CN101012115A - Oily soil surface concrete adhesive, preparing method and using method - Google Patents

Oily soil surface concrete adhesive, preparing method and using method Download PDF

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Publication number
CN101012115A
CN101012115A CN 200710036908 CN200710036908A CN101012115A CN 101012115 A CN101012115 A CN 101012115A CN 200710036908 CN200710036908 CN 200710036908 CN 200710036908 A CN200710036908 A CN 200710036908A CN 101012115 A CN101012115 A CN 101012115A
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CN
China
Prior art keywords
soil surface
oily soil
oil
concrete adhesive
surface concrete
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 200710036908
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Chinese (zh)
Inventor
钟世云
苗永志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongji University
Original Assignee
Tongji University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongji University filed Critical Tongji University
Priority to CN 200710036908 priority Critical patent/CN101012115A/en
Publication of CN101012115A publication Critical patent/CN101012115A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an oil concrete additive, making method and using method in the architectural material technical domain, which is characterized by the following: adopting bisphenol A typed epoxide resin as base resin and low-molecular polyamide as hardener; adding PVC resin as oil-adsorbing fill; adopting ethinyltrichloride or chloroform as surface processor; obtaining the product with maximum positive strength at 1.91-3.14Mpa.

Description

Oily soil surface concrete adhesive, preparation method and using method
Technical field
The invention belongs to building material technical field, be specifically related to a kind of oily soil surface concrete adhesive, preparation method and using method.
Background technology
The crack of concrete building structures, breakage are ubiquitous problems, and it is aging that data shows that China has at least 40% concrete structure to face, undercapacity, the problem that weather resistance and security are low excessively, need improve weather resistance to these structural strengthening and repairings, guarantee normally to use.Adopting polymkeric substance or polymer mortar is more advanced concrete structure recovery technique at present, and having bonding, stressed evenly cohesive force is strong, and is easy to use, short construction period, plurality of advantages such as it is in extensive range to bond.But concrete structure in factory, workshop and oil storage facility is in case generation damages or cracking tends to by oil pollution.Just can't remove because in a single day concrete porous structure, greasy dirt infiltrate, greasy dirt kind in the while varying environment, greasy dirt content is had nothing in common with each other again, and these are all given and use the damage of general polymer rehabilitating concrete to cause very big difficulty.
The bonding of greasy dirt flooring results from automotive industry the earliest, and its use can be removed degreasing metal surface from, and steps such as cleaning are saved cost, raise the efficiency.Pasta glue in using at present mainly is divided into 4 types: chlorine dibutyl glue kinds putty type tackiness agent, polyvinyl chloride (PVC) RESINS class putty type tackiness agent, epoxies tackiness agent, modified acrylic ester adhesion agent.
Above adhesive for oily surface generally is used for the surface has the smeary metal with the bonding between other cleaning materials, and service requirements metal surface greasy dirt thickness is not more than 25 μ m.But the matrix material of oil-containing concrete structure does not appear in the newspapers as yet.
Summary of the invention
The object of the present invention is to provide a kind of oily soil surface concrete adhesive, preparation method and using method.
The oily soil surface concrete adhesive that the present invention proposes is made up of Resins, epoxy, solidifying agent, coupling agent, oil-absorbing resin and surperficial molten finish, and each composition weight umber is:
The composition weight umber
Resins, epoxy 100
Solidifying agent 40~70
Coupling agent 4~6
Oil-absorbing resin 30~40
Molten oil assistant is an amount of.
Among the present invention, can also add proper amount of diluting.
Among the present invention, described thinner is reactive thinner 501 (epoxy propane butyl ether).
Among the present invention, described Resins, epoxy is bisphenol A type epoxy resin, as Resins, epoxy E-51 etc.
Among the present invention, described solidifying agent is a low molecular polyamides, as polyamide 6 51 etc.
Among the present invention, described coupling agent is a silane coupling agent, as KH-550 etc.
Among the present invention, described oil-absorbing resin is a polyvinyl chloride resin, sticks with paste P450 etc. as polyvinyl chloride resin.
Among the present invention, the molten oil assistant in described surface is trieline or chloroform etc.
The preparation method of the oily soil surface concrete adhesive that the present invention proposes, concrete steps are: accurate by weight ratio weighing Resins, epoxy, solidifying agent, coupling agent and thinner (the thinner consumption suitably changes according to environment for use or do not use), place container to stir, add oil-absorbing resin again, putting into mortar after stirring grinds, until the resin homodisperse, promptly get desired product.
The using method of the oily soil surface concrete adhesive that the present invention proposes, concrete steps are:
(1) zone of damage is arranged for the surface, dry the molten oil assistant of spraying behind the surperficial oil stain earlier, pour the tackiness agent colloid then into until filling up defect area.
(2) for the distress in concrete zone, dry up residual greasy dirt in the seam with air compressor earlier, the molten oil assistant of sprayed surface adopts pumping injection or hand dropping mode to pour into tackiness agent according to the fracture spaces position at last again.
The present invention has following advantage:
1, can solidify existing under the smeary environment, solidify the back concrete material is had higher cohesive force.General greasy dirt concrete is just drawing cohesive strength can reach 1.91~3.14MPa.Can be used for factory, the grouting leak-stopping and the reinforcement of workshop and oil storage place concrete structure damage reparation or distress in concrete.
2, starting material are Industrial products, be simple and easy to, preparation is convenient, can be according to concrete degree of impairment with using with joining, and constructing operation is easy.
3, be widely used, for common lubricating oil, sewing-machine oil, the concrete of the different pollution by oils of hydropress wet goods all has unusual effect.
Embodiment
Below in conjunction with concrete test examples the present invention being prepared service condition describes.
Embodiment 1:
Bonding substrates is a standard C 30Mortar, maintenance standing and drying in the air after 28 days immerses in the common lubricating oil greater than 48 hours before the test in the water.Scrape after base material is taken out from oil before the bonding and do surperficial oil slick, be coated with glue bond behind the spraying trieline.The colloidal materials specification sees Table 1, and material mixture ratio and performance see Table 2.
Table 1 pasta collagen material source
Material The specification or the trade mark The source
Resins, epoxy Bisphenol A type epoxy resin E-51 Huge Xinghua, Shanghai worker company limited
Solidifying agent Low molecular polyamides 651 Huge Xinghua, Shanghai worker company limited
Coupling agent Silane coupling agent KH-550 Huge Xinghua, Shanghai worker company limited
Oil-absorbing resin Polyvinyl chloride resin lake P450 Tianyuan Chemical Plant., Shanghai
Table 2 pasta glue pollutes the bonding of mortar to common lubricating oil
Project Proportioning
The material usage mass fraction Resins, epoxy 100
Solidifying agent 60
Coupling agent 4
Polyvinyl chloride resin 30
Thinner 0
Performance The curing conservation time 3 days
Tensile bond strength 2.58MPa
Collapse mode Adhere to and destroy
Embodiment 2
Mortar immerses in the antiwear hydraulic oil, and base material working method and bonding using method are with embodiment 1, and the colloidal materials specification sees Table 1.
Project Proportioning
The material usage mass fraction Resins, epoxy 100
Solidifying agent 40
Coupling agent 5
Polyvinyl chloride resin 35
Thinner 0
Performance The curing conservation time 3 days
Tensile bond strength 3.14MPa
Collapse mode The base material cohesive failure
Embodiment 3:
Mortar immerses in the antiwear hydraulic oil, and base material working method and bonding using method are with embodiment 1, and the colloidal materials specification sees Table 1.
Project Proportioning
The material usage mass fraction Resins, epoxy 100
Solidifying agent 60
Coupling agent 6
Polyvinyl chloride resin 40
Thinner 20
Performance The curing conservation time 3 days
Tensile bond strength 1.91MPa
Collapse mode Adhere to and destroy
Embodiment 4:
Mortar immerses in the antiwear hydraulic oil, and base material working method and bonding using method are with embodiment 1, and the colloidal materials specification sees Table 1.
Project Proportioning
The material usage mass fraction Resins, epoxy 100
Solidifying agent 70
Coupling agent 5
Polyvinyl chloride resin 40
Thinner 0
Performance The curing conservation time 3 days
Tensile bond strength 2.02MPa
Collapse mode Adhere to and destroy

Claims (10)

1, a kind of oily soil surface concrete adhesive is characterized in that being made up of Resins, epoxy, solidifying agent, coupling agent, oil-absorbing resin and surperficial molten finish, and each composition weight umber is:
The composition weight umber
Resins, epoxy 100
Solidifying agent 40~70
Coupling agent 4~6
Oil-absorbing resin 30~40
Molten oil assistant is an amount of.
2, oily soil surface concrete adhesive according to claim 1 is characterized in that also adding proper amount of diluting.
3, oily soil surface concrete adhesive according to claim 2 is characterized in that thinner adopts epoxy propane butyl ether.
4, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that described Resins, epoxy is bisphenol A type epoxy resin.
5, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that described solidifying agent is a low molecular polyamides.
6, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that described coupling agent is a silane coupling agent.
7, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that described oil-absorbing resin is a polyvinyl chloride resin.
8, oily soil surface concrete adhesive according to claim 1 and 2 is characterized in that the molten oil assistant in described surface is trieline or chloroform.
9, a kind of preparation method of oily soil surface concrete adhesive, it is characterized in that concrete steps are: accurate by weight ratio weighing Resins, epoxy, solidifying agent, coupling agent and thinner, place container to stir, add oil-absorbing resin again, putting into mortar after stirring grinds, until the resin homodisperse, promptly get desired product.
10, a kind of using method of oily soil surface concrete adhesive is characterized in that concrete steps are:
(1) zone of damage is arranged for the surface, dry the molten oil assistant of spraying behind the surperficial oil stain earlier, pour the tackiness agent colloid then into until filling up defect area.
(2) for the distress in concrete zone, dry up residual greasy dirt in the seam with air compressor earlier, the molten oil assistant of sprayed surface adopts pumping injection or hand dropping mode to pour into tackiness agent according to the fracture spaces position at last again.
CN 200710036908 2007-01-29 2007-01-29 Oily soil surface concrete adhesive, preparing method and using method Pending CN101012115A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200710036908 CN101012115A (en) 2007-01-29 2007-01-29 Oily soil surface concrete adhesive, preparing method and using method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200710036908 CN101012115A (en) 2007-01-29 2007-01-29 Oily soil surface concrete adhesive, preparing method and using method

Publications (1)

Publication Number Publication Date
CN101012115A true CN101012115A (en) 2007-08-08

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200710036908 Pending CN101012115A (en) 2007-01-29 2007-01-29 Oily soil surface concrete adhesive, preparing method and using method

Country Status (1)

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CN (1) CN101012115A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104464867A (en) * 2014-12-03 2015-03-25 中国工程物理研究院材料研究所 Preparation method of high-strength cement solidifying body for radioactive used oil
CN106398419A (en) * 2016-07-08 2017-02-15 天津米科技有限公司 An oil-absorbing and oil-blocking interface agent for concrete surfaces

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104464867A (en) * 2014-12-03 2015-03-25 中国工程物理研究院材料研究所 Preparation method of high-strength cement solidifying body for radioactive used oil
CN104464867B (en) * 2014-12-03 2017-03-15 中国工程物理研究院材料研究所 A kind of preparation method of Spent Radioactive machine oil high strength cement firming body
CN106398419A (en) * 2016-07-08 2017-02-15 天津米科技有限公司 An oil-absorbing and oil-blocking interface agent for concrete surfaces
CN106398419B (en) * 2016-07-08 2019-06-28 天津米一科技有限公司 A kind of concrete surface oil suction oil resistance interfacial agents

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