CN101003769A - Water based detergent for oil dirty - Google Patents
Water based detergent for oil dirty Download PDFInfo
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- CN101003769A CN101003769A CN 200610161545 CN200610161545A CN101003769A CN 101003769 A CN101003769 A CN 101003769A CN 200610161545 CN200610161545 CN 200610161545 CN 200610161545 A CN200610161545 A CN 200610161545A CN 101003769 A CN101003769 A CN 101003769A
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Abstract
This invention discloses a waterborne detergent for cleaning oil stains. The detergent is composed of: oleic acid 2-10%, ethanolamine 10-20%, surfactant 10-20%, sodium metasilicate 5-10%, sodium carbonate 5-10%, sodium fluosilicate 2-4%, defoamer 0.05-0.1%, and water. The detergent has good anti-rust performance on a variety of metals and alloys, and is suitable for cleaning oil stains on metals and alloys. The detergent has good effect on oil stains of machine tools, hardware, household range hoods, and especially dark red fused-ring aromatic hydrocarbon stains in oil-refinery apparatus.
Description
Technical field
The present invention relates to a kind of clean-out system, be specially adapted to clean the water base metal cleaning agent of various metal surface greasy dirts.
Background technology
Hydrocarbon mixture and less water based cleaning agents such as still using gasoline kerosene are cleaned in China's industry at present.With hydrocarbon mixture clean-out systems such as gasoline kerosene, not only waste energy in a large number, cause environmental pollution, and clean the workman and poison easily, again very easily presence of fire and cause heavy economic losses and fatal accident.
Utilize aqueous cleaning agent, working concentration is 3～5%, and then one ton of aqueous cleaning agent can replace 20～30 tons of gasoline kerosene.If it is that aqueous cleaning agent replaces that half gasoline kerosene hydrocarbon mixture clean-out system is arranged, aqueous cleaning agent supply in year breach is about 200,000 tons more than.
Use aqueous cleaning agent, reach save energy, reduce production costs, reduce environmental pollution, fire safety progressively realizes the long-range dream of " with water for oil " having vast market prospect.
Just see at present that aqueous cleaning agent also has masses of work to do to development aspect normal temperatureization, low bubble, the efficient and multifunction.
Existing relevant Chinese patent CN1743441A " high-permeability metal cleaning agent and preparation " is primarily aimed at the antirust problem that precision instrument solves ferrous metal, the antirust problem of the difficult multiple metal that cleans of all still unresolved heavy oil stain of at present existing patent, and prior art generally all is to be prepared from being higher than under the condition of normal temperature.
Summary of the invention
Purpose of the present invention just is to realize " with water for oil ", and provides a kind of cleaning grease ability strong, low bubble, multiple metal and alloy is had the water based detergent for oil dirty of antirust ability.
Technical scheme of the present invention is: a kind of water base metal cleaning agent that cleans various metal surface greasy dirts is provided, this clean-out system can be removed bolarious condensed-nuclei aromatics grease in light, severe grease on the metallic surface and the refining equipment effectively, the method of producing this clean-out system simultaneously is simple, easily operation.It is characterized in that: make according to following weight proportion by following raw materials according:
Oleic acid 2～10%
Ethanolamines 10～20%
Tensio-active agent 10～20%
Starso 5～10%
Yellow soda ash 5～10%
Sodium Silicofluoride 2～4%
Defoamer 0.05%～0.1%
Water surplus
Ethanolamines is a kind of or its any mixture in monoethanolamine, diethanolamine, the trolamine; Tensio-active agent is a kind of or its any mixture in polyoxyethylene aliphatic alcohol ether class JFC, polyxyethylated alkylphenol class OP-10,6501, the Nekal BX.
Defoamer is a silicon oil foam killer.
The concrete preparation method of water based detergent for oil dirty of the present invention comprises following process:
1. Starso and yellow soda ash Sodium Silicofluoride are dissolved in water.
2. oleic acid, ethanolamines, the stirring reaction product is the thickness transparence under the normal temperature, adds tensio-active agent and defoamer, promptly gets the thickness transparent liquid after stirring.
3. in 2. pouring into 1., fully stir, add the water of surplus, promptly get desired product after fully stirring.
The present invention has following advantage: mechanical means, member are combined by multiple metallographic phase connection often, the soap class that the present invention is formed with oleic acid by ethanolamines, and existing cleansing power is again the rust-preventive agent that prevents the iron and steel corrosion; Benzotriazole is the inhibiter that prevents copper and alloy thereof; Sodium Silicofluoride is the inhibiter of aluminium and magnesium and alloy thereof, and experiment shows that water based detergent for oil dirty of the present invention all has rustless property preferably to iron and steel, copper, aluminium, magnesium, tin and alloy thereof; The present invention adopts self-emulsifying high effective antifoaming agent BD3037, and its froth breaking is very competent, and usage quantity is few, and the present invention 5% solution method is in accordance with regulations measured, and a few second, foam promptly disappeared; Owing to add alkali-metal carbonate and silicate among the present invention, improve the scale removal ability, the present invention is especially to difficult washing oil dirt, for example sedimentary grease of cooker hood, the old old grease of lathe, and sedimentary macromole and superpolymer dirt all have good removing ability in petroleum chemical enterprise's equipment; Water based detergent for oil dirty of the present invention can prepare at normal temperatures, saves the energy, easily operation.
Embodiment
Embodiment 1
Oleic acid 3%
Monoethanolamine 10%
Tensio-active agent: OP-10, JFC, 6501 each 6%
Starso 5%
Yellow soda ash 5%
Sodium Silicofluoride 2%
Defoamer 0.05%
Water surplus
Embodiment 2
Oleic acid 6%
Diethanolamine 15%
Tensio-active agent: OP-10,6501, BX each 6%
Starso 10%
Yellow soda ash 5%
Sodium Silicofluoride 2.5%
Defoamer 0.08%
Water surplus
Above-mentioned two embodiment are used for mechanical component such as family expenses cooker hood, the old old dirt of old lathe and bearing and clean, and effect is good, generally is made into 2%～5% solution and carries out.
Embodiment 3
Oleic acid 8%
Trolamine 20%
Tensio-active agent: 6501 BX each 10%
Starso 4%
Yellow soda ash 10%
Sodium Silicofluoride 4%
Defoamer 0.1%
Water surplus
This embodiment is used for the matting of certain refinery hydroeracking unit high-pressure air cooler A-101 grease, and the grease sample 80% is the garnet condensed-nuclei aromatics by analysis, and carbon number is about 22, and number of rings is insoluble to organic solvent, strong acid and highly basic greater than 5.Adopt the water based detergent for oil dirty of embodiment 3 prescriptions to clean, device operation back heat exchange is respond well.
Claims (2)
1. water based detergent for oil dirty, form by tensio-active agent, rust-preventive agent, inorganic alkaline auxiliary agent and water, the oleate soap class that it is characterized in that forming with oleic acid and ethanolamines process building-up reactions is as rust-preventive agent, the inorganic alkaline auxiliary agent is Starso, yellow soda ash, Sodium Silicofluoride, consisting of of water based detergent for oil dirty, by weight percentage:
Oleic acid 2～10%
Ethanolamines 10～20%
Tensio-active agent 10～20%
Starso 5～10%
Yellow soda ash 5～10%
Sodium Silicofluoride 2～4%
Defoamer 0.05～0.1%
Water surplus
2. water based detergent for oil dirty according to claim 1 is characterized in that ethanolamines is a kind of or its any mixture in monoethanolamine, diethanolamine, the trolamine; Tensio-active agent is meant that polyoxyethylene aliphatic alcohol ether class, polyxyethylated alkylphenol class and coconut oil diethanolamine and Nekal BX are a kind of or its any mixture in the sodium butylnaphthalenesulfonate; Defoamer is meant silicon oil foam killer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101615456A CN100497574C (en) | 2006-12-27 | 2006-12-27 | Water based detergent for oil dirty |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101615456A CN100497574C (en) | 2006-12-27 | 2006-12-27 | Water based detergent for oil dirty |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101003769A true CN101003769A (en) | 2007-07-25 |
| CN100497574C CN100497574C (en) | 2009-06-10 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101615456A Expired - Fee Related CN100497574C (en) | 2006-12-27 | 2006-12-27 | Water based detergent for oil dirty |
Country Status (1)
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| CN (1) | CN100497574C (en) |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102500823A (en) * | 2011-10-13 | 2012-06-20 | 四川宁江山川机械有限责任公司 | Method for replacing grinding fluid with cleaning/degreasing fluid for use on band sawing machine |
| CN102676317A (en) * | 2012-05-07 | 2012-09-19 | 安徽绿朋实业有限公司 | Multifunctional water-based oil-stain cleaning agent of automobile parts and preparation method thereof |
| CN102888298A (en) * | 2012-09-20 | 2013-01-23 | 江苏天宇石化冶金设备有限公司 | Cleaning agent for range hood |
| CN102899190A (en) * | 2012-09-28 | 2013-01-30 | 上海群乐船舶附件启东有限公司 | Range hood cleaning agent |
| CN103820793A (en) * | 2012-11-16 | 2014-05-28 | 季爱英 | Industrial dewaxing agent |
| CN104059795A (en) * | 2014-06-07 | 2014-09-24 | 滁州斯迈特复合材料有限公司 | Cleaning agent of automobile part welding machine |
| CN104264170A (en) * | 2014-09-28 | 2015-01-07 | 无锡康柏斯机械科技有限公司 | Cleaning agent for mechanical components and parts and production process of cleaning agent |
| CN104830548A (en) * | 2015-05-13 | 2015-08-12 | 吴江市震宇缝制设备有限公司 | Oil stain detergent for sewing machine overhauling |
| CN104830556A (en) * | 2015-05-20 | 2015-08-12 | 龚灿锋 | Surface cleaning agent for chemical equipment |
| CN104894582A (en) * | 2015-05-15 | 2015-09-09 | 合肥学院 | Cleaning agent for cleaning finished part after machining |
| CN104928695A (en) * | 2015-04-29 | 2015-09-23 | 安徽长城输送机械制造有限公司 | Steel material surface scrubbing liquid |
| CN106085626A (en) * | 2016-06-20 | 2016-11-09 | 李亚云 | Water base oils and fats abluent and preparation method thereof |
| CN106675818A (en) * | 2016-12-27 | 2017-05-17 | 江西宜信堂医疗科技有限公司 | Oil removing agent and preparation method thereof |
| CN107090369A (en) * | 2017-06-14 | 2017-08-25 | 苏州锐耐洁电子科技新材料有限公司 | A kind of strong cleaning agent of washability |
| CN107338072A (en) * | 2017-07-26 | 2017-11-10 | 徐文忠 | Reformer corrosion inhibiter and preparation method thereof |
| CN107354041A (en) * | 2017-08-22 | 2017-11-17 | 南通科星化工有限公司 | It is a kind of to be used to remove the cleaning agent to remove grease |
| CN107384623A (en) * | 2017-08-21 | 2017-11-24 | 马鞍山中粮生物化学有限公司 | A kind of chemical industry equipment cleaning agent and its preparation technology |
| CN107475734A (en) * | 2017-08-22 | 2017-12-15 | 南通科星化工有限公司 | A kind of cleaning agent for being used to remove grease stain on metallic surface |
| CN109535790A (en) * | 2018-11-16 | 2019-03-29 | 旭贞新能源科技(上海)有限公司 | A kind of coating suitable for antirust |
| CN110042405A (en) * | 2019-05-30 | 2019-07-23 | 廊坊师范学院 | The preparation method of aqueous low surface clean antirust one-step method treatment fluid |
| CN112813440A (en) * | 2020-12-31 | 2021-05-18 | 上海福岛新材料科技有限公司 | Water-based cleaning agent for improving coating adhesion force for coating pretreatment and preparation method thereof |
| FR3117386A1 (en) * | 2020-12-14 | 2022-06-17 | Indepsol | INJECTABLE COMPOSITION FOR DEPOLLUTION PURPOSES, METHOD FOR INJECTION AND DEVICE FOR IMPLEMENTING IT |
| CN115532802A (en) * | 2022-10-20 | 2022-12-30 | 生态环境部南京环境科学研究所 | Method for degrading and repairing PAHs in polluted soil |
| CN115772448A (en) * | 2022-12-01 | 2023-03-10 | 湖南金裕环保科技有限公司 | Ground heavy oil stain cleaning agent and preparation method thereof |
-
2006
- 2006-12-27 CN CNB2006101615456A patent/CN100497574C/en not_active Expired - Fee Related
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102500823A (en) * | 2011-10-13 | 2012-06-20 | 四川宁江山川机械有限责任公司 | Method for replacing grinding fluid with cleaning/degreasing fluid for use on band sawing machine |
| CN102676317A (en) * | 2012-05-07 | 2012-09-19 | 安徽绿朋实业有限公司 | Multifunctional water-based oil-stain cleaning agent of automobile parts and preparation method thereof |
| CN102676317B (en) * | 2012-05-07 | 2013-06-05 | 安徽绿朋实业有限公司 | Multifunctional water-based oil-stain cleaning agent of automobile parts and preparation method thereof |
| CN102888298A (en) * | 2012-09-20 | 2013-01-23 | 江苏天宇石化冶金设备有限公司 | Cleaning agent for range hood |
| CN102899190A (en) * | 2012-09-28 | 2013-01-30 | 上海群乐船舶附件启东有限公司 | Range hood cleaning agent |
| CN103820793A (en) * | 2012-11-16 | 2014-05-28 | 季爱英 | Industrial dewaxing agent |
| CN104059795A (en) * | 2014-06-07 | 2014-09-24 | 滁州斯迈特复合材料有限公司 | Cleaning agent of automobile part welding machine |
| CN104264170A (en) * | 2014-09-28 | 2015-01-07 | 无锡康柏斯机械科技有限公司 | Cleaning agent for mechanical components and parts and production process of cleaning agent |
| CN104928695A (en) * | 2015-04-29 | 2015-09-23 | 安徽长城输送机械制造有限公司 | Steel material surface scrubbing liquid |
| CN104830548A (en) * | 2015-05-13 | 2015-08-12 | 吴江市震宇缝制设备有限公司 | Oil stain detergent for sewing machine overhauling |
| CN104894582A (en) * | 2015-05-15 | 2015-09-09 | 合肥学院 | Cleaning agent for cleaning finished part after machining |
| CN104894582B (en) * | 2015-05-15 | 2017-11-17 | 合肥学院 | The cleaning agent that a kind of component end item to after machining is cleaned |
| CN104830556A (en) * | 2015-05-20 | 2015-08-12 | 龚灿锋 | Surface cleaning agent for chemical equipment |
| CN106085626A (en) * | 2016-06-20 | 2016-11-09 | 李亚云 | Water base oils and fats abluent and preparation method thereof |
| CN106675818A (en) * | 2016-12-27 | 2017-05-17 | 江西宜信堂医疗科技有限公司 | Oil removing agent and preparation method thereof |
| CN107090369A (en) * | 2017-06-14 | 2017-08-25 | 苏州锐耐洁电子科技新材料有限公司 | A kind of strong cleaning agent of washability |
| CN107338072B (en) * | 2017-07-26 | 2019-09-13 | 徐文忠 | Reformer corrosion inhibiter and preparation method thereof |
| CN107338072A (en) * | 2017-07-26 | 2017-11-10 | 徐文忠 | Reformer corrosion inhibiter and preparation method thereof |
| CN107384623A (en) * | 2017-08-21 | 2017-11-24 | 马鞍山中粮生物化学有限公司 | A kind of chemical industry equipment cleaning agent and its preparation technology |
| CN107354041A (en) * | 2017-08-22 | 2017-11-17 | 南通科星化工有限公司 | It is a kind of to be used to remove the cleaning agent to remove grease |
| CN107475734A (en) * | 2017-08-22 | 2017-12-15 | 南通科星化工有限公司 | A kind of cleaning agent for being used to remove grease stain on metallic surface |
| CN109535790A (en) * | 2018-11-16 | 2019-03-29 | 旭贞新能源科技(上海)有限公司 | A kind of coating suitable for antirust |
| CN110042405A (en) * | 2019-05-30 | 2019-07-23 | 廊坊师范学院 | The preparation method of aqueous low surface clean antirust one-step method treatment fluid |
| FR3117386A1 (en) * | 2020-12-14 | 2022-06-17 | Indepsol | INJECTABLE COMPOSITION FOR DEPOLLUTION PURPOSES, METHOD FOR INJECTION AND DEVICE FOR IMPLEMENTING IT |
| CN112813440A (en) * | 2020-12-31 | 2021-05-18 | 上海福岛新材料科技有限公司 | Water-based cleaning agent for improving coating adhesion force for coating pretreatment and preparation method thereof |
| CN115532802A (en) * | 2022-10-20 | 2022-12-30 | 生态环境部南京环境科学研究所 | Method for degrading and repairing PAHs in polluted soil |
| CN115772448A (en) * | 2022-12-01 | 2023-03-10 | 湖南金裕环保科技有限公司 | Ground heavy oil stain cleaning agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100497574C (en) | 2009-06-10 |
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Legal Events
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090610 Termination date: 20121227 |
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| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20070725 Assignee: Zhenjiang Huayin Printed Circuit Board Co., Ltd. Assignor: Jiangsu University of Science and Technology Contract record no.: 2010320000718 Denomination of invention: Water based detergent for oil dirty Granted publication date: 20090610 License type: Exclusive License Record date: 20100602 |
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| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model |