CN101012412A - Leather cleaning agent - Google Patents

Leather cleaning agent Download PDF

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Publication number
CN101012412A
CN101012412A CN 200710061473 CN200710061473A CN101012412A CN 101012412 A CN101012412 A CN 101012412A CN 200710061473 CN200710061473 CN 200710061473 CN 200710061473 A CN200710061473 A CN 200710061473A CN 101012412 A CN101012412 A CN 101012412A
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CN
China
Prior art keywords
chinese
prickly ash
honey locust
weight
extraction liquid
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Granted
Application number
CN 200710061473
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Chinese (zh)
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CN100494333C (en
Inventor
李文娟
何明威
李梦瑶
胡志刚
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Taiyuan Normal University
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Taiyuan Normal University
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Priority to CNB2007100614732A priority Critical patent/CN100494333C/en
Publication of CN101012412A publication Critical patent/CN101012412A/en
Application granted granted Critical
Publication of CN100494333C publication Critical patent/CN100494333C/en
Expired - Fee Related legal-status Critical Current
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  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses an environment-protective leather abluent, which comprises the following parts: 90-97.5% Chinese honey locust and peppertree extract liquid, 1-5% acetate triethanolamine, 1-3% carbowax 6000 and 0.5-2% pingpingjia. The invention makes color fresh on the leather, which protects leather effectively.

Description

A kind of leather cleaning agent
Technical field
The present invention relates to clean-out system, be specially a kind of leather cleaning agent.
Background technology
Clean leather and goods thereof, should decontamination keep the flexibility of leather and bright degree again, also require clean-out system to have certain sterilization, anthelmintic activity and go mouldy, damage by worms preventing, and clean-out system itself can not bring harm to environment to prevent crowfoot cracks.
Chinese patent 86102134 " a kind of sanitising agent that is used for leatherware " is formed leather cleaning agent with rosin, pure white oil, lead naphthenate or manganese naphthenate.Along with the variation that construction of environmental protection requires, the use of leadization thing should be avoided as far as possible.
In the composition of Chinese patent 91109941.7 " leather brightening agent for washing " siloxanes, wetting Agent for Printing Inks, tensio-active agent, mould inhibitor are arranged.
Chinese patent 91111736.9 " detergent and protectant preparation method " (Germany Henkel Kommanditgesellschaft auf Aktien) then is with the wax emulsion of alkylglycoside as emulsifying agent.
Chinese patent 90106961.2 " treatment process of leather and leatherware " (French Luo Na. Blanck Chemical Company), relating to solution-treated leather with the acrylate that contains lanthanum or cerium, purpose is to prevent that leather from rotting.
Chinese patent 011334178.5 " pure natural clean-out system " uses Chinese honey locust to leach cream, tea saponin crystal.
Above patent perhaps biases toward decontamination, perhaps biases toward the light of leather, perhaps biases toward the protection of the film forming of leather, perhaps biases toward anticorrosion to leather.And integrate decontamination, sterilization, protection leather, environmental protection, and have concurrently and help the clean-out system that dyes with tint retention actually rare.
Summary of the invention
The object of the present invention is to provide a kind of leather cleaning agent, this clean-out system has the effect of decontamination, sterilization, protection leather, and environment is not worked the mischief.
A kind of leather cleaning agent provided by the invention, its components based on weight percentage: Chinese honey locust and Chinese prickly ash extraction liquid 90~97.5%, acetic acid triethanolamine 1~5%, polyethylene glycol 6000 1~3%, peregal 0.5~2%;
Wherein, described Chinese honey locust and Chinese prickly ash extraction liquid adopt following method to make:
By weight Chinese honey locust: water=1: 15~25, after Chinese honey locust pulverized, water reflux extraction 1~2 hour was cooled to the room temperature after-filtration, adds suitable quantity of water in filtrate, was 15~25 times of Chinese honey locust weight to keep the solution total amount;
By weight Chinese prickly ash: industrial alcohol=1: 15~25, after Chinese prickly ash pulverized, carried out reflux extraction 0.5~1 hour with industrial alcohol, be cooled to the room temperature after-filtration, in filtrate, suitably add industrial alcohol, be 15~25 times of Chinese prickly ash weight to keep solution weight:
With resulting Chinese honey locust extraction liquid and Chinese prickly ash extraction liquid by weight the Chinese honey locust extraction liquid: Chinese prickly ash extraction liquid=2-6: 1 mixes, and promptly makes Chinese honey locust and Chinese prickly ash extraction liquid.
The preparation method of leather cleaning agent: after above-mentioned material was mixed in proportion, stirring and dissolving left standstill one day, promptly made leather cleaning agent.
Described Chinese honey locust and Chinese prickly ash extraction liquid preferably adopt following method to make:
By weight Chinese honey locust: water=1: 20, after Chinese honey locust pulverized, water reflux extraction 1 hour was cooled to the room temperature after-filtration, adds suitable quantity of water in filtrate, was 20 times of Chinese honey locust weight to keep the solution total amount;
By weight Chinese prickly ash: industrial alcohol=1: 20, after Chinese prickly ash pulverized, carried out reflux extraction 0.5 hour with industrial alcohol, be cooled to the room temperature after-filtration, in filtrate, suitably add industrial alcohol, be 20 times of Chinese prickly ash weight to keep solution weight;
With resulting Chinese honey locust extraction liquid and Chinese prickly ash extraction liquid by weight the Chinese honey locust extraction liquid: Chinese prickly ash extraction liquid=mix at 4: 1 promptly makes Chinese honey locust and Chinese prickly ash extraction liquid.
The contrast of the present invention and prior art:
Patent 86102134 " a kind of sanitising agent that is used for leatherware " is used manganese naphthenate (or plumbous), and the present invention does not use.
Patent 91109941.7 " leather brightening agent for washing " is used siloxanes, and the present invention does not use.
Patent 91111736.9 " detergent and protectant preparation method " is used R-O-C, and (G) n glycoside, the present invention uses natural gleditschia-saponin.
Patent 90106961.2 " treatment process of leather and leatherware " is used the acrylate of lanthanum or cerium, and the present invention does not use.
Patent 011334178.5 " pure natural clean-out system " uses Chinese honey locust to leach cream, tea saponin crystal, and the present invention uses Chinese honey locust, Chinese prickly ash leaching liquid.
Advantage of the present invention and effect:
Contain saponin in the Chinese honey locust, soap is sewed multiple components such as sugar, tannin, phenols, alkaloid, can be water-soluble, and have and clean and germicidal action.3-hydroxyl-12-oleanene-28-acid, 3,16-dihydroxyl-12-oleanene-28-acid is the composition of two kinds of Chinese honey locust sapogenins, and the Chinese honey locust sapogenin has good complexing cleanup action (" ACTA Scientiae Circumstantiae " 2006 the 8th phases, Jiang Yufeng, Zhan Huiying etc. to heavy metal ion such as copper, cadmium, lead, zinc; " herbal medicine " calendar year 2001 the 3rd phase Wang Ji raises, Korea Spro Victoria is sincere etc.).
Pericarpium Zanthoxyli fruit contains multiple components such as limonene, cumic alcohol, Mang geraniol, different methyl allylphenol, and the Chinese prickly ash decoction has restraining effect to various bacteria such as anthrax bacteria, suis, staphylococcus, Pseudomonas aeruginosas, and anthelmintic action is arranged.
The present invention utilizes the extract of Chinese honey locust and Chinese prickly ash and acetic acid triethanolamine, polyoxyethylene glycol, peregal to form leather cleaning agent, not only have cleaning, sterilization, anthelmintic function, and clean leather and goods thereof with this clean-out system, any surface finish, can prevent crowfoot cracks, anti-going mouldy, and have concurrently to help and dye and tint retention, can make the leather color clear firm.Not only environment is not worked the mischief in addition, and the Chinese honey locust sapogenin that has in the clean-out system there is good complexing action to heavy metal ion such as copper, cadmium, lead, zinc, helps the purification of soil.This clean-out system can be used for cleaning leatherware such as leather shoes, fur clothing, suitcase and leather sofa.
Embodiment
Embodiment 1
The component of leather cleaning agent and proportioning: Chinese honey locust and Chinese prickly ash extract 9.3kg, acetic acid triethanolamine 0.3kg, polyethylene glycol 6000 0.3kg, paregal O 0.1kg.
The preparation of Chinese honey locust and Chinese prickly ash extraction liquid:
After the 1kg Chinese honey locust pulverized, with the water reflux extraction of 20kg 1 hour, being cooled to the room temperature after-filtration, adding suitable quantity of water in filtrate, is 20 times of Chinese honey locust weight to keep the solution total amount.
After the 0.25kg Chinese prickly ash pulverized, carrying out reflux extraction 0.5 hour with the industrial alcohol (volume percent is 95% aqueous ethanolic solution) of 5kg, be cooled to the room temperature after-filtration, suitably add industrial alcohol in filtrate, is 20 times of Chinese prickly ash weight to keep solution weight.Resulting Chinese honey locust extraction liquid and Chinese prickly ash extraction liquid are mixed, promptly make Chinese honey locust and Chinese prickly ash extraction liquid.
The preparation of leather cleaning agent: after above-mentioned mixing of materials, stirring and dissolving leaves standstill and promptly made product in one day.
Using method and effect: clean-out system is sprayed on leather surface, uses the even wiping of clean softish cloth then, can make leather surface bright and clean, and form protective membrane, to reach the effect of waterproof, mildew-resistant, mothproof, fixation.
Embodiment 2
The component of leather cleaning agent and proportioning: Chinese honey locust and Chinese prickly ash extract 9.75kg, acetic acid triethanolamine 0.1kg, polyethylene glycol 6000 0.1kg, peregal os-15 0.05kg.
All the other are with embodiment 1.
Embodiment 3
The component of leather cleaning agent and proportioning: Chinese honey locust and Chinese prickly ash extract 9.5kg, acetic acid triethanolamine 0.2kg, polyethylene glycol 6000 0.25kg, paregal O 0.05kg.
All the other are with embodiment 1.
Embodiment 4
The component of leather cleaning agent and proportioning: Chinese honey locust and Chinese prickly ash extract 9kg, acetic acid triethanolamine 0.5kg, polyethylene glycol 6000 0.3kg, paregal O 0.2kg.
All the other are with embodiment 1.

Claims (2)

1, a kind of leather cleaning agent is characterized in that, components based on weight percentage: Chinese honey locust and Chinese prickly ash extraction liquid 90~97.5%, acetic acid triethanolamine 1~5%, polyethylene glycol 6000 1~3%, peregal 0.5~2%;
Wherein, described Chinese honey locust and Chinese prickly ash extraction liquid adopt following method to make:
By weight Chinese honey locust: water=1: 15~25, after Chinese honey locust pulverized, water reflux extraction 1~2 hour was cooled to the room temperature after-filtration, adds suitable quantity of water in filtrate, was 15~25 times of Chinese honey locust weight to keep the solution total amount;
By weight Chinese prickly ash: industrial alcohol=1: 15~25, after Chinese prickly ash pulverized, carried out reflux extraction 0.5~1 hour with industrial alcohol, be cooled to the room temperature after-filtration, in filtrate, suitably add industrial alcohol, be 15~25 times of Chinese prickly ash weight to keep solution weight;
With resulting Chinese honey locust extraction liquid and Chinese prickly ash extraction liquid by weight the Chinese honey locust extraction liquid: Chinese prickly ash extraction liquid=2-6: 1 mixes, and promptly makes Chinese honey locust and Chinese prickly ash extraction liquid.
2, clean-out system as claimed in claim 1 is characterized in that described Chinese honey locust and Chinese prickly ash extraction liquid adopt following method to make:
By weight Chinese honey locust: water=1: 20, after Chinese honey locust pulverized, water reflux extraction 1 hour was cooled to the room temperature after-filtration, adds suitable quantity of water in filtrate, was 20 times of Chinese honey locust weight to keep the solution total amount;
By weight Chinese prickly ash: industrial alcohol=1: 20, after Chinese prickly ash pulverized, carried out reflux extraction 0.5 hour with industrial alcohol, be cooled to the room temperature after-filtration, in filtrate, suitably add industrial alcohol, be 20 times of Chinese prickly ash weight to keep solution weight;
With resulting Chinese honey locust extraction liquid and Chinese prickly ash extraction liquid by weight the Chinese honey locust extraction liquid: Chinese prickly ash extraction liquid=mix at 4: 1 promptly makes Chinese honey locust and Chinese prickly ash extraction liquid.
CNB2007100614732A 2007-01-29 2007-01-29 Leather cleaning agent Expired - Fee Related CN100494333C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2007100614732A CN100494333C (en) 2007-01-29 2007-01-29 Leather cleaning agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2007100614732A CN100494333C (en) 2007-01-29 2007-01-29 Leather cleaning agent

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CN101012412A true CN101012412A (en) 2007-08-08
CN100494333C CN100494333C (en) 2009-06-03

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104498201A (en) * 2014-12-17 2015-04-08 广东菲安妮皮具股份有限公司 Leather care detergent
CN106854536A (en) * 2017-01-04 2017-06-16 长沙协浩吉生物工程有限公司 A kind of compound method of fur clothing cleaning agent
CN107267693A (en) * 2017-08-15 2017-10-20 宁夏成丰农业科技开发股份有限公司 A kind of improved tibet lamp process for tanning
CN107955731A (en) * 2017-11-30 2018-04-24 成都梓楠家具有限公司 A kind of leather sofa cleaning agent
CN108034516A (en) * 2017-11-30 2018-05-15 成都梓楠家具有限公司 A kind of smart home articles for use antibacterial cleaning solution

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104498201A (en) * 2014-12-17 2015-04-08 广东菲安妮皮具股份有限公司 Leather care detergent
CN106854536A (en) * 2017-01-04 2017-06-16 长沙协浩吉生物工程有限公司 A kind of compound method of fur clothing cleaning agent
CN107267693A (en) * 2017-08-15 2017-10-20 宁夏成丰农业科技开发股份有限公司 A kind of improved tibet lamp process for tanning
CN107955731A (en) * 2017-11-30 2018-04-24 成都梓楠家具有限公司 A kind of leather sofa cleaning agent
CN108034516A (en) * 2017-11-30 2018-05-15 成都梓楠家具有限公司 A kind of smart home articles for use antibacterial cleaning solution

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C06 Publication
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C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Zhejiang Red Dragonfly Shoes Industrial Co., Ltd.

Assignor: Taiyuan Normal College

Contract fulfillment period: 2009.7.30 to 2014.7.29 contract change

Contract record no.: 2009990001142

Denomination of invention: Leather cleaning agent

Granted publication date: 20090603

License type: Exclusive license

Record date: 20091014

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.7.30 TO 2014.7.29; CHANGE OF CONTRACT

Name of requester: ZHEJIANG HONGQINGTING SHOES CO., LTD.

Effective date: 20091014

CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20090603

Termination date: 20150129

EXPY Termination of patent right or utility model