CN101077586A - Blanking device for optical film and blanking method for optical film - Google Patents

Blanking device for optical film and blanking method for optical film Download PDF

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Publication number
CN101077586A
CN101077586A CNA2007101079754A CN200710107975A CN101077586A CN 101077586 A CN101077586 A CN 101077586A CN A2007101079754 A CNA2007101079754 A CN A2007101079754A CN 200710107975 A CN200710107975 A CN 200710107975A CN 101077586 A CN101077586 A CN 101077586A
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CN
China
Prior art keywords
stamping
pad
blooming piece
blanking
polarizing
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CNA2007101079754A
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Chinese (zh)
Inventor
金子铁夫
大谷彰
重松崇之
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Nitto Denko Corp
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Nitto Denko Corp
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Publication of CN101077586A publication Critical patent/CN101077586A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B26HAND CUTTING TOOLS; CUTTING; SEVERING
    • B26FPERFORATING; PUNCHING; CUTTING-OUT; STAMPING-OUT; SEVERING BY MEANS OTHER THAN CUTTING
    • B26F1/00Perforating; Punching; Cutting-out; Stamping-out; Apparatus therefor
    • B26F1/38Cutting-out; Stamping-out
    • B26F1/40Cutting-out; Stamping-out using a press, e.g. of the ram type
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B26HAND CUTTING TOOLS; CUTTING; SEVERING
    • B26DCUTTING; DETAILS COMMON TO MACHINES FOR PERFORATING, PUNCHING, CUTTING-OUT, STAMPING-OUT OR SEVERING
    • B26D7/00Details of apparatus for cutting, cutting-out, stamping-out, punching, perforating, or severing by means other than cutting
    • B26D7/18Means for removing cut-out material or waste
    • B26D7/1845Means for removing cut-out material or waste by non mechanical means

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  • Life Sciences & Earth Sciences (AREA)
  • Forests & Forestry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Perforating, Stamping-Out Or Severing By Means Other Than Cutting (AREA)
  • Laminated Bodies (AREA)
  • Details Of Cutting Devices (AREA)
  • Polarising Elements (AREA)

Abstract

The invention provides a blanking apparatus of optical membrane and blanking method of optical membrane. The said blanking apparatus can prevent the dust adhere to the optical membrane by suppressing generating statical electricity on blanking optical membrane. The blanking apparatus of optical membrane comprises mat and blanking cutter for loading optical membrane to blank the optical membrane loaded on the mat, wherein the surface opposite to the blanking cutter contact surface on the said mat is performed conduction treatment.

Description

The blanking apparatus of blooming piece and the blanking method of blooming piece
Technical field
Thereby the present invention relates to a kind of being used for becomes the required size of product requirement, blanking apparatus that shape forms blooming and the blanking method of blooming piece with blooming piece stamping-outs such as for example polarizing diaphragms.
Background technology
Generally speaking, the lip-deep blooming piece that is installed on display etc. is (a for example polarizing coating) by using the required size of blooming piece stamping-out (cut-out) one-tenth that the stamping-out cutter will rectangular blooming piece or rectangle to make.For example in the blanking apparatus of following patent documentation 1 record, the upright stamping-out cutter of establishing is pressed to blooming piece with pressing plate in the side from it across blooming piece on pedestal, the blooming piece stamping-out is become the blooming piece of required size between stamping-out cutter and pressing plate.
, static takes place in blooming piece usually easily when it is carried out stamping-out, and blooming is charged easily.In addition, when blooming piece is carried out stamping-out, produce dust.Therefore, the dust that produces in the stamping-out process is attached to blooming by electrostatic interaction, and the quality of blooming is descended.
Therefore, in above-mentioned blanking apparatus in the past, it is big that the surface roughness of the contact-making surface by making pressing plate becomes, and reduces the contact area with blooming piece as much as possible, and static takes place when suppressing stamping-out thus.
[patent documentation 1] TOHKEMY 2002-58405 communique
Yet, when the surface roughness of the contact-making surface that as above-mentioned blanking apparatus in the past, increases pressing plate, be easy to generate dust on the contrary, can not prevent effectively that dust from adhering to.
Summary of the invention
Therefore, thus the object of the present invention is to provide and a kind ofly can prevent that dust is attached to the blanking apparatus of blooming and the blanking method of blooming piece by suppressing that static takes place when the stamping-out blooming piece.
The inventor has carried out conscientious research in order to achieve the above object, found that, by in blooming piece the face that enters the face opposition side of a side with the stamping-out cutter being carried out conductive processing, thereby can reduce generation static, has finished the present invention thus.
That is, the blanking apparatus of blooming piece of the present invention can contact the pad and the stamping-out cutter that are provided for the mounting blooming piece relatively with leaving, and the blooming piece of mounting on pad carried out stamping-out; It is characterized in that the face at above-mentioned pad place to the face opposition side that contacts with the stamping-out cutter carries out conductive processing.
In the blanking apparatus of above-mentioned formation, the face at the pad place to the face opposition side that contacts with the stamping-out cutter carries out conductive processing, thereby prevent to be accompanied by the stamping-out action static takes place, so, even, can prevent that also this dust is attached to blooming along with the stamping-out action produces dust.
At this, blooming piece is meant the sheet of blooming stamping-out one-tenth as the stage before the needed size of commodity, the shape, comprises rectangular sheet, this two conception of species of monolithic type.
Usually, for rectangular sheet, send blooming piece towards the place ahead successively, and meanwhile carry out stamping-out continuously with the stamping-out cutter, thus form blooming; For the blooming piece of monolithic type, the stamping-out blooming piece forms blooming one by one mostly.
The blanking apparatus of blooming piece of the present invention is characterised in that the face at this pad place with the contact of stamping-out cutter forms even surface.Constitute according to this, the situation that forms matsurface with the face that the stamping-out cutter is contacted is compared, and the generation of dust is suppressed.
The blanking method of blooming piece of the present invention is that the blooming piece mounting is carried out stamping-out on pad; It is characterized in that, use the pad that the face of the face opposition side that contacts with the stamping-out cutter has been carried out conductive processing, the relative contact with the stamping-out cutter of above-mentioned pad is left.
By using the pad that the face of the face opposition side that contacts with the stamping-out cutter has been carried out conductive processing, the blooming piece mounting is carried out stamping-out on this pad, thereby can prevent static, therefore along with stamping-out action generation, even, can prevent that also this dust is attached to blooming along with the stamping-out action produces dust.
The blanking method of blooming piece of the present invention is characterised in that, uses the pad that the face of stamping-out cutter contact is formed even surface.
According to this method, compare as the situation of the pad of matsurface with the face that uses the stamping-out cutter to contact, can suppress the generating capacity of dust.
The blanking method of blooming piece of the present invention is characterised in that, blooming piece is formed spool body, pulls out blooming piece from this spool body, with its mounting in the pad on.
In said method, blooming piece is formed spool body, when when spool body is pulled out blooming piece, become the state of easy generation stripping charge, but because padding of mounting blooming piece executed conductive processing, when with the blooming piece mounting when pad is gone up, remove stripping charge, so, even, can prevent that also this dust is attached to blooming along with the stamping-out action of blooming piece produces dust.
Blanking apparatus according to blooming piece of the present invention, by the face to the face opposition side that contacts with the stamping-out cutter carries out conductive processing at the pad place, thereby can prevent to take place when blooming piece from being cut off by the stamping-out cutter static, so, can prevent that blooming is charged, therefore, even along with the stamping-out action produces dust, can prevent effectively that also this dust is attached to blooming, can easily make high-quality blooming.
Blanking method according to blooming piece of the present invention, by using the pad of the face of the face opposition side that contacts with the stamping-out cutter having been implemented conductive processing, thereby can prevent to take place when blooming piece from being cut off by the stamping-out cutter static, so, can prevent that blooming is charged, therefore, even along with the stamping-out action produces dust, can prevent effectively that also this dust is attached to blooming, can easily make high-quality blooming.
Description of drawings
Fig. 1 is the whole skeleton diagram that constitutes of blanking apparatus that embodiment of the present invention is shown.
Fig. 2 is the general profile chart that leaves position and stamping-out position that this stamping-out knife system is shown.
Fig. 3 is the cutaway view that pad is shown.
Fig. 4 is the amplification view that the stacked formation of this polarizing diaphragm is shown.
Fig. 5 is the amplification view of stacked formation that the blooming piece of another embodiment is shown.
The specific embodiment
Below, be example explanation embodiments of the present invention with reference to the accompanying drawings with the blanking apparatus, blooming piece is the polarisation of light diaphragm of only transmission certain vibration direction.Fig. 1 is the skeleton diagram that the integral body formation of blanking apparatus is shown, and Fig. 2 is the general profile chart that leaves position and stamping-out position that this stamping-out knife system is shown, and Fig. 3 is the cutaway view that pad is shown, and Fig. 4 and Fig. 5 are the amplification view that the stacked formation of this polarizing diaphragm is shown.
The polarizing diaphragm of handling in embodiment of the present invention 2 has as triacetyl cellulose (TAC) film high transparent, high-durability of diaphragm 20,21 clamps the structure of polyvinyl alcohol (PVA) film, and this polyvinyl alcohol (PVA) film is the polarizing coating 18 (as the polarizing coating of core component) that has adsorbed iodo-complexes or dichroic dye.
In addition, at the stacked little bond layer 22 of face side of the diaphragm 20 of upside, at the stacked protecting film 23 of the face side of this little bond layer 22.In addition, at the surperficial stacked thicker bond layer 24 of the diaphragm 21 of downside, at the surperficial stacked diffusion barrier 25 of this bond layer 24 than little bond layer 22.
Polarizing diaphragm 2 can consider that also laminated phase-difference film 30 as shown in Figure 5 forms it into the situation of blooming piece 2.In this case, phase retardation film 30 is laminated to the downside of bond layer 24, by another bond layer 31 diffusion barrier 25 is laminated to this bond layer 31 again.Such polarizing coating 4 uses pasting display behind bond layer 24 peel separation films 25.
In situation shown in Figure 1, illustrate such example, promptly, in advance polarizing diaphragm 2 is formed duplexer, be wound into spool body 2A then, but also can be respectively the multiple film etc. that constitutes polarizing diaphragm 2 be formed spool body, pull it successively, use after forming duplexer.The situation that the duplexer that forms polarizing diaphragm 2 is also arranged.Polarizing diaphragm 2 forms and pad 5 cardinal principle same widths described later.
Below, the blanking apparatus 1 of polarizing diaphragm 2 is described.Blanking apparatus 1 with polarizing diaphragm 2 mountings under the state on the above-mentioned pad 5, use stamping-out knife system 7 that its stamping-out is become as needed size of commodity and shape, thereby form polarizing coating 4.In this embodiment, it is the situation of drum that rectangular polarizing diaphragm is rolled into that polarizing diaphragm 2 is shown, but is not limited thereto, for example also applicable to the polarizing diaphragm 2 that uses single sheet, by these polarizing diaphragm 2 stamping-out polarizing coatings 4.
As shown in Figure 1, blanking apparatus 1 has not shown drive unit, and the stamping-out knife system 7 that two ends is wound up into above-mentioned pad 5, the roller 3,3 of the ring type of roller 3,3.Two rollers 3,3 use metal to make in order to have except that the electric work energy.Perhaps, also can consider by conductive processing is implemented on its surface, thereby it is had except that the electric work energy.
Such as shown in Figures 2 and 3, pad 6 is for being a charged plastic sheet that prevents that layer from constituting by the base material 10 of upside (face side of mounting polarizing diaphragm 2) with by the conductive processing layer 11 that apply or evaporation etc. is located at base material 10 lower surfaces.Base material 10 as pad 6 for example preferably uses polystyrene (PS), PETG (PET), polypropylene (PP).As the thickness t 1 of base material 10, for example be set at 500~600 μ m.As the thickness t 1 of conductive processing layer 11, as for can bring into play the charged thickness that prevents function, then the thickness t 1 of also comparable base material 10 is thin.As the roughness of the top 10a of base material 10, promptly surface roughness (JIS B version in 0,601 1994) is preferably Ra:0.01~0.6 μ m (then better as being 0.02~0.1 μ m), Rz:0.1~2 μ m (then better as being 0.2~1 μ m).Ra represents center line average roughness, and Rz represents 10 mean roughness.That is, the surface roughness of base material 10 is compared the value of the even surface that is dead smooth with the surface roughness of former base material 10.
As the material that constitutes conductive processing layer 11, for example can list by metal or indium tin oxides such as aluminium, the evaporation of tin-oxide, the conducting film that sputter obtains, contain from tin, antimony, at least a metal ingredient of selecting in the indium and the alcohol colloidal sol of silicon charged prevents to use the film constituent, by from tin, antimony, the water dispersible colloidal sol of at least a conductive metal oxide of selecting in the indium and water silica sol constitute chargedly prevents to use the film constituent, the hydrolytie polycondensation thing of metal alkoxide, the conjugated system electroconductive polymer, the charged preventor of polymer electrolyte, the materials such as interfacial agent of low molecule-type.
In these charged materials that prevent usefulness, particularly the charged preventor of conjugated system electroconductive polymer, polymer electrolyte can easily form the high conductive processing layer 11 of durability at base material 10 by following method, so, can obtain preferably using.As the concrete example of conjugation electroconductive polymer, preferably use polyaniline, polythiophene, polypyrrole, p-phenylene vinylene or their replacement.They can be coated onto by the electroconductive polymer that will be dissolved in the solubility in the solvent on the base material and to form conductive processing layer 11, or by the directly polymerization and form conductive processing layer 11 on base material 10 of monomer and oxidant.
Concrete example as the charged preventor of polymer electrolyte, preferably use PEO, polyether ester amides, polyetheramides acid imide, oxirane epihalohydrins copolymer, methoxy poly (ethylene glycol) (methyl) acrylate copolymer of nonionic system, (methyl) acrylates copolymer that contains quaternary ammonium group of cation system, contain quaternary ammonium group maleimide copolymer, contain the metering system imide copolymer of quaternary ammonium group, the kayexalate of anion system, the carbonyl betaine-graft copolymer of both sexes class etc.They can be coated onto on the base material after being dissolved into appropriate solvent, or also can with suitable mixed with polymers after carry out melt extruded and form film, be adhered to base material film then.
Above-mentioned stamping-out knife system 7 has supporting station 15, be fixed in the stamping-out cutter of the bottom surface of this supporting station 15 (being also referred to as the Thomsons cutter) but 16, and the not shown up-down drive device that movably supporting station supported of easy on and off.Stamping-out knife system 7 is configured to stamping-out cutter 16 in the reference position position that upper surface (mounting surface) 6a with respect to pad 6 leaves towards the top.Stamping-out cutter 16 forms the shape of the shape that can according to circumstances polarizing diaphragm 2 stamping-outs be become desired.For example, in the situation of this embodiment, forming when observing from the bottom surface is rectangle.
Being configured to of stamping-out cutter 16 supported its supporting station 15 by above-mentioned up-down drive device leaving between position X and the stamping-out position Y, in this X position, the tip-shape point of a knife 17 of stamping-out cutter 16 leaves with respect to the upper surface 6a of pad 6, and this stamping-out position Y makes point of a knife 17 be contacted with the position of pad 6 (entering into the base material 10 of pad 6 in fact slightly) for leave position X decline from this.
Below, illustrate that the stamping-out position 1 of using above-mentioned formation is with the order of polarizing diaphragm 2 stamping-outs one-tenth as needed area of commodity and shape (cutting off the ground stamping-out).Pad 6 synchronously moves towards upstream side C2 from downstream C1 with the driving of roller 3,3, after the upset, from upstream side C2 towards downstream side C1 move, carry out such action repeatedly.Pad 6 upload offset vibrating diaphragm sheet 2 and make its protecting film 23 be in above (diffusion barrier 25 be in below), use is from the suitable mechanisms such as clamping device of width both sides, itself and pad 6 are become one, thereby make pad 6 and polarizing diaphragm 2 synchronously move to downstream C2 from upstream side C1.At this moment, in stamping-out knife system 7, leaving position X, polarizing diaphragm 2 can be inserted between stamping-out cutter 16 and the pad 6.
Polarizing diaphragm 2 one arrive stamping-out knife systems 7 under, then temporarily stop to fill up the driving of 6 drive division, the drive division of the cut-off knife device 7 that liquidates drives, and stamping-out knife system 7 is descended from leaving position X.Like this, the point of a knife 17 of stamping-out cutter 16 enters into polarizing diaphragm 2 from protecting film 23 sides.When stamping-out knife system 7 was further descended, as shown in Figure 4, the point of a knife 17 of stamping-out cutter 16 became the stamping-out position Y that enters into pad 6 slightly.By making stamping-out knife system 7 drop to stamping-out position Y like this, thereby by stamping-out cutter 16 mounting is cut off and stamping-out cutter 16 corresponding area and shapes in the polarizing diaphragm 2 of pad 6, stamping-out becomes polarizing coating 4.Polarizing diaphragm 2 behind the stamping-out batches it at downstream C2, or directly discarded etc., be subjected to suitable processing.
After as described above polarizing diaphragm 2 stamping-outs being become polarizing coating 4, drive the drive division of stamping-out knife system 7 once more, stamping-out knife system 7 is risen, arrive and leave position X.By the intermitten of each such drive division stamping-out polarizing diaphragm 2 successively, thereby make polarizing coating 4 successively.Then, the polarizing coating 4 of stamping-out can for example be piled up and take care of.
In the manufacture process of polarizing coating 4, when stamping-out cutter 16 enters into the synthetic resin layer of polarizing diaphragm 2, easily by the charged state of both friction generation polarizing diaphragms 2, but owing on pad 6, conductive processing layer 11 is located at the lower surface of the base material 10 of upside, so, prevent that by this conductive processing layer 11 polarizing coating 4 is charged.On the other hand, when polarizing diaphragm 2 being carried out stamping-out when it is cut off, mainly produce the dust of synthetic resin from the base material 10 of section, pad 6, but as described above, on pad 6, conductive processing layer 11 is located at the lower surface of the base material 10 of upside, is prevented adhering to of dust, so, dust is not adhered to the polarizing coating 4 of manufacturing, therefore, can make high-quality polarization film 4.
Particularly when stamping-out polarizing coating 4, as the point of a knife 17 of stamping-out cutter 16 become from fill up 6 above 6a enter into the stamping-out position Y of base material 10, from base material 10 dust takes place then easily, but sliding situation flattens on the surface that will fill up 6 base material 10 as described above, even the point of a knife 17 of stamping-out cutter 16 enters into base material 10, compare with the situation of the thicker prior art of the surface roughness of base material 10, its dust generation is also lower.That is, and compared in the past, and can reduce the generation of dust, and can prevent that polarizing coating 4 is charged, so, reduce the generation of dust before comparable, and prevent that by conductive processing layer 11 polarizing coating 4 is charged, so, can prevent positively that dust is attached to polarizing coating 4.
In addition, in this embodiment, make the roller 3,3 of pad 6 of reeling with metal, and it is applied the charged function that prevents, or apply the charged function that prevents on the surface, and, be conductive processing layer 11 with pad 6 sides that are wound up into roller 3,3, the conductive processing layer 11 of pad 6 contacts often with roller 3,3, correspondingly improve the electric energy power of removing, so, can positively prevent adhering to of dust, make high-quality polarization film 4.
, when making polarizing coating 4,, can think that the contact-making surface at pad 6 and polarizing diaphragm 2 also produces small position skew even actuator pad 6 as described above makes the polarizing diaphragm 2 same moved further of mounting in upper surface 6a.In other words, the state of the lower surface 2a friction of the top 6a of the pad 6 of generation driving side and the polarizing diaphragm 2 of slave end, become polarizing diaphragm 2 easy charged states, but owing to be provided with the conductive processing layer 11 that is used to prevent that polarizing coating 4 is charged at pad 6, so, can prevent to fill up the charged of 6 polarizing diaphragms 2 that bring with the position skew of polarizing diaphragm 2, therefore, even as described above in the contact-making surface generation position skew of pad 6 with polarizing diaphragm 2, also can similarly prevent adhering to of dust, obtain high-quality polarization film 4.
In addition, though usually when the state that when roller 2A pulls out polarizing diaphragm 2, becomes easy generation stripping charge, but owing to be provided with conductive processing layer 11 at pad 6, so, as with polarizing diaphragm 2 mountings in the pad 6 on, then stripping charge is removed, this point also can prevent adhering to of dust, so, can make high-quality polarization film 4.In addition, as described above, polarizing diaphragm 2 is not limited to be pre-formed and is drum, and a plurality of films that also will constitute polarizing diaphragm 2 sometimes form independently spool body respectively, on one side mounting is on pad 5 described later, one side forms the duplexer of polarizing diaphragm 2.Yet, even at the state that when each spool body is pulled out film, produces stripping charge,, removing electricity by the conductive processing layer 11 that fills up 6 as overlapped film on pad 6, the result can make high-quality polarization film 4.
Because the surface roughness of the base material 10 of pad 6 forms even surface, so, when the point of a knife 17 of stamping-out cutter 16 from fill up 6 above 6a enter into base material 10 and when forming polarizing coating 4, can prevent effectively that air from entering into 25 of bond layer 24 and diffusion barriers, therefore, light leak can be prevented effectively, high-quality polarization film 4 can be made.
Polarizing diaphragm 2 is from stacking gradually protecting film 23, little bond layer 22, diaphragm 20, polarizing coating 18, diaphragm 21, bond layer 24, reaching diffusion barrier 25.When making stamping-out cutter 16 enter into such polarizing diaphragm 2 from downside, the slurry that then forms bond layer 24 is attached to stamping-out cutter 16, is difficult to obtain smooth section.Yet in this embodiment, making stamping-out cutter 16 is that protecting film 23 sides enter into polarizing diaphragm 2 from the top of polarizing diaphragm 2, cuts off polarizing diaphragm 2 by little bond layer 22.This little bond layer 22 is littler than the thickness of bond layer 24, and bonding force is little, so, compare from the situation that bond layer 24 sides enter with stamping-out cutter 16, can entirely carry out the cut-out (section is smooth) of polarizing diaphragm 2.
Pad 6 becomes annular, the position change at random that the point of a knife 17 of stamping-out cutter 16 enters when stamping-out polarizing coating 4, so, need not change it at a circle of pad 6, use repeatedly serially.Yet, if use pad 6 repeatedly, make the point of a knife of stamping-out cutter 16 enter into same position for more than 17 time or near its part, this part fragilityization becomes and can not successfully carry out the stamping-out of polarizing coating 4, so, preferably fill up 6 every the scheduled time or predetermined winding number replacing.
The invention is not restricted to above-mentioned embodiment.For example in the above-described embodiment, polarizing coating 4 is for carrying out the situation of stamping-out from polarizing diaphragm 2 each 1 row ground, but be not limited thereto, also can use the polarizing coating 4 wideer corresponding to pad 6 width than the polarizing diaphragm 2 of above-mentioned embodiment, or reduce the external diameter of stamping-out cutter 16, side by side from polarizing diaphragm 2 stamping-out multiple row polarizing coatings 4.
In such situation, it is many that the quantity of the polarizing coating 4 of stamping-out becomes, can think that the amount of dust also correspondingly becomes many, but in embodiments of the present invention, because the face at the pad 6 places pair face opposition side that contacts with stamping-out cutter 16 has carried out conductive processing, so, even the quantitative change of dust is many, can prevent effectively that also its dust is attached to polarizing coating 4, obtain high-quality polarization film 4.
In the blanking apparatus 1 of above-mentioned embodiment, pad 6 is an annular, with polarizing diaphragm 2 mountings thereon, but is not limited thereto.For example also can be used as blanking apparatus, the endless-belt that be wound in roller 3,3 of pad outside 6 is set, rectangular pad 6 is supplied with and carried out mounting to this endless-belt, to pad 6, use 7 pairs of polarizing diaphragms of stamping-out knife system 2 to carry out stamping-out polarizing diaphragm 2 mountings.In such blanking apparatus,, thereby can prevent that dust is attached to polarizing coating 4, can make high-quality polarization film 4 by use and the same pad 6 of above-mentioned embodiment.
Embodiment 1~embodiment 4 is shown here.As the electric evaluation method of removing that illustrates in these embodiments, use sheet resistance value sheet resistance analyzer (the Hiresta MCP-HT450 of Mitsubishi Chemical's (system)) to press sheet resistance value Ω/ (unit: the every side of ohm) of applied voltage 500V mensuration conductive processing layer 11.
Embodiment 1
(situation that the organic solvent soluble polyaniline is used for the polypropylene screen of conductive processing layer 11)
Have agitating device, thermometer, and the separable flask of 101 (10 liters) capacity of straight connector in add distilled water 6000g, 36% hydrochloric acid 360ml, and aniline 400g (4.295 moles) successively, make the aniline dissolving.In addition, on one side with frozen water cooling, 97% concentrated sulfuric acid 434g (4.295 moles) is joined among the distilled water 1493g in the beaker on one side and mix the modulation aqueous sulfuric acid.This aqueous sulfuric acid is joined in the above-mentioned separable flask, flask integral body is cooled to-4 ℃ with low temperature thermostat bath.
Then, in beaker, ammonium peroxydisulfate 980g (4.295 moles) is joined distilled water 2293g and make its dissolving, the modulation aqueous oxidizing agent solution.In low temperature thermostat bath, flask integral body is cooled off, the temperature of reactant mixture is remained on below-3 ℃, simultaneously, under agitation use the ratio of pipe pump from straight connector divides above-mentioned peroxy-disulfuric acid aqueous ammonium in 1ml/ below to drip at leisure the acidic aqueous solution of aniline salt.At first, water white solution is along with the carrying out of polymerization, becomes blackish greenly from verdigris color, then, separates out cyan powder.Temperature in the reaction system is adjusted to below 0 ℃.Like this, need 7 hours, finish the dripping of peroxy-disulfuric acid aqueous ammonium after, continue to stir 1 hour in the temperature below-3 ℃.
Filter the polymer powder that sorting obtains, wash, acetone cleans, and at room temperature carries out vacuum drying, obtains cyan polymer powder 430g.With its press molding is the disk of diameter 13mm, thick 700 μ m, and (van derPauw) measures its electrical conductivity by the vanderburg method, learns to be 14S/cm.
In addition, the electric conductivity organic polymer powder 350g of above-mentioned interpolation is added in the 2N ammoniacal liquor 41, presses rotating speed 5000rpm with automatic homomixer and stirred 5 hours.Mixture is from the blackish green bluish violet that becomes.
By Buchner filter powder is filtered sorting, in beaker, stir on one side, with distilled water repeatedly clean on one side, become neutrality up to filtrate, then, clean with acetone, become colourless up to filtrate.
After this, at room temperature powder is carried out 10 hours vacuum drying, obtain pitchy impurity elimination polymer powder 280g.The polyaniline that obtains is dissolved into N-methyl-2-pyrroles, modulates the solution of 0.5 weight %.Then, mix these solution 100 weight portions, 200 parts of malonic acid, reach 900 parts of isopropyl alcohols, obtain coating liquid.
This coating liquid is coated to the single face of the polypropylene screen of thick 500 μ m, in 80 ℃ air drier dry 2 minutes, forms the conductive processing layer 11 of thick 0.07 μ m.
The sheet resistance of the film that obtains is 7 * 10 7Ω/.With the Ra of the surface roughness of the face of conductive processing layer 11 opposition side of polypropylene screen be 0.063 μ m, Rz is 0.275 μ m.
Embodiment 2
(situation that the mixture of organic solvent soluble polyaniline and adhesive polymer is used for the PETG film of conductive processing layer 11)
200 parts of polyaniline 100 weight portions, the malonic acid that modulation is obtained by embodiment 1, wire saturated polyester resin " バ イ ロ Application RV-290 " N-methyl-2-pyrroles's solution 100 parts, 1.0 weight % of Toyo Boseki K.K's system and make coating liquid.
This coating liquid is coated to the single face of the PETG film of thick 480 μ m, in 80 ℃ air drier dry 2 minutes, forms the conductive processing layer 11 of thick 0.1 μ m.
The sheet resistance of the film that obtains is 9 * 10 7Ω/.With the Ra of the surface roughness of the face of conductive processing layer 11 opposition side of PETG film be 0.067 μ m, Rz is 0.351 μ m.
Embodiment 3
(situation that will gather 3, the 4-dioxy thiophene is used for the polypropylene screen of conductive processing layer 11)
With 3,100 parts of 4-dioxy thiophenes and p-toluenesulfonic acid iron aqueous isopropanols 500 parts, 5 weight % are coated to the single face of the polypropylene screen of thick 500 μ m, at room temperature place.Carry out polymerisation and on base material, form film.With flowing water it is cleaned, after the drying, form the conductive processing layer 11 of thick 0.05 μ m.
The sheet resistance of the film that obtains is 3 * 10 8Ω/.With surface roughness and embodiment 1, the embodiment 2 of the face of conductive processing layer 11 opposition side of polypropylene screen similarly be the surface roughness of non-conductive treated side.
Embodiment 4
(situation that will gather 3, the 4-dioxy thiophene is used for the PETG film of conductive processing layer 11)
(50/50: mixed solvent dilution polythiophene weight ratio) is conducting polymer (Na ガ セ ケ system テ Star Network corporate system, a trade name: デ Na ト ロ Application P502RG), modulate the coating liquid of 1.0 weight % to water/isopropyl alcohol.
This coating liquid is coated to the single face of the PETG film of thick 480 μ m, in 80 ℃ air drier dry 2 minutes, forms the conductive processing layer 11 of thick 0.03 μ m.
The sheet resistance of the film that obtains is 7 * 10 7Ω/.PETG and the Ra of surface roughness of face of conductive processing layer 11 opposition side be 0.06 μ m, Rz is 0.30 μ m.
Can obtain to remove electric effect fully by conductive processing layer 11 shown in these embodiment 1~embodiment 4, can eliminate dust adhering on polarizing coating 4 substantially along with the stamping-out operation generation of polarizing coating 4.In addition, by conductive processing layer 11 being formed the surface roughness shown in these embodiment 1~embodiment 4, thereby can make the amount of dust of the synthetic resin that when stamping-out cutter 16 enters into pad 6, takes place, obtain high-quality polarization film 4 than reducing significantly in the past.

Claims (5)

1. the blanking apparatus of a blooming piece can relatively freely contact the pad and the stamping-out cutter that are provided for the mounting blooming piece with leaving, and the blooming piece of mounting on pad carried out stamping-out; It is characterized in that the face at above-mentioned pad place to the face opposition side that contacts with the stamping-out cutter has been implemented conductive processing.
2. the blanking apparatus of blooming piece according to claim 1 is characterized in that, the face that contacts at pad place stamping-out cutter is an even surface.
3. the blanking method of a blooming piece carries out stamping-out with the blooming piece mounting on pad; It is characterized in that, use the pad of the face of the face opposition side that contacts with the stamping-out cutter having been implemented conductive processing, the relative contact with the stamping-out cutter of above-mentioned pad is left.
4. the blanking method of blooming piece according to claim 3 is characterized in that, uses the pad of the face of stamping-out cutter contact as even surface.
5. according to the blanking method of claim 3 or 4 described blooming pieces, it is characterized in that blooming piece is a spool body, pulls out blooming piece from this spool body, with its mounting in the pad on.
CNA2007101079754A 2006-05-22 2007-05-22 Blanking device for optical film and blanking method for optical film Pending CN101077586A (en)

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JP2006141757A JP2007307683A (en) 2006-05-22 2006-05-22 Punching device of optical film sheet and punching method of optical film sheet

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JP2007307683A (en) 2007-11-29
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