CN101036623A - One-pack type hair dye utilizing optical energy - Google Patents
One-pack type hair dye utilizing optical energy Download PDFInfo
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- CN101036623A CN101036623A CNA2007100883584A CN200710088358A CN101036623A CN 101036623 A CN101036623 A CN 101036623A CN A2007100883584 A CNA2007100883584 A CN A2007100883584A CN 200710088358 A CN200710088358 A CN 200710088358A CN 101036623 A CN101036623 A CN 101036623A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G18/00—Cultivation of mushrooms
- A01G18/60—Cultivation rooms; Equipment therefor
- A01G18/64—Cultivation containers; Lids therefor
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G18/00—Cultivation of mushrooms
- A01G18/60—Cultivation rooms; Equipment therefor
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Abstract
The invention provides a single-component hair dye using light energy, the hair dye would not damage skin and hair, and is comparative stable. The hair dye is prepared by adding silver salts of 0.3%-5.0% by weight (wherein silver halide is not contained) and amino acid of 0.2%-5.0% by weight (wherein reducible amino acid such as cysteine or the like, and sulfur-containing amino acid such as acimetion or the like are not contained). The amino acid preferably is neutral amino acid, acidic amino acid, basic amino acid (wherein reducible amino acid such as sulfur-containing amino acid and cysteine or the like is not contained). Especially preferable amino acid is basic amino acid such as arginine, histidine, lysine, or the like. PH of the preparation can be adjusted to 2-8. Further, 0.01%-1.5% dihydroxyacetone by weight can be added in the hair dye, and the PH of the preparation is adjusted to 2-7.
Description
Technical field
The present invention relates to a kind of stable one-pack type hair dye that utilizes luminous energy, this hair dye is injured skin and hair not.
Background technology
Being used for that hair is carried out painted goods has as the hair dye of quasi drug (quasi-drugs) with as the hair dye of cosmetics.
Oxide hair dye and non-oxide hair dye are arranged in the hair dye.
Oxide hair dye is the hair dye of insoluble chromatopexis in hair that oxidation dye is infiltrated in hair and will generate by oxidation polymerization.
Non-oxide hair dye is to make the polyphenol of oxidation dye infiltration in hair and the hair dye of iron ion generation black pigment.
These hair dyes are called as permanent hair dye because the color retention time is grown (2 months～3 months).
But, for these permanent hair dyes, because will be through oxidation dye is infiltrated chemical treatment in hair or chemical reaction thereafter, thereby have the shortcoming that produces hair damages or scytitis.
On the other hand, acid hair dye and chromotrichia material are arranged in the hair dye.
Acid hair dye is based on the protein of hair and the incompatible hair dye of having hair dyed of ionic bond of acid stain, because the color retention time lacks (2 week～3 week), is called as semipermanent hair dye.
The chromotrichia material is based on the hair dye that dyestuff-pigment was had hair dyed to adhering to of hair surface, for temporarily painted, adopt just flush away simply of shampoo, thereby is called as temporary transient hair dye.
The special collection of [non-patent literature 1] FRAGRANCE JOURNAL 2001-8 " function of hair dye-hair dye and nearest exploitation trend " the 11st page～15 pages
In addition, acid stain is arranged not only in the hair dye, use the hair dye of silver salt in the past in addition.
The hair dye of described use silver salt is to use the 1st liquid that contains sodium sulfide solution and contains the hair dye of the 2nd liquid of silver nitrate aqueous solution; Or use contains the 1st liquid of Potassium monosulfide. alcoholic solution and the hair dye of the 2nd liquid that contains silver nitrate aqueous solution etc.
In use, dip in last the 1st liquid wetting hair, be coated with the 2nd liquid with other brush then, then hair is dyed black with brush.This is that Argentous sulfide. owing to black is attached on the keratin of hair surface and produces.
When so dyeing, on hair, be attached with stench (hydrogen sulfide) such as putrid egg.Though this stench can easily be removed by washing, obviously this is not preferred.
[non-patent literature 2] open country is always write doctor's nationality shop, " revising and enlarging six editions perfumeries " room, half field and is published big positive in January, 4
Clear and in May, 3 publication " face-beautifying method in modern age " the 292nd page～297 pages in [non-patent literature 3] メ イ Ox Mountain work ten thousand Li Ge studies
For the above-mentioned improvement method of the hair dye of silver salt of having used various motions have been proposed.
For example, have motion to propose a kind of hair dye, it contains A agent and B agent; Described A agent is made of the aqueous solution that contains diamidogen silver coordination salt and/or ethanolamine silver coordination salt; Described B agent is made of the aqueous solution that contains dyestuff intermediates such as p-phenylenediamine (PPD).
[patent documentation 1] spy opens flat 04-312514 communique
Also have motion to propose to contain the hair dye of various gradation compositions such as silver halide, developer in addition as the gradation composition of the preparation of having hair dyed.As the mode of preparation, there are double-formulation or one-pack type.In described various medicaments, can enumerate reducing substances as developer, wherein example goes out aminoacid such as glycine.
[patent documentation 2] spy opens flat 04-187625 communique
On the other hand, as the hair dye that utilizes luminous energy, proposed to contain silver nitrate and/or actol and contained the paste of wetting agents such as alcohol, propylene glycol such as surfactant, hexadecanol such as polyoxyethylene stearyl base ether or aqueous one-pack type hair dye.
[patent documentation 3] spy opens the 2002-348221 communique
Also have motion to propose following one-pack type hair dye in addition: in liquid paraffin, to use surfactants such as polyoxyethylene stearyl base ether, in water-soluble compositions such as propylene glycol, methyl parahydroxybenzoate, purified water, carry out emulsifying, further mixing boric acid, Cera Flava are made emulsion, add any one the aqueous solution in the coordination ion of actol, silver nitrate, Argentous fluoride, silver therein, make the one-pack type hair dye of emulsion.
This hair dye is coated on the hair, be exposed in common living environment under the daylight, place hair washing after 1 day, hair is in the state that is coloured to the copper brown.Then, even hair washing every day after 20 days, does not find that the hair-dyeing state changes yet.
[patent documentation 4] spy opens the 2004-99502 communique
In addition, in order to form the artificial black that shines on people's skin, have motion to propose following artificial tanned compositions, it contains: (a) dihydroxy acetone; (b) be selected from aminoacid or its salt in the group of forming by alanine, valine, leucine, isoleucine, proline, methionine, phenylalanine, tryptophan, glycine, serine, threonine, cysteine, tyrosine, agedoite, glutamine, lysine, arginine, histidine and above-mentioned amino acid whose mixture; (c) topical carrier, the pH of said composition is below 4, its color rendering properties is improved.
Above-mentioned dihydroxy acetone is by form the artificial material that shines black on people's skin with the containing that nitrogen protein reacts of skin.
But this artificial tanned compositions does not react with the keratin of hair, thereby can not dye to hair.
The flat 9-510971 communique of [patent documentation 5] special table
Summary of the invention
The present commercially available hair dye that utilizes luminous energy has substantially coloring hairs is reddish slightly tawny trend.
Be under the situation of purpose so that poliosis is dyeed, fashionable colors are to appear as the color of self-colored dark brown to greyish black system, thereby commercially available product can fully realize this purpose hardly.
In addition and since the single tinting strength, tinting power of commercially available product a little less than, must recoat repeatedly, so for the user, have the more trouble of access times.
The object of the present invention is to provide a kind of improved one-pack type hair dye that utilizes luminous energy of shortcoming that makes above-mentioned prior art.
The present invention is topmost to be characterised in that, the described one-pack type hair dye that utilizes luminous energy can improve hair dyeing power by add aminoacid at silver salt (wherein not comprising silver halide) in the hair dye cream base, and the combination of kind that can be by aminoacid (wherein not comprising sulfur-containing amino acid such as reproducibility aminoacid such as cysteine and methionine) and cooperation ratio makes the color harmony form and aspect have to a certain degree scope.
Especially, the invention is characterized in, in the described hair dye, by combination silver salt (wherein not comprising silver halide) and basic amino acid, can suppress reddish slightly color in the past, can be the color of purple to tea purple or dark brown colour system with coloring hairs.
Further, the invention is characterized in, be added with a spot of dihydroxy acetone in the described hair dye.
In addition, the invention is characterized in that being combined with in the described hair dye with methyl sulfate ion or ethyl sulfate ion is that the cationic surface active agent of counter ion is as employed surfactant in the hair dye cream base.
The one-pack type hair dye that utilizes luminous energy of the present invention does not produce scytitis, can not damage hair.And, preparation stabilization.
In addition, because it is an one-pack type hair dye, thereby operation easily.Further, this hair dye has following advantage: after it is coated hair, need only through periods of direct sunlight more than 30 minutes, silver salt just is attached on the hair securely, the color retention time is grown (2 months～3 months), even compare also not inferior with permanent hair dye.
And, can be to be suitable for dying the color of the dark brown of poliosis with coloring hairs to greyish black colour system.Further, by adding a spot of dihydroxy acetone, can be with the face tone dark of hair dyeing.
In addition, when in the hair dye cream base, cooperating specific cationic surface active agent, can further improve stability of formulation.
The specific embodiment
Silver salt (wherein not comprising silver halide) by cooperating 0.3 weight %～5.0 weight % in the hair dye cream base and 0.2%～5.0% aminoacid (wherein not comprising sulfur-containing amino acid such as reproducibility aminoacid such as cysteine and methionine) can obtain to utilize the one-pack type hair dye of luminous energy.
As above-mentioned silver salt (wherein not comprising silver halide), be preferably silver nitrate, silver sulfate, actol.
As above-mentioned aminoacid, can use neutral amino acids such as Beta-alanine, hydroxy phenylalanine, 4-aminobutyric acid, DL-aminobutyric acid, tyrosine, hydroxyproline; Acidic amino acid such as glutamic acid, aspartic acid; Basic amino acids such as arginine, histidine, lysine further can use sulfamic acids such as taurine.
In these aminoacid, be preferably basic amino acids such as arginine, histidine, lysine especially.
In these preparations, pH is adjusted into 2～8.
Further, in above-mentioned prescription, cooperate 0.01%～1.5% dihydroxy acetone (hereinafter referred is DHA), the pH of preparation is adjusted into 2～7, make the one-pack type hair dye that utilizes luminous energy.
The pH of above-mentioned preparation can adjust arbitrarily, when still not being illustrated in the following embodiments, adjusts with the aqueous solution of citric acid or sodium hydroxide.
In addition, the known additive that can make an addition in the hair dye can be arbitrarily, only otherwise the infringement stability of formulation gets final product.For example can enumerate, as 50% sodium lactate of the composition of preserving moisture, as disodium edetate of stabilizing agent etc.
The characteristics of above-mentioned hair dye cream base are as described below.
General hair conditioner (hair conditioner) or hair care agent hairs such as (hair rinse) be with in the goods, uses stearyl trimethyl ammonium chloride, INCROQUAT TMC-80 ECONOL TM22 etc. to have the cationic surface active agent of chain alkyl chain in a large number and make its characteristic obtain performance.
In the commercially available hair dye cream that utilizes luminous energy, also can cooperate above-mentioned cationic surface active agent on a small quantity.
In common suppurative mastitis (hair cream), cooperate the above-mentioned cationic surface active agent below 1% to have no to hinder, by in suppurative mastitis, cooperating these cationic surface active agents and combined with higher alcohols, can reduce oil-phase component, provide bed knife (セ Star ト カ) excellent can stickness goods.
But the one-pack type hair dye that utilizes luminous energy for using silver salt might have problems when utilizing this prescription.
This be because, the silver salt in the hair dye cream base prescription produces silver chloride with chloride ion reaction as the counter ion of cationic surface active agent.
To its sensitivity of auroral poles, thereby silver salt moves to hair lentamente from suppurative mastitis as the sensitive material that is used to take a picture in this reaction, before the fixing colour developing of reduction, cream mutually in by fast restore, separate out as black particles with forms such as silver or silver oxide.
Therefore, dye blackly though show hair in appearance, because these black particles can be washed off and residue in hardly on the hair by shampoo, thereby it is not suitable in the one-pack type hair dye cream base.
Therefore, when being the cationic surface active agent of counter ion, in order not reduce the dyeing capacity of hair dye, use level is subjected to remarkable restriction to cooperation alkyl trimethyl chloride-based cationic surface active agent etc. with chloride ion (further with the halogen ion).
When utilizing the use level so be restricted, might can not bring into play performance fully aspect the flexibility of hair or the bed knife.
The black particles of silver is separated out phenomenon and is not only occurred when using alkyl trimethyl ammonium chloride cationoid type surfactant, also extensively occurs when the halogen ion exists.
Further, in the time of in employed silver salt is soluble in water, this phenomenon produces quickly.
In addition, the material of generally knowing as Reducing agent is unsuitable for being engaged in the one-pack type hair dye that utilizes luminous energy that uses silver salt.
This be because, if in preparation, the powerful reducing substances that silver salt and ascorbic acid, sulphite, cysteine etc. contain sulfur reduction aminoacid etc. coexists, then silver salt moment is reduced and separates out the silver-colored microgranule of black, thereby its hair dyeing ability is significantly reduced.
If with silver salt coexistence be the more weak reducing substances of reducing power, the degree that changes according to its use level, preservation state is different and difference, but As time goes on the state of preparation also can change.
So, owing to As time goes on hair dyeing power reduce, even thereby be the week reduction material, preferably it is not matched with in the one-pack type hair dye cream base that utilizes luminous energy that uses silver salt yet.
Further, when the one-pack type hair dye that will be combined with sulfur-containing amino acid such as methionine is coated on the hair, can produce the uncomfortable stink of sulfur class, bring sense of discomfort to user.
And the hair dye that is combined with sulfur-containing amino acid not only can not generate Argentous sulfide. on hair, and does not find that it has the effect-effect that coloring hairs one-tenth is arrived grey colour system as the brown of the object of the invention.
Employed surfactant is preferably the senior alcohol ether of polyoxyethylene and/or is the cationic surface active agent of counter ion with methyl sulfate ion or ethyl sulfate ion in the one-pack type hair dye cream base that the present invention relates to.
As the senior alcohol ether of polyoxyethylene, can enumerate, polyoxyethylene (5,5) cetyl ether (hereinafter referred is POE (5, a 5) cetyl ether), polyoxyethylene (20) cetyl ether (hereinafter referred is POE (a 20) cetyl ether), polyoxyethylene (20) docosyl ether (hereinafter referred is POE (a 20) docosyl ether) etc.
As being the cationic surface active agent of counter ion with methyl sulfate ion or ethyl sulfate ion, can enumerate ethyl sulfuric acid lanoline fatty amide propyl ethyl Dimethyl Ammonium (hereinafter referred is the lanolin derivative quaternary ammonium salt), methylsulfuric acid lanoline fatty amide propyl trimethyl ammonium, ethyl sulfuric acid docosyl ethyl Dimethyl Ammonium, methylsulfuric acid docosyl trimethyl ammonium etc.
Particularly these are the cationic surface active agent of counter ion with ethyl sulfate ion, methyl sulfate ion, can the effect of tetchiness ground in the presence of silver salt to light yet, can give full play to as the effect that utilizes the one-pack type hair dye of luminous energy.
And, by cooperating above-mentioned specific cationic surface active agent, can further improve stability of formulation.
Being suitable for the ethyl sulfuric acid lanoline fatty amide propyl ethyl Dimethyl Ammonium (hereinafter referred is the lanolin derivative quaternary ammonium salt) as above-mentioned cationic surface active agent, is the quaternary ammonium salt of being made by following formula by lanoline fatty amide propyl dimethyl amine and diethyl sulphuric acid.
In the following formula, R is a lanoline fatty amide propyl residue.
[embodiment 1]
Among the embodiment 1, use following hair dye cream base A.
[hair dye cream base A]
Ring-type silicone 6.7 weight %
Methylphenylsilanone. 8.3 weight %
Simmondsia oil (jojoba oil) 1.7 weight %
Hexadecanol 6.8 weight %
Lipophile glycerol monostearate 0.8 weight %
POE (5,5) cetyl ether 1.1 weight %
POE (20) cetyl ether 1.1 weight %
Make 100 weight % with purified water.
This hair dye cream base A is softish milky paste.
In the preparation of 1 example of embodiment, use above-mentioned hair dye cream base A, cooperate silver nitrate, cooperate histidine as aminoacid as silver salt.The unit of the use level of each composition is gram (g).
| Prescription | No.1 | No.2 | No.3 |
| Cream base A silver nitrate histidine DHA pH | 70.0 1.5 1.0 3.6 | 70.0 1.5 3.4 | 70.0 1.5 0.4 3.6 |
Make 100g with purified water.
[stability of formulation test]
Stability test is to judge through the state after 1 week under 45 ℃ the load temperature.
[dye test of topknot]
The topknot of 1 commercially available bundle 1g is used in dye test, and this topknot is to be used to have hair dyed the white Crinis Carbonisatus (pieces room system) of test.The unguentum of the hair dye that utilizes luminous energy of 1 about 0.5g of coating on this topknot sees through southern side glass pane irradiation daylight 1 time, irradiation time 2 hours under the fine sun.In addition, under about 60cm of room fluorescent lights, placed 6 hours for 1 time on the 1st.
Then, use the shampoo thorough washing, after the rinsing, dry topknot.
Repeat this operation 3 times.
The initial color of above-mentioned prescription No.1 preparation is white, and is As time goes on not painted, is stable.Its result in the topknot dye test: the color of topknot is dark brown.
Prescription No.2 preparation is for mismatching amino acid whose comparative example, and the initial color of preparation is shallow dark brown, As time goes on is coloured to dark brownly a little, is unsettled.Its result in dye test: the color of topknot is the black tea color, hair dyeing power a little less than.
Prescription No.3 preparation is similarly comparative example, though the initial color of preparation is a white, As time goes on grizzle is unsettled.Its result in dye test: the color of topknot is have darker redness dark brown, hair dyeing power a little less than.
[embodiment 2]
In the preparation of 2 examples of embodiment, use above-mentioned hair dye cream base A, cooperate silver nitrate, cooperate hydroxyproline as aminoacid as silver salt.
| Prescription | No.4(g) |
| Cream base A silver nitrate hydroxyproline DHA | 70.0 1.5 1.0 |
PH is adjusted into 4.0, makes 100g with purified water.
The initial color of above-mentioned prescription No.4 preparation is a white, and As time goes on invariant color is stable.Its result in dye test: the color of topknot is the black tea color that has darker redness, is bright-coloured tone.
[embodiment 3]
In the preparation of 3 examples of embodiment, use above-mentioned hair dye cream base A, cooperate silver sulfate as silver salt, and the aminoacid that is cooperated changes to some extent.The unit of the use level of each composition is gram (g).
| Prescription | No.5 | No.6 |
| The cream base A silver sulfate aminoacid DHA composition of preserving moisture: 50% sodium lactate pH | 70.0 1.5 histidine 1.0 0.4 10.0 4.5 | 70.0 1.5 arginine, 0.4 glutamic acid 0.4 0.2 3.9 |
Make 100g with purified water.
The initial color of above-mentioned prescription No.5 preparation is white, As time goes on grizzle a little.Its result in dye test: the color of topknot is dark brown.
The initial color of above-mentioned prescription No.6 preparation is a white, As time goes on becomes atomic pink.Its result in dye test: the color of topknot is the black tea color that has darker redness, is bright-coloured tone.
[embodiment 4]
In the preparation of the comparative example of 4 examples of embodiment, use above-mentioned hair dye cream base A, change silver salt and aminoacid, and further be combined with the stearyl trimethyl ammonium chloride.The unit of the use level of each composition is gram (g).
| Prescription | No.7 | No.8 |
| Cream base A silver salt aminoacid stearyl trimethyl ammonium chloride DHA pH | 70.0 silver nitrate 1.0 histidine 1.0 0.5 0.4 5.6 | 70.0 Silver monobromide 0.8 glutamic acid 1.0 3.2 |
Make 100g with purified water.
The preparation of above-mentioned prescription No.7 is the comparative example that has cooperated stearyl trimethyl ammonium chloride (it is to have the cationic surface active agent of chloride ion as counter ion), and is though the initial color of preparation is white, As time goes on significantly painted.Its result in dye test: hair dyeing power significantly reduces.
The preparation of above-mentioned prescription No.8 is the comparative example that has cooperated the silver salt with bromide ion, and the initial color of preparation is a white, As time goes on complete no change.Its result in dye test:, and also do not have painted to hair even be subjected to the sun exposure unguentum also not have variable color fully.
[embodiment 5]
Use following hair dye cream base B among the embodiment 5.
[hair dye cream base B]
Ring-type silicone 1.5g
Squalane (squalan) 1.0g
Simmondsia oil 1.2g
Hexadecanol 4.0g
Lipophile glycerol monostearate 0.4g
POE (5,5) cetyl ether 0.6g
POE (20) docosyl ether 0.6g
Lanolin derivative quaternary ammonium salt (50% solution) 0.8g
Make 70g with purified water.
This hair dye cream base B is the milky paste of a little higher than above-mentioned hair dye cream base A of viscoelasticity.
In the preparation of 5 examples of embodiment, use above-mentioned hair dye cream base B, cooperate silver nitrate, cooperate histidine as aminoacid as silver salt.The unit of the use level of each composition is gram (g).
| Prescription | No.9 | No.10 | No.11 | No.12 |
| Cream base B silver nitrate histidine DHA pH | 70.0 1.5 1.0 3.5 | 70.0 1.5 3.8 | 70.0 3.0 1.0 0.54 3.2 | 70.0 3.0 1.0 0.54 7.2 |
Make 100g with purified water.
The initial color of the preparation of above-mentioned prescription No.9 is extremely shallow dark brown, As time goes on is changed to shallow dark brown.Its result in dye test: the color of topknot is dark dark brown.
The preparation of prescription No.10 is not for cooperating amino acid whose comparative example, and its initial color be white, still grizzle As time goes on.Its result in dye test: the color of topknot is have darker redness dark brown, hair dyeing power a little less than.
The initial color of the preparation of above-mentioned prescription No.11 is a white, and As time goes on (10 days) become orange.Its result in dye test: the color of topknot is a persimmon.It is suitable for commercial use.
The preparation of prescription No.12 is that pH surpasses 7.0 comparative example, with sodium bicarbonate its pH is adjusted, and making its initial color is Lycoperdon polymorphum Vitt, but it becomes grey black at once, is unsettled.Its result in dye test: almost do not have hair dyeing power for topknot.
[embodiment 6]
In the preparation of 6 examples of embodiment, use above-mentioned hair dye cream base B, cooperate silver nitrate, cooperate arginine as aminoacid as silver salt.The unit of the use level of each composition is gram (g).
| Prescription | No.13 | No.14 | No.15 | No.16 |
| Cream base B silver nitrate arginine DHA stabilizing agent: disodium edetate pH | 70.0 1.5 2.0 6.0 | 70.0 1.5 2.0 0.1 3.1 | 70.0 1.5 2.0 0.1 3.8 | 70.0 1.5 2.0 0.1 7.8 |
Make 100g with purified water.
The initial color of the preparation of above-mentioned prescription No.13 is white, As time goes on no change.Its result in dye test: the color of topknot is for having more wine-colored purple.
The initial color of the preparation of above-mentioned prescription No.14 is a white, does not As time goes on take place painted.Its result in dye test: the color of topknot is the tea purple.
The initial color of preparation of prescription No.15 is white, and is As time goes on not painted, is stable.Its result in dye test: the color of topknot is have purple dark brown.
The preparation of prescription No.16 is that pH surpasses 7.0 comparative example, be colored as at first dark brown, then preparation painted significantly.Its result in dye test: though the color of topknot is dark brown, As time goes on dyeing capacity reduces.
[embodiment 7]
In the preparation of 7 examples of embodiment, use above-mentioned hair dye cream base B, cooperate silver nitrate, cooperate tyrosine as aminoacid as silver salt.The unit of the use level of each composition is gram (g).
| Prescription | No.17 | No.18 |
| Cream base B silver nitrate tyrosine DHA pH | 70.0 1.5 1.0 1.0 2.5 | 70.0 1.5 2.0 1.0 2.8 |
Make 100g with purified water.
The initial color of the preparation of above-mentioned prescription No.17 is a white, As time goes on becomes Sandy.Its result in dye test: the color of topknot is dark brown.
The initial color of the preparation of above-mentioned prescription No.18 is a white, As time goes on slowly becomes dark brown.Its result in dye test: the color of topknot is dark brown.
[embodiment 8]
In the preparation of 8 examples of embodiment, use above-mentioned hair dye cream base B, cooperate silver nitrate, cooperate Beta-alanine or hydroxy phenylalanine as aminoacid as silver salt.The unit of the use level of each composition is gram (g).
| Prescription | No.19 | No.20 |
| Cream base B silver nitrate aminoacid DHA pH | 70.0 1.5 Beta-alanines 2.0 1.0 2.5 | 70.0 hydroxy phenylalanine 0.6 1.2 4.6 |
Make 100g with purified water.
The initial color of the preparation of above-mentioned prescription No.19 is white, As time goes on grizzle.Its result in dye test: the color of topknot is the tea purple.
The preparation of above-mentioned prescription No.20 is not for cooperating the comparative example of silver nitrate, and the initial color of preparation is white, As time goes on no change.Its result in dye test: though to topknot handle 3 times not painted yet.This shows if there is not silver salt, then utilizes aminoacid and DHA not to have hair dyed.
[embodiment 9]
In the preparation of 9 examples of embodiment, use above-mentioned hair dye cream base B, cooperate silver nitrate, cooperate aminobutyric acid as aminoacid as silver salt.The unit of the use level of each composition is gram (g).
| Prescription | No.21 | No.22 | No.23 |
| Cream base B silver nitrate aminoacid DHA pH | 70.0 1.5 DL-aminobutyric acids 2.0 1.0 4.6 | 70.0 1.0 4-aminobutyric acids 1.0 0.2 5.7 | 70.0 4-aminobutyric acid 1.0 1.0 5.8 |
Make 100g with purified water.
The initial color of the preparation of above-mentioned prescription No.21 is a white, and As time goes on variable color does not take place.Its result in dye test: the color of topknot is red.
The initial color of the preparation of above-mentioned prescription No.22 is a white, As time goes on becomes dark brown a little.
Its result in dye test: the color of topknot is for reddish slightly dark brown.
The preparation of above-mentioned prescription No.23 is not for cooperating the comparative example of silver nitrate, and initial color is a white, As time goes on invariant color.Its result in dye test: though to topknot handle 3 times not painted yet.This shows if do not have silver salt, utilizes aminoacid and DHA not to have hair dyed.
[embodiment 10]
In the preparation of 10 examples of embodiment, use above-mentioned hair dye cream base B, the silver salt and the aminoacid that are cooperated change to some extent.The unit of the use level of each composition is gram (g).
| Prescription | No.24 | No.25 |
| Cream base B silver salt aminoacid DHA pH | 70.0 silver nitrate 1.5 glutamic acid 2.0 1.0 6.9 | 70.0 actol 4.0 histidine 1.0 3.5 |
Make 100g with purified water.
The initial color of the preparation of above-mentioned prescription No.24 is white, As time goes on grizzle.Its result in dye test: the color of topknot is for reddish slightly dark brown.
The initial color of the preparation of above-mentioned prescription No.25 is white, and is As time goes on not painted.Its result in dye test: the color of topknot is for reddish slightly dark brown.
[embodiment 11]
In the preparation of 11 examples of embodiment, use above-mentioned hair dye cream base B, cooperate silver nitrate as silver salt, the aminoacid that is cooperated changes to some extent.The unit of the use level of each composition is gram (g).
| Prescription | No.26 | No.27 |
| Cream base B silver nitrate amino acid additive pH | 70.0 2.0 histidine, 2.0 Beta-alanines, 1.0 50% sodium lactates 10.0 4.8 | 70.0 1.5 arginine, 1.0 disodium edetate 0.1 3.1 |
Make 100g with purified water.
In the preparation of above-mentioned prescription No.26, adjust pH with lactic acid.The initial color of preparation is white, and is As time goes on not painted.Its result in dye test: the color of topknot is a gray purple.
The initial color of the preparation of above-mentioned prescription No.27 is white, and is As time goes on not painted.Its result in dye test: the color of topknot is the tea purple.
[embodiment 12]
In the preparation of 12 examples of embodiment, use above-mentioned hair dye cream base B, silver salt that is cooperated and aminoacid change to some extent, and pH is heightened.The unit of the use level of each composition is gram (g).
| Prescription | No.28 | No.29 |
| Cream base B silver salt aminoacid pH | 70.0 silver nitrate 1.0 taurines 2.0 6.5 | 70.0 silver sulfate 0.5 lysine 1.6 histidine 1.0 7.7 |
Make 100g with purified water.
The initial color of the preparation of above-mentioned prescription No.28 is white, and is As time goes on not painted.Its result in dye test: the color of topknot is the not good merchantable that has atomic redness.
The initial color of the preparation of above-mentioned prescription No.29 is white, and is As time goes on not painted.Its result in dye test: the color of topknot is a Dun.
[embodiment 13]
In the preparation of 13 examples of embodiment, use above-mentioned hair dye cream base B, adjust the amount of silver salt a little, and change pH, cooperate.The unit of the use level of each composition is gram (g).
| Prescription | No.30 | No.31 | No.32 |
| Cream base B silver nitrate arginine DHA pH | 70.0 0.38 0.5 0.25 3.1 | 70.0 0.1 0.2 0.1 8.0 | 70.0 0.1 0.2 0.1 2.8 |
Make 100g with purified water.
The dye test result of the preparation of above-mentioned prescription No.30: the color of topknot is the black tea color.
The dye test result of the preparation of above-mentioned prescription No.31: almost be unstained.
The dye test result of the preparation of above-mentioned prescription No.32: almost be unstained.
[embodiment 14]
In the preparation of 14 examples of embodiment, use above-mentioned hair dye cream base B, the amount of heightening silver salt cooperates.The unit of the use level of each composition is gram (g).
| Prescription | No.33 | No.34 |
| Cream base B silver nitrate arginine DHA pH | 70.0 4.0 4.0 0.5 2.7 | 70.0 4.0 2.0 0.1 5.3 |
Make 100g with purified water.
The dye test result of the preparation of above-mentioned prescription No.33: the color of topknot is a reddish violet.
The dye test result of the preparation of above-mentioned prescription No.34: the color of topknot is a reddish violet.
[embodiment 15]
In the preparation of 15 examples of embodiment, use above-mentioned hair dye cream base B, make the amount of silver salt constant, change amino acid whose amount and pH and cooperate.The unit of the use level of each composition is gram (g).
| Prescription | No.35 | No.36 | No.37 | No.38 | No.39 |
| Cream base B silver nitrate arginine DHA pH | 70.0 1.5 2.0 0.01 8.0 | 70.0 1.5 2.0 0.1 7.8 | 70.0 1.5 2.0 0.1 3.1 | 70.0 1.5 0.5 0.1 3.1 | 70.0 1.5 0.5 0.5 2.4 |
Make 100g with purified water.
The dye test result of the preparation of above-mentioned prescription No.35: the color of topknot is the tea purple.
The dye test result of the preparation of above-mentioned prescription No.36: the color of topknot is dark brown.
The dye test result of the preparation of above-mentioned prescription No.37: the color of topknot is purplish slightly redness.
The dye test result of above-mentioned prescription No.38 preparation: the color of topknot is red.
The dye test result of above-mentioned prescription No.39 preparation: the color of topknot is purplish slightly redness.
[embodiment 16]
In the preparation of 16 examples of embodiment, use above-mentioned hair dye cream base B, add or do not add silver salt and change aminoacid at DHA and cooperate.The unit of the use level of each composition is gram (g).
| Prescription | No.40 | No.41 | No.42 |
| Cream base B silver nitrate aminoacid DHA pH | 70.0 1.0 4-aminobutyric acids 0.5 0.4 5.7 | 70.0 4-aminobutyric acid 0.2 0.4 5.8 | 70.0 hydroxy phenylalanine 0.2 1.2 4.6 |
Make 100g with purified water.
The initial color of above-mentioned prescription No.40 preparation is a white, As time goes on becomes dark brown.
The dye test result: the color of topknot is for reddish slightly dark brown.
The preparation of above-mentioned prescription No.41 is the comparative example of no silver salt, the dye test result: not painted.
The preparation of above-mentioned prescription No.42 also is the comparative example of no silver salt, the dye test result: not painted.
[embodiment 17]
In the preparation of 17 examples of embodiment, use above-mentioned hair dye cream base B, cooperate aminoacid and in aminoacid, have the aminoacid of chloride ion.The unit of the use level of each composition is gram (g).
| Prescription | No.43 | No.44 | No.45 |
| Cream base B silver nitrate aminoacid DHA pH | 70.0 2.0 lysines 3.0 0.1 3.2 | 70.0 3.0 lysine hydrochlorides 3.0 0.26 3.1 | 70.0 0.5 lysine hydrochloride 4.0 6.2 |
Make 100g with purified water.
The initial color of the preparation of above-mentioned prescription No.43 is a white, As time goes on becomes dark brown.The dye test result of said preparation: the color of topknot is reddish slightly not good merchantable.
The dye test result of the preparation of above-mentioned prescription No.44: have red darker faint yellow.
The dye test result of the preparation of above-mentioned prescription No.45: darker is faint yellow.
By above-mentioned prescription No.44 preparation and No.45 preparation as can be known, the chloride ion of lysine hydrochloride reduces hair dyeing power.
[embodiment 18]
Among the embodiment 18, use following hair dye cream base C.
[hair dye cream base C]
Ring-type silicone 1.0g
Methylphenylsilanone. 1.5g
Simmondsia oil 1.0g
Hexadecanol 5.0g
Lipophile glycerol monostearate 0.4g
POE (5,5) cetyl ether 0.6g
POE (20) docosyl ether 0.6g
Lanolin derivative quaternary ammonium salt (50% solution) 1.2g
Make 70g with purified water.
This hair dye cream base C is the milky paste that viscosity further is higher than above-mentioned hair dye cream base B.
In the preparation of 18 examples of embodiment, use above-mentioned hair dye cream base C, cooperate silver nitrate, basic amino acid.The unit of the use level of each composition is gram (g).
| Prescription | No.46 | No.47 | No.48 |
| Cream base C silver nitrate basic amino acid pH | 70.0 1.0 lysines 2.0 7.6 | 70.0 1.0 lysines 3.0 4.8 | 70.0 1.0 lysines, 1.0 arginine 1.0 4.7 |
Make 100g with purified water.
The initial color of the preparation of above-mentioned prescription No.46 is a white, As time goes on becomes lark.The dye test result of said preparation: the color of topknot is a Lycoperdon polymorphum Vitt.
The initial color of the preparation of above-mentioned prescription No.47 is a white, As time goes on invariant color.The dye test result of said preparation: the color of topknot is a dark brown.
The initial color of the preparation of above-mentioned prescription No.48 is a white, As time goes on becomes lark.The dye test result of said preparation: the color of topknot is a dark brown.
Utilizability on the industry
The present invention relates to a kind of one-pack type hair dye that utilizes luminous energy, it can make the tone based on silver salt have certain scope by regulating pH, and its preparation is stable.
In addition,, thereby need not to resemble and before using, two kinds of liquid are mixed in the past the hair dye because of the present invention to utilize the hair dye of luminous energy be one-pack type, simple to operate during use.
Further, by in preparation, adding DHA, tone is deepened.
In addition, coat hair after, only by periods of direct sunlight more than 30 minutes, silver or silver oxide can be attached on the hair securely, can not produce because the damage of the hair that alkali or oxidation reaction etc. are caused etc.
And even compare with permanent hair dye, the color retention time that also has equal extent is grown the effect of (2 months～3 months).
Owing to have these effect/effects, the one-pack type hair dye of luminous energy that utilizes of the present invention has bigger utilizability towards aging society.
Claims (5)
1. one-pack type hair dye that utilizes luminous energy, this hair dye is characterised in that, it is by cooperating the silver salt of 0.3 weight %～5.0 weight % and the aminoacid of 0.2 weight %～5.0 weight % to make in the hair dye cream base, do not comprise silver halide in the described silver salt, do not comprise sulfur-containing amino acid such as reproducibility aminoacid such as cysteine and methionine in the described aminoacid.
2. one-pack type hair dye that utilizes luminous energy, this hair dye is characterised in that, it is prepared as follows and forms: cooperate at least one aminoacid in neutral amino acid, acidic amino acid, basic amino acid, the sulfamic acid of being selected from of the silver salt of 0.3 weight %～5.0 weight % and 0.2 weight %～5.0 weight % in the hair dye cream base, and the pH of said preparation is adjusted into 2～8; Do not comprise silver halide in the described silver salt, do not comprise sulfur-containing amino acid such as reproducibility aminoacid such as cysteine and methionine in the described basic amino acid.
3. one-pack type hair dye that utilizes luminous energy, this hair dye is characterised in that, it is prepared as follows and forms: cooperate at least one basic amino acid in arginine, histidine, the lysine of being selected from of the silver salt of 0.3 weight %～5.0 weight % and 0.2 weight %～5.0 weight % in the hair dye cream base, and the pH of said preparation is adjusted into 2～8; Do not comprise silver halide in the described silver salt.
4. one-pack type hair dye that utilizes luminous energy, this hair dye is characterised in that, it is prepared as follows and forms: in the hair dye cream base, cooperate 0.3 weight %～5.0 weight % silver salt, 0.2 weight %～5.0 weight % be selected from least one aminoacid in arginine, histidine, the lysine and the dihydroxy acetone of 0.01 weight %～1.5 weight %, and the pH of said preparation is adjusted into 2～7; Do not comprise silver halide in the described silver salt.
5. as any described one-pack type hair dye that utilizes luminous energy of claim 1～4, this hair dye is characterised in that, it is combined with methyl sulfate ion or ethyl sulfate ion is that the cationic surface active agent of counter ion is as the surfactant that uses in described hair dye cream base.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006074421 | 2006-03-17 | ||
| JP2006074421A JP4184385B2 (en) | 2006-03-17 | 2006-03-17 | One-component hair dye using light energy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101036623A true CN101036623A (en) | 2007-09-19 |
Family
ID=38591132
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007100883584A Pending CN101036623A (en) | 2006-03-17 | 2007-03-16 | One-pack type hair dye utilizing optical energy |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP4184385B2 (en) |
| KR (1) | KR20070094467A (en) |
| CN (1) | CN101036623A (en) |
| TW (1) | TW200803906A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108697605A (en) * | 2016-02-17 | 2018-10-23 | 株式会社雅邬乐 | Photosensitive hair dye |
| TWI641389B (en) * | 2016-06-15 | 2018-11-21 | 萬能學校財團法人萬能科技大學 | A hair care composition |
| CN111484421A (en) * | 2020-04-29 | 2020-08-04 | 洛阳冠银生物科技有限公司 | Antibacterial silver ion compound, non-irritant silver ion antibacterial agent and preparation method and application thereof |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4349473B1 (en) * | 2008-12-26 | 2009-10-21 | コスメテックスローランド株式会社 | Hair dye |
| BR112014007239B8 (en) | 2011-09-26 | 2019-03-06 | Unilever Nv | Hair dyeing composition and method |
| JP5486106B1 (en) * | 2013-04-19 | 2014-05-07 | 川田 力也 | Photosensitive hair dye composition using water-soluble complex consisting of silver oxide and amino acid, and photosensitive hair dye |
| MX358244B (en) * | 2013-05-09 | 2018-08-10 | Procter & Gamble | Hair care conditioning composition comprising histidine. |
-
2006
- 2006-03-17 JP JP2006074421A patent/JP4184385B2/en not_active Expired - Fee Related
-
2007
- 2007-02-27 KR KR1020070019520A patent/KR20070094467A/en not_active Application Discontinuation
- 2007-03-16 CN CNA2007100883584A patent/CN101036623A/en active Pending
- 2007-03-16 TW TW096109095A patent/TW200803906A/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108697605A (en) * | 2016-02-17 | 2018-10-23 | 株式会社雅邬乐 | Photosensitive hair dye |
| TWI641389B (en) * | 2016-06-15 | 2018-11-21 | 萬能學校財團法人萬能科技大學 | A hair care composition |
| CN111484421A (en) * | 2020-04-29 | 2020-08-04 | 洛阳冠银生物科技有限公司 | Antibacterial silver ion compound, non-irritant silver ion antibacterial agent and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4184385B2 (en) | 2008-11-19 |
| TW200803906A (en) | 2008-01-16 |
| JP2007246467A (en) | 2007-09-27 |
| KR20070094467A (en) | 2007-09-20 |
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