CN101077677A - Gravure rubber wheel directly transfer printing pattern metallic plate - Google Patents
Gravure rubber wheel directly transfer printing pattern metallic plate Download PDFInfo
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- CN101077677A CN101077677A CN 200610081047 CN200610081047A CN101077677A CN 101077677 A CN101077677 A CN 101077677A CN 200610081047 CN200610081047 CN 200610081047 CN 200610081047 A CN200610081047 A CN 200610081047A CN 101077677 A CN101077677 A CN 101077677A
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Abstract
The present invention is printed metal plate with intaglio offset transfer printed patterns and its making process. On the surface of coated steel sheet, patterns are first printed with ink fitting the surface coating of steel sheet and through intaglio offset printing, and high temperature cured paint or UV cured paint is then roller coated to the surface of the patterns. The printed metal plate has high decorating effect. Compared with available technology, the present invention has the advantages of environment friendship and low cost.
Description
Technical field
The invention belongs to the colour printed metallic plate field of usefulness such as household appliances shell, building internal and external ornament, particularly be fit to the steel plate and the manufacture method thereof of panel beatings such as various bendings, impact, stretching behind the indirect stamp of employing intaglio plate rubber roll.
Background technology
With the chromatic metallic plate of household appliances shell, building internal and external ornament, as outer case of refrigerator, refrigerator side plate, microwave oven shell, air conditioner casing, washing machine shell etc., adopt colored pre-coated steel plate and colored laminate steel in the market.
Colored pre-coated steel plate adopts following structure: base material, make by steel plates such as cold-reduced sheet, electrolytic galvanized sheet, heat zinc coating plate, aluminium plating zinc plates, and the chemical treatment layer is arranged on two face, the skin of chemical treatment layer has front coating protection layer and CB coating protective layer.This colored pre-coated steel plate does not have any pollution as household appliances shell to environment, but floral designs generally can not be printed in the surface, and is not high as the appliance shell class.And existing colored pre-coated steel plate surface is because production technology characteristic and face coat characteristics, no suitable printing technology realization decorative pattern/pattern effect behind the external coating, and existing coating and printing ink do not possess affinity.
Colored laminate steel adopts following structure: base material, by cold-reduced sheet, electrolytic galvanized sheet, heat zinc coating plate, steel plates such as aluminium plating zinc plate are made, the chemical treatment layer is arranged on two face, the outer application acrylic resin of positive chemical treatment layer, also have PETG and polyvinyl chloride composite membrane on it, various printing treatment are carried out to realize surface detail in this composite membrane PETG layer back side, can produce chlorine and dioxide gas but polyvinyl chloride layer is follow-up during as the garbage disposal fusion, environment is polluted, and because of its rapidoprint and technology more complicated, cost is very high.
Surface of steel plate is realized printing quality, can be undertaken by following dual mode usually:
Serigraphy: the steel plate to application carries out serigraphy, but because can only be to the single steel plate stamp, print speed printing speed is slow, can not satisfy the industrialized mass production requirement.
The transfer paper transfer printing: can be earlier the decorative pattern of printing appointment on surface-treated offset medium such as film, paper, under high temperature and high pressure, carry out transfer printing then, the decorative pattern of film or paper surface disappearance or thin out after the transfer printing, but this technology is owing to the waste of film after the transfer printing or paper, cost is still very high, becomes the resistance of popularization.
Below be the example of two transfer paper transfer printings:
CN00801213 discloses a kind of method of using gravure-transfer paper to make transfer-coated steel plate, be characterized in adopting specific transfer printing coating, form the intaglio plate transfer paper of anticipation decorative pattern, then with its hot pressing on the primer coating film layer, peel off the tape base of intaglio plate transfer paper, the coated heat hardening resin forms the facial ornament coating in the back, the described method of the document can fast speed be produced continuously, compare with former chromatic colour coated steel plate, can make the good transfer-coated steel plates of physical property such as processability, ultra-violet resistance, scratch-resistant, solvent resistance.
CN01135216 discloses a kind of personalized colorful steel plate manufacture method; color steel sheet is cut into the scale material; peel positive outermost diaphragm off; and with personalized pattern; photo; literal; after information such as symbol design in computer and handle; output and with printer prints on transfer printing paper or film; the one side and the outermost layer structure driving fit of colored steel front of printing ink will be printed on then on transfer printing paper or the film; effect by heat and pressure; originally the dye sublimation that was imprinted on transfer printing paper or the film is become gas phase; transfer in the colored steel front surface structure, and then paste strippable diaphragm on the colored steel surface.
In sum, prior art is applied to household electrical appliances and problem, especially the intaglio plate stamp that decorative pattern prints can't be realized in architectural decoration common color coated steel sheet surface, in view of this, and special proposition the present invention.
Summary of the invention
Another object of the present invention is to provide a kind of metallic plate of gravure rubber wheel transfer pattern.
The present invention can be achieved in the following manner; on the basis of above-mentioned colored pre-coated steel plate; surface tension and additive to existing front coating protection layer improve; certainly; the technical scheme that can realize purpose of the present invention in all prior aries all can be introduced into as of the present invention additional; and employing gravure rubber wheel transfer printing process; use the printing ink that mates with the surface of steel plate coating directly at coated steel sheet surface printing decorative pattern, the coating material solidified or UV photocureable coating protection in decorative pattern surface roller coating elevated temperature heat afterwards.
Particularly; the invention provides and using the linear oil-free polyester resin coating series of macromolecule to be coated with the technology that is contained on the steel plate on the metallic plate; with the heated-air drying baking oven formation primer coating that is heating and curing; use printing ink with surface of steel plate coating coupling directly at coated steel sheet surface printing decorative pattern then, afterwards in decorative pattern surface roller coating elevated temperature heat coating material solidified or UV photocureable coating to protect a series of continuous production processes be the method for the manufacturing stamp metallic plate of feature.
The method of manufacturing stamp metallic plate of the present invention is as follows:
Surface of steel plate cleaning → dry tack free → surface of steel plate chemical treatment → surface of steel plate baking → surface of steel plate primer coating (back-protective of back side coating simultaneously lacquer) → priming paint hot setting → surperficial stamp → surperficial Lacquer finish → surperficial pasting protective film
The substrate steel sheet that is used for stamp of the present invention, described substrate can be cold-rolled steel sheet, hot-dip galvanizing sheet steel, plated steel sheet, aluminum-zinc alloy steel plate and other class alloy-steel plate.
The chemical treatment layer of the substrate of described steel plate can be selected the chemical treatment of chromating, phosphatization or organic coating, and this type of technology is disclosed any in can prior art, and they are introduced into the present invention's technology as a setting.
Epoxy primer is the most classical priming paint type, has antiseptic property under the best film, and is strong with pretreatment layer and most of finish paint snap-in force; Polyamine fat and polyester priming paint are the novel priming paint of developing in recent years, and its corrosion resistance and epoxy primer are equally matched; In addition, water-based acrylic priming paint is another kind of novel priming paint, belongs to environmentally friendly machine.
In the present invention, described primer coating has three functions, and at first for guaranteeing the adhesive force between substrate surface and the printing inks, next provides base material good anti-corrosion and weather resistance, and the 3rd provides the function of printed layer basis color.
According to practical use and needs, primer coating can be selected singly to be coated with single baking or two and be coated with two bakings, and wherein two colors that are coated with two bakings can identical or complete difference.
Solidification temperature requirement the highest metallic plate temperature in baking oven of priming paint is 180-250 ℃ and heats 40-100 second that preferred temperature is about 224-249 ℃.
To primer base,, require primer coating film that enough pliabilitys and extensibility must be arranged for guaranteeing follow-up stamp metallic plate processing forming.
Common intaglio plate stamp is to use electronic engraving or laser engraving mode to be engraved on the decorative pattern engraving metallograph roller of appointment floral designs; During production, the air drying type printing ink of specific composition is filled in the decorative pattern of engraving.
But because steel plate belongs to hard material, the metallograph roller can not directly directly contact with the stock steel plate, therefore must use rubber tire to shift the printing ink on intaglio plate version roller surface as intermediate.
For guaranteeing the clear of printing floral designs, in the rotary printing process, should constantly in the decorative pattern of metallograph roller engraving, add fresh printing ink, while is thoroughly cleaned rubber tire before each printing, rubber tire surface ink decorative pattern was clear, even when the assurance rubber tire contacted with the steel plate that was coated with priming paint.
For guaranteeing to specify the effect of decorative pattern, can select printing of the same colour, dichromatism printing or polychrome printing technology as required, can increase the volatilization that infrared lamp promotes solvent in the printing ink behind the printing unit.
Decorative pattern finish printing and drying after, selects suitable varnish or gloss oil to face cap light, to reach requirements such as lustrous surface that printed steel plate designs, case hardness, surperficial aquatic foods degree of reflecting, surperficial pliability, surperficial chemical proofing.
In the present invention, the optional elevated temperature heat cured varnish of selecting of surperficial Lacquer finish, surface state can be Gao Guang, inferior light, half light or dodge pearl effect, generally requires solidification temperature to heat 40-100 second for the highest metallic plate temperature for 180-250 ℃; For pursuing better aquatic foods degree of reflecting, can select the UV gloss oil in addition, but should be specifically noted that UV gloss oil itself buckling performance, impact resistance and with the matching of coating, printing ink, avoid in the following process process, occurring gloss oil and ftracture, come off etc. bad.
After finishing surperficial Lacquer finish, for avoid scratching in subsequent transportation, the process, scratch defect, generally paste transparent protective film on the surface.Also can not paste diaphragm according to actual conditions.
Above technology all can realize continuous coating, stamp, Lacquer finish and paste transparent protective film at coil or single steel plate.
Can be used for organic overlay film of the present invention comprises: polyethylene film (PE), vinyl overlay film (PVC), fluoro resin overlay film (PVF), Kynoar (PVDF), polyester-based overlay film (PET), allyl resin overlay film (PMMA) etc., wherein PE, PET film are most widely used general.
The printed steel plate that utilizes described technology to obtain, its architectural feature is as follows:
| (6) transparent protective film (30-80um) |
| (5) face cap photosphere (high temperature varnish 2-20um; UV gloss oil 4-100um) |
| (4) printed layer |
| (3) primer coating (may for two-layer) 4-30um |
| (2) chemical treatment layer＜1um |
| (1) steel plate (cold-reduced sheet, galvanized sheet, aluminium sheet etc.) 0.2-1.5mm |
| (2) chemical treatment layer＜1um |
| (7) back-protective layer (3-16um) |
Advantage of the present invention is as follows
1. printed steel plate of the present invention and colored pre-coated steel plate of the prior art relatively make it have better decorative effect, have promoted product specification; Compare with original colored laminate steel; when having realized floral designs of the same race, the PVC material of having forgone, more favourable to environmental protection; and reduced use as pet film and polyvinyl chloride film chemical raw material, reduced product cost.
2. the product narrated of the present invention not only has the intensity and the processing characteristics of metal material itself, also because a series of application stamps that carry out on the surface, improve corrosion resistance, chemical proofing (as acid, alkali and organic solvent), the anti-fouling performance of steel plate, can satisfy machine-shaping requirement and the protective action of using material as appliance shell, building internal and external ornament.
Description of drawings
Below be description of drawings of the present invention,, and, can be expressly understood the present invention more in conjunction with following embodiment by description of drawings, concrete:
Fig. 1 is the schematic diagram of stamp mode embodiment one of the present invention;
Fig. 2 is the schematic diagram of stamp mode embodiment two of the present invention;
In Figure of description of the present invention, each parts mark and component names corresponding relation are as follows: intaglio plate version roller 1, scraper 2, printing rubber roll 3, backing roll 4, planar support transport tape 5, printing inks storage tank 6, steel plate 7, sink 8, cleaning roller 9;
The specific embodiment
In the present embodiment, what adopt is that the printing technology process is as follows, one intaglio plate version roller 1, described intaglio plate version roller 1 is immersed in the printing inks storage tank 6 constantly to apply printing ink, intaglio plate version roller 1 usefulness scraper 2 behind the dipping printing ink strikes off unnecessary printing ink, printing ink decorative pattern on the intaglio plate version roller 1 has been transferred on the surface of printing rubber roll 3, and the printing rubber roll 3 printing ink decorative pattern that it is surperficial has been imprinted on the steel plate 7, and the another side of steel plate is provided with a backing roll 4.
In the present embodiment, what adopt is that the printing technology process is as follows, one intaglio plate version roller 1, described intaglio plate version roller 1 is immersed in the printing inks storage tank 6 constantly to apply printing ink, intaglio plate version roller 1 usefulness scraper 2 behind the dipping printing ink strikes off unnecessary printing ink, printing ink decorative pattern on the intaglio plate version roller 1 has been transferred on the surface of printing rubber roll 3, the printing rubber roll 3 printing ink decorative pattern that it is surperficial has been imprinted on the steel plate 7, being supported on the planar support transport tape 5 of steel plate 7, opposite side at printing rubber roll 3, a cleaning roller 9 is set, and described cleaning roller 9 has been immersed in the sink 8, and constantly is cleaned.Another scraper 2 is set on printing rubber roll 3.
In the steel plate stamp process of the present invention,, can increase a cleaning roller in the printing rubber roll position if run into the unintelligible problem of ink printing lines.
Studies show that in the printing method, the hardness of transfer roll is in the 20-60Shore scope in scheme of the present invention; If the employing cleaning roller, then the hardness of cleaning roller is hard more good more.
Usually, the printing ink in the intaglio plate version roller 1 has only 40-50% can be transferred to printing rubber roll 3 surfaces, and along with the growth of time, ratio of printing ink transfer can be reduced to 20%.
In addition, the steel surface roughness that is printed is big more, can select softer printing rubber roll 3; General steel plate is selected 60 degree; Transfer roll is soft excessively, can cause pattern deformation, and roller itself is subject to solvent infiltration damage; The surface tension difference of printing ink and coating is little, helps the infiltration of surperficial varnish.
Present embodiment is printing ink specific targets and use technology in the printing method of specification of the present invention.
| Formula material | Former fluid viscosity Cha Shi 5# | Ratio |
| Resin M edium | 45.8 | 3 parts |
| Tusche | 16.8 | 1 part |
After described resin and printing ink mix with following ratio, that is, resin M edium: tusche=3: 1, the viscosity of their mixture under the 5# cup is 18 seconds.
With printing ink and solvent that described resin and tusche are configured to, their ratio is printing ink: solvent=100/20,40,60,80,100, and the viscosity of ink solutions is as follows behind the solvent dilution of measuring under such condition:
| 20 | 40 | 60 | 80 | 100 | |
| Viscosity | 17.22 | 13.48 | 12 | 10.8 | 10.25 |
By research, researcher's direction of the present invention, preferred solvent burden ratio, employing be common type solvent: the ratio of slow curing solvent=1: 1.
Under the condition of proportioning, preferred printing condition is as follows at described printing ink of the present invention:
(1) baking temperature: 180 degree;
(2) SP value (surface tension) is more than 13;
(3) to the continuous application printing technology speed of coil of strip can reach 15-40 rice/minute, to the printing technology speed of single steel plate can reach 5-20 rice/minute.
Experimental example one
This experimental example is the experimental example that utilizes the steel plate of above-mentioned stamp to carry out panel beating, and concrete test index is as follows:
| Pilot project | Performance indications | Test method | The result | Standard | |
| Glossiness | Standard gloss ± 10% | 60 ° of vancometers | Excellent | GB/T13448 | |
| T is curved | Nothing is peeled off, flawless | 180°/OT | Excellent | GB/T13448 | |
| Cupping | Nothing is peeled off, | Draw | 5 | Excellent | GB/T13448 |
| Impact | No rete separates | 9J impacts | Excellent | GB/T13448 | |
| Pencil hardness | ≥H | The broken hardness of plough | Excellent |
Claims (9)
1. the metallic plate of a gravure rubber wheel transfer pattern, it is characterized in that the surface can realize specifying the floral designs effect, adopt steel plate as base material, the chemical treatment layer is arranged on two face, there is primer coating outside at positive chemical treatment layer, in the outside of front primer coating printed layer is arranged, and in the outside of printed layer finish coat is arranged, wherein, curved, the cupping of T, impact index are as follows:
Test method Pilot project Performance indications The result
180°/OT T is curved Nothing is peeled off, flawless Excellent
Draw 5 road 5*5mm grids, cupping feeding 8mm on the model Cupping Nothing is peeled off, flawless Excellent
9J impacts Impact No rete separates Excellent
2. metallic plate according to claim 1 is characterized in that the glossiness of described metallic plate, pencil hardness are as follows:
Test method Pilot project Performance indications The result
60 ° of vancometers Glossiness Standard gloss ± 10% Excellent
The broken hardness of plough Pencil hardness ≥H Excellent
3. metallic plate according to claim 1 is characterized in that also comprising a transparent protective film in the described metallic plate that its thickness is about 30-80um.
4. metallic plate according to claim 1 is characterized in that described face cap photosphere, and its thickness is about 2-20um when adopting high temperature varnish, is about 4-100um when adopting the UV gloss oil; The thickness of printed layer is about 6-20um, and the thickness of primer coating is about 4-30um; The thickness of chemical treatment layer is less than 1um, and the thickness of steel plate is about 0.2-1.5mm, and the thickness of back-protective layer is about 3-16um.
5. according to claim 1 or 3 described metallic plates, it is characterized in that said base material can be selected from following base material a kind of, cold-reduced sheet, heat zinc coating plate, electrolytic galvanized sheet, zinc-iron alloy plate, aluminium alloy plate etc.
6. metallic plate according to claim 1 is characterized in that described printed layer is a gravure rubber wheel transfer printing printed layer.
7. metallic plate according to claim 1 is characterized in that described metallic plate is provided with the chemical treatment layer of phosphatization and/or chromate sealing.
8. metallic plate according to claim 1 is characterized in that described described prime coat is Polyurethane prime coat, epoxy primer layer, polyester prime coat or water-based acrylic prime coat.
9. metallic plate according to claim 2; it is following a kind of to it is characterized in that described diaphragm can be selected from, polyethylene film (PE), vinyl film (PVC), fluoro resin film (PVF), Kynoar (PVDF), polyester-based overlay film (PET), allyl resin film (PMMA).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610081047 CN101077677A (en) | 2006-05-23 | 2006-05-23 | Gravure rubber wheel directly transfer printing pattern metallic plate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610081047 CN101077677A (en) | 2006-05-23 | 2006-05-23 | Gravure rubber wheel directly transfer printing pattern metallic plate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101077677A true CN101077677A (en) | 2007-11-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610081047 Pending CN101077677A (en) | 2006-05-23 | 2006-05-23 | Gravure rubber wheel directly transfer printing pattern metallic plate |
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| CN102485480A (en) * | 2010-12-01 | 2012-06-06 | 海尔集团公司 | Color coating line film covering machine set and method for processing polyester film color plate through using color coating line film covering machine set |
| CN101817267B (en) * | 2009-12-11 | 2012-06-13 | 宇龙计算机通信科技(深圳)有限公司 | Printing method and device for overlapping printing ink on different bottom colors |
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| CN105730119A (en) * | 2016-05-05 | 2016-07-06 | 谢汝木 | Transfer-printing metal plate having three-dimensional textures and manufacture method thereof |
| CN106121162A (en) * | 2016-08-19 | 2016-11-16 | 墙煌新材料股份有限公司 | A kind of metal finish heat insulation decoration integrated plate and processing method thereof and application |
| CN106626613A (en) * | 2016-12-23 | 2017-05-10 | 青岛海尔特种钢板研制开发有限公司 | Precoated metal plate and manufacturing method thereof |
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| CN111873572A (en) * | 2020-08-21 | 2020-11-03 | 苏州兴禾源复合材料有限公司 | Heat transfer printing color coating steel plate and production process |
| CN113600461A (en) * | 2021-08-05 | 2021-11-05 | 深圳华美金属材料科技有限公司 | Novel 3D color-coated sheet and preparation method thereof |
| CN114258419A (en) * | 2019-09-25 | 2022-03-29 | 巴斯夫涂料有限公司 | Method for making structured articles using removable protective layer and structured articles resulting therefrom |
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| CN101817267B (en) * | 2009-12-11 | 2012-06-13 | 宇龙计算机通信科技(深圳)有限公司 | Printing method and device for overlapping printing ink on different bottom colors |
| CN102485480A (en) * | 2010-12-01 | 2012-06-06 | 海尔集团公司 | Color coating line film covering machine set and method for processing polyester film color plate through using color coating line film covering machine set |
| CN102485480B (en) * | 2010-12-01 | 2015-02-25 | 海尔集团公司 | Color coating line film covering machine set and method for processing polyester film color plate |
| CN103253018A (en) * | 2013-05-21 | 2013-08-21 | 辽宁超烁图码科技板业有限公司 | Production method of printing metal plate and printing metal plate produced through production method |
| CN103253018B (en) * | 2013-05-21 | 2016-01-20 | 辽宁超烁图码科技板业有限公司 | The stamp metallic plate that the production method of stamp metallic plate and employing the method are produced |
| CN104608514A (en) * | 2013-11-01 | 2015-05-13 | 联想(北京)有限公司 | Printing method |
| CN104527249A (en) * | 2014-11-21 | 2015-04-22 | 杭州中粮包装有限公司 | Partial pearly luster mixing metal printing method |
| CN105599388A (en) * | 2014-11-25 | 2016-05-25 | 合肥海尔特种钢板研制开发有限公司 | Wire drawing type printed color steel plate for household electrical appliances and production method thereof |
| CN105730119A (en) * | 2016-05-05 | 2016-07-06 | 谢汝木 | Transfer-printing metal plate having three-dimensional textures and manufacture method thereof |
| CN106121162A (en) * | 2016-08-19 | 2016-11-16 | 墙煌新材料股份有限公司 | A kind of metal finish heat insulation decoration integrated plate and processing method thereof and application |
| CN106121162B (en) * | 2016-08-19 | 2018-11-27 | 墙煌新材料股份有限公司 | A kind of metal finish heat insulation decoration integrated plate |
| CN106626613A (en) * | 2016-12-23 | 2017-05-10 | 青岛海尔特种钢板研制开发有限公司 | Precoated metal plate and manufacturing method thereof |
| CN110077707A (en) * | 2019-04-30 | 2019-08-02 | 深圳市启航金品科技有限公司 | A kind of aluminium alloy packing box and its production technology |
| CN114258419A (en) * | 2019-09-25 | 2022-03-29 | 巴斯夫涂料有限公司 | Method for making structured articles using removable protective layer and structured articles resulting therefrom |
| CN111873572A (en) * | 2020-08-21 | 2020-11-03 | 苏州兴禾源复合材料有限公司 | Heat transfer printing color coating steel plate and production process |
| CN113600461A (en) * | 2021-08-05 | 2021-11-05 | 深圳华美金属材料科技有限公司 | Novel 3D color-coated sheet and preparation method thereof |
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