CN101012115A - Oily soil surface concrete adhesive, preparing method and using method - Google Patents
Oily soil surface concrete adhesive, preparing method and using method Download PDFInfo
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- CN101012115A CN101012115A CN 200710036908 CN200710036908A CN101012115A CN 101012115 A CN101012115 A CN 101012115A CN 200710036908 CN200710036908 CN 200710036908 CN 200710036908 A CN200710036908 A CN 200710036908A CN 101012115 A CN101012115 A CN 101012115A
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- soil surface
- oily soil
- oil
- concrete adhesive
- surface concrete
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Abstract
The invention discloses an oil concrete additive, making method and using method in the architectural material technical domain, which is characterized by the following: adopting bisphenol A typed epoxide resin as base resin and low-molecular polyamide as hardener; adding PVC resin as oil-adsorbing fill; adopting ethinyltrichloride or chloroform as surface processor; obtaining the product with maximum positive strength at 1.91-3.14Mpa.
Description
Technical field
The invention belongs to building material technical field, be specifically related to a kind of oily soil surface concrete adhesive, preparation method and using method.
Background technology
The crack of concrete building structures, breakage are ubiquitous problems, and it is aging that data shows that China has at least 40% concrete structure to face, undercapacity, the problem that weather resistance and security are low excessively, need improve weather resistance to these structural strengthening and repairings, guarantee normally to use.Adopting polymkeric substance or polymer mortar is more advanced concrete structure recovery technique at present, and having bonding, stressed evenly cohesive force is strong, and is easy to use, short construction period, plurality of advantages such as it is in extensive range to bond.But concrete structure in factory, workshop and oil storage facility is in case generation damages or cracking tends to by oil pollution.Just can't remove because in a single day concrete porous structure, greasy dirt infiltrate, greasy dirt kind in the while varying environment, greasy dirt content is had nothing in common with each other again, and these are all given and use the damage of general polymer rehabilitating concrete to cause very big difficulty.
The bonding of greasy dirt flooring results from automotive industry the earliest, and its use can be removed degreasing metal surface from, and steps such as cleaning are saved cost, raise the efficiency.Pasta glue in using at present mainly is divided into 4 types: chlorine dibutyl glue kinds putty type tackiness agent, polyvinyl chloride (PVC) RESINS class putty type tackiness agent, epoxies tackiness agent, modified acrylic ester adhesion agent.
Above adhesive for oily surface generally is used for the surface has the smeary metal with the bonding between other cleaning materials, and service requirements metal surface greasy dirt thickness is not more than 25 μ m.But the matrix material of oil-containing concrete structure does not appear in the newspapers as yet.
Summary of the invention
The object of the present invention is to provide a kind of oily soil surface concrete adhesive, preparation method and using method.
The oily soil surface concrete adhesive that the present invention proposes is made up of Resins, epoxy, solidifying agent, coupling agent, oil-absorbing resin and surperficial molten finish, and each composition weight umber is:
The composition weight umber
Resins, epoxy 100
Solidifying agent 40~70
Coupling agent 4~6
Oil-absorbing resin 30~40
Molten oil assistant is an amount of.
Among the present invention, can also add proper amount of diluting.
Among the present invention, described thinner is reactive thinner 501 (epoxy propane butyl ether).
Among the present invention, described Resins, epoxy is bisphenol A type epoxy resin, as Resins, epoxy E-51 etc.
Among the present invention, described solidifying agent is a low molecular polyamides, as polyamide 6 51 etc.
Among the present invention, described coupling agent is a silane coupling agent, as KH-550 etc.
Among the present invention, described oil-absorbing resin is a polyvinyl chloride resin, sticks with paste P450 etc. as polyvinyl chloride resin.
Among the present invention, the molten oil assistant in described surface is trieline or chloroform etc.
The preparation method of the oily soil surface concrete adhesive that the present invention proposes, concrete steps are: accurate by weight ratio weighing Resins, epoxy, solidifying agent, coupling agent and thinner (the thinner consumption suitably changes according to environment for use or do not use), place container to stir, add oil-absorbing resin again, putting into mortar after stirring grinds, until the resin homodisperse, promptly get desired product.
The using method of the oily soil surface concrete adhesive that the present invention proposes, concrete steps are:
(1) zone of damage is arranged for the surface, dry the molten oil assistant of spraying behind the surperficial oil stain earlier, pour the tackiness agent colloid then into until filling up defect area.
(2) for the distress in concrete zone, dry up residual greasy dirt in the seam with air compressor earlier, the molten oil assistant of sprayed surface adopts pumping injection or hand dropping mode to pour into tackiness agent according to the fracture spaces position at last again.
The present invention has following advantage:
1, can solidify existing under the smeary environment, solidify the back concrete material is had higher cohesive force.General greasy dirt concrete is just drawing cohesive strength can reach 1.91~3.14MPa.Can be used for factory, the grouting leak-stopping and the reinforcement of workshop and oil storage place concrete structure damage reparation or distress in concrete.
2, starting material are Industrial products, be simple and easy to, preparation is convenient, can be according to concrete degree of impairment with using with joining, and constructing operation is easy.
3, be widely used, for common lubricating oil, sewing-machine oil, the concrete of the different pollution by oils of hydropress wet goods all has unusual effect.
Embodiment
Below in conjunction with concrete test examples the present invention being prepared service condition describes.
Embodiment 1:
Bonding substrates is a standard C
30Mortar, maintenance standing and drying in the air after 28 days immerses in the common lubricating oil greater than 48 hours before the test in the water.Scrape after base material is taken out from oil before the bonding and do surperficial oil slick, be coated with glue bond behind the spraying trieline.The colloidal materials specification sees Table 1, and material mixture ratio and performance see Table 2.
Table 1 pasta collagen material source
Material | The specification or the trade mark | The source |
Resins, epoxy | Bisphenol A type epoxy resin E-51 | Huge Xinghua, Shanghai worker company limited |
Solidifying agent | Low molecular polyamides 651 | Huge Xinghua, Shanghai worker company limited |
Coupling agent | Silane coupling agent KH-550 | Huge Xinghua, Shanghai worker company limited |
Oil-absorbing resin | Polyvinyl chloride resin lake P450 | Tianyuan Chemical Plant., Shanghai |
Table 2 pasta glue pollutes the bonding of mortar to common lubricating oil
Project | Proportioning | |
The material usage mass fraction | Resins, epoxy | 100 |
Solidifying agent | 60 | |
Coupling agent | 4 | |
Polyvinyl chloride resin | 30 | |
Thinner | 0 | |
Performance | The curing conservation time | 3 days |
Tensile bond strength | 2.58MPa | |
Collapse mode | Adhere to and destroy |
Embodiment 2
Mortar immerses in the antiwear hydraulic oil, and base material working method and bonding using method are with embodiment 1, and the colloidal materials specification sees Table 1.
Project | Proportioning | |
The material usage mass fraction | Resins, epoxy | 100 |
Solidifying agent | 40 | |
Coupling agent | 5 | |
Polyvinyl chloride resin | 35 | |
Thinner | 0 | |
Performance | The curing conservation time | 3 days |
Tensile bond strength | 3.14MPa | |
Collapse mode | The base material cohesive failure |
Embodiment 3:
Mortar immerses in the antiwear hydraulic oil, and base material working method and bonding using method are with embodiment 1, and the colloidal materials specification sees Table 1.
Project | Proportioning | |
The material usage mass fraction | Resins, epoxy | 100 |
Solidifying agent | 60 | |
Coupling agent | 6 | |
Polyvinyl chloride resin | 40 | |
Thinner | 20 | |
Performance | The curing conservation time | 3 days |
Tensile bond strength | 1.91MPa | |
Collapse mode | Adhere to and destroy |
Embodiment 4:
Mortar immerses in the antiwear hydraulic oil, and base material working method and bonding using method are with embodiment 1, and the colloidal materials specification sees Table 1.
Project | Proportioning | |
The material usage mass fraction | Resins, epoxy | 100 |
Solidifying agent | 70 | |
Coupling agent | 5 | |
Polyvinyl chloride resin | 40 | |
Thinner | 0 | |
Performance | The curing conservation time | 3 days |
Tensile bond strength | 2.02MPa | |
Collapse mode | Adhere to and destroy |
Claims (10)
1, a kind of oily soil surface concrete adhesive is characterized in that being made up of Resins, epoxy, solidifying agent, coupling agent, oil-absorbing resin and surperficial molten finish, and each composition weight umber is:
The composition weight umber
Resins, epoxy 100
Solidifying agent 40~70
Coupling agent 4~6
Oil-absorbing resin 30~40
Molten oil assistant is an amount of.
2, oily soil surface concrete adhesive according to claim 1 is characterized in that also adding proper amount of diluting.
3, oily soil surface concrete adhesive according to claim 2 is characterized in that thinner adopts epoxy propane butyl ether.
4, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that described Resins, epoxy is bisphenol A type epoxy resin.
5, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that described solidifying agent is a low molecular polyamides.
6, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that described coupling agent is a silane coupling agent.
7, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that described oil-absorbing resin is a polyvinyl chloride resin.
8, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that the molten oil assistant in described surface is trieline or chloroform.
9, a kind of preparation method of oily soil surface concrete adhesive, it is characterized in that concrete steps are: accurate by weight ratio weighing Resins, epoxy, solidifying agent, coupling agent and thinner, place container to stir, add oil-absorbing resin again, putting into mortar after stirring grinds, until the resin homodisperse, promptly get desired product.
10, a kind of using method of oily soil surface concrete adhesive is characterized in that concrete steps are:
(1) zone of damage is arranged for the surface, dry the molten oil assistant of spraying behind the surperficial oil stain earlier, pour the tackiness agent colloid then into until filling up defect area.
(2) for the distress in concrete zone, dry up residual greasy dirt in the seam with air compressor earlier, the molten oil assistant of sprayed surface adopts pumping injection or hand dropping mode to pour into tackiness agent according to the fracture spaces position at last again.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200710036908 CN101012115A (en) | 2007-01-29 | 2007-01-29 | Oily soil surface concrete adhesive, preparing method and using method |
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CN 200710036908 CN101012115A (en) | 2007-01-29 | 2007-01-29 | Oily soil surface concrete adhesive, preparing method and using method |
Publications (1)
Publication Number | Publication Date |
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CN101012115A true CN101012115A (en) | 2007-08-08 |
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CN 200710036908 Pending CN101012115A (en) | 2007-01-29 | 2007-01-29 | Oily soil surface concrete adhesive, preparing method and using method |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104464867A (en) * | 2014-12-03 | 2015-03-25 | 中国工程物理研究院材料研究所 | Preparation method of high-strength cement solidifying body for radioactive used oil |
CN106398419A (en) * | 2016-07-08 | 2017-02-15 | 天津米科技有限公司 | An oil-absorbing and oil-blocking interface agent for concrete surfaces |
-
2007
- 2007-01-29 CN CN 200710036908 patent/CN101012115A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104464867A (en) * | 2014-12-03 | 2015-03-25 | 中国工程物理研究院材料研究所 | Preparation method of high-strength cement solidifying body for radioactive used oil |
CN104464867B (en) * | 2014-12-03 | 2017-03-15 | 中国工程物理研究院材料研究所 | A kind of preparation method of Spent Radioactive machine oil high strength cement firming body |
CN106398419A (en) * | 2016-07-08 | 2017-02-15 | 天津米科技有限公司 | An oil-absorbing and oil-blocking interface agent for concrete surfaces |
CN106398419B (en) * | 2016-07-08 | 2019-06-28 | 天津米一科技有限公司 | A kind of concrete surface oil suction oil resistance interfacial agents |
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