CN100585918C - Solidifying and drying method of lead acid cell unformed plate - Google Patents

Solidifying and drying method of lead acid cell unformed plate Download PDF

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Publication number
CN100585918C
CN100585918C CN200810121004A CN200810121004A CN100585918C CN 100585918 C CN100585918 C CN 100585918C CN 200810121004 A CN200810121004 A CN 200810121004A CN 200810121004 A CN200810121004 A CN 200810121004A CN 100585918 C CN100585918 C CN 100585918C
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Prior art keywords
curing
humidity
hours
time
lead
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CN200810121004A
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Chinese (zh)
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CN101383411A (en
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包有富
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Zhejiang Yongda Power Industry Co ltd
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ZHEJIANG YONDER ELECTRIC POWER INDUSTRY Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

The invention discloses a curing and drying process of the unformed plate in a lead-acid battery. The process comprises a curing stage and a drying stage, wherein the temperature at the curing stage is 55-70 DEG C, the curing humidity is 90-98 percent, and the curing time is 0-12 hours, the drying temperature is 55-70 DEG C, the drying humidity is below 30 percent, and the drying time is 24 hours. The curing and drying time of the unformed plate in the lead-acid battery can be shortened, and the energy consumption and the cost can be reduced.

Description

A kind of lead-acid battery plate curing drying means
Technical field
The present invention relates to a kind of lead-acid battery plate curing drying means.
Background technology
In the production process of sour battery, unconverted free lead and moisture are too high in the lead-acid battery green plate lead plaster, need be cured drying and make it drop to lower level, and free lead drops to below 6%, and moisture drops to below 1%.Concrete technological process is elder generation and cream, and the lead plaster coated plate that will become reconciled then generates the humidogene pole plate, again the humidogene pole plate is generated dried green plate by curing and dying process.
At present lead-acid battery plate curing technology has two kinds of hot setting and normal temperature cures, and the hot setting temperature is 75~90 ℃, and humidity is 90~98%; The normal temperature cure temperature is 40~50 ℃, and humidity is 90~98%.Baking temperature is 60~90 ℃ in the drying process, and humidity is below 30%.The above-mentioned curing and dying process production cycle is longer, needs 48 hours to 72 hours even longer, causes manufacturer's equipment and place anxiety, and cost is higher, causes the waste of the energy, and influences product delivery date.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of lead-acid battery plate curing drying means, can shorten lead-acid battery plate curing drying time, cuts down the consumption of energy and cost.
For solving above-mentioned prior art problems, the present invention adopts following scheme: a kind of lead-acid battery plate curing drying means, comprise cure stage and drying stage, and the cure stage temperature is 55~70 ℃, solidifying humidity is 90~98%, and be 0~12 hour curing time; Baking temperature is 55~70 ℃, and dry humidity is below 30%, and be 24 hours drying time.
As preferably, be 0 described curing time, promptly is not cured, and directly carries out drying; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time, like this, does not promptly need to solidify also to reach qualified product.
As preferably, described cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and be 6 hours curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
As preferably, described cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and be 12 hours curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
As preferably, be 0 hour described curing time, promptly is not cured, and directly carries out drying; Baking temperature is 70 ℃, and dry humidity is below 30%, and be 24 hours drying time.
As preferably, described cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and be 6 hours curing time; Baking temperature is 70 ℃, and dry humidity is below 30%, and be 24 hours drying time.
As preferably, described cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and be 12 hours curing time; Baking temperature is 70 ℃, and dry humidity is below 30%, and be 24 hours drying time.
As preferably, be 0 described curing time, promptly is not cured, and directly carries out drying; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
As preferably, described cure stage temperature is 70 ℃, and solidifying humidity is 90~98%, and be 6 hours curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
As preferably, described cure stage temperature is 70 ℃, and solidifying humidity is 90~98%, and be 12 hours curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
Beneficial effect:
The invention provides a kind of lead-acid battery plate curing drying means, can shorten lead-acid battery plate curing drying time, cut down the consumption of energy and cost.After adopting the present invention, production capacity can improve more than 25%, and energy consumption and cost can descend more than 25%, and solidifying at most only needs 36 hours drying time, wherein solidifies dry 24 hours 0~12 hour.
Embodiment
Embodiment one:
A kind of lead-acid battery plate curing drying means, the cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and baking temperature is 55 ℃, and dry humidity is below 30%.Solidified dry 24 hours experimental result such as table 1 0~12 hour:
Table 1
Curing time/h Drying time/h Free lead/% Moisture/%
0 24 4.60 0.85
1 24 4.30 0.92
2 24 4.32 0.86
4 24 4.08 0.90
6 24 3.89 0.88
8 24 3.68 0.92
10 24 3.46 0.85
12 24 3.29 0.88
Embodiment two:
A kind of lead-acid battery plate curing drying means, the cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and baking temperature is 60 ℃, and dry humidity is below 30%.Solidified dry 24 hours experimental result such as table 2 0~12 hour:
Table 2
Curing time/h Drying time/h Free lead/% Moisture/%
0 24 4.55 0.65
1 24 4.30 0.63
2 24 4.25 0.66
4 24 4.18 0.68
6 24 3.80 0.68
8 24 3.55 0.70
10 24 3.32 0.75
12 24 3.15 0.75
Embodiment three:
A kind of lead-acid battery plate curing drying means, the cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and baking temperature is 70 ℃, and dry humidity is below 30%.Solidified dry 24 hours experimental result such as table 3 0~12 hour:
Table 3
Curing time/h Drying time/h Free lead/% Moisture/%
0 24 4.40 0.25
1 24 4.30 0.18
2 24 4.37 0.30
4 24 4.00 0.30
6 24 3.80 0.25
8 24 3.65 0.31
10 24 3.45 0.25
12 24 3.20 0.35
Embodiment four:
A kind of lead-acid battery plate curing drying means, the cure stage temperature is 60 ℃, and solidifying humidity is 90~98%, and baking temperature is 55 ℃, and dry humidity is below 30%.Solidified dry 24 hours experimental result such as table 4 0~12 hour:
Table 4
Curing time/h Drying time/h Free lead/% Moisture/%
0 24 3.60 0.85
1 24 3.30 0.88
2 24 3.35 0.88
4 24 3.28 0.86
6 24 3.83 0.85
8 24 3.60 0.90
10 24 3.45 0.95
12 24 3.25 0.92
Embodiment five:
A kind of lead-acid battery plate curing drying means, the cure stage temperature is 60 ℃, and solidifying humidity is 90~98%, and baking temperature is 60 ℃, and dry humidity is below 30%.Solidified dry 24 hours experimental result such as table 5 0~12 hour:
Table 5
Curing time/h Drying time/h Free lead/% Moisture/%
0 24 3.05 0.55
1 24 2.85 0.57
2 24 2.85 0.56
4 24 2.77 0.60
6 24 2.80 0.65
8 24 2.65 0.65
10 24 2.45 0.65
12 24 2.25 0.68
Embodiment six:
A kind of lead-acid battery plate curing drying means, the cure stage temperature is 60 ℃, and solidifying humidity is 90~98%, and baking temperature is 70 ℃, and dry humidity is below 30%.Solidified dry 24 hours experimental result such as table 6 0~12 hour:
Table 6
Curing time/h Drying time/h Free lead/% Moisture/%
0 24 3.85 0.20
1 24 3.85 0.20
2 24 3.90 0.25
4 24 3.80 0.33
6 24 3.78 0.28
8 24 3.75 0.35
10 24 3.65 0.30
12 24 3.70 0.35
Embodiment seven:
A kind of lead-acid battery plate curing drying means, the cure stage temperature is 70 ℃, and solidifying humidity is 90~98%, and baking temperature is 55 ℃, and dry humidity is below 30%.Solidified dry 24 hours experimental result such as table 7 0~12 hour:
Table 7
Curing time/h Drying time/h Free lead/% Moisture/%
0 24 5.25 0.65
1 24 5.15 0.65
2 24 4.85 0.62
4 24 4.80 0.60
6 24 4.85 0.65
8 24 4.60 0.64
10 24 4.65 0.65
12 24 4.55 0.62
Embodiment eight:
A kind of lead-acid battery plate curing drying means, the cure stage temperature is 70 ℃, and solidifying humidity is 90~98%, and baking temperature is 60 ℃, and dry humidity is below 30%.Solidified dry 24 hours experimental result such as table 8 0~12 hour:
Table 8
Curing time/h Drying time/h Free lead/% Moisture/%
0 24 4.85 0.35
1 24 4.85 0.32
2 24 4.60 0.35
4 24 4.65 0.30
6 24 4.55 0.30
8 24 4.60 0.33
10 24 4.50 0.35
12 24 4.45 0.35
Embodiment nine:
A kind of lead-acid battery plate curing drying means, the cure stage temperature is 70 ℃, and solidifying humidity is 90~98%, and baking temperature is 70 ℃, and dry humidity is below 30%.Solidified dry 24 hours experimental result such as table 9 0~12 hour:
Table 9
Curing time/h Drying time/h Free lead/% Moisture/%
0 24 5.45 0.07
1 24 5.45 0.08
2 24 5.43 0.08
4 24 5.40 0.10
6 24 5.53 0.10
8 24 5.30 0.08
10 24 5.5 0.08
12 24 5.20 0.12
From above embodiment as can be seen, a kind of lead-acid battery plate curing drying means of the present invention, from the time than short many of present process time, mainly be meant cure stage, at least shorten for 50% time, be that the curing process production capacity improves at least 50%, energy consumption descends more than 50%.

Claims (10)

1. a lead-acid battery plate curing drying means comprises cure stage and drying stage, it is characterized in that: the cure stage temperature is 55~70 ℃, and solidifying humidity is 90~98%, and be 0~12 hour curing time; Baking temperature is 55~70 ℃, and dry humidity is below 30%, and be 24 hours drying time.
2. a kind of lead-acid battery plate curing drying means according to claim 1, it is characterized in that: be 0 described curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
3. a kind of lead-acid battery plate curing drying means according to claim 1, it is characterized in that: described cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and be 6 hours curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
4. a kind of lead-acid battery plate curing drying means according to claim 1, it is characterized in that: described cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and be 12 hours curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
5. a kind of lead-acid battery plate curing drying means according to claim 1, it is characterized in that: be 0 hour described curing time; Baking temperature is 70 ℃, and dry humidity is below 30%, and be 24 hours drying time.
6. a kind of lead-acid battery plate curing drying means according to claim 1, it is characterized in that: described cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and be 6 hours curing time; Baking temperature is 70 ℃, and dry humidity is below 30%, and be 24 hours drying time.
7. a kind of lead-acid battery plate curing drying means according to claim 1, it is characterized in that: described cure stage temperature is 55 ℃, and solidifying humidity is 90~98%, and be 12 hours curing time; Baking temperature is 70 ℃, and dry humidity is below 30%, and be 24 hours drying time.
8. a kind of lead-acid battery plate curing drying means according to claim 1, it is characterized in that: be 0 described curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
9. a kind of lead-acid battery plate curing drying means according to claim 1, it is characterized in that: described cure stage temperature is 70 ℃, and solidifying humidity is 90~98%, and be 6 hours curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
10. a kind of lead-acid battery plate curing drying means according to claim 1, it is characterized in that: described cure stage temperature is 70 ℃, and solidifying humidity is 90~98%, and be 12 hours curing time; Baking temperature is 55 ℃, and dry humidity is below 30%, and be 24 hours drying time.
CN200810121004A 2008-09-12 2008-09-12 Solidifying and drying method of lead acid cell unformed plate Expired - Fee Related CN100585918C (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109698324A (en) * 2018-06-01 2019-04-30 骆驼集团蓄电池研究院有限公司 A kind of lead-acid battery green plate curing and dying process

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CN101908622B (en) * 2010-08-06 2012-06-27 天能电池集团有限公司 Process for curing power lead-acid storage battery electrode plate
CN101944605B (en) * 2010-09-14 2016-03-09 彭滨 A kind of accumulator plate drying technology
CN102244300B (en) * 2011-06-03 2014-04-02 界首市华宇电源有限公司 Lead acid battery taking graphene as additive
CN102324500A (en) * 2011-07-28 2012-01-18 天能电池集团有限公司 Heat treatment process of storage battery grid
CN102339993A (en) * 2011-09-28 2012-02-01 江苏富思特电源有限公司 Curing process for tubular positive plate of lead-acid storage battery
CN103400966B (en) * 2013-07-09 2015-08-05 超威电源有限公司 A kind of technique for solidifying lead acid battery polar plate
CN103762340B (en) * 2014-01-14 2015-09-09 天能集团江苏科技有限公司 A kind of lead-acid accumulator green plate quick high-temp curing and dying process
CN104505519A (en) * 2014-12-10 2015-04-08 天能电池集团有限公司 Age hardening process before grid plate coating of lead-acid storage battery
CN109585788B (en) * 2018-11-20 2021-12-10 天能电池(芜湖)有限公司 Curing process for 90 ℃ high-energy battery grid
CN112002876B (en) * 2020-07-23 2022-03-01 天能电池集团股份有限公司 Quick manufacturing process for lead storage battery pole plate
CN112201775B (en) * 2020-09-16 2021-12-21 超威电源集团有限公司 Curing process for rapidly reducing content of free lead in green plate
CN112467090B (en) * 2020-11-06 2021-12-14 浙江天能汽车电池有限公司 Curing and drying process for positive plate of start-stop storage battery and storage battery plate group
CN112436109B (en) * 2020-11-20 2022-09-06 安徽省华森电源有限公司 Rapid curing process for lead paste of lead-acid storage battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109698324A (en) * 2018-06-01 2019-04-30 骆驼集团蓄电池研究院有限公司 A kind of lead-acid battery green plate curing and dying process
CN109698324B (en) * 2018-06-01 2021-08-31 骆驼集团蓄电池研究院有限公司 Curing and drying process of green plate for lead-acid battery

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Assignee: ZHEJIANG YONGDA Group Co.

Assignor: ZHEJIANG YONGDA ELECTRIC POWER INDUSTRY CO.,LTD.

Contract record no.: 2010330002256

Denomination of invention: Solidifying and drying method of lead acid cell unformed plate

Granted publication date: 20100127

License type: Exclusive License

Open date: 20090311

Record date: 20101208

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Address after: Zhejiang city of Huzhou province Changxing County 313000 Long bridge of peace in the town

Patentee after: ZHEJIANG YONGDA POWER INDUSTRY Co.,Ltd.

Address before: 313103 Bridge No. 7 of Changxing County peace Town, Changxing County, Zhejiang

Patentee before: ZHEJIANG YONGDA ELECTRIC POWER INDUSTRY CO.,LTD.

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Termination date: 20210912