CN101015761A - Pressure-swing-adsorption purging regeneration method without using vacuum pump - Google Patents
Pressure-swing-adsorption purging regeneration method without using vacuum pump Download PDFInfo
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- CN101015761A CN101015761A CN 200610166599 CN200610166599A CN101015761A CN 101015761 A CN101015761 A CN 101015761A CN 200610166599 CN200610166599 CN 200610166599 CN 200610166599 A CN200610166599 A CN 200610166599A CN 101015761 A CN101015761 A CN 101015761A
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- adsorption
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- swing
- regeneration method
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- 238000001179 sorption measurement Methods 0.000 title claims abstract description 41
- 238000011069 regeneration method Methods 0.000 title claims abstract description 24
- 238000010926 purge Methods 0.000 title claims description 36
- 238000000746 purification Methods 0.000 claims abstract description 21
- 239000007789 gas Substances 0.000 claims description 25
- 238000010521 absorption reaction Methods 0.000 claims description 12
- 239000003463 adsorbent Substances 0.000 claims description 11
- 230000008929 regeneration Effects 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 9
- 238000013022 venting Methods 0.000 claims description 5
- 239000002912 waste gas Substances 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 4
- 230000009466 transformation Effects 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 abstract description 4
- 238000007664 blowing Methods 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 239000002594 sorbent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 230000008569 process Effects 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 230000000274 adsorptive effect Effects 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000012535 impurity Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005261 decarburization Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000008246 gaseous mixture Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
A variable-pressure adsorption blowing regeneration method without vacuum pump uses extraction purification two-stage variable-pressure adsorption PSA device, and avoids vacuum pump to uses blown gas to desorb the adsorption bed layer to completely regenerate the sorbent. The invention can reduce electricity consumption and reduce maintenance cost.
Description
Technical field
The present invention relates to the method that a kind of admixture of gas separates, particularly a kind of vacuum pump less pressure-swing-adsorption purging regeneration method.
Background technology
Wet method decarburization technique power consumption is 100-135 degree/ton ammonia, and solvent loss is 10 yuan of/ton ammonia substantially, and hydrogen loss is 0.5-3% (carbon third is 3%, and NHD is 1%, low-temperature rectisol 0.5%); Now adopt vavuum pump to vacuumize, it is in order to reduce the dividing potential drop of absorbed component, to make adsorbent obtain better regeneration effect that vavuum pump vacuumizes.But vavuum pump belongs to power-equipment, and its maintenance cost remote-effects are to the economic benefit of company.This technology power consumption is 50-130 degree/ton ammonia (an adsorptive pressure height, power consumption is low), hydrogen loss 2-4% (with adsorptive pressure and all press number of times change).Decrease than wet method decarburization technique power consumption, solvent-free loss, however the hydrogen loss rate rises to some extent.
Summary of the invention
The purpose of this invention is to provide a kind of further reduction power consumption, the hydrogen loss rate is dropped to minimum zone, and reduce the pressure-swing-adsorption purging regeneration method without using vacuum pump of the required maintenance cost of power-equipment.
The object of the present invention is achieved like this: a kind of pressure-swing-adsorption purging regeneration method without using vacuum pump, and adopt and purify, purify two sections transformation absorption PSA devices, utilize sweep gas that adsorption bed is forced desorb, make adsorbent obtain holomorphosis.
Purification system and cleaning system are through repeatedly all pressing step.It is 20 times that purification system is all pressed step.It is four times that cleaning system is all pressed step.The purging regeneration that is used for purification section along exitting of purification section.The contrary venting of purification section be used to the to purify purging regeneration of workshop section.The purification of purification section purges waste gas be used to the to purify purging regeneration of workshop section.
Pressure-swing-adsorption purging regeneration method without using vacuum pump provided by the present invention utilizes sweep gas that adsorption bed is forced desorb, makes adsorbent obtain holomorphosis, does not need to use vavuum pump, has reduced power consumption, has reduced the required maintenance cost of power-equipment.
Description of drawings
Fig. 1 is a process flow diagram of the present invention.
The specific embodiment
Pressure is that 2.0MPa, temperature enter four towers that are in adsorption step in the adsorption tower group less than 45 ℃ conversion gas by out-of-bounds sending into purification system after moisture trap is removed free water, from bottom to top by bed, goes out the middle gas of tower and enters cleaning system.When the concentration forward position that is adsorbed impurity exports near bed, close the terminal valve of absorption, make it stop absorption, reclaim the purified gas of bed dead space by all pressing step for 20 times, then against the step-down of absorption direction.Easily absorbed component is discharged, and adsorbent is tentatively regenerated, and with residual absorption impurity on the further desorb adsorbent of sweep gas, adsorbent obtains holomorphosis again.After purging end, utilize cleaning system gaseous mixture, purification system all to calm the anger and export middle gas to boost near adsorptive pressure bed is reverse, adsorbent bed just begins to enter next sorption cycle process.Contrary venting air inlet cabinet purges stripping gas air inlet in early stage cabinet, later stage emptying.
Middle gas enters and purifies three towers that are in adsorption step in the adsorption tower group, from bottom to top by adsorption tower, goes out adsorption cleaning pneumatic transmission high-pressure unit.When the impurity concentration forward position of absorption when the adsorbent bed outlet, close the terminal valve of absorption.Make it stop absorption, reclaim the purified gas of adsorption bed dead space, carry out then entering three surge tanks respectively, then enter the gaseous mixture surge tank, as the sweep gas of purifying plant against the step-down of absorption direction along putting three times by all pressing step for four times.After purging end, the adsorbent of purifier obtains holomorphosis.Utilize cleaning system all to press with purified gas and boost near adsorptive pressure bed is reverse, adsorbent bed just begins to enter next sorption cycle process.
Single tower circulation step of purifying:
(the adsorption bed nature desorb of (desorb of adsorption bed nature) → contrary putting all falls in absorption (absorbing the CO2 Purge gas) → several times, and reclaim high concentration CO 2) → purge and reclaim (utilize to purify to purge waste gas adsorption bed is forced desorb, and reclaim high concentration CO 2) → purge vent (utilize purify purge waste gas adsorption bed is forced desorb) → several times all to rise (adsorption bed recovery gas) → enter adsorption process of next circulation
Purify single tower circulation step:
(the adsorption bed nature desorb of (desorb of adsorption bed nature) → suitable putting all falls in absorption (absorbing the CO2 Purge gas) → several times, be used for the purging regeneration of purification section along venting) → contrary putting (adsorption bed nature desorb, contrary venting be used to the to purify purging regeneration of workshop section) → purge (utilize to purify to purge waste gas adsorption bed is forced desorb, sweep gas be used to purify the purging regeneration of workshop section) → several times all rise (adsorption bed recovery gas) → enter adsorption process of next circulation.
Claims (7)
1, a kind of pressure-swing-adsorption purging regeneration method without using vacuum pump adopts and purifies, purifies two sections transformation absorption PSA devices, it is characterized in that: utilize sweep gas that adsorption bed is forced desorb, make adsorbent obtain holomorphosis.
2, pressure-swing-adsorption purging regeneration method without using vacuum pump according to claim 1 is characterized in that: purification system and cleaning system are through repeatedly all pressing step.
3, pressure-swing-adsorption purging regeneration method without using vacuum pump according to claim 1 and 2 is characterized in that: it is 20 times that purification system is all pressed step.
4, pressure-swing-adsorption purging regeneration method without using vacuum pump according to claim 1 and 2 is characterized in that: it is four times that cleaning system is all pressed step.
5, according to the described pressure-swing-adsorption purging regeneration method without using vacuum pump according to claim 1 of claim 1, it is characterized in that: the purging regeneration that is used for purification section along exitting of purification section.
6, pressure-swing-adsorption purging regeneration method without using vacuum pump according to claim 1 is characterized in that: the contrary venting of purification section be used to the to purify purging regeneration of workshop section.
7, pressure-swing-adsorption purging regeneration method without using vacuum pump according to claim 1 is characterized in that: the purification of purification section purges waste gas be used to the to purify purging regeneration of workshop section.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610166599 CN101015761A (en) | 2006-12-28 | 2006-12-28 | Pressure-swing-adsorption purging regeneration method without using vacuum pump |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200610166599 CN101015761A (en) | 2006-12-28 | 2006-12-28 | Pressure-swing-adsorption purging regeneration method without using vacuum pump |
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| Publication Number | Publication Date |
|---|---|
| CN101015761A true CN101015761A (en) | 2007-08-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200610166599 Pending CN101015761A (en) | 2006-12-28 | 2006-12-28 | Pressure-swing-adsorption purging regeneration method without using vacuum pump |
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| Country | Link |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103405993A (en) * | 2013-04-09 | 2013-11-27 | 内蒙古乌拉山化肥有限责任公司 | Pressure swing adsorption method |
| CN103933825A (en) * | 2014-04-03 | 2014-07-23 | 湖北宜化化工股份有限公司 | Device and process for recycling reversely-released gas of PSA (Primary Secondary Amine) purification section to refinement section |
| CN107983029A (en) * | 2017-12-26 | 2018-05-04 | 同方威视技术股份有限公司 | Gas cleaning plant and trace materials detection device |
| CN111655657A (en) * | 2017-12-05 | 2020-09-11 | Bp北美公司 | Process for recovering paraxylene in a pressure swing adsorption unit with varying hydrogen purge pressure |
| CN113713564A (en) * | 2021-09-07 | 2021-11-30 | 安徽泉盛化工有限公司 | Pressure swing adsorption system |
-
2006
- 2006-12-28 CN CN 200610166599 patent/CN101015761A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103405993A (en) * | 2013-04-09 | 2013-11-27 | 内蒙古乌拉山化肥有限责任公司 | Pressure swing adsorption method |
| CN103933825A (en) * | 2014-04-03 | 2014-07-23 | 湖北宜化化工股份有限公司 | Device and process for recycling reversely-released gas of PSA (Primary Secondary Amine) purification section to refinement section |
| CN103933825B (en) * | 2014-04-03 | 2016-04-20 | 湖北宜化化工股份有限公司 | A kind of PSA clean-up stage inverse put gas is recovered to rectifying section retracting device and recovery process again |
| CN111655657A (en) * | 2017-12-05 | 2020-09-11 | Bp北美公司 | Process for recovering paraxylene in a pressure swing adsorption unit with varying hydrogen purge pressure |
| CN111655657B (en) * | 2017-12-05 | 2023-05-26 | 英力士美国化学公司 | Method for recovering para-xylene in pressure swing adsorption unit with varying hydrogen purge pressure |
| CN107983029A (en) * | 2017-12-26 | 2018-05-04 | 同方威视技术股份有限公司 | Gas cleaning plant and trace materials detection device |
| CN113713564A (en) * | 2021-09-07 | 2021-11-30 | 安徽泉盛化工有限公司 | Pressure swing adsorption system |
| CN113713564B (en) * | 2021-09-07 | 2024-04-26 | 安徽泉盛化工有限公司 | Pressure swing adsorption system |
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| PB01 | Publication | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Open date: 20070815 |