CN101012411B - Aluminum and aluminum alloy cleaning agent and using method thereof - Google Patents
Aluminum and aluminum alloy cleaning agent and using method thereof Download PDFInfo
- Publication number
- CN101012411B CN101012411B CN2007100102467A CN200710010246A CN101012411B CN 101012411 B CN101012411 B CN 101012411B CN 2007100102467 A CN2007100102467 A CN 2007100102467A CN 200710010246 A CN200710010246 A CN 200710010246A CN 101012411 B CN101012411 B CN 101012411B
- Authority
- CN
- China
- Prior art keywords
- abluent
- aluminium
- cleaning
- clean
- polyoxyethylene ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 11
- 229910000838 Al alloy Inorganic materials 0.000 title abstract 5
- 239000012459 cleaning agent Substances 0.000 title description 4
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 18
- 239000004411 aluminium Substances 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 5
- 238000002347 injection Methods 0.000 claims abstract description 3
- 239000007924 injection Substances 0.000 claims abstract description 3
- 229910000737 Duralumin Inorganic materials 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 150000003333 secondary alcohols Chemical class 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 abstract description 9
- 239000008103 glucose Substances 0.000 abstract description 9
- -1 alkyl phenol Chemical compound 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 5
- 150000005826 halohydrocarbons Chemical class 0.000 abstract description 4
- 238000005406 washing Methods 0.000 abstract description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 3
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 238000005494 tarnishing Methods 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 11
- 229910045601 alloy Inorganic materials 0.000 description 9
- 239000000956 alloy Substances 0.000 description 9
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002161 passivation Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000010731 rolling oil Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The invention discloses an aluminium and aluminium alloy abluent, which comprises the following parts: 5-25W% alkyl phenol polyoxyethylene ether, 5-25W% aliphatic alcohol polyoxyethylene ether, 1-10W% cationic modified alkyl phenol polyoxyethylene ether, 2-10W% propanediol butyl ether, 2-8W% glucose, 1-8W% sodium bisilicate and 40-80W% water. The product displays light yellow transparent liquid with density at 1.05+-0.02 g/cm<3>, which simplifies normal disposal technique. The aluminum and aluminium alloy is cleaned by using ultrasonic or pressure injection system in 50-70 DEG C for 5-10 minutes. The abluent has high washing-ratio (more than 99%), anti-lightlossing and anti-tarnishing performance, realizes high accuracy cleaning and passivating at the same time and simplifies the conventional processing technology. Compared with the halohydrocarbon, the washing cost of the abluent is reduced 40%-50%. And the abluent avoids the harm form solvent base abluent to environment and operation staff and realizes the harmless environment friendly cleaning at the same time.
Description
Technical field:
The invention belongs to the detergent composition field, being specifically related to the tensio-active agent is the mixture of mixture, nonionic compound and cationic compound of main compsn, particularly propylene glycol.Also relate to simultaneously with the organic solvent that contains carbon, hydrogen compound and metallic substance being cleaned or the field of oil removing.
Background technology:
Aluminium and alloy thereof (particularly with its process zero, parts and precision instrument) cleaning more complicated and tired much more difficult than the cleaning of other metals; This is because aluminium and alloy adsorptivity thereof are strong, chemical property is active; Common clean-out system is residual more, is difficult to satisfy accurate cleaning cleaning the requirement of rate.This be because:
1. the function grease that uses in aluminium and the alloy component process of manufacture thereof (ROLLING OIL, rolling oil, lubricated wet goods); Belong to the difficult grease that cleans, generally adopt the powerful leaning solvent of halogenated hydrocarbon (80 ℃～90 ℃) under hot conditions to clean the cleaning of this quasi-grease.The ortho-water based cleaning agent from cleaning speed also or aspect such as cleaning dynamics all can't reach requirement.
2. aluminium and alloy thereof are extremely responsive for the impurity in the empty G&W, and loss of gloss easy to change, and application immediately or carry out organic covering after cleaning if set up one passivation procedure separately then production cost is significantly improved, and make technological process complicated more.Transparent passivating process how in cleaning process, to accomplish the anti-loss of gloss of anti-discolouring simultaneously is a matting thorny difficult problem in the industry always.
3. extensive, serialization industrial production requires cleaning liquid that bigger cleaning capacity and long cleaning interval are arranged, and common clean-out system can not satisfy this requirement.
What provide like CN1796607, CN1616798 all is aqueous cleaning agent, but only effective to the greasy dirt of metallic surface.This is a kind of dirt detergent of metal for CN1616627 (ZL200410009622), obviously is what to have satisfied not to the special demands of aluminium and duraluminum.CN1067265 provides a kind of sour water based cleaning agent, aluminium and duraluminum, copper, stainless steel is cleaned, yet be characterized in residual flux recrement and the oxide compound that the welding place to these metals becomes, but also need heat.So far also not to effective clean-out system of aluminium and duraluminum.
Summary of the invention:
To the defective of prior art, the purpose of this invention is to provide a kind of to aluminium and alloy thereof (particularly with its process zero, parts and precision instrument) effective clean-out system.
Technical scheme of the present invention is: with tensio-active agent is main, particularly is that main compsn clean-out system is to be by following component and proportioning (W%) with the nonionogenic tenside:
TX10 5～25
AEO 5～25
Cation-modified TX10 1～10
Ucar 35 butyl ether 2～10
Glucose 2～8
Starso 1～8
Water 40～80
Wherein said: TX10 is the alkylphenol of 8～12 carbon, and oxyethyl group is 8～10; The alcohol of AEO is generally the primary alconol or the secondary alcohol of 8～14 carbon, and oxyethyl group is 8～10; The alkylphenol of 6～16 carbon of cation-modified TX10, oxyethyl group is 8～12, as trade names be Tomadyne100 for well, also can use dodecyl phenol polyethenoxy ether (9～11 of oxyethyl groups).
Facts have proved that the effect of filling a prescription as follows is better:
(1) TX10 10
AEO 9
Tomadyne100 5
Ucar 35 butyl ether 5
Glucose 5
Starso 2
Water 64
(2) TX10 20
AEO 18
Tomadyne100 6
Ucar 35 butyl ether 4
Glucose 4
Starso 3
Water 45
(3) TX10 7
AEO 8
Cation-modified TX10 3
Ucar 35 butyl ether 5
Glucose 3
Starso 6
Water 68
Product of the present invention preparation is very simple, with above-mentioned raw materials at normal temperature or (must not above the 70 ℃) mixed dissolution of heating even.Product is a light yellow transparent liquid, density (g/cm
3) (proportion) be 1.05 ± 0.02.
When clean-out system of the present invention early cleans aluminium and closes MO on the duraluminum, vegetable and animals oils and other functional greases, adopt UW or pressure injection to clean, at 50～70 ℃, under about 5 minutes of the time condition, the rate of cleaning is more than 99%.Cleaning performance is:
1. high-detergency; Aluminium after the cleaning and alloy thereof in addition parts surface use the brilliant white X, and no two-dimensional surpasses 0.05mm and the three-dimensional dimension loose particles above 0.02mm, with UV-light (fluorescence less when wavelength 0.32～0.38um) is checked.
2. realize that through giving aluminium and alloy surface hydrophobicity thereof its surface has good anti-loss of gloss, discoloration-resisting.
3. cleaning speed, cleaning dynamics and wash degree three aspects surpass halohydrocarbon (like trichloroethane) solvent cleaner simultaneously, and have overcome acomia thorough removing metal break flour of halohydrocarbon (like trichloroethane) solvent cleaner and the greasy deficiency of carbonization.
Compared with prior art; The present invention makes aluminium and alloy cleaning efficiency first mate's raising, high-accuracy please the washing of realization of parts in addition, cleans and passivation completion simultaneously under same processing condition, has simplified conventional treatment process; Clean cost and clean reduction by 40%～50% than halohydrocarbon; Simultaneously, avoided the harm of leaning solvent, realized innoxious environment-friendly type cleaning environment and operator.
Below with embodiment the present invention is described further.
Instance 1
Press following formulated clean-out system:
Polyoxyethylene nonylphenol 100Kg
Ethoxylated dodecyl alcohol 90Kg
Tomadyne100 50Kg
Ucar 35 butyl ether 50Kg
Glucose 50Kg
Starso 20Kg
Water 640Kg
Above-mentioned raw materials is mixed to transparent under 25～35 ℃.Product is a light yellow transparent liquid, density (g/cm
3) (proportion) be 1.05 ± 0.02.
When the engine parts that one type of duraluminum of cleaning is processed, adopt ultrasonic cleaning, at 50～70 ℃, about 5 minutes of time.Aluminium after the cleaning and alloy thereof in addition parts surface use the brilliant white X, and no two-dimensional surpasses 0.05mm and the three-dimensional dimension loose particles above 0.02mm, with UV-light (fluorescence less when wavelength 0.32～0.38um) is checked; Its surface hydrophobicity is good, no loss of gloss, no variable color, and the rate of cleaning surpasses 99%.
Instance 2
Press following formulated clean-out system:
Dodecyl phenol polyethenoxy ether 200Kg
Lauryl alcohol Soxylat A 25-7 180Kg
Tomadyne100 60Kg
Ucar 35 butyl ether 40Kg
Glucose 40Kg
Starso 30Kg
Water 450Kg
The preparation of product, use and effect thereof are with instance 1.
Instance 3
Press following formulated clean-out system:
Polyoxyethylene nonylphenol 70Kg
Ethoxylated dodecyl alcohol 80Kg
Tomadyne100 30Kg
Ucar 35 butyl ether 50Kg
Glucose 30Kg
Starso 60Kg
Water 680Kg
Being formulated under 20～25 ℃ of product carried out, and the duraluminum instrument piping is with the pressure wash cycles, at 50～70 ℃, and about 5 minutes of time.Effect is with instance 1.
Instance 4
Press following formulated clean-out system:
Polyoxyethylene octylphenol ether 230Kg
Lauryl alcohol Soxylat A 25-7 170Kg
Dodecyl phenol polyethenoxy ether 60kg
Ucar 35 butyl ether 40Kg
Glucose 20Kg
Starso 30Kg
Water 450Kg
The preparation of product, use and effect thereof are with instance 1.
Claims (3)
1. aluminium and duraluminum clean-out system is characterized in that its component and weight percent proportioning (W%) are:
Wherein said: TX10 is the alkylphenol of 8～12 carbon, and oxyethyl group is 8～10; The alcohol of AEO is generally the primary alconol or the secondary alcohol of 8～14 carbon, and oxyethyl group is 8～10; The alkylphenol of 6～16 carbon of cation-modified TX10, oxyethyl group is 8～12; Product is a light yellow transparent liquid, density (g/cm
3) be 1.05 ± 0.02.
2. according to said aluminium of claim 1 and duraluminum clean-out system, it is characterized in that its component and weight percent proportioning (W%) are:
3. the method for use of aluminium as claimed in claim 1 and duraluminum clean-out system is characterized in that adopting UW or pressure injection to clean, at 50～70 ℃, under 5～10 minutes time condition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100102467A CN101012411B (en) | 2007-02-01 | 2007-02-01 | Aluminum and aluminum alloy cleaning agent and using method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100102467A CN101012411B (en) | 2007-02-01 | 2007-02-01 | Aluminum and aluminum alloy cleaning agent and using method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101012411A CN101012411A (en) | 2007-08-08 |
| CN101012411B true CN101012411B (en) | 2012-06-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100102467A Expired - Fee Related CN101012411B (en) | 2007-02-01 | 2007-02-01 | Aluminum and aluminum alloy cleaning agent and using method thereof |
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| Country | Link |
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| CN (1) | CN101012411B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104611118A (en) * | 2013-11-01 | 2015-05-13 | 沈阳工业大学 | Aluminum and aluminum alloy water-based cutting fluid |
| CN104593794A (en) * | 2013-11-01 | 2015-05-06 | 沈阳工业大学 | A cleaning agent for aluminum and alloys thereof |
| CN103624636A (en) * | 2013-11-27 | 2014-03-12 | 天广消防股份有限公司 | Surface processing process of aluminum and aluminum alloy workpieces |
| CN103774168B (en) * | 2014-01-23 | 2016-05-04 | 潍柴动力(潍坊)再制造有限公司 | Manufacture again special dirt detergent and preparation method thereof |
| CN105665368A (en) * | 2016-01-18 | 2016-06-15 | 广东鸿泰科技股份有限公司 | Surface cleaning treatment method for aluminum alloy workpiece |
| CN105951114A (en) * | 2016-05-11 | 2016-09-21 | 江西洪都航空工业集团有限责任公司 | Aluminum-lithium alloy degreasing solution and degreasing technique |
| CN106077864B (en) * | 2016-06-29 | 2018-03-09 | 余姚市弘顺机械有限公司 | A kind of oil cooler dries Welding |
| CN106833936A (en) * | 2017-02-15 | 2017-06-13 | 中卫市创科知识产权投资有限公司 | A kind of aqueous treatment agent producing process |
| WO2018203995A1 (en) * | 2017-05-01 | 2018-11-08 | Ecolab Usa Inc. | Alkaline warewash detergent for aluminum surfaces |
| CN110713864B (en) * | 2018-07-13 | 2023-09-26 | Bl 科技公司 | Antifouling dispersant compositions and methods of use |
| CN111088120B (en) * | 2019-12-30 | 2021-05-07 | 深圳金泽万长石化有限公司 | Strong decontamination cleaning solution and preparation method thereof |
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|---|---|---|---|---|
| CN1339578A (en) * | 2001-09-14 | 2002-03-13 | 成都航利生物材料研究所 | Cleaning agent for metal equipment |
| CN1417385A (en) * | 2002-11-29 | 2003-05-14 | 广西大学 | Surface scale eliminating method for anode guide rod in aluminium electrolysis |
| CN1524939A (en) * | 2003-09-15 | 2004-09-01 | 李伟光 | Multifunctional scrubbing cleanser |
| CN1847381A (en) * | 2006-04-30 | 2006-10-18 | 北京市航天焊接材料厂 | Multifunctional environment-friendly cleaning agent and preparation method thereof |
-
2007
- 2007-02-01 CN CN2007100102467A patent/CN101012411B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339578A (en) * | 2001-09-14 | 2002-03-13 | 成都航利生物材料研究所 | Cleaning agent for metal equipment |
| CN1417385A (en) * | 2002-11-29 | 2003-05-14 | 广西大学 | Surface scale eliminating method for anode guide rod in aluminium electrolysis |
| CN1524939A (en) * | 2003-09-15 | 2004-09-01 | 李伟光 | Multifunctional scrubbing cleanser |
| CN1847381A (en) * | 2006-04-30 | 2006-10-18 | 北京市航天焊接材料厂 | Multifunctional environment-friendly cleaning agent and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN101012411A (en) | 2007-08-08 |
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Address after: 116000 No.51 Qinglong Street, Longtou branch, high tech Industrial Park, Shahekou District, Dalian City, Liaoning Province Patentee after: DALIAN SANDAOKE CHEMISTRY Co.,Ltd. Address before: 116023 No. 30, high energy street, hi tech Zone, Liaoning, Dalian Patentee before: DALIAN SANDAAOKE CHEMISTRY Co.,Ltd. |
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Granted publication date: 20120613 |