celadon.
Decorative layer is taken out, making it have decoration the outer of texture faces down, on production line, use conventional spray gun after fire-retardant Polyurethane expanding foam solution is sprayed at the back side of decorative panel equably, conveyer belt is sent decorative panel to foaming chamber, the polymerization of in limited space, foaming, and environment temperature is controlled at more than 10 ℃, setting time was controlled at 40 seconds, fire-retardant Polyurethane expanding foam solution polymerization forming; Become composite plate from the decorative layer of foaming chamber output, then dicing.
Fire-retardant Polyurethane expanding foam solution is according to being that 100 fens each component weight ratios are with the phosphorous PPG of major ingredient:
Phosphorous PPG (major ingredient) 100
Poly isocyanate 218
Ethylenediamine PPG 40
Triethylene diamine (33%) 8
Organo-aluminium tin 1.5
F-11 50
Organosilicon 4
Three (β-chloroethene is stupid) phosphate 30.
Embodiment 2
One, according to the preparation method of the decorative layer of embodiment 1, make decorative layer.
Two, composite heat-insulating layer on decorative layer
Open the mould loam cake of making decorative layer, on the back side of the tabular decorative layer of moulding, be coated with adhesive, in mould, pour into the fire retardant polystyrene expanding foam solution then, adjust loam cake height and tabular decorative layer distance and be 30 millimeters and fix after, foaming under 65-90 ℃ of temperature, foams and decorative layer are formed composite plate under adhesive and the effect of foaming expansive force.
The fire retardant polystyrene expanding foam solution is 100 minutes with the major ingredient polystyrene; Each component according to weight ratio is:
Polystyrene (major ingredient) 100
Butane 10
Water 160
Washing powder 5
UV-9 0.2
Tetrabromoethane 1.5
Cumyl peroxide 0.8
Antioxidant 264 0.5
Feed nitrogen pressure/MPa 0.3
Embodiment 3
One, according to the preparation method of the decorative layer of embodiment 1, make decorative layer.
Two, the back side of decorative layer is coated with adhesive, make it bonding with the EPS plate, constitute composite plate;
EPS is a polystyrene self-extinguishing type moulded foam plate, can be that U.S. building material Co., Ltd in sky, Shenyang or the rich peaceful foam in Nanjing Co., Ltd produce.
Claims (8)
1, a kind of preparation method of exterior wall thermal-insulation water-proof decoration plate is characterized in that:
One, the making of decorative layer
(1) makes mould;
The bottom surface of tabular die is provided with the decoration line;
(2) batching:
Is 100 parts with following each component with major ingredient unsaturated-resin 196, and the each component weight ratio is following ratio, and mixing becomes not polymeric polyester body;
Unsaturated-resin 196S 100
Fire retardant 2-75
Ultra-violet absorber 0.5-2
Initator 1-2
Promoter 2-6;
(3) moulding: after the polymeric polyester body does not soak into toning with glass mat, apply in mould, cover die cover, normal pressure heating down is tabular decorative layer at 30-100 ℃ of temperature compacted under;
Two, composite heat-insulating layer on decorative layer
The decoration texture of decorative layer is faced down, use conventional spray gun after fire-retardant Polyurethane expanding foam solution is sprayed at the back side of decorative panel equably, make decorative panel enter foaming chamber, the polymerization of in limited space, foaming, environment temperature is controlled at more than 10 ℃, setting time is controlled at 20-40 between second, and fire-retardant Polyurethane expanding foam solution polymerization forming is with dicing after decorative layer becomes composite plate;
Fire-retardant Polyurethane expanding foam solution is 100 parts with the phosphorous PPG of major ingredient, and each component according to weight ratio is:
Phosphorous PPG (major ingredient) 100
Poly isocyanate 218
Ethylenediamine PPG 30-40
Triethylene diamine (33%) 4-10
Catalyst 1-2
Blowing agent 40-50
Stabilizing agent 4-6
Fire retardant 30-40.
2, a kind of preparation method of exterior wall thermal-insulation water-proof decoration plate is characterized in that:
One, the making of decorative layer
(1) makes mould;
The bottom surface of tabular die is provided with the decoration line;
(2) batching:
Is 100 parts with following each component with major ingredient unsaturated-resin 196, and the each component weight ratio is following ratio, and mixing becomes not polymeric polyester body;
Unsaturated-resin 196S 100
Fire retardant 2-75
Ultra-violet absorber 0.5-2
Initator 1-2
Promoter 2-6;
(3) moulding: after the polymeric polyester body does not soak into toning with glass mat, apply in mould, cover die cover, normal pressure heating down is tabular decorative layer at 30-100 ℃ of temperature compacted under;
Two, composite heat-insulating layer on decorative layer
Decorative layer is after die for molding, directly the decorative layer back side in mould is coated with adhesive, in mould, pour into the fire retardant polystyrene expanding foam solution then, according to the thickness requirement of made heat-insulation layer adjust the loam cake height and fixing after, foaming under 65-90 ℃ of temperature becomes composite plate with decorative layer.
The fire retardant polystyrene expanding foam solution is 100 parts with the major ingredient polystyrene, and each component according to weight ratio is:
Polystyrene (major ingredient) 100
Water 160
Blowing agent 8-12
Dispersant 4-5
Fire retardant 2-3
Antioxidant 0.2-0.6
Feed nitrogen 0.3-0.5MPa.
3, a kind of preparation method of exterior wall thermal-insulation water-proof decoration plate is characterized in that:
One, the making of decorative layer
(1) makes mould;
The bottom surface of tabular die is provided with the decoration line;
(2) batching:
Is 100 parts with following each component with major ingredient unsaturated-resin 196, and the each component weight ratio is following ratio, and mixing becomes not polymeric polyester body;
Unsaturated-resin 196S 100
Fire retardant 2-75
Ultra-violet absorber 0.5-2
Initator 1-2
Promoter 2-6;
(3) moulding: after the polymeric polyester body does not soak into toning with glass mat, apply in mould, cover die cover, normal pressure heating down is tabular decorative layer at 30-100 ℃ of temperature compacted under;
Two, composite heat-insulating layer on decorative layer
The back side of decorative layer is coated with adhesive, makes it bonding, constitute composite plate with the EPS plate.
4, the preparation method according to the described exterior wall thermal-insulation water-proof decoration plate of claim 1 is characterized in that: in the batching of decorative layer, fire retardant is tri-chlorination two antimony or three (β-chloroethyl) phosphate or aluminium hydroxides; Ultra-violet absorber is UV-9 or UV-531; Initator is to contain 50% peroxidating, first and second copper solutions; Promoter being contains the styrene solution of 6% naphthoic acid cobalt.
5, the preparation method according to the described exterior wall thermal-insulation water-proof decoration plate of claim 2 is characterized in that: in the batching of decorative layer, fire retardant is tri-chlorination two antimony or three (β-chloroethyl) phosphate or aluminium hydroxides; Ultra-violet absorber is UV-9 or UV-531; Initator is to contain 50% peroxidating, first and second copper solutions; Promoter being contains the styrene solution of 6% naphthoic acid cobalt.
6, the preparation method according to the described exterior wall thermal-insulation water-proof decoration plate of claim 3 is characterized in that: in the batching of decorative layer, fire retardant is tri-chlorination two antimony or three (β-chloroethyl) phosphate or aluminium hydroxides; Ultra-violet absorber is UV-9 or UV-531; Initator is to contain 50% peroxidating, first and second copper solutions; Promoter being contains the styrene solution of 6% naphthoic acid cobalt.
7, the preparation method according to the described exterior wall thermal-insulation water-proof decoration plate of claim 1 is characterized in that: the catalyst in the fire-retardant Polyurethane expanding foam solution is an organo-aluminium tin; Blowing agent is a F-11; Stabilizing agent is an organosilicon; Fire retardant is barium metaborate or tetrabromobisphenol A or three (β-chloroethene is stupid) phosphate.
8, the preparation method according to the described exterior wall thermal-insulation water-proof decoration plate of claim 2 is characterized in that: the blowing agent in the fire retardant polystyrene expanding foam solution is a butane; Dispersant is a washing powder; Fire retardant is tetrabromoethane or cumyl peroxide; Antioxidant is antioxidant 264.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610014045A CN100586704C (en) | 2006-06-05 | 2006-06-05 | Method for manufacturing exterior wall thermal-insulation water-proof decoration plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200610014045A CN100586704C (en) | 2006-06-05 | 2006-06-05 | Method for manufacturing exterior wall thermal-insulation water-proof decoration plate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101085548A true CN101085548A (en) | 2007-12-12 |
| CN100586704C CN100586704C (en) | 2010-02-03 |
Family
ID=38936802
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200610014045A Expired - Fee Related CN100586704C (en) | 2006-06-05 | 2006-06-05 | Method for manufacturing exterior wall thermal-insulation water-proof decoration plate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100586704C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104029445A (en) * | 2014-06-24 | 2014-09-10 | 浙江杉盛模塑科技有限公司 | Smc product and preparation method thereof |
| CN108034188A (en) * | 2017-12-04 | 2018-05-15 | 安徽复材科技有限公司 | A kind of preparation method of mineral wool enhancing phenolic foam composite plate |
| CN110816014A (en) * | 2018-08-11 | 2020-02-21 | 陈军 | Continuous production equipment and method for thermosetting composite polyphenyl thermal insulation decorative plate |
-
2006
- 2006-06-05 CN CN200610014045A patent/CN100586704C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104029445A (en) * | 2014-06-24 | 2014-09-10 | 浙江杉盛模塑科技有限公司 | Smc product and preparation method thereof |
| CN104029445B (en) * | 2014-06-24 | 2016-03-09 | 浙江杉盛模塑科技有限公司 | SMC goods and preparation method thereof |
| CN108034188A (en) * | 2017-12-04 | 2018-05-15 | 安徽复材科技有限公司 | A kind of preparation method of mineral wool enhancing phenolic foam composite plate |
| CN110816014A (en) * | 2018-08-11 | 2020-02-21 | 陈军 | Continuous production equipment and method for thermosetting composite polyphenyl thermal insulation decorative plate |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100586704C (en) | 2010-02-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN204626840U (en) | Composite paint decorative lamination integration plate | |
| CN104631738B (en) | A kind of inorganic ornamental surface heat insulation decoration board and its continuous production method | |
| CN101823860B (en) | High-strength active powder fiber concrete slab and manufacturing method thereof | |
| CN104831888A (en) | Energy-saving thermal insulation and decoration integrated board with varnish panel and processing technology thereof | |
| CN100586704C (en) | Method for manufacturing exterior wall thermal-insulation water-proof decoration plate | |
| CN105418160A (en) | External wall heat insulating material | |
| CN101319541B (en) | Production method of polyurethane construction outer layer insulating brick | |
| CN104295035B (en) | A kind of hard foam polyurethane heat insulation decoration integrated board and preparation method thereof | |
| CN101275410A (en) | Weatherability polyurethane heat preserving combined board and method for producing the same | |
| CN103243880A (en) | Production method of integrated non-flammable heat-insulating sound-proof lightweight decorating building board | |
| CN101508545B (en) | Process for manufacturing decoration thin panel | |
| CN109296155A (en) | A kind of imitative page rock building heat preservation decorative panel and preparation method of stereoscopic effect | |
| CN206154809U (en) | Composite foamed intermediate layer heat preservation decorative board | |
| CN204645487U (en) | Energy-saving lacquer painting plate insulation and decoration integrated plate | |
| CN101077926B (en) | Polyurethane artificial stone and preparation method | |
| CN1594800A (en) | External wall composite heated board and production method thereof | |
| CN102806745A (en) | Production technology of waterproof and heat-insulated integrated board | |
| CN101392589B (en) | True mineral varnish composite sheet material and method for producing the same | |
| CN113999554B (en) | Preparation method of water-based inorganic nano-silica granite coating | |
| CN202990303U (en) | Non-combustible heat-insulation lightweight decorative integrated building board with air bubble interlayer | |
| CN100529291C (en) | Assembling wall body and producing method thereof | |
| CN101705725B (en) | Refractory integral board, manufacturing method thereof and refractory composite board | |
| CN105544755A (en) | Low-heat-conductivity A-grade non-ignitable sandwich insulation board and manufacturing method thereof | |
| CN2425158Y (en) | Multi-colour internal and external wall insulating decorative brick of polystyrene foam base material | |
| CN101168264A (en) | Method for manufacturing hard bubble polyurethane exterior wall thermal insulation decorative plate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100203 Termination date: 20120605 |