CN100999603A - Light non-toxic plasticine and preparation process thereof - Google Patents
Light non-toxic plasticine and preparation process thereof Download PDFInfo
- Publication number
- CN100999603A CN100999603A CN 200710066623 CN200710066623A CN100999603A CN 100999603 A CN100999603 A CN 100999603A CN 200710066623 CN200710066623 CN 200710066623 CN 200710066623 A CN200710066623 A CN 200710066623A CN 100999603 A CN100999603 A CN 100999603A
- Authority
- CN
- China
- Prior art keywords
- plasticine
- toxic
- water
- light non
- acrylonitrile copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 231100000252 nontoxic Toxicity 0.000 title claims abstract description 22
- 230000003000 nontoxic effect Effects 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910021538 borax Inorganic materials 0.000 claims abstract description 18
- 235000011187 glycerol Nutrition 0.000 claims abstract description 18
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 18
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 18
- 239000003755 preservative agent Substances 0.000 claims abstract description 17
- 230000002335 preservative effect Effects 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004793 Polystyrene Substances 0.000 claims abstract description 14
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- 229920002223 polystyrene Polymers 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- 238000005187 foaming Methods 0.000 claims abstract description 10
- 229920001577 copolymer Polymers 0.000 claims description 13
- 230000029087 digestion Effects 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 claims description 4
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 claims description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000000945 filler Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 101100325962 Arabidopsis thaliana BHLH80 gene Proteins 0.000 description 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 210000001747 pupil Anatomy 0.000 description 1
- 239000012173 sealing wax Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Abstract
The present invention relates to one kind of children's toy plasticine and its preparation process. The light non-toxic toy plasticine consists of polystyrene acrylonitile through high temperature foaming treatment 3-10 wt%, polyvinyl alcohol 10-30 wt%, borax 0.01-0.05 wt%, glycerin 1-8 %, water base preservative 0.01-0.15 wt% and water for the rest. The present invention has the advantages of light weight, bright color, good hand feeling, etc. and may be used as children's toy, in making model, sculpture draft, etc.
Description
Technical field
The present invention relates to a kind of children's toy plasticine and preparation method thereof.
Background technology
Traditional plasticine major ingredient comprises animal tallow leftover bits and pieces, old powder, terra alba, sealing wax and rubber etc.It exists, and color is gloomy, temperature difference bad adaptability, and cold day is hard and pinch motionlessly, and hot day is soft and easy sending out stuck with paste sticking hand, pollutes, and existence that main is has been forbidden using in primary school, kindergarten by certain toxicity that its component causes.In addition, the employed filler of existing plasticine is generally flour or lime carbonate etc., and the density of its product is big, takes material, the production cost height.
Summary of the invention
In order to solve the technical problem that above-mentioned plasticine exists, an object of the present invention is to provide a kind of lightweight, bright in luster, temperature difference adaptability strong, the children's toy plasticine of safety non-toxic.
In addition, another object of the present invention has provided the preparation method of above-mentioned children's toy plasticine.
In order to realize first above-mentioned technical purpose, the present invention has adopted following technical scheme:
A kind of light non-toxic plasticine comprises following component by weight percentage: polystyrene acrylonitrile copolymer 3～10%, and polyvinyl alcohol 10～30%, borax 0.01～0.05%, glycerine 1～8%, water-borne preservative 0.01～0.15%, surplus is a water; Wherein said polystyrene acrylonitrile copolymer is handled through the high temperature foaming.
As preferably, above-mentioned light non-toxic plasticine comprises following component by weight percentage: polystyrene acrylonitrile copolymer 4～8%, polyvinyl alcohol 15～25%, borax 0.01～0.03%, glycerine 1～5%, water-borne preservative 0.01～0.10%.
As most preferably, above-mentioned light non-toxic plasticine comprises following component by weight percentage: polystyrene acrylonitrile copolymer 5%, polyvinyl alcohol 20%, borax 0.02%, glycerine 4%, water-borne preservative 0.08%.
Above-mentioned light non-toxic plasticine also comprises pigment, and described pigment can be selected from Lithol Red, medium chrome yellow medium yellow, phthalein Pulan, phthalein viridescent, black, the basic rhodamine of hydroxyl material.
Above-mentioned light non-toxic plasticine also comprises essence, and essence can be common commercially available essence.Certain plasticine composition of the present invention can be made of above-mentioned major ingredient merely, also can add other auxiliary material.
In order to realize second above-mentioned technical purpose, the present invention has adopted following technical scheme:
A kind of preparation method of light non-toxic plasticine is characterized in that comprising the steps:
(1) with the foaming of styrene acrylonitrile copolymer high temperature, temperature is 100～150 ℃;
(2) polyvinyl alcohol, water high-temperature digestion, temperature is 90～110 ℃;
(3) solution that above-mentioned step (1) and step (2) are made mixes, and adds glycerine, regulates pH value with borax again, adds water-borne preservative then, mixes.
The present invention is colloid with the polyvinyl alcohol, and polystyrene acrylonitrile copolymer foaming thing is a filler, the finished product lightweight, temperature difference adaptability is strong, safety non-toxic, added pigment after product color bright-coloured.The present invention has used 0.01～0.05% borax to be used to regulate pH value, and the soft durometer of control product makes the product have good hand feeling.In addition, the present invention is the water content high product, so the present invention's viscosity of having used 1～8% glycerine to be used to regulate product, keeps moisture content not lose simultaneously.
Compare with traditional plasticine, outstanding advantage of the present invention is: lightweight; Bright in luster; Good hand touch, soft tough, fine and smooth, lubricated, tack-free; Temperature difference adaptability is strong; Nontoxic, pollution-free; Cost is low.After tested, product of the present invention meets the requirement of GB6675-86 (Chinese toy safety standards) standard, EN71 (European toy safety standard) and ASTM-F963 (U.S. test association toy safety standard).Plasticine of the present invention can be used as child, pupil's toy, teaching aid, also can be applicable to aspects such as Modelling, sculpture draft, mould examination type.
Embodiment
Embodiment 1
A kind of light non-toxic plasticine, component by weight percentage is as follows:
Polystyrene acrylonitrile copolymer 5%, polyvinyl alcohol 20%, borax 0.02%, glycerine 4%, water-borne preservative 0.08%, surplus is a water.
The production technique of this product is as follows:
(1) with the foaming of styrene acrylonitrile copolymer high temperature, temperature is 120 ℃;
(2) polyethylene alcohol and water high-temperature digestion, temperature are 100 ℃;
(3) solution that above-mentioned step (1) and step (2) are made mixes, and adds glycerine, adds borax again and regulates pH value, adds water-borne preservative then, mixes cooling.
Embodiment 2
A kind of light non-toxic plasticine, component by weight percentage is as follows:
Polystyrene acrylonitrile copolymer 8%, polyvinyl alcohol 15%, borax 0.03%, glycerine 3%, water-borne preservative 0.03%, essence, Lithol Red are an amount of, and surplus is a water.
The production technique of this product is as follows:
(1) with the foaming of styrene acrylonitrile copolymer high temperature, temperature is 150 ℃;
(2) polyethylene alcohol and water high-temperature digestion, temperature are 100 ℃;
(3) solution that above-mentioned step (1) and step (2) are made mixes, and adds glycerine, adds borax again and regulates pH value, adds water-borne preservative, essence and Lithol Red then, mixes cooling.
Embodiment 3
A kind of light non-toxic plasticine, component by weight percentage is as follows:
Polystyrene acrylonitrile copolymer 10%, polyvinyl alcohol 25%, borax 0.04%, glycerine 8%, water-borne preservative 0.1%, phthalein is dark green an amount of, and surplus is a water.
The production technique of this product is as follows:
(1) with the foaming of styrene acrylonitrile copolymer high temperature, temperature is 100 ℃;
(2) polyethylene alcohol and water high-temperature digestion, temperature are 100 ℃;
(3) solution that above-mentioned step (1) and step (2) are made mixes, and adds glycerine, adds borax again and regulates pH value, adds water-borne preservative and phthalein viridescent then, mixes cooling.
Embodiment 4
A kind of light non-toxic plasticine, component by weight percentage is as follows:
Polystyrene acrylonitrile copolymer 6%, polyvinyl alcohol 20%, borax 0.02%, glycerine 3%, water-borne preservative 0.05%, the hydroxyl material is black an amount of, and surplus is a water.
The production technique of this product is as follows:
(1) with the foaming of styrene acrylonitrile copolymer high temperature, temperature is 100 ℃;
(2) polyethylene alcohol and water high-temperature digestion, temperature are 100 ℃;
(3) solution that above-mentioned step (1) and step (2) are made mixes, and adds glycerine, adds borax again and regulates pH value, and it is black to add water-borne preservative and hydroxyl material then, mixes cooling.
Claims (6)
1. light non-toxic plasticine is characterized in that comprising by weight percentage following component:
Polystyrene acrylonitrile copolymer 3～10%
Polyvinyl alcohol 10～30%
Borax 0.01～0.05%
Glycerine 1～8%
Water-borne preservative 0.01～0.15%,
Surplus is a water; Wherein said polystyrene acrylonitrile copolymer is handled through the high temperature foaming.
2. a kind of light non-toxic plasticine according to claim 1 is characterized in that comprising by weight percentage following component:
Polystyrene acrylonitrile copolymer 4～8%
Polyvinyl alcohol 15～25%
Borax 0.01～0.03%
Glycerine 1～5%
Water-borne preservative 0.01～0.10%.
3. a kind of light non-toxic plasticine according to claim 1 is characterized in that comprising by weight percentage following component:
Polystyrene acrylonitrile copolymer 5%
Polyvinyl alcohol 20%
Borax 0.02%
Glycerine 4%
Water-borne preservative 0.08%.
4. according to the described a kind of light non-toxic plasticine of any claim of claim 1～3, it is characterized in that described component also comprises pigment, describedly can be selected from that Lithol Red, medium chrome yellow medium yellow, phthalein Pulan, phthalein viridescent, hydroxyl material are black, basic rhodamine.
5. according to the described a kind of light non-toxic plasticine of any claim of claim 1～3, it is characterized in that described component also comprises essence.
6. the preparation method of a kind of light non-toxic plasticine according to claim 1 is characterized in that comprising the steps:
(1) with the foaming of styrene acrylonitrile copolymer high temperature, temperature is 100～150 ℃;
(2) polyvinyl alcohol, water high-temperature digestion, temperature is 90～110 ℃;
(3) solution that above-mentioned step (1) and step (2) are made mixes, and adds glycerine, regulates pH value with borax again, adds water-borne preservative then, mixes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100666239A CN100447195C (en) | 2007-01-08 | 2007-01-08 | Light non-toxic plasticine and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100666239A CN100447195C (en) | 2007-01-08 | 2007-01-08 | Light non-toxic plasticine and preparation process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN100999603A true CN100999603A (en) | 2007-07-18 |
| CN100447195C CN100447195C (en) | 2008-12-31 |
Family
ID=38258433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100666239A Expired - Fee Related CN100447195C (en) | 2007-01-08 | 2007-01-08 | Light non-toxic plasticine and preparation process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100447195C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101913808A (en) * | 2010-07-30 | 2010-12-15 | 邢春生 | Toy clay and preparation method thereof |
| CN102010524A (en) * | 2009-09-08 | 2011-04-13 | 真彩文具有限公司 | Non-toxic color mud |
| CN104446643A (en) * | 2014-10-29 | 2015-03-25 | 武汉艾迪创研科技有限公司 | Active restoring agent capable of restoring original appearance of space sand and preparation method of active restoring agent |
| CN104692716A (en) * | 2013-12-07 | 2015-06-10 | 招远鲁娃婴幼儿用品有限公司 | Toy clay |
| CN104877285A (en) * | 2014-02-28 | 2015-09-02 | 宁波宝林达进出口有限公司 | Cotton mud preparation process |
| CN110204841A (en) * | 2019-03-26 | 2019-09-06 | 周平 | Children's craft plasticine and preparation method thereof |
| CN115819906A (en) * | 2021-12-30 | 2023-03-21 | 义乌聚邦玩具有限公司 | Crackling mastic composition |
| CN115819905A (en) * | 2021-12-30 | 2023-03-21 | 义乌聚邦玩具有限公司 | High-performance degradable decompression daub |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102113721A (en) * | 2010-01-04 | 2011-07-06 | 盛启升 | Soft polyurethane (PU) foaming three-dimensional face mask |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1063701A (en) * | 1992-01-27 | 1992-08-19 | 上海浦江橡胶厂 | Atoxic plasticine composition and method for making thereof |
| CN1245732A (en) * | 1998-08-24 | 2000-03-01 | 增城市荔城佳彩文化用品二厂 | Children's toy clay which can be repeatedly kneaded and moulded for modelling |
| CN1240218A (en) * | 1999-07-12 | 2000-01-05 | 李高嵩 | Soft color plastics |
-
2007
- 2007-01-08 CN CNB2007100666239A patent/CN100447195C/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102010524A (en) * | 2009-09-08 | 2011-04-13 | 真彩文具有限公司 | Non-toxic color mud |
| CN101913808A (en) * | 2010-07-30 | 2010-12-15 | 邢春生 | Toy clay and preparation method thereof |
| CN101913808B (en) * | 2010-07-30 | 2012-07-11 | 邢春生 | Toy clay and preparation method thereof |
| CN104692716A (en) * | 2013-12-07 | 2015-06-10 | 招远鲁娃婴幼儿用品有限公司 | Toy clay |
| CN104877285A (en) * | 2014-02-28 | 2015-09-02 | 宁波宝林达进出口有限公司 | Cotton mud preparation process |
| CN104446643A (en) * | 2014-10-29 | 2015-03-25 | 武汉艾迪创研科技有限公司 | Active restoring agent capable of restoring original appearance of space sand and preparation method of active restoring agent |
| CN104446643B (en) * | 2014-10-29 | 2016-08-24 | 武汉艾迪创研科技有限公司 | A kind of activation recovering agent of reducible space sand plain looks and preparation method thereof |
| CN110204841A (en) * | 2019-03-26 | 2019-09-06 | 周平 | Children's craft plasticine and preparation method thereof |
| CN115819906A (en) * | 2021-12-30 | 2023-03-21 | 义乌聚邦玩具有限公司 | Crackling mastic composition |
| CN115819905A (en) * | 2021-12-30 | 2023-03-21 | 义乌聚邦玩具有限公司 | High-performance degradable decompression daub |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100447195C (en) | 2008-12-31 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: PUJIANG JINTAILANG TOYS CO., LTD. Free format text: FORMER OWNER: DU JINGCAI Effective date: 20100514 |
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Free format text: CORRECT: ADDRESS; FROM: 322000 NO.30, BAIHUI VENTURE PARK, PUJIANG COUNTY, ZHEJIANG PROVINCE TO: 322200 NO.30, BAIHUI VENTURE PARK, PUJIANG COUNTY, ZHEJIANG PROVINCE |
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| TR01 | Transfer of patent right |
Effective date of registration: 20100514 Address after: 322200 Zhejiang province Pujiang County Parkway Park No. 30 Patentee after: Pujiang County Kintaro Toys Co., Ltd. Address before: 322000 Zhejiang province Pujiang County Parkway Park No. 30 Patentee before: Du Jingcai |
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| CP03 | Change of name, title or address |
Address after: 322204 Zhejiang County of Pujiang Province Huang Zhai Zhen Parkway Park No. 30 Patentee after: Zhejiang Silver Dragon animation culture Limited by Share Ltd Address before: 322200 Zhejiang province Pujiang County Parkway Park No. 30 Patentee before: Pujiang County Kintaro Toys Co., Ltd. |
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| CP03 | Change of name, title or address | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20081231 Termination date: 20180108 |
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| CF01 | Termination of patent right due to non-payment of annual fee |