CN100572329C - Air bubble mix light-textured soil - Google Patents

Air bubble mix light-textured soil Download PDF

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Publication number
CN100572329C
CN100572329C CNB2006100706496A CN200610070649A CN100572329C CN 100572329 C CN100572329 C CN 100572329C CN B2006100706496 A CNB2006100706496 A CN B2006100706496A CN 200610070649 A CN200610070649 A CN 200610070649A CN 100572329 C CN100572329 C CN 100572329C
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air bubble
soil
mix light
calcium stearate
textured soil
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Expired - Fee Related
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CNB2006100706496A
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CN101195540A (en
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于润清
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention discloses a kind of air bubble mix light-textured soil, for comprising raw material soil, solidifying agent cement, water, previously prepared bubble and additive, employing after thorough mixing stirs, forms in proportion, wherein additive comprises the calcium stearate suspension as the emulsion form of hydrophober, and the addition of hydrophober is in 0.1%~1.5% of the relative solidifying agent cement weight of calcium stearate.The present invention can mix use within a short period of time, has shortened the time of air bubble mix light-textured soil construction operation greatly, has improved the service efficiency of construction operation efficient and equipment.

Description

Air bubble mix light-textured soil
Technical field
The present invention relates to a kind of building operation materials, especially relate to a kind of air bubble mix light-textured soil with hydrophobic performance.
Background technology
Because the unit weight of air bubble mix light-textured soil is little, have higher intensity and deformation characteristic, and favorable durability, thermal insulation, be convenient to construction, sound insulation and freeze-thaw-ability and superior environmental protection characteristic, air bubble mix light-textured soil has a very wide range of applications in road construction, the bridges and culverts that can be applied to solving in the soft basic embankment in super highway is jumped car, road is widened the relative settlement of stylish old road base, the stability of highfill embankment, in the constructions such as thermal insulation of frozen soil area embankment, can shorten the construction period greatly, improve construction quality, reduce the expense of maintenance and management after engineering is runed significantly.Simultaneously, for the ease of maintaining, the air bubble mix light-textured soil that uses contains hydrophober more, by hydrophober the water-intake rate after air bubble mix light-textured soil fully absorbs water is reduced, under the situation of not damaging air bubble mix light-textured soil intensity, improve its hydrophobicity greatly, thereby strengthened the water resistance of air bubble mix light-textured soil engineering so that to its maintaining.And calcium stearate is the hydrophober of main component is a kind of in numerous air bubble mix light-textured soil hydrophober, it can significantly improve the hydrophobicity performance of air bubble mix light-textured soil, reduce the water-intake rate of air bubble mix light-textured soil, as containing 0.1%~1.0% calcium stearate hydrophober of solid formulation cement weight in the air bubble mix light-textured soil, after its completely solidified, weight after air bubble mix light-textured soil fully absorbs water when not absorbing water weight 110~130%, and the weight of the air bubble mix light-textured soil that does not contain calcium stearate hydrophober after fully absorbing water when not absorbing water weight 180~200%, as seen, the hydrophobicity that contains the air bubble mix light-textured soil of calcium stearate hydrophober is improved greatly, water-intake rate then reduces, this for air bubble mix light-textured soil in road construction, banket, be very important in the construction operation below the ground water table particularly.But the calcium stearate hydrophober that air bubble mix light-textured soil contained in the current construction operation is solid, powdery, and because calcium stearate is insoluble in water, with after water mixes, always float over the surface of air bubble mix light-textured soil or become lumphy structure, the short period of time is difficult to mix.Therefore it is mixed even that needs stir when long the chien shih calcium stearate earlier when using the air bubble mix light-textured soil construction operation of the calcium stearate hydrophober that contains solid, powdery, sometimes the time can reach tens hours, prolonged the time of this air bubble mix light-textured soil construction operation greatly, this is for the continuous construction operation of big construction volume, operation easier is sizable, not only reduce construction operation efficient, and reduced the service efficiency of equipment.
Summary of the invention
Technical problem to be solved by this invention has provided a kind of air bubble mix light-textured soil, and it can mix use within a short period of time, has shortened the time of air bubble mix light-textured soil construction operation greatly, has improved the service efficiency of construction operation efficient and equipment.
This air bubble mix light-textured soil, for comprising raw material soil, water coal ash, solidifying agent cement, water, previously prepared bubble and additive, employing after thorough mixing stirs, forms in proportion, wherein additive comprises the calcium stearate suspension as the emulsion form of hydrophober, and the addition of hydrophober is in 0.1%~1.5% of the relative solidifying agent cement weight of calcium stearate.
Air bubble mix light-textured soil unit weight can be 0.5~1.2Kg/cm 3, intensity is 0.3~5MPa.And raw material soil can adopt particle diameter to discard soil or/and fine sand less than the engineering of 5mm.
When producing this air bubble mix light-textured soil, can be with raw material soil, the water coal ash, solidifying agent cement, water, additive such as bubble and hydrophober is inserted in the agitator in proportion, mix and to use, wherein, can adopt raw material soil usage quantity to be no more than 5 times of solidifying agent cement by weight, water coal ash usage quantity is no more than 50% of solidifying agent cement by weight, water can adopt 1 square metre air bubble mix light-textured soil to use 100~300kg, and when preparing bubble in advance, the whipping agent usage quantity of the bubble that is used to produce can adopt 1 square metre air bubble mix light-textured soil to use 0.1~2kg to determine its usage quantity, wherein with 1kg usage quantity the best.The diameter of raw material soil particle should be less than the discarded soil of the engineering of 5mm or/and fine sand, the particle diameter of water coal ash also should be less than 5mm, to improve the flowing property and the workability of air bubble mix light-textured soil, solidifying agent cement then can adopt trass cement, ordinary Portland cement, portland blast-furnace slag cement etc., water takes place after solidifying agent cement adds and between the water produce Ca (OH) 2 products with effect, Ca (OH) 2 forms cured article as effect fixed, that strengthen soil body skeleton with clay particle generation ion-exchange, and is good with the effect of using portland blast-furnace slag cement; And can in air bubble mix light-textured soil, add subsidiary material and other additives such as terra alba, silica flour, and not only reduced the consumption of solidifying agent cement, can play simultaneously catalysis, the purpose of cure material early.Bubble then can adopt current people foam device preparation relatively more commonly used, promptly pass through the interfacial activity class, protein, materials such as resene adopt pump of constant delivery type to deliver to foam device as an amount of multiplying power dilution of pore forming material back, produce a large amount of micro-bubble groups with the pressurized air thorough mixing, pressurized air can pressurize by air compressor machine, control distribution pressure with reducing valve, with pressure stable and tolerance to the foam device air feed, the bubble that produces is by densification, diameter is that the bubble population about 30~300 μ is formed, and has certain stability, with raw material soil, solidifying agent cement etc. can form a large amount of and small nonconductive pores after mixing in air bubble mix light-textured soil, according to the requirement of difference construction, the bubble volume containing ratio in the air bubble mix light-textured soil can be controlled in 40%~70%.
As hydrophober emulsion form calcium stearate suspension is that the middle adding weight part content of 200~400 parts of water is 0.3~10 part emulsifying agent for adopting at weight part content then, after stirring, mix, be warming up to 50~100 ℃ and insulation then, adding weight part content is 100~300 parts stearic acid, through stirring fusing fully, drip again in calcium hydroxide weight part content be 20~50 parts aqua calcis to pH value 9~12, stir and be incubated 10~120 minutes; Afterwards the mixed solution that makes is made by colloidal mill grinding and high-pressure homogeneous postcooling; Solid content in the emulsion form calcium stearate suspension that makes is 20~70%, and its viscosity is<800mpa.s.
In the preparation process of whole hydrophober, temperature can remain on 50~100 ℃, and can adopt in the container of the retort class that has whipping appts and carry out, whole process of preparation just can be carried out in starting the process of stirring like this, with being evenly distributed of the calcium stearate that generates in the degree of uniformity that improves mixed solution in the preparation process and the hydrophober milk sap, and made things convenient for people's operation; And for the emulsification that improves hydrophober and dispersing property and through grinding the dispersed uniform of rear suspension liquid calcium stearate particles, emulsifying agent can adopt the polyethenoxy ether class material, as fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylenated alcohol sodium sulfate, in the alkyl phenol polyethenoxy ether sodium sulfate any one or any two above mixtures, wherein be commercial Industrial products at the various raw materials that use, and equipment such as the retort used, colloid mill and the mixed solution after grinding is carried out high-pressure homogeneous equipment such as high pressure homogenizer also be some public equipment.
Because the hydrophober that this air bubble mix light-textured soil contains is the calcium stearate suspension that adopts emulsion form, like this, calcium stearate particles as the hydrophober main component will mix with compositions such as solidifying agent cement at short notice at air bubble mix light-textured soil, its result of use has substantially exceeded the result of use of solid powdery calcium stearate under the isodose situation.This air bubble mix light-textured soil can be with raw material soil when preparation is used, the water coal ash, solidifying agent cement, water, additives such as the calcium stearate suspension of previously prepared bubble and emulsion form and other material join simultaneously and stir in the stirrer, the calcium stearate suspension of emulsion form and other composition of water can mix at 5~10 minutes, this has shortened the time that calcium stearate mixes in the air bubble mix light-textured soil greatly, improved the air bubble mix light-textured soil operating efficiency, solidify the hydrophobic performance of back at air bubble mix light-textured soil by calcium stearate, reduce the water-intake rate of this air bubble mix light-textured soil, reach the water resistance of air bubble mix light-textured soil, satisfied the requirement that air bubble mix light-textured soil is worked continuously and constructed fully.
And the calcium stearate suspension of emulsion form can adopt the calcium hydroxide reaction of stearic acid after the fusing and dropping to generate calcium stearate, and by having good emulsification, dissemination, and the mixed solution that forms as emulsifying agent of the polyethenoxy ether class tensio-active agent that can be dissolved in the hard water of various hardness, and at the process colloidal grinding, behind the homogeneous with of the emulsification of tiny calcium stearate particles at emulsifying agent, just can be dispersed in the mixed solution under the dissemination, form lactous calcium stearate suspension, thereby interpolation continuously in the air bubble mix light-textured soil of construction operation prepares continuously, by the dissemination of emulsifying agent, calcium stearate mixed in moment and air bubble mix light-textured soil.
Embodiment
Embodiment one
Adopt through processing screening back particle diameter less than 5mm fine sand 600kg as raw material soil, the water coal ash adopts 40kg, water 260kg, adopt portland blast-furnace slag cement 150kg as solidifying agent, hydrophober calcium stearate suspension is in calcium stearate 1.65kg, the bubble add-on adopts pump of constant delivery type to deliver to foam device with the whipping agent dilution back of adopting 1.1kg, produce a large amount of micro-bubble groups with the pressurized air thorough mixing, producing diameter is the amount of the bubble population about 30~300 μ, with fine sand, portland blast-furnace slag cement, the water coal ash, water, bubble, additives such as hydrophober calcium stearate suspension are inserted in the agitator, stir and got final product in 5~10 minutes, after air bubble mix light-textured soil construction completely solidified, its unit weight can be 0.9~1.1Kg/cm 3, intensity is 0.9~1.4MPa, and the weight of air bubble mix light-textured soil after fully absorbing water when not absorbing water weight 118%.
Embodiment two
Employing is discarded native 250kg as raw material soil through handling screening back particle diameter less than the 5mm engineering, water coal ash 50kg, water 160kg, and adopt ordinary Portland cement 100kg as solidifying agent, calcium stearate suspension is in calcium stearate 0.5kg, the bubble add-on adopts pump of constant delivery type to deliver to foam device with the whipping agent dilution back of adopting 0.4kg, produce a large amount of micro-bubble groups with the pressurized air thorough mixing, producing diameter is the amount of the bubble population about 30~300 μ, with fine sand, the water coal ash, portland blast-furnace slag cement, water, bubble, additives such as hydrophober calcium stearate suspension are inserted in the agitator, stir and got final product in 5~10 minutes, after air bubble mix light-textured soil construction completely solidified, its unit weight can be 0.6~0.85Kg/cm 3, intensity is 0.5~0.7MPa, and the weight of air bubble mix light-textured soil after fully absorbing water when not absorbing water weight 112%.
Embodiment three
Employing adds 380kg water in the retort that has whipping appts, and under evenly stirring, add the alkylphenol polyoxyethylene of 1.3kg as emulsifying agent, mix with water, be warming up to 60 ℃ and insulation then, the stearic acid that adds 100kg, stirring is melted fully and is incubated, drip again in behind the aqua calcis of calcium hydroxide 20kg to pH value be 10~12, stir and be incubated 25 minutes, react completely, afterwards the mixed solution that makes is made emulsion form calcium stearate suspension hydrophober by colloidal mill grinding and high-pressure homogeneous postcooling; Solid content in the emulsion form calcium stearate suspension that makes is 25%, and its viscosity is 650mpa.s, and outward appearance is an oyster white.
Embodiment four
Adopt the step identical with embodiment three, the consumption that just adopts water is 280kg, the fatty alcohol-polyoxyethylene ether and the 1.2kg polyoxyethylenated alcohol sodium sulfate emulsifying agent that add 0.3kg, maintain the temperature under 78 ℃, the stearic acid that adds 130kg melts, the aqua calcis dripping quantity is in calcium hydroxide 26kg, and pH value 10~11 is incubated 60 minutes and stirring; Solid content in the emulsion form calcium stearate suspension that makes is 37%, and its viscosity is 715mpa.s, and outward appearance is an oyster white.
Embodiment five
Adopt the step identical with embodiment three, the consumption that just adopts water is 350kg, add 1.8kg fatty alcohol-polyoxyethylene ether, 1.2kg alkylphenol polyoxyethylene, 2.1kg polyoxyethylenated alcohol sodium sulfate and 2.4kg alkyl phenol polyethenoxy ether sodium sulfate as emulsifying agent, and maintain the temperature under 93 ℃, the stearic acid that adds 250kg melts, the aqua calcis dripping quantity in calcium hydroxide 50kg after, pH value 10~11 is incubated 100 minutes and stirs; Solid content in the emulsion form calcium stearate suspension that makes is 52%, and its viscosity is 780mpa.s, and outward appearance is an oyster white.

Claims (4)

1, air bubble mix light-textured soil forms after thorough mixing stirs in proportion for employing comprises raw material soil, water coal ash, solidifying agent cement, water, bubble and additive, and it is characterized in that: described air bubble mix light-textured soil unit weight is 0.5~1.2Kg/cm 3, intensity is 0.3~5Mpa, described additive comprises the emulsion form calcium stearate suspension as hydrophober, and the addition of hydrophober is in 0.1%~1.5% of the relative solidifying agent cement weight of calcium stearate.
2, air bubble mix light-textured soil as claimed in claim 1 is characterized in that: described raw material soil is discarded soil or/and fine sand for particle diameter less than the engineering of 5mm.
3, air bubble mix light-textured soil as claimed in claim 1, it is characterized in that: described emulsion form calcium stearate suspension is that the middle adding weight part content of 200~400 parts of water is 0.3~10 part emulsifying agent for adopting at weight part content, after stirring, mix, be warming up to 50~100 ℃ and insulation then, adding weight part content is 100~300 parts stearic acid, through stirring fusing fully, drip again in calcium hydroxide weight part content be 20~50 parts aqua calcis to pH value 9~12, stir and be incubated 10~120 minutes; Afterwards the mixed solution that makes is made by colloidal mill grinding and high-pressure homogeneous postcooling; Solid content in this emulsion form calcium stearate suspension is 20~70%, and its viscosity is<800mpa.s.
4, air bubble mix light-textured soil as claimed in claim 3 is characterized in that: described emulsifying agent be in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, polyoxyethylenated alcohol sodium sulfate, the alkyl phenol polyethenoxy ether sodium sulfate any one or any two more than.
CNB2006100706496A 2006-12-04 2006-12-04 Air bubble mix light-textured soil Expired - Fee Related CN100572329C (en)

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Publication number Priority date Publication date Assignee Title
CN102010220A (en) * 2010-09-28 2011-04-13 广东冠生土木工程技术有限公司 High-water resistance bubble mixing light-weight soil
CN103774517B (en) * 2012-10-25 2015-10-21 中国石油化工股份有限公司 A kind of asphalt pavement regeneration method of adding regenerative agent
CN107324705B (en) * 2017-06-19 2020-01-14 中交四航工程研究院有限公司 Foamed light soil and roadbed made of waste incineration fly ash
CN107879658A (en) * 2017-11-14 2018-04-06 潍坊友容实业有限公司 The building materials of salt-soda soil feed ditch efficiency of construction can be improved
CN107963863A (en) * 2017-11-14 2018-04-27 潍坊友容实业有限公司 The irrigating facility composite soil prepared using salt affected soil
CN109232019A (en) * 2018-11-26 2019-01-18 天津城建大学 A kind of bubble lightweight salinized soil
CN112390661A (en) * 2020-11-24 2021-02-23 河海大学 Lightweight curing method for lightweight cured waste soil and waste soil backfill

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