CN100564383C

CN100564383C - Organosilicon compound and manufacture method thereof

Info

Publication number: CN100564383C
Application number: CNB2005800081934A
Authority: CN
Inventors: 菊池武利; 肥后笃; 阿波秀明; 三宅邦仁
Original assignee: Sumitomo Chemical Co Ltd
Current assignee: Sumitomo Chemical Co Ltd
Priority date: 2004-03-16
Filing date: 2005-03-10
Publication date: 2009-12-02
Anticipated expiration: 2025-03-10
Also published as: DE112005000588T5; US20070203275A1; KR20060134117A; US7741393B2; CN1930174A; KR101127908B1; WO2005087781A1; JP4539131B2; JP2005263640A

Abstract

The invention provides silicoorganic compound, contain the organic materials composition of these silicoorganic compound and the manufacture method of these silicoorganic compound etc.Described silicoorganic compound can be used in the painted or thermal degradation when of the organic materials when suppressing to be shaped, and it is represented with following formula (I): in the formula (I), and R ₁～R ₂₀Represent alkyl, alkoxyl group, aryloxy, cycloalkyl, alkyl-cycloalkyl, aryl, dialkyl amido etc. respectively independently, the substituting group that above-mentioned aryloxy and aryl can be selected from alkyl, alkoxyl group and alkoxyalkyl replaces.

Description

Organosilicon compound and manufacture method thereof

Technical field

The present invention relates to novel organosilicon compounds, its manufacture method and contain silicoorganic compound and the organic materials composition of organic materials.

Background technology

Thermoplastic resin, thermosetting resin, natural or organic materialss such as synthetic rubber, mineral oil, lubricating oil, tackiness agent or coating, when during fabrication, adding man-hour and use, sometimes effect such as Yin Re and oxygen and produce deterioration and with the reduction of the intensity rerum natura reduction of the organic materials that causes because of molecular breakdown or molecule crosslinked phenomenon, mobility variations, painted or surface physical property etc., thus commodity value is significantly impaired.

In addition, as a kind of polycarbonate of thermoplastic resin,, be widely used in the material of construction such as shell, optical lens or window glass of electronic machine because of excellent cause such as shock-resistance, the transparency and dimensional stability.

In the patent documentation 1, be the stablizer of the polycarbonate represented of following formula, proposed the silane type stablizer of following formula (A) expression as main repeating unit.

The general formula of main repeating unit is:

In the formula, R ₁', R ₂', R ₃' and R ₄' represent independently that respectively alkyl, aralkyl or the aryl of hydrogen atom, carbon number 1～10, W represent alkylidene group, Sauerstoffatom, sulphur atom, sulfoxide group or sulfuryl that alkylidene group, ring alkylidene group, aryl replace.

In the formula (A), R ₅'～R ₇' represent independently that respectively the alkyl of hydrogen atom, carbon number 1～20, the alkoxyl group of carbon number 1～20 maybe can have the aryl of substituent carbon number 6～20 or the silyl of following formula (B) expression,

In the formula (B), the alkylidene group of X ' expression singly-bound, Sauerstoffatom, sulphur atom or carbon number 1～10.Y ₁'～Y ₃' represent the alkyl of hydrogen atom, carbon number 1～20, the alkyl silyl of carbon number 1～20, the alkyl siloxy of carbon number 1～20, the aryl that substituent carbon number 6～20 can be arranged, the aryl silyl of carbon number 6～20, the aryl siloxy-or the siloxanes of carbon number 6～20 respectively independently.Patent documentation 1: the spy opens the 2001-247758 communique

Summary of the invention

But, when the inventor uses patent documentation 1 described silane type stablizer (A), when finding hot forming be with the polycarbonate representative organic materialss such as polyester, polyolefine, natural rubber, synthetic rubber, mineral oil, lubricating oil, tackiness agent anti-coloring effect, solar heat protection degradation effects or suppress gel and tell on not necessarily abundant.

By silicoorganic compound of the present invention, painted, the thermal degradation when of organic materialss such as the above-mentioned polycarbonate in the time of can being suppressed at hot forming or the generation of flake glue etc.

That is, first embodiment of the present invention relates to the silicoorganic compound (hereinafter referred to as silicoorganic compound of the present invention) that following formula (I) is represented.

In the formula (I), R ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30, the alkoxyl group of carbon number 1～30, the alkoxyalkyl of carbon number 2～30, the aryloxy of carbon number 6～18, the aryl of carbon number 6～18, the cycloalkyl of carbon number 5～8, the alkyl-cycloalkyl of carbon number 6～20, the alkylthio of carbon number 1～30 or the dialkyl amido of carbon number 2～30 respectively independently.

Wherein, R ₁～R ₂₀Be not hydrogen atom entirely, and, 1～3 hydrogen atom in the aryl of the aryloxy of above-mentioned carbon number 6～18 and carbon number 6～18 can be replaced by 1～3 substituting group, and described substituting group is selected from the alkyl of carbon number 1～30, the alkoxyl group of carbon number 1～30 and the alkoxyalkyl of carbon number 2～30.

In addition, second embodiment of the present invention relates to the manufacture method of the silicoorganic compound of aforesaid formula (I) expression, it is characterized in that, make the phenide compound of following formula (III)～(VI) expression and the replacement silicon compound reaction of following formula (VII) expression, then the gained reaction product is hydrolyzed, carries out condensation as required again.

In the formula (III)～(VI), M represents MgX or Li.X represents halogen atom.R ₁～R ₂₀Identical with above-mentioned definition.Wherein, R ₁～R ₂₀Be not hydrogen atom entirely.

In the formula (VII), Y ₁～Y ₃Represent halogen atom or alkoxyl group respectively independently.

And then, the 3rd embodiment of the present invention relates to organic material compositions (following note is made " organic materials composition of the present invention "), it is characterized in that, the silicoorganic compound that contain organic materials and represent as above-mentioned formula (I), the weight ratio of this organic materials and silicoorganic compound is 100: 0.0001～100: 10 a scope.

Embodiment

Below describe the present invention in detail.

The silicoorganic compound that the formula (I) of first embodiment of the present invention is represented describe.

R in the formula (I) ₁～R ₂₀The alkyl of expression for example can be enumerated the alkyl of carbon numbers 1～30 such as methyl, ethyl, n-propyl, sec.-propyl, normal-butyl, isobutyl-, sec-butyl, the tertiary butyl, tert-pentyl, iso-octyl, uncle's octyl group or 2-ethylhexyl.In the alkyl of this carbon number 1～30, preferable methyl, ethyl or the tertiary butyl.

R ₁～R ₂₀The alkoxyl group of expression for example can be enumerated the alkoxyl group of carbon numbers 1～30 such as methoxyl group, oxyethyl group, positive propoxy, isopropoxy, n-butoxy, isobutoxy, sec-butoxy, tert.-butoxy, uncle's pentyloxy, different octyloxy, uncle's octyloxy or 2-ethyl hexyl oxy.In the alkoxyl group of this carbon number 1～30, preferred methoxy or ethoxy.

R ₁～R ₂₀The alkoxyalkyl of expression for example can be enumerated methoxymethyl, ethoxyl methyl, n-propoxymethyl, the isopropoxy methyl, the n-butoxy methyl, the isobutoxy methyl, the sec-butoxy methyl, the tert.-butoxy methyl, tert-pentyl oxygen methyl, iso-octyl oxygen methyl, uncle's octyl group oxygen methyl, 2-ethylhexyl oxygen methyl, methoxy ethyl, ethoxyethyl group, the positive propoxy ethyl, the isopropoxy ethyl, the n-butoxy ethyl, the isobutoxy ethyl, the sec-butoxy ethyl, the tert.-butoxy ethyl, tert-pentyl oxygen ethyl, iso-octyl oxygen ethyl, the alkoxyalkyl of carbon numbers 2～30 such as uncle's octyl group oxygen ethyl or 2-ethylhexyl oxygen ethyl.

R ₁～R ₂₀The alkylthio of expression for example can be enumerated methylthio group, ethylmercapto group, n-propyl sulfenyl, sec.-propyl sulfenyl, normal-butyl sulfenyl, isobutyl-sulfenyl, sec-butyl sulfenyl, tertiary butyl sulfenyl, tert-pentyl sulfenyl, iso-octyl sulfenyl, uncle's octyl group sulfenyl or 2-ethylhexyl sulfenyl etc.

R ₁～R ₂₀The aryl of expression, for example can enumerate phenyl, 2-aminomethyl phenyl, 3-aminomethyl phenyl, 4-aminomethyl phenyl, 2-p-methoxy-phenyl, 3-p-methoxy-phenyl, 4-p-methoxy-phenyl, 2-p-methoxy-phenyl, 3-p-methoxy-phenyl or 4-p-methoxy-phenyl etc. can be by the monocycle～trinucleated aryl (carbon number 6～18) of 1～3 substituting group replacement, and described substituting group is selected from the alkyl of carbon number 1～3 and the alkoxyl group of carbon number 1～3.

R ₁～R ₂₀The aryloxy of expression, for example can enumerate phenoxy group, 2-methylphenoxy, 3-methylphenoxy, 4-methylphenoxy, 2-tertiary butyl phenoxy group, 3-tertiary butyl phenoxy group, 4-tertiary butyl phenoxy group, 2,4-dimethyl phenoxy, 2,6-dimethyl phenoxy, 2,4-di-t-butyl phenoxy group, 2,6-di-t-butyl phenoxy group, 2,4,6-trimethylammonium phenoxy group, 2,4, the aryloxy of carbon numbers 6～18 such as 6-tri-butyl-phenoxy, 2-methoxyl group phenoxy group, 3-methoxyl group phenoxy group or 4-methoxyl group phenoxy group.In the aryloxy of this carbon number 6～18, preferred phenoxy group.

R ₁～R ₂₀The cycloalkyl of expression for example can be enumerated the cycloalkyl of carbon numbers 5～8 such as cyclopentyl, cyclohexyl, suberyl or ring octyl group.

R ₁～R ₂₀The alkyl-cycloalkyl of expression for example can be enumerated the alkyl-cycloalkyl of 1-methylcyclopentyl, 1-methylcyclohexyl or 1-methyl-carbon numbers 6～20 such as 4-isopropylcyclohexyl-.

R ₁～R ₂₀The dialkyl amido of expression for example can be enumerated dimethylamino, diethylamino, di amino, diisopropylaminoethyl, di-n-butyl amino, diisobutyl amino, two sec-butyl amino, di-t-butyl amino, two tert-pentyl amino, diisooctyl amino, two uncle's octyl groups amino or two (2-ethylhexyl) amino etc.

Silicoorganic compound of the present invention, for example, can make by the following method: make the phenide compound of following formula (III)～(VI) expression and the replacement silicon compound reaction of following formula (VII) expression, the reaction product with gained is hydrolyzed then, carries out condensation as required again.

As by above-mentioned phenide compound with replace the silicon compound reaction and the reaction product that obtains, typically can enumerate: (the φ that makes by the phenide compound and the replacement silicon compound (VIII) of formula (III) and formula (VI) _III) φ _VISiH (Yj) makes the phenide compound of formula (IV) and formula V and replacement silicon compound (VIII) reaction obtain (φ _IV) φ _V(herein, j represents 1～3 arbitrary integer, φ to SiH (Yj) _IIITo φ _VIExpression (III) is to organic residue of the phenide compound of formula (VI)), by with these compound hydrolysis, condensation, and make silicoorganic compound of the present invention.

For the MgX in " M " of phenide compound (III)～(VI), X represents halogen atom.

This halogen atom for example can be enumerated chlorine atom, bromine atoms or iodine atom.

Above-mentioned phenide compound (III)～(VI) can be made by the following method: " M " in this formula (III)～(VI) reacted in the presence of reaction solvent for the starting compound and the reaction reagents such as magnesium, lithium or n-Butyl Lithium of hydrogen atom or halogen atom.

Above-mentioned reaction solvent can use ethers reaction solvent (tetrahydrofuran (THF), ether, t-butyl methyl ether or di-n-butyl ether etc.), or the mixture of this ethers reaction solvent and hydrocarbon reaction solvent (normal hexane or normal heptane etc.) etc.

The phenide compound of being made by above-mentioned reaction (III)～(VI) both can directly be used for reaction solution reaction afterwards, used after also it can being separated by ordinary method.

Replace the Y in the silicon compound (VII) ₁～Y ₃Expression halogen atom (chlorine atom, bromine atoms or iodine atom etc.) or alkoxyl group (methoxyl group, oxyethyl group, isopropoxy or n-butoxy etc.).

The reaction of phenide compound (III)～(VI) and replacement silicon compound (VII) in the presence of reaction solvent or not, is carried out under the temperature range about-80～200 ℃ usually.

When in the presence of this reaction solvent, reacting, can use mixture of ether solvents such as tetrahydrofuran (THF), ether, t-butyl methyl ether or di-n-butyl ether or this ether solvent and varsol (normal hexane or normal heptane etc.) etc.

In this reaction, both can in replacing silicon compound (VII), add phenide compound (III)～(VI), also can in phenide compound (III)～(VI), add replacement silicon compound (VII), but the method for more preferably in replacing silicon compound (VII), adding phenide compound (III)～(VI).

Mol ratio when phenide compound (III)～(VI) and replacement silicon compound (VII) reaction is the replacement silicon compound (VII) with respect to 1 mole preferably, and the total mole number of phenide compound (III)～(VI) is the scope about 1.8～2.2 moles.

At this moment, can suitably regulate the usage ratio separately of phenide compound (III)～(VI).

With phenide compound (III)～(VI) and replace silicon compound (VII) reaction and the reaction product hydrolysis after, carry out condensation, obtain silicoorganic compound (I) thus.

The hydrolysis of above-mentioned reaction product can be carried out in the presence of the aqueous solution of water or inorganic salt (sodium-chlor or ammonium chloride etc.).

As required, the aqueous acid of hydrogenchloride water or sulfuric acid water etc. can and be used in this hydrolysis.

Above-mentioned condensation is often carried out simultaneously with hydrolysis, also can be warming up to by the reaction mixture that will obtain after the hydrolysis about 280 ℃, makes it carry out condensation reaction.

The carrying out of these reactions for example can be followed the trail of by analytical procedures such as vapor-phase chromatography or liquid phase chromatography.

During purifying silicoorganic compound (I), can use ordinary methods such as distillation, partial crystallization or column chromatography.

Solvent for use during partial crystallization, can use for example aromatic hydrocarbon solvent such as toluene or dimethylbenzene, aliphatic solventss such as normal hexane or normal heptane, alicyclic hydrocarbon solvents such as hexanaphthene, alcoholic solvents such as methyl alcohol, ethanol or Virahol, ketones solvent such as acetone or methyl iso-butyl ketone (MIBK), esters solvents such as ethyl acetate, ether solvents such as tetrahydrofuran (THF) or ether, nitrile solvents such as acetonitrile, amide solvents such as dimethyl formamide, halogenated hydrocarbon solvents such as chloroform, methylene dichloride or chlorobenzene, and the mixture of these solvents.

Thus, can make the silicoorganic compound of formula (I) expression.

These silicoorganic compound (I) for example can be enumerated following compound.

R ₁～R ₂₀Be the silicoorganic compound of alkyl:

1,1,3,3-four (2-aminomethyl phenyl) sily oxide, 1,1,3,3-four (3-aminomethyl phenyl) sily oxide, 1,1,3,3-four (4-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-ethylphenyl) sily oxide, 1,1,3,3-four (3-ethylphenyl) sily oxide, 1,1,3,3-four (4-ethylphenyl) sily oxide, 1,1,3,3-four (2-n-butylphenyl) sily oxide, 1,1,3,3-four (3-n-butylphenyl) sily oxide, 1,1,3,3-four (4-n-butylphenyl) sily oxide, 1,1,3,3-four (2-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (3-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (4-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (uncle's 2-octyl phenyl) sily oxide, 1,1,3,3-four (uncle's 3-octyl phenyl) sily oxide, 1,1,3,3-four (uncle's 4-octyl phenyl) sily oxide, 1,1,3,3-four (2, the 3-3,5-dimethylphenyl) sily oxide, 1,1,3,3-four (2, the 4-3,5-dimethylphenyl) sily oxide, 1,1,3,3-four (2, the 5-3,5-dimethylphenyl) sily oxide, 1,1,3,3-four (2, the 6-3,5-dimethylphenyl) sily oxide, 1,1,3,3-four (3, the 4-3,5-dimethylphenyl) sily oxide, 1,1,3,3-four (3, the 5-3,5-dimethylphenyl) sily oxide, 1,1,3,3-four (2,3-diethyl phenyl) sily oxide, 1,1,3,3-four (2,4-diethyl phenyl) sily oxide, 1,1,3,3-four (2,5-diethyl phenyl) sily oxide, 1,1,3,3-four (2,6-diethyl phenyl) sily oxide, 1,1,3,3-four (3,4-diethyl phenyl) sily oxide, 1,1,3,3-four (3,5-diethyl phenyl) sily oxide, 1,1,3,3-four (2,3-di-n-butyl phenyl) sily oxide, 1,1,3,3-four (2,4-di-n-butyl phenyl) sily oxide, 1,1,3,3-four (2,5-di-n-butyl phenyl) sily oxide, 1,1,3,3-four (2,6-di-n-butyl phenyl) sily oxide, 1,1,3,3-four (3,4-di-n-butyl phenyl) sily oxide, 1,1,3,3-four (3,5-di-n-butyl phenyl) sily oxide, 1,1,3,3-four (2, the 3-di-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2, the 4-di-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2, the 5-di-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2, the 6-di-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (3, the 4-di-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (3, the 5-di-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2,3-two uncle's octyl phenyls) sily oxide, 1,1,3,3-four (2,4-two uncle's octyl phenyls) sily oxide, 1,1,3,3-four (2,5-two uncle's octyl phenyls) sily oxide, 1,1,3,3-four (2,6-two uncle's octyl phenyls) sily oxide, 1,1,3,3-four (3,4-two uncle's octyl phenyls) sily oxide, 1,1,3,3-four (3,5-two uncle's octyl phenyls) sily oxide, 1,1,3,3-four (2,3, the 4-trimethylphenyl) sily oxide, 1,1,3,3-four (2,3, the 5-trimethylphenyl) sily oxide, 1,1,3,3-four (2,3, the 6-trimethylphenyl) sily oxide, 1,1,3,3-four (2) sily oxide, 1,1,3,3-four (2,4, the 6-trimethylphenyl) sily oxide, 1,1,3,3-four (2,3,4-triethyl phenyl) sily oxide, 1,1,3,3-four (2,3,5-triethyl phenyl) sily oxide, 1,1,3,3-four (2,3,6-triethyl phenyl) sily oxide, 1,1,3,3-four (2,4,5-triethyl phenyl) sily oxide, 1,1,3,3-four (2,4,6-triethyl phenyl) sily oxide, 1,1,3,3-four (2,3,4-three n-butylphenyl) sily oxide, 1,1,3,3-four (2,3,5-three n-butylphenyl) sily oxide, 1,1,3,3-four (2,3,6-three n-butylphenyl) sily oxide, 1,1,3,3-four (2,4,5-three n-butylphenyl) sily oxide, 1,1,3,3-four (2,4,6-three n-butylphenyl) sily oxide, 1,1,3,3-four (2,3,4-tri-tert phenyl) sily oxide, 1,1,3,3-four (2,3,5-tri-tert phenyl) sily oxide, 1,1,3,3-four (2,3,6-tri-tert phenyl) sily oxide, 1,1,3,3-four (2,4,5-tri-tert phenyl) sily oxide, 1,1,3,3-four (2,4,6-tri-tert phenyl) sily oxide, 1,1,3,3-four (2,3,4-three uncle's octyl phenyls) sily oxide, 1,1,3,3-four (2,3,5-three uncle's octyl phenyls) sily oxide, 1,1,3,3-four (2,3,6-three uncle's octyl phenyls) sily oxide, 1,1,3,3-four (2,4,5-three uncle's octyl phenyls) sily oxide, 1,1,3,3-four (2,4,6-three uncle's octyl phenyls) sily oxide.

R ₁～R ₂₀Be the silicoorganic compound of alkoxyl group:

1,1,3,3-four (2-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (3-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (4-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (3-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (4-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-n-butoxy phenyl) sily oxide, 1,1,3,3-four (3-n-butoxy phenyl) sily oxide, 1,1,3,3-four (4-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (3-tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (4-tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (uncle's 2-octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (uncle's 3-octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (uncle's 4-octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (2, the 3-Dimethoxyphenyl) sily oxide, 1,1,3,3-four (2, the 4-Dimethoxyphenyl) sily oxide, 1,1,3,3-four (2, the 5-Dimethoxyphenyl) sily oxide, 1,1,3,3-four (2, the 6-Dimethoxyphenyl) sily oxide, 1,1,3,3-four (3, the 4-Dimethoxyphenyl) sily oxide, 1,1,3,3-four (3, the 5-Dimethoxyphenyl) sily oxide, 1,1,3,3-four (2,3-diethoxy phenyl) sily oxide, 1,1,3,3-four (2,4-diethoxy phenyl) sily oxide, 1,1,3,3-four (2,5-diethoxy phenyl) sily oxide, 1,1,3,3-four (2,6-diethoxy phenyl) sily oxide, 1,1,3,3-four (3,4-diethoxy phenyl) sily oxide, 1,1,3,3-four (3,5-diethoxy phenyl) sily oxide, 1,1,3,3-four (2,3-two n-butoxy phenyl) sily oxide, 1,1,3,3-four (2,4-two n-butoxy phenyl) sily oxide, 1,1,3,3-four (2,5-two n-butoxy phenyl) sily oxide, 1,1,3,3-four (2,6-two n-butoxy phenyl) sily oxide, 1,1,3,3-four (3,4-two n-butoxy phenyl) sily oxide, 1,1,3,3-four (3,5-two n-butoxy phenyl) sily oxide, 1,1,3,3-four (2,3-two tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (2,4-two tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (2,5-two tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (2,6-two tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (3,4-two tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (3,5-two tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (2,3-two uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (2,4-two uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (2,5-two uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (2,6-two uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (3,4-two uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (3,5-two uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (2,3, the 4-trimethoxyphenyl) sily oxide, 1,1,3,3-four (2,3, the 5-trimethoxyphenyl) sily oxide, 1,1,3,3-four (2,3, the 6-trimethoxyphenyl) sily oxide, 1,1,3,3-four (2,4, the 5-trimethoxyphenyl) sily oxide, 1,1,3,3-four (2,4, the 6-trimethoxyphenyl) sily oxide, 1,1,3,3-four (2,3,4-triethoxy phenyl) sily oxide, 1,1,3,3-four (2,3,5-triethoxy phenyl) sily oxide, 1,1,3,3-four (2,3,6-triethoxy phenyl) sily oxide, 1,1,3,3-four (2,4,5-triethoxy phenyl) sily oxide, 1,1,3,3-four (2,4,6-triethoxy phenyl) sily oxide, 1,1,3,3-four (2,3,4-three n-butoxy phenyl) sily oxide, 1,1,3,3-four (2,3,5-three n-butoxy phenyl) sily oxide, 1,1,3,3-four (2,3,6-three n-butoxy phenyl) sily oxide, 1,1,3,3-four (2,4,5-three n-butoxy phenyl) sily oxide, 1,1,3,3-four (2,4,6-three n-butoxy phenyl) sily oxide, 1,1,3,3-four (2,3,4-three tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (2,3,5-three tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (2,3,6-three tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (2,4,5-three tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (2,4,6-three tert.-butoxy phenyl) sily oxide, 1,1,3,3-four (2,3,4-three uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (2,3,5-three uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (2,3,6-three uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (2,4,5-three uncle's octyl group oxygen phenyl) sily oxide, 1,1,3,3-four (2,4,6-three uncle's octyl group oxygen phenyl) sily oxide.

R ₁～R ₂₀A part be alkyl, remainder is the silicoorganic compound of alkoxyl group:

1,1,3,3-four (2-methyl-3-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-methyl-4-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-methyl-5-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-methyl-6-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (3-methyl-4-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (3-methyl-5-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-methoxyl group-3-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-methoxyl group-4-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-methoxyl group-5-aminomethyl phenyl) sily oxide, 1,1,3,3-four (3-methoxyl group-4-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-methyl-3-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-methyl-4-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-methyl-5-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-methyl-6-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (3-methyl-4-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (3-methyl-5-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-oxyethyl group-3-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-oxyethyl group-4-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-oxyethyl group-5-aminomethyl phenyl) sily oxide, 1,1,3,3-four (3-oxyethyl group-4-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-methyl-3-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-methyl-4-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-methyl-5-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-methyl-6-n-butoxy phenyl) sily oxide, 1,1,3,3-four (3-methyl-4-n-butoxy phenyl) sily oxide, 1,1,3,3-four (3-methyl-5-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-n-butoxy-3-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-n-butoxy-4-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-n-butoxy-5-aminomethyl phenyl) sily oxide, 1,1,3,3-four (3-n-butoxy-4-aminomethyl phenyl) sily oxide, 1,1,3,3-four (2-ethyl-3-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-ethyl-4-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-ethyl-5-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-ethyl-6-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (3-ethyl-4-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (3-ethyl-5-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-methoxyl group-3-ethylphenyl) sily oxide, 1,1,3,3-four (2-methoxyl group-4-ethylphenyl) sily oxide, 1,1,3,3-four (2-methoxyl group-5-ethylphenyl) sily oxide, 1,1,3,3-four (3-methoxyl group-4-ethylphenyl) sily oxide, 1,1,3,3-four (2-ethyl-3-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-ethyl-4-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-ethyl-5-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-ethyl-6-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (3-ethyl-4-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (3-ethyl-5-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-oxyethyl group-3-ethylphenyl) sily oxide, 1,1,3,3-four (2-oxyethyl group-4-ethylphenyl) sily oxide, 1,1,3,3-four (2-oxyethyl group-5-ethylphenyl) sily oxide, 1,1,3,3-four (3-oxyethyl group-4-ethylphenyl) sily oxide, 1,1,3,3-four (2-ethyl-3-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-ethyl-4-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-ethyl-5-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-ethyl-6-n-butoxy phenyl) sily oxide, 1,1,3,3-four (3-ethyl-4-n-butoxy phenyl) sily oxide, 1,1,3,3-four (3-ethyl-5-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-n-butoxy-3-ethylphenyl) sily oxide, 1,1,3,3-four (2-n-butoxy-4-ethylphenyl) sily oxide, 1,1,3,3-four (2-n-butoxy-5-ethylphenyl) sily oxide, 1,1,3,3-four (3-n-butoxy-4-ethylphenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-3-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-4-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-5-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-6-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (the 3-tertiary butyl-4-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (the 3-tertiary butyl-5-p-methoxy-phenyl) sily oxide, 1,1,3,3-four (2-methoxyl group-3-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2-methoxyl group-4-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2-methoxyl group-5-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (3-methoxyl group-4-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-3-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-4-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-5-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-6-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (the 3-tertiary butyl-4-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (the 3-tertiary butyl-5-ethoxyl phenenyl) sily oxide, 1,1,3,3-four (2-oxyethyl group-3-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2-oxyethyl group-4-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2-oxyethyl group-5-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (3-oxyethyl group-4-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-3-n-butoxy phenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-4-n-butoxy phenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-5-n-butoxy phenyl) sily oxide, 1,1,3,3-four (the 2-tertiary butyl-6-n-butoxy phenyl) sily oxide, 1,1,3,3-four (the 3-tertiary butyl-4-n-butoxy phenyl) sily oxide, 1,1,3,3-four (the 3-tertiary butyl-5-n-butoxy phenyl) sily oxide, 1,1,3,3-four (2-n-butoxy-3-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2-n-butoxy-4-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (2-n-butoxy-5-tert-butyl-phenyl) sily oxide, 1,1,3,3-four (3-n-butoxy-4-tert-butyl-phenyl) sily oxide.

R ₁～R ₂₀Be the silicoorganic compound of alkoxyalkyl, aryloxy, cycloalkyl, alkyl-cycloalkyl or aryl:

1,1,3,3-four (2-methoxymethyl phenyl) sily oxide, 1,1,3,3-four (3-methoxymethyl phenyl) sily oxide, 1,1,3,3-four (4-methoxymethyl phenyl) sily oxide, 1,1,3,3-four (2-phenyl oxygen phenyl) sily oxide, 1,1,3,3-four (3-Phenoxyphenyl) sily oxide, 1,1,3,3-four (4-Phenoxyphenyl) sily oxide, 1,1,3,3-four (2-cyclohexyl phenyl) sily oxide, 1,1,3,3-four (3-cyclohexyl phenyl) sily oxide, 1,1,3,3-four (4-cyclohexyl phenyl) sily oxide, 1,1,3,3-four (2-xenyl) sily oxide, 1,1,3,3-four (3-xenyl) sily oxide, 1,1,3,3-four (4-xenyl) sily oxide.

R ₁～R ₂₀Be the silicoorganic compound of alkylthio or dialkyl amido:

1,1,3,3-four (2-methylthio group phenyl) sily oxide, 1,1,3,3-four (3-methylthio group phenyl) sily oxide, 1,1,3,3-four (4-methylthio group phenyl) sily oxide, 1,1,3,3-four (2-N, N-dimethylaminophenyl) sily oxide, 1,1,3,3-four (3-N, N-dimethylaminophenyl) sily oxide, 1,1,3,3-four (4-N, N-dimethylaminophenyl) sily oxide, 1,1,3,3-four (2-N, N-diethylamino phenyl) sily oxide, 1,1,3,3-four (3-N, N-diethylamino phenyl) sily oxide, 1,1,3,3-four (4-N, N-diethylamino phenyl) sily oxide, 1,1,3,3-four (2-N, N-di-n-butyl aminophenyl) sily oxide, 1,1,3,3-four (3-N, N-di-n-butyl aminophenyl) sily oxide, 1,1,3,3-four (4-N, N-di-n-butyl aminophenyl) sily oxide.

The silicoorganic compound of asymmetric shape:

1,3-phenylbenzene-1, two (2-aminomethyl phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (3-aminomethyl phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (4-aminomethyl phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (2-tert-butyl-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (3-tert-butyl-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (4-tert-butyl-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (2-p-methoxy-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (3-p-methoxy-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (4-p-methoxy-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1,3-two (2, the 3-Dimethoxyphenyl) sily oxide, 1,3-phenylbenzene-1,3-two (2, the 4-Dimethoxyphenyl) sily oxide, 1,3-phenylbenzene-1,3-two (2, the 5-Dimethoxyphenyl) sily oxide, 1,3-phenylbenzene-1,3-two (2, the 6-Dimethoxyphenyl) sily oxide, 1,3-phenylbenzene-1,3-two (3, the 4-Dimethoxyphenyl) sily oxide, 1,3-phenylbenzene-1, two (3, the 5-Dimethoxyphenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (2-methyl-3-p-methoxy-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (2-methyl-4-p-methoxy-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (2-methyl-5-p-methoxy-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (2-methyl-6-p-methoxy-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (3-methyl-4-p-methoxy-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (3-methyl-5-p-methoxy-phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (2-methoxyl group-3-aminomethyl phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (2-methoxyl group-4-aminomethyl phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (2-methoxyl group-5-aminomethyl phenyl) sily oxide of 3-, 1,3-phenylbenzene-1, two (3-methoxyl group-4-aminomethyl phenyl) sily oxide of 3-etc.

In the silicoorganic compound of formula of the present invention (I), the R in the formula (I) ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30, the alkoxyl group of carbon number 1～30, the alkoxyalkyl of carbon number 2～30, the aryloxy of carbon number 6～18, the aryl of carbon number 6～18, the cycloalkyl of carbon number 5～8, the alkyl-cycloalkyl of carbon number 6～20, the alkylthio of carbon number 1～30 or the dialkyl amido of carbon number 2～30 respectively independently.Preferred " wherein, the R in the formula (I) ₁～R ₂₀Be not hydrogen atom entirely, and 1～3 hydrogen atom in the aryl of the aryloxy of above-mentioned carbon number 6～18 and carbon number 6～18 can replace with 1～3 substituting group in the alkoxyalkyl of the alkoxyl group of the alkyl that is selected from carbon number 1～30, carbon number 1～30 and carbon number 2～30 " compound.

In addition, in the above-claimed cpd, the R in the formula (I) ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30 or the alkoxyl group of carbon number 1～30 respectively independently.More preferably " wherein, the R in the formula (I) ₁～R ₂₀Be not hydrogen atom entirely " compound.

And then, in the silicoorganic compound of the present invention, the R in the formula (I) ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30 or the alkoxyl group of carbon number 1～30 respectively independently, R ₁And R ₆And R ₁₁And R ₁₆Identical, R ₂And R ₇And R ₁₂And R ₁₇Identical, R ₃And R ₈And R ₁₃And R ₁₈Identical, R ₄And R ₉And R ₁₄And R ₁₉Identical, R ₅And R ₁₀And R ₁₅And R ₂₀Identical.Preferred especially " wherein, the R in the formula (I) ₁～R ₂₀Be not hydrogen atom entirely " compound.

In the manufacture method of the silicoorganic compound of formula of the present invention (I), the R in the formula (I) ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30, the alkoxyl group of carbon number 1～30, the alkoxyalkyl of carbon number 2～30, the aryloxy of carbon number 6～18, the aryl of carbon number 6～18, the cycloalkyl of carbon number 5～8, the alkyl-cycloalkyl of carbon number 6～20, the alkylthio of carbon number 1～30 or the dialkyl amido of carbon number 2～30 respectively independently.Preferred " wherein, the R in the formula (I) ₁～R ₂₀Be not hydrogen atom entirely, and 1～3 substituting group that 1～3 hydrogen atom in the aryl of the aryloxy of above-mentioned carbon number 6～18 and carbon number 6～18 can be selected from the alkoxyalkyl of the alkoxyl group of alkyl, carbon number 1～30 of carbon number 1～30 and carbon number 2～30 replaces " the compound manufacture method.

In addition, in the manufacture method of this compound, the R in the formula (I) ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30 or the alkoxyl group of carbon number 1～30 respectively independently.More preferably " wherein, the R in the formula (I) ₁～R ₂₀Be not hydrogen atom entirely " the compound manufacture method.

And then, in the manufacture method of silicoorganic compound of the present invention, the R in the formula (I) ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30 or the alkoxyl group of carbon number 1～30 respectively independently, R ₁And R ₆And R ₁₁And R ₁₆Identical, R ₂And R ₇And R ₁₂And R ₁₇Identical, R ₃And R ₈And R ₁₃And R ₁₈Identical, R ₄And R ₉And R ₁₄And R ₁₉Identical, R ₅And R ₁₀And R ₁₅And R ₂₀Identical.Preferred especially " wherein, the R in the formula (I) ₁～R ₂₀Be not hydrogen atom entirely " the manufacture method of compound.

Silicoorganic compound of the present invention (I) are useful as organic materials for the stablizer of thermal degradation when or oxidative degradation etc.As above-mentioned organic materials, for example can enumerate following organic materials.These organic materialss can use separately, or use two kinds or more kinds of mixtures.

Thermoplastic resin as described below:

(1) high density polyethylene(HDPE) (HD-PE), new LDPE (film grade) (LD-PE) or straight chain shape new LDPE (film grade) polyethylene such as (LLDPE), (2) polypropylene, (3) ethylene/propene copolymer, (4) methylpentene polymer, (5) EEA (ethylene/ethyl acrylate copolymerization) resin, (6) ethylene/acetic acid ethylene copolymer, (7) polystyrene, poly-(p-methylstyrene) or poly-polystyrene type such as (alpha-methyl styrenes), (8) AS (vinyl cyanide/styrene copolymerized) resin, (9) ABS (acrylonitrile/butadiene/styrene copolymerization) resin such as transparent ABS resin, (10) AAS (special acrylic rubber/vinyl cyanide/styrene copolymerized) resin, (11) ACS (vinyl cyanide/chlorinatedpolyethylene/styrene copolymerized) resin, (12) AB (acrylonitrile/butadiene copolymerization) resin, (13) MS (methyl methacrylate/styrene copolymerized) resin, (14) chlorinatedpolyethylene, sovprene or chlorinated rubber, (15) polyvinyl chloride or polyvinylidene chloride, (16) methacrylic resin, (17) ethylene/vinyl alcohol copolymer resins, (18) polyacrylic ester, (19) ionomer resin, (20) polyvinyl alcohol, (21) cellulosic resin such as cellulose triacetate, (22) urethane, below the engineering resin shown in (23)～(34), (35)～(40) resin shown in, and the cyclic polyolefin resin (41) shown in the following registrar entitling.

(23) fluoro-resin such as tetrafluoroethylene, (24) modified polyphenylene ether resin and polyphenylene sulfide, (25) polyacetal, (26) polymeric amide, (27) polyethylene terephthalate, polybutylene terephthalate, vibrin such as liquid crystalline polymers [LCP] or poly(lactic acid), (28) polycarbonate, (29) polysulfones, polyether-ether-ketone or polyethersulfone, (30) aromatic polyester resin, (31) polyamidoimide, (32) polyimide, (33) polyarylester, (34) polyetherimide, (35) polyhutadiene, (36) 1,2-polyhutadiene, (37) polyisoprene, (38) segmented copolymer or the styrene/butadiene copolymers that is hydrogenated, (39) segmented copolymer or the styrene/isoprene multipolymer that is hydrogenated, (40) butadiene/acrylonitrile copolymer, (41) cyclic polyolefin resin:

Topas (registered trademark of Ticona company)

In this formula, l and m are positive integer.

ARTON (registered trademark of JSR)

In this formula, n is a positive integer.X and R represent substituting groups such as alkyl.

APEL (registered trademark of Mitsui Chemicals)

In this formula, l, m and n represent positive integer respectively independently.

ZEONEX (registered trademark of Japanese ZEON)

In this formula, n is a positive integer.In addition, the R in this formula ₁And R ₂Represent substituting groups such as alkyl respectively independently.

(42) silicon rubber, (43) epichloro hydrin rubber, (44) acrylic rubber, (45) natural rubber, (46) chlorine rubber-like coating, (47) Polyester resin lacquer, (48) polyurethane resin coating, (49) epoxypaint, (50) acrylic resin paint, (51) ethenoid resin paint, (52) amino alkyd resin coating, (53) phthalic resin coating, (54) nitrocellulose resin coating, (55) oil paint, (56) wax etc.

The thermosetting resin of (57) shown below～(64):

(57) Resins, epoxy, (58) Phthalic acid, diallyl ester prepolymer, (59) silicone resin, (60) unsaturated polyester resin, (61) acrylic acid modified benzene guanamine resin, (62) benzene guanamine/melamine resin, (63) urea-formaldehyde resin and (64) resol.

In the organic materials composition of the present invention, preferably contain the composition of thermoplastic resin [above-mentioned (1)～(41)] as organic materials.

Contain in the composition of these thermoplastic resins, more preferably contain polyethylene, polypropylene or cyclic polyolefin resin polyolefinic compositions such as [(41)], contain the composition of engineering resins [(23)～(34)] such as polymeric amide, polyethylene terephthalate and polybutylene terephthalate.

In addition, contain in the organic materials composition of engineering resin, more preferably contain the composition of engineering resin with ester bond.

These contain in the composition of the engineering resin with ester bond, especially preferably contain the composition of polycarbonate or polyester, particularly preferably contain the composition of polycarbonate.

And then, contain in the polyolefinic organic materials compositions such as above-mentioned polyethylene, polypropylene or cyclic polyolefin resin, more preferably contain the composition of polypropylene or cyclic polyolefin resin.

Said polyolefins does not have particular determination.

For example, can be radical polymerization and the polyolefine that obtains, also can be to carry out the polyolefine that polymerization manufactures by the catalyzer that use contains the metal of periodictable IVb, Vb, VIb or VIII family.As the catalyzer that contains above-mentioned metal, it can be the metal complex that contains 1 or more a plurality of ligands, described ligand is for example carried out coordinate oxide compound, halogenide, alcoholate, ester, aryl etc. by π key or σ key, these coordination compoundes can directly use, and also can be supported on the base materials such as magnesium chloride, titanium chloride, aluminum oxide or silicon oxide and use.

Said polyolefins, for example preferred polyolefine that adopts Ziegler-Natta catalyst, TNZ catalyzer, metalloscene catalyst or Philips type catalyzer etc. to manufacture that uses.

In the engineering resin, polyamide resin is the resin that amido linkage is arranged in the polymer chain, so long as resin that can heating and melting gets final product.

For example, can be the resin that any methods of the condensation reaction by two amines and omega-dicarboxylic acids, the condensation reaction of aminocarboxylic acids, the ring-opening polymerization of lactams etc. manufactures.

The object lesson of these polyamide resins can be enumerated nylon 66, nylon 69, NYLON610, nylon 612, poly--bis(p-aminocyclohexyl) methane lauramide, nylon 46, nylon 6, nylon 12, belong to the multipolymer of the nylon 66/6 of multipolymer of nylon 66 and nylon 6 or nylon 6/12 and so on.

In the engineering resin, vibrin is the resin that ester bond is arranged in the polymer chain, so long as resin that can heating and melting gets final product.For example can enumerate polyester such as polyethylene terephthalate that polycondensation by omega-dicarboxylic acids and dihydroxy compound etc. obtains or polybutylene terephthalate.This polyester both can be equal polyester, also can be copolyesters.

The polycarbonate that the present invention is used for example can be enumerated reactions such as making dihydric phenol and carbonate precursors such as carbonyl halide, haloformate or carbonic ether and the resin made.

Above-mentioned dihydric phenol, for example can enumerate dihydroxyphenyl propane, Resorcinol, methyl hydroquinone, Resorcinol, 2, two (4-hydroxy phenyl) pentanes of 2-, '-biphenyl diphenol, two (2-hydroxy phenyl) methane, two (4-hydroxy phenyl) methane, 1, two (4-hydroxy phenyl) ethane of 1-, 3, two (4-hydroxy phenyl) pentanes of 3-, 2,2 '-dihydroxybiphenyl base, 1, the 5-dihydroxy naphthlene, 2, the 6-dihydroxy naphthlene, two (4-hydroxy phenyl) sulfone, two (3,5-dimethyl-4-hydroxy phenyl) sulfone, 2,2-two (3,5-dimethyl-4-hydroxy phenyl) propane, 2,4 '-dihydroxy-diphenyl sulfone, 4,4 '-dihydroxydiphenyl ether, 4,4 '-dihydroxyl-2,5-3,5-dimethylphenyl ether, 2, two (3, the 5-two chloro-4-hydroxy phenyls) propane of 2-, 2,2-two (3,5-two bromo-4-hydroxy phenyls) propane, 2, two (the 3-chloro-4-hydroxy phenyl) propane of 2-, 2, two (the 3-bromo-4-hydroxy phenyl) propane of 2-, 2, two (the 3-fluoro-4-hydroxy phenyl) propane of 2-, 2, two (the 4-hydroxy phenyls)-1 of 2-, 1,1,3,3, the 3-HFC-236fa, 1, the 1-bis(4-hydroxyphenyl) cyclohexane, 1,1-two (3,5-two chloro-4-hydroxy phenyls) hexanaphthene, 4,4 '-dihydroxy benaophenonel, 3,3 ', 5,5 '-tetramethyl--4,4 '-dihydroxy benaophenonel, two (4-hydroxy phenyl) thioether, two (3-methyl-4-hydroxy phenyl) thioether, two (3,5-dimethyl-4-hydroxy phenyl) thioether, two (4-hydroxy phenyl) thioether or 9, two (4-hydroxy phenyl) fluorenes of 9-etc.

Above-mentioned carbonyl halide for example can be enumerated carbonyl chloride or carbonyl bromide etc.

In addition, above-mentioned haloformate for example can be enumerated the haloformate of dihydric phenols such as two chloroformic acid Resorcinol esters, or formic acid glycol ester such as halo formic acid glycol ester etc.

And then above-mentioned carbonic ether for example can be enumerated diphenyl carbonate, carbonic acid two (chloro-phenyl-) ester, carbonic acid two (tolyl) ester, carbonic acid dinaphthyl ester or methylcarbonate etc.

The polycarbonate that the present invention is used also can be enumerated the dendritic polycarbonate of branch.

This divides dendritic polycarbonate to prepare by making the compound that contains 3 or more a plurality of phenol hydroxyls and the phenol mixture and the reaction of above-mentioned carbonate precursor of dihydric phenol.

The compound that contains 3 or more a plurality of phenol hydroxyls, for example can enumerate 1,3,5-trihydroxybenzene, 2, two (the 4-hydroxy phenyl sec.-propyl) phenol, 2 of 4-, two (2-hydroxy-5-methyl base the benzyl)-4-methylphenols of 6-, 2-(4-hydroxy phenyl)-2-(2, the 4-dihydroxy phenyl) propane, 1, two { two (4-hydroxy phenyl) methyl } benzene of 4-etc.Above-mentioned polycarbonate can be made by methods such as interfacial polymerization, pyridine method or ester-interchange methods.The polycarbonate that makes with this method can be homopolymer or multipolymer.In addition, polycarbonate can be polyestercarbonate or poly phosphate carbonic ether.

During the molecular weight of polycarbonate viscosity-average molecular weight (under 25 ℃, the value that gets by the melt viscosity conversion of methylene dichloride) expression, preferred 10000～100000 scope, more preferably 12000～50000 scope.

In addition, polycarbonate can be a polymer alloy.As the resin beyond the polycarbonate that forms polymer alloy, can enumerate polyolefine such as polyethylene or polypropylene;

Methacrylic resins such as polymethylmethacrylate;

Acronitrile-butadiene-styrene (ABS resin);

Saturated polyester (PET, PBT);

Polymeric amide;

Polyphenylene ether (PPE);

Polyester resin;

Acrylic resin;

Silicone based resin;

Polyimide resin;

Polyetherimide resin;

Urethane;

Polyphenylene sulfide;

Polysulfone resin;

Polystyrene resin;

Acrylonitritrile-styrene resin (AS);

Resol;

Resins, epoxy;

Styrene/butadiene/styrene block copolymers (SBS);

Iso-butylene/synthetic polyisoprene;

Styrene/butadiene rubbers;

Ethylene/propylene rubber;

Acrylic elastomer;

Polyester elastomer;

Polyamide-based elastomerics;

Methyl methacrylate/Butadiene (MBS);

Methyl methacrylate/vinyl cyanide/vinylbenzene (MAS) thermoplastic elastomer;

Hydrogenated styrene/Butadiene segmented copolymer (SEBS);

Styrene/isoprene/styrene segmented copolymer (SIS);

Hydrogenated styrene/isoprene/styrene block copolymer (SEPS) etc.

And then polycarbonate can be filled with glass fibre, carbon fiber or fluoro-resin etc.

Organic materials composition of the present invention is characterised in that, contain above-mentioned organic materials and aforesaid silicoorganic compound (I), and the weight ratio of this organic materials and silicoorganic compound is 100: 0.0001～100: 10 a scope.

For organic materials composition of the present invention, the weight ratio of organic materials and organosilicon compound (I) can not fully prevent the deterioration of organic materials sometimes less than 100: 0.0001 o'clock.

On the other hand, the weight ratio of organic materials and organosilicon compound (I) surpasses at 100: 10 o'clock, and the deterioration preventing effect of organic materials does not improve so, and is but unfavorable economically.

As organic materials composition of the present invention, the R in the above-mentioned formula (I) ₁～R ₂₀Represent independently respectively hydrogen atom, carbon number 1～30 alkyl,, the alkoxyl group of carbon number 1～30, the alkoxyalkyl of carbon number 2～30, the aryloxy of carbon number 6～18, the aryl of carbon number 6～18, the cycloalkyl of carbon number 5～8, the alkyl-cycloalkyl of carbon number 6～20, the alkylthio of carbon number 1～30 or the dialkyl amido of carbon number 2～30.Preferred " wherein, the R in the formula (I) ₁～R ₂₀Be not hydrogen atom entirely, and 1～3 substituting group that 1～3 hydrogen atom in the aryl of the aryloxy of above-mentioned carbon number 6～18 and carbon number 6～18 can be selected from the alkoxyalkyl of the alkoxyl group of alkyl, carbon number 1～30 of carbon number 1～30 and carbon number 2～30 replaces " composition.

In addition, as organic materials composition of the present invention, the R in the formula (I) ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30 or the alkoxyl group of carbon number 1～30 respectively independently.More preferably " wherein, the R in the formula (I) ₁～R ₂₀Be not hydrogen atom entirely " composition.

And then, as organic materials composition of the present invention, the R in the formula (I) ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30 or the alkoxyl group of carbon number 1～30 respectively independently, R ₁And R ₆And R ₁₁And R ₁₆Identical, R ₂And R ₇And R ₁₂And R ₁₇Identical, R ₃And R ₈And R ₁₃And R ₁₈Identical, R ₄And R ₉And R ₁₄And R ₁₉Identical, R ₅And R ₁₀And R ₁₅And R ₂₀Identical.Preferred especially " wherein, the R in the formula (I) ₁～R ₂₀Be not hydrogen atom entirely " composition.

As required, organic materials composition of the present invention can also contain other additive, for example phenol antioxidant, Phosphorus antioxidant, sulphur class antioxidant, UV light absorber, photostabilizer, azanol, metal passivator, metallic soap class, nucleator, lubricant, antifogging agent, softening agent, fire retardant, releasing agent, static inhibitor, pigment, dyestuff, filler, whipping agent or organo-peroxide etc.

In addition, also can add Benzopyranone kind described in No. 4325853 specification sheets of United States Patent (USP), No. 4338244 specification sheets of United States Patent (USP), No. 5175312 specification sheets of United States Patent (USP), No. 5216053 specification sheets of United States Patent (USP), No. 5252643 specification sheets of United States Patent (USP), DE-A-4316611 communique, DE-A-4316622 communique, DE-A-4316876 communique, EP-A-589839 communique, EP-A-591102 communique, the CA-2132132 communique etc. or dihydroindolines etc.

Can also add epoxy compounds or oxygen heterocycle butanes such as epoxidised soybean oil.

When the organic materials in the organic materials composition of the present invention is polycarbonate, as addible additive beyond the silicoorganic compound, can enumerate phenol antioxidant, Phosphorus antioxidant, sulphur class antioxidant, UV light absorber, releasing agent, dyestuff, fire retardant, static inhibitor, pigment or filler.

The preferred above-mentioned thermoplastic resin of organic materials in the organic materials composition of the present invention.

In addition, preferred above-mentioned polyolefine or the engineering resin of this thermoplastic resin.Preferred above-mentioned polycarbonate of this project resin or above-mentioned polyester.

The special optimization polycarbonate of above-mentioned engineering resin.

And then, said polyolefins optimization polypropylene or cyclic polyolefin.

When the organic materials in the organic materials composition of the present invention was polycarbonate, above-mentioned phenol antioxidant can be enumerated the antioxidant of following (1)～(17).

(1) alkylation monophenol

2, the 6-di-tert-butyl-4-methy phenol, 2,4, the 6-tri-butyl-phenol, 2, the 6-DI-tert-butylphenol compounds, the 2-tertiary butyl-4, the 6-xylenol, 2,6-di-t-butyl-4-ethylphenol, 2,6-di-t-butyl-4-normal-butyl phenol, 2,6-di-t-butyl-4-isobutyl-phenol, 2,6-two cyclopentyl-4-methylphenol, 2-(Alpha-Methyl cyclohexyl)-4, the 6-xylenol, 2,6-two (octadecyl)-4-methylphenol, 2,4,6-thricyclohexyl phenol, 2,6-di-t-butyl-4-methoxymethyl phenol, 2,6-dinonyl-4-methylphenol, 2,4-dimethyl-6-(phenol of 1 '-methyl undecyl-1 '-yl), 2,4-dimethyl-6-(phenol or 2 of 1 '-methyl heptadecyl-1 '-yl), 4-dimethyl-6-(1 '-methyl tridecyl-1 '-yl) phenol, and their mixture.

(2) alkylthiomethyl phenol

2,4-dioctyl sulphomethyl-6-tert.-butyl phenol, 2,4-dioctyl sulphomethyl-6-methylphenol, 2,4-dioctyl sulphomethyl-6-ethylphenol, 2,6-two (dodecyl sulphomethyl)-4-nonylphenol and their mixture.

(3) Resorcinol and alkylated hydroquinone

2,6-di-t-butyl-4-methoxyphenol, 2,5-di-tert-butyl hydroquinone, 2,5-two tert-pentyl Resorcinol, 2,6-phenylbenzene-4-octadecyl oxy phenol, 2,6-di-tert-butyl hydroquinone, 2,5-di-t-butyl-4-hydroxyanisol, 3,5-di-tert-butyl-hydroxy phenyl stearate, two (3, the 5-di-tert-butyl-hydroxy phenyl) adipic acid ester and their mixture.

(4) tocopherol

Alpha-tocopherol, 5,8-dimethyl tocol, Gamma-Tocopherol, Delta-Tocopherol, and their mixture.

(5) hydroxylation sulfo-diphenyl ether

2,2 ,-thiobis (6-tert.-butyl phenol), 2,2 '-thiobis (4-methyl-6-tert butyl phenol), 2,2 '-thiobis (4-octyl phenol), 4,4 '-thiobis (3 methy 6 tert butyl phenol), 4,4 '-thiobis (2-methyl-6-tert butyl phenol), 4,4 '-thiobis (3, the 6-di-tert-pentyl phenol), 4,4 '-(2,6-dimethyl-4-hydroxy phenyl) disulfide, and their mixture.

(6) alkylidene diphenyl phenol and derivative thereof

2,2 '-methylene-bis (4-methyl-6-tert butyl phenol), 2,2 '-methylene-bis(4-ethyl-6-t-butyl phenol), 2,2 '-methylene-bis [4-methyl-6-(Alpha-Methyl cyclohexyl) phenol], 2,2 '-methylene-bis(4-methyl-6-cyclohexyl phenol), 2,2 '-methylene-bis(4-methyl-6-nonyl phenol), 2,2 '-methylene-bis (4, the 6-DI-tert-butylphenol compounds), 2,2 '-ethylenebis (4, the 6-DI-tert-butylphenol compounds), 2,2 '-ethylenebis (4-isobutyl--6-tert.-butyl phenol), 2,2 '-methylene-bis [6-(α-Jia Jibianji)-4-nonylphenol], 2,2 '-methylene-bis [6-(α, α-Er Jiajibianji)-the 4-nonylphenol], 4,4 '-methylene-bis (the 6-tertiary butyl-2-methylphenol), 4,4 '-methylene-bis (2, the 6-DI-tert-butylphenol compounds), 4,4 '-butylidene-bis(3-methyl-6-t-butyl phenol), 1, the 1-bis(4-hydroxyphenyl) cyclohexane, 1, two (5-tertiary butyl-4-hydroxy-2-aminomethyl phenyl) butane of 1-, 2, two (the 3-tertiary butyl-5-methyl-2-hydroxybenzyl)-4-methylphenols of 6-, 1,1,3-three (5-tertiary butyl-4-hydroxy-2-aminomethyl phenyl) butane, 1, two (5-tertiary butyl-4-hydroxy-2-the aminomethyl phenyl)-3-dodecyl sulfydryl butane of 1-, ethylene glycol bis [3, two-the 3 '-tertiary butyls-4 ' of 3--hydroxy phenyl) butyric ester], two (3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) Dicyclopentadiene (DCPD), two [2-(3 '-tertiary butyl-2 '-hydroxyl-5 '-the methyl-benzyl)-6-tertiary butyl-4-aminomethyl phenyl] terephthalate, 1,1-two (3,5-dimethyl-2-hydroxy phenyl) butane, 2,2-two (3, the 5-di-tert-butyl-hydroxy phenyl) propane, 2, two (5-tertiary butyl-4-hydroxy-2-the aminomethyl phenyl)-4-dodecyl sulfydryl butane of 2-, 1,1,5,5-four (5-tertiary butyl-4-hydroxy-2-aminomethyl phenyl) pentane, the 2-tertiary butyl-6-(3 '-tertiary butyl-5 '-methyl-2 '-hydroxybenzyl)-4-aminomethyl phenyl acrylate, 2,4-two tert-pentyls-6-[1-(2-hydroxyl-3, the 5-di-tert-pentyl-phenyl) ethyl] phenyl acrylate, and their mixture.

(7) O-, N-and S-benzyl derivative

3,5,3 ', 5 '-tetra-tert-4,4 '-dihydroxyl dibenzyl ether, octadecyl-4-hydroxyl-3,5-dimethyl benzyl mercaptoacetate, three (3, the 5-di-tert-butyl-4-hydroxyl benzyl) amine, two (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzyl) dithio terephthalate, two (3, the 5-di-tert-butyl-4-hydroxyl benzyl) thioether, iso-octyl-3,5-di-tert-butyl-4-hydroxyl benzyl mercaptoacetate, and their mixture.

(8) hydroxybenzyl malonic ester derivative

Two (octadecyl)-2,2-two (3,5-di-t-butyl-2-hydroxybenzyl) malonic ester, two (octadecyl)-2-(3-tertiary butyl-4-hydroxy-5-methyl-benzyl) malonic ester, two (dodecyl) mercaptoethyl-2, two (3, the 5-di-tert-butyl-4-hydroxyl benzyl) malonic esters of 2-, two [4-(1,1,3, the 3-tetramethyl butyl) phenyl]-2,2-two (3, the 5-di-tert-butyl-4-hydroxyl benzyl) malonic ester, and their mixture.

(9) aromatic hydroxy benzyl derivative

1,3,5-trimethylammonium-2,4,6-three (3, the 5-di-tert-butyl-4-hydroxyl benzyl) benzene, 1, two (3, the 5-di-tert-butyl-4-hydroxyl benzyl)-2,3,5 of 4-, 6-tetramethyl-benzene, 2,4,6-three (3,5-tertiary butyl-4-hydroxy benzyl) phenol, and their mixture.

(10) pyrrolotriazine derivatives

2, two (n-octyl the sulphur)-6-(4-hydroxyl-3,5-di-tert-butyl amido)-1 of 4-; 3, the 5-triazine; 2-n-octyl sulphur-4, two (the 4-hydroxyls-3 of 6-; 5-di-tert-butyl amido)-1,3,5-triazines; 2-n-octyl sulphur-4; two (4-hydroxyl-3, the 5-di-t-butyl phenoxy groups)-1,3 of 6-; the 5-triazine; 2,4,6-three (3; 5-di-t-butyl-4-phenoxy group)-1; 3, the 5-triazine; three (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzyl) isocyanuric acid ester; three (3; the 5-di-tert-butyl-4-hydroxyl benzyl) isocyanuric acid ester; 2; 4,6-three (3,5-di-tert-butyl-hydroxy phenyl ethyl)-1; 3; the 5-triazine; 2,4,6-three (3; 5-di-tert-butyl-hydroxy phenyl propyl group)-1; 3, the 5-triazine; three (3,5-dicyclohexyl-4-hydroxybenzyl) isocyanuric acid ester; three [2-(3 '; 5 '-di-t-butyl-4 '-hydroxyl cinnamoyl oxygen) ethyl] isocyanuric acid ester, and their mixture.

(11) benzyl phosphate derivative

Dimethyl-3,5-di-tert-butyl-4-hydroxyl benzyl phosphoric acid ester, diethyl-3,5-di-tert-butyl-4-hydroxyl benzyl phosphoric acid ester, two (octadecyl)-3,5-di-tert-butyl-4-hydroxyl benzyl phosphoric acid ester, two (octadecyl)-5-tertiary butyl-4-hydroxies-3-methyl-benzyl phosphoric acid ester, 3, the calcium salt of 5-di-tert-butyl-4-hydroxyl benzyl phosphate monoester, and their mixture.

(12) acyl aminophenols derivative

4-hydroxy-n-lauroyl aniline, 4-hydroxy-n-stearanilide, octyl group-N-(3, the 5-di-tert-butyl-hydroxy phenyl) carbamate, and their mixture.

(13) β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid and following monobasic or the ester of polyvalent alcohol

Methyl alcohol, ethanol, octanol, stearyl alcohol, ethylene glycol, 1, ammediol, 1,4-butyleneglycol, 1,6-hexylene glycol, 1,9-nonanediol, neopentyl glycol, glycol ether, THIOGLYCOL, spiral shell glycol, triglycol, tetramethylolmethane, three (hydroxyethyl) isocyanuric acid ester, N, N '-two (hydroxyethyl) oxamide, 3-sulfo-undecyl alcohol, 3-sulfo-pentadecanol, trimethylammonium hexylene glycol, TriMethylolPropane(TMP), 4-hydroxymethyl-1-phospha-2,6,7-trioxa-l-phosphabicyclo [2,2,2] octane, and their mixture.

(14) β-(5-tertiary butyl-4-hydroxy-3-aminomethyl phenyl) propionic acid and following monobasic or the ester of polyvalent alcohol

(15) β-(3,5-dicyclohexyl-4-hydroxy phenyl) propionic acid and following monobasic or the ester of polyvalent alcohol

(16) 3,5-di-tert-butyl-hydroxy phenyl acetate and following monobasic or the ester of polyvalent alcohol

(17) acid amides of β-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid

N; [3-(3 ' for N '-two; 5 '-di-t-butyl-4 '-hydroxy phenyl) propionyl] hydrazine, N; [3-(3 ' for N '-two; 5 '-di-t-butyl-4 '-hydroxy phenyl) propionyl] hexamethylene-diamine, N; N '-two [3-(3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) propionyl] trimethylene diamines, and their mixture.

Particularly preferred phenol antioxidant can be enumerated following compound.

Phenol antioxidant can use the mixture of two or more.

2; the 6-di-tert-butyl-4-methy phenol; 2; 4; the 6-tri-butyl-phenol; 2; 4-dioctyl sulphomethyl-6-methylphenol; 2; 2 '-thiobis (6-tert.-butyl phenol); 4; 4 '-thiobis (3 methy 6 tert butyl phenol); 2; 2 '-methylene-bis (4-methyl-6-tert butyl phenol); 2; 2 '-methylene-bis(4-ethyl-6-t-butyl phenol); 2; 2 '-methylene-bis [4-methyl-6-(Alpha-Methyl cyclohexyl) phenol]; 2; 2 '-methylene-bis(4-methyl-6-cyclohexyl phenol); 2; 2 '-methylene-bis (4; the 6-DI-tert-butylphenol compounds); 2; 2 '-ethylenebis (4; the 6-DI-tert-butylphenol compounds); 4; 4 '-methylene-bis (the 6-tertiary butyl-2-methylphenol); 4; 4 '-methylene-bis (2; the 6-DI-tert-butylphenol compounds); 4; 4 '-butylidene-bis(3-methyl-6-t-butyl phenol); 1; the 1-bis(4-hydroxyphenyl) cyclohexane; 1; two (5-tertiary butyl-4-hydroxy-2-aminomethyl phenyl) butane of 1-; 1; 1; 3-three (5-tertiary butyl-4-hydroxy-2-aminomethyl phenyl) butane; ethylene glycol bis [3; two-the 3 '-butyl-4 ' of 3--hydroxy phenyl butyric ester]; the 2-tertiary butyl-6-(3 '-tertiary butyl-5 '-methyl-2 '-hydroxybenzyl)-4-aminomethyl phenyl acrylate; 2; 4-two tert-pentyls-6-[1-(2-hydroxyl-3; the 5-di-tert-pentyl-phenyl) ethyl] phenyl acrylate; 2; 4; 6-three (3; 5-di-t-butyl-4-phenoxy group)-1; 3; the 5-triazine; three (the 4-tertiary butyls-3-hydroxyl-2; the 6-dimethyl benzyl) isocyanuric acid ester; two (3; the 5-di-tert-butyl-4-hydroxyl benzyl) isocyanuric acid ester; three [2-(3 '; 5 '-di-t-butyl-4 '-hydroxyl cinnamoyl oxygen) ethyl] isocyanuric acid ester; diethyl-3; 5-di-tert-butyl-4-hydroxyl benzyl phosphoric acid ester; two Octadecane bases-3; 5-di-tert-butyl-4-hydroxyl benzyl phosphoric acid ester; 3; the calcium salt of 5-di-tert-butyl-4-hydroxyl benzyl phosphate monoester; Octadecane base 3-(3; the 5-di-tert-butyl-hydroxy phenyl) propionic ester; Ji Wusi base four (3; 5-di-t-butyl-4-hydroxyl cortex cinnamomi acid ester); sulfo-divinyl two (3; 5-di-t-butyl-4-hydroxyl cortex cinnamomi acid ester); 1; 3; 5-trimethylammonium-2; 4; 6-three (3; the 5-di-tert-butyl-4-hydroxyl benzyl) benzene; 3; 6-two oxa-hexa-methylenes two (3; 5-di-t-butyl-4-hydroxyl cortex cinnamomi acid ester); hexa-methylene two (3; 5-di-t-butyl-4-hydroxyl cortex cinnamomi acid ester); triglycol two (5-tertiary butyl-4-hydroxy-3-tolyl acrylic acid ester); 3; two [the 2-(3-(3-tertiary butyl-4-hydroxy-5-aminomethyl phenyl) propionyl oxygen)-1 of 9-; the 1-dimethyl ethyl]-2; 4; 8; 10-four oxaspiros [55] undecane; N; [3-(3 ' for N '-two; 5 '-di-t-butyl-4 '-hydroxy phenyl) propionyl] hydrazine; N; N '--two [3-(3 ', 5 '-di-t-butyl-4 '-hydroxy phenyl) propionyl] hexamethylene-diamine etc.

In addition, Phosphorus antioxidant can be listed below, and they also can use the mixture of two or more.

Three (nonyl phenyl) phosphorous acid ester, three (2, the 4-di-tert-butyl-phenyl) phosphorous acid ester, two (octadecyl) pentaerythritol diphosphites, two (2, the 4-di-tert-butyl-phenyl) pentaerythritol diphosphites, two (2,4-di-t-butyl-6-aminomethyl phenyl) pentaerythritol diphosphites, two (2,6-di-t-butyl-4-aminomethyl phenyl) pentaerythritol diphosphites, four (2, the 4-di-tert-butyl-phenyl)-4,4 '-diphenylene diphosphites, 2,2 '-methylene-bis (4, the 6-di-tert-butyl-phenyl)-2-ethylhexyl phosphorous acid ester, 2,2 '-ethylenebis (4, the 6-di-tert-butyl-phenyl) fluorophosphites, two (2,4-di-t-butyl-6-aminomethyl phenyl) ethide phosphite ester, 2-(2,4,6-tri-tert phenyl)-5-ethyl-5-butyl-1,3,2-oxygen phospha cyclohexane (オキサホスホリ Na Application), 2,2 '; 2 "-nitrilo [triethyl three (3,3 ', 5,5 '-tetra-tert-1,1 '-xenyl-2,2 '-two bases) phosphorous acid ester or 2,4,8,10-four-tertiary butyl-6-[3-(3-methyl-4-hydroxyl-5-tert-butyl-phenyl) propoxy-] dibenzo [d, f] [1,3,2] two oxa-phosphorus suberane (オキサホス Off エピ Application), two (2,4-diisopropylbenzyl phenyl) pentaerythritol diphosphites etc.

Sulphur class antioxidant can exemplify as follows, and they also can use the mixture of two or more.

3, the two dodecane esters, 3 of 3 '-thio-2 acid, 3 '-thio-2 acid tridecane ester, 3, the two tetradecane esters, 3 of 3 '-thio-2 acid, the two octadecane esters, 3 of 3 '-thio-2 acid, 3 '-thio-2 acid dodecyl stearyl, Ji Wusi base four (3-dodecyl thiopropionate) etc.

Benzopyranone kind can enumerate 5,7-di-t-butyl-3-(3, the 4-3,5-dimethylphenyl)-3H-benzofuran-2-ones etc.

UV light absorber can exemplify as follows, and they also can use the mixture of two or more.

(1) salicylic acid ester derivative

Salol, Whitfield's ointment-4-tertiary butyl phenyl ester, 3 '; 5 '-di-t-butyl-4 '-hydroxy-benzoic acid-2; 4-di-t-butyl phenyl ester, 4 tert octylphenyl salicylate, two (4-tert.-butylbenzene formyl radical) Resorcinol, benzoyl Resorcinol, 3 '; 5 '-di-t-butyl-4 '-hydroxy-benzoic acid n-Hexadecane ester, 3 '; 5 '-di-t-butyl-4 '-hydroxy-benzoic acid octadecane ester, 3 '; 5 '-di-t-butyl-4 '-hydroxy-benzoic acid (2-methyl-4; the 6-di-tert-butyl) ester, and their mixture etc.

(2) 2-hydroxyl benzophenone derivant

2; 4-dihydroxy benaophenonel, 2-hydroxyl-4-methoxy benzophenone, 2-hydroxyl-4-octyloxy benzophenone, 2; 2 '-dihydroxyl-4-methoxy benzophenone, two (5-benzoyl-4-hydroxyl-2-p-methoxy-phenyl) methane, 2; 2 '; 4; 4 '-tetrahydroxybenzophenone, and their mixture etc.

(3) 2-(2 '-hydroxy phenyl) benzotriazole, 2-(2-hydroxy-5-methyl base phenyl) benzotriazole, 2-(3 ', 5 '-di-t-butyl-2 '-hydroxy phenyl) benzotriazole, 2-(5 '-tertiary butyl-2 '-hydroxy phenyl) benzotriazole, 2-(2 '-hydroxyl-5 '-uncle's octyl phenyl) benzotriazole, 2-(the 3-tertiary butyl-2-hydroxy-5-methyl base phenyl)-5-chlorobenzotriazole, 2-(3 '-sec-butyl-2 '-hydroxyl-5 '-tert-butyl-phenyl) benzotriazole, 2-(2 '-hydroxyl-4 '-octyl group oxygen phenyl) benzotriazole, 2-(3 ', 5 '-two tert-pentyls-2 '-hydroxy phenyl) benzotriazole, 2-[2 '-hydroxyl-3 ', 5 '-two (α, α-Er Jiajibianji) phenyl]-the 2H-benzotriazole, the 2-[(3 '-tertiary butyl-2 '-hydroxy phenyl)-5 '-(2-octyl group oxygen carbonyl ethyl) phenyl]-the 5-chlorobenzotriazole, the 2-[3 '-tertiary butyl-5 '-[2-(2-ethylhexyl oxygen) carbonyl ethyl]-2 '-hydroxy phenyl]-the 5-chlorobenzotriazole, the 2-[3 '-tertiary butyl-2 '-hydroxyl-5 '-(2-methoxycarbonyl ethyl) phenyl]-the 5-chlorobenzotriazole, the 2-[3 '-tertiary butyl-2 '-hydroxyl-5 '-(2-methoxycarbonyl ethyl) phenyl] benzotriazole, the 2-[3 '-tertiary butyl-2 '-hydroxyl-5-(2-octyl group oxygen carbonyl ethyl) phenyl] benzotriazole, the 2-[3 '-tertiary butyl-2 '-hydroxyl-5 '-[2-(2-ethylhexyl oxygen) carbonyl ethyl] phenyl] benzotriazole, 2-[2-hydroxyl-3-(3,4,5,6-tetrahydrophthalimide methyl)-and the 5-aminomethyl phenyl] benzotriazole, 2-(3,5-di-t-butyl-2-hydroxy phenyl)-the 5-chlorobenzotriazole, 2-(3 '-dodecyl-2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole and 2-[3 '-tertiary butyl-2 '-hydroxyl-5 '-(2-iso-octyl oxygen carbonyl ethyl) phenyl] mixture of benzotriazole, 2,2 '-methylene-bis [6-(2H-benzotriazole-2-yl)-4-(1,1,3, the 3-tetramethyl butyl) phenol, 2,2 '-methylene-bis [the 4-tertiary butyl-6-(2H-benzotriazole-2-yl) phenol], poly-(3～11) (ethylene glycol) and 2-[3 '-tertiary butyl-2 '-hydroxyl-5 '-(2-methoxycarbonyl ethyl) phenyl] condenses of benzotriazole, poly-(3～11) (ethylene glycol) and 3-[(2H-benzotriazole-2-yl)-the 5-tert-butyl-hydroxy phenyl] condenses of methyl propionate, the 3-[3-tertiary butyl-5-(5-chloro-2H-benzotriazole-2-yl)-4-hydroxy phenyl] propionic acid 2-ethylhexyl, the 3-[3-tertiary butyl-5-(5-chloro-2H-benzotriazole-2-yl)-4-hydroxy phenyl] n-octyl propionate, the 3-[3-tertiary butyl-5-(5-chloro-2H-benzotriazole-2-yl)-4-hydroxy phenyl] methyl propionate, the 3-[3-tertiary butyl-5-(5-chloro-2H-benzotriazole-2-yl)-4-hydroxy phenyl] propionic acid, and their mixture etc.

(4) 2-(2-hydroxy phenyl)-1,3,5-triazines class

2,4,6-three (2-hydroxyl-4-octyl group oxygen phenyl)-1,3, the 5-triazine, 2-(2-hydroxyl-4-octyl group oxygen phenyl)-4,6-two (2, the 4-3,5-dimethylphenyl)-1,3,5-triazines, 2-[2,4-dihydroxy phenyl-4, two (2, the 4-3,5-dimethylphenyl)-1 of 6-, 3, the 5-triazine, 2, two (2-hydroxyl-4-propyl group oxygen the phenyl)-6-(2 of 4-, the 4-3,5-dimethylphenyl)-1,3,5-triazines, 2-(2-hydroxyl-4-octyl group oxygen phenyl)-4, two (4-the aminomethyl phenyl)-1,3,5-triazines of 6-, 2-(2-hydroxyl-4-dodecyl oxygen phenyl)-4, two (2, the 4-3,5-dimethylphenyl)-1,3 of 6-, the 5-triazine, 2-[2-hydroxyl-4-(2-hydroxyl-3-butyl oxygen propoxy-) phenyl]-4, two (2, the 4-3,5-dimethylphenyl)-1 of 6-, 3, the 5-triazine, 2-[2-hydroxyl-4-(2-hydroxyl-3-octyl group oxygen propoxy-) phenyl]-4, two (2, the 4-3,5-dimethylphenyl)-1 of 6-, 3, the 5-triazine, 2-(4,6-phenylbenzene-1,3,5-triazine-2-yl)-and the 5-[(hexyl) oxygen]-phenol, and their mixture etc.

(5) malonic ester class

To anisole methylene radical dimethyl malonate, HOSTAVIN B-CAPXP, and their mixture etc.

Particularly preferred UV light absorber can exemplify as follows, and they also can use the mixture of two or more.

Salol; Whitfield's ointment-4-tertiary butyl phenyl ester; 3 '; 5 '-di-t-butyl-4 '-hydroxy-benzoic acid-2; 4-di-t-butyl phenyl ester; 4 tert octylphenyl salicylate; 2; the 4-dihydroxy benaophenonel; 2-hydroxyl-4-methoxy benzophenone; 2-hydroxyl-4-octyloxy benzophenone; 2; 2 '-dihydroxyl-4-methoxy benzophenone; two (5-benzoyl-4-hydroxyl-2-p-methoxy-phenyl) methane; 2; 2 '; 4; 4 '-tetrahydroxybenzophenone; 2-(2-hydroxy-5-methyl base phenyl) benzotriazole; 2-(3 '; 5 '-di-t-butyl-2 '-hydroxy phenyl) benzotriazole; 2-(5 '-tertiary butyl-2 '-hydroxy phenyl) benzotriazole; 2-(2 '-hydroxyl-5 '-uncle's octyl phenyl) benzotriazole; 2-(the 3-tertiary butyl-2-hydroxy-5-methyl base phenyl)-5-chlorobenzotriazole; 2-(3 '-sec-butyl-2 '-hydroxyl-5 '-tert-butyl-phenyl) benzotriazole; 2-(2 '-hydroxyl-4 '-octyl group oxygen phenyl) benzotriazole; 2-(3 '; 5 '-two tert-pentyls-2 '-hydroxy phenyl) benzotriazole; 2-[2 '-hydroxyl-3 '; 5 '-two (α; α-Er Jiajibianji) phenyl]-the 2H-benzotriazole; 2; 2 '-methylene-bis [6-(2H-benzotriazole-2-yl)-4-(1; 1; 3; the 3-tetramethyl butyl) phenol; 2-(2-hydroxyl-4-octyl group oxygen phenyl)-4; 6-two (2; the 4-3,5-dimethylphenyl)-1; 3; the 5-triazine; 2-(4; 6-phenylbenzene-1; 3,5-triazine-2-yl)-the 5-[(hexyl) oxygen]-phenol; to anisole methylene radical dimethyl malonate; HOSTAVIN B-CAPXP etc.

Photostabilizer can exemplify as follows.

(1) hindered amine light stabilizer

Two (2,2,6; 6-tetramethyl--4-piperidyl) sebate; two (2,2,6; 6-tetramethyl--4-piperidyl) succinate; two (1,2,2; 6,6-pentamethyl--4-piperidyl) sebate; two (N-octyloxies-2,2; 6,6-tetramethyl--4-piperidyl) sebate; two (N-benzyl oxygen-2,2; 6,6-tetramethyl--4-piperidyl) sebate; two (N-cyclohexyl oxygen-2,2; 6,6-tetramethyl--4-piperidyl) sebate; two (1,2; 2,6,6-pentamethyl--4-piperidyl)-2-(3; the 5-di-tert-butyl-4-hydroxyl benzyl)-2-butyl malonic acid ester; two (1-acryl-2,2,6; 6-tetramethyl--4-piperidyl)-2, two (3, the 5-the di-tert-butyl-4-hydroxyl benzyl)-2-butyl malonic acids of 2-; two (1; 2,2,6; 6-pentamethyl--4-piperidyl) sebate; 2,2,6; 6-tetramethyl--4-piperidino methyl acrylate; 4-[3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionyl oxygen]-1-[2-(3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionyl oxygen) ethyl]-2; 2,6, the 6-tetramethyl piperidine; 2-methyl-2-(2; 2,6,6-tetramethyl--4-piperidyl) amino-N-(2; 2,6,6-tetramethyl--4-piperidyl) propionic acid amide; four (2; 2,6,6-tetramethyl--4-piperidyl)-1; 2,3,4-ethylene-dimalonic acid ester; four (1; 2,2,6; 6-pentamethyl--4-piperidyl)-1,2,3; 4-ethylene-dimalonic acid ester; 1,2,3; 4-BTCA and 1,2,2; 6, the mixed ester compound of 6-pentamethyl--pure and mild 1-tridecanol of 4-piperidines; 1,2; 3,4-BTCA and 2,2; 6, the mixed ester compound of 6-tetramethyl--pure and mild 1-tridecanol of 4-piperidines; 1,2; 3,4-BTCA and 1,2; 2,6,6-pentamethyl--4-piperidines pure and mild 3; two (2-hydroxyl-1, the 1-dimethyl ethyls)-2,4 of 9-; 8, the undecanoic mixed ester compound of 10-four oxaspiros [55]; 1,2; 3,4-BTCA and 2,2; 6; 6-tetramethyl--4-piperidines is pure and mild 3, two (2-hydroxyl-1, the 1-dimethyl ethyls)-2 of 9-; 4; 8, the undecanoic mixed ester compound of 10-four oxaspiros [55]; Succinic acid dimethylester and 1-(2-hydroxyethyl)-4-hydroxyl-2,2; 6; the polycondensate of 6-tetramethyl piperidine; poly-[(6-morpholino-1,3,5-triazines-2; 4-two bases) ((2; 2,6,6-tetramethyl--4-piperidyl) imino-) hexa-methylene ((2; 2; 6,6-tetramethyl--4-piperidyl) imino-)]; it is poly-that [(6-(1,1; 3; the 3-tetramethyl butyl) imino--1,3,5-triazines-2; 4-two bases ((2; 2,6,6-tetramethyl--4-piperidyl) imino-) hexa-methylene ((2; 2; 6,6-tetramethyl--4-piperidyl) imino-)); N, N '-two (2; 2; 6,6-tetramethyl--4-piperidyl) polycondensate of hexamethylene-diamine and glycol dibromide; N; N '; 4, and 7-four [4, the two (N-butyl-N-(2 of 6-; 2; 6,6-tetramethyl--4-piperidyl) amino)-1,3; 5-triazine-2-yl]-4; 7-diaza decane-1, the 10-diamines; N, N '; 4-three [4; 6-is two, and (N-butyl-N-(2,2,6; 6-tetramethyl--4-piperidyl) amino)-1; 3,5-triazine-2-yl]-4,7-diaza decane-1; the 10-diamines; N; N ', 4,7-four [4; two (N-butyl-the N-(1 of 6-; 2,2,6; 6-pentamethyl--4-piperidyl) amino)-1; 3,5-triazine-2-yl]-4,7-diaza decane-1; the 10-diamines; or N; N '-4-three [4, the two (normal-butyls-just (1,2 of 6-; 2; 6,6-pentamethyl--4-piperidyl) amino)-1,3; 5-triazine-2-yl]-4; 7-diaza decane-1, the 10-diamines, and their mixture etc.

(2) esters of acrylic acid photostabilizer

Alpha-cyano-β; β-diphenyl-ethyl acrylate, alpha-cyano-β; β-diphenyl 2-Propenoic acid-2-ethylhexyl ester, α-methoxycarbonyl base methyl cinnamate, alpha-cyano-Beta-methyl p-methoxycinnamic acid methyl esters, alpha-cyano-Beta-methyl p-methoxycinnamic acid butyl ester, α-methoxycarbonyl base p-methoxycinnamic acid methyl esters or N-(beta-methoxy-formyl radical-beta-cyano vinyl)-2-methyl indoline, and their mixture etc.

(3) nickel class photostabilizer

2, nickel coordination compound, nickel dibutyl dithiocarbamate, the nickel salt of single alkane ester, the nickel coordination compound of ketoxime and their mixture etc. of 2 '-thiobis [4-(1,1,3, the 3-tetramethyl butyl) phenol].

(4) oxamide light stabilizer

4,4 '-dioctyl oxygen-N, N '-oxalyl pentanoic, 2,2 '-diethoxy-N, N '-oxalyl pentanoic, 2,2 '-dioctyl oxygen-5,5 '-di-tert-butyl aniline, 2,2 '-two (dodecyl) oxygen-5,5 '-di-tert-butyl aniline, 2-oxyethyl group-2 '-ethyl-N, N '-oxalyl pentanoic, N, N '-two (3-dimethylaminopropyl) oxamide, the 2-oxyethyl group-5-tertiary butyl-2 '-phenetidine, 2-oxyethyl group-5,4 '-di-t-butyl-2 '-ethyl-N, N '-oxalyl pentanoic, and their mixture etc.

Oxyamine, for example can enumerate N, N-dibenzyl oxyamine, N, N-diethyl oxyamine, N, N-dioctyl oxyamine, N, N-dilauryl oxyamine, N, N-two (tetradecyl) oxyamine, N, N-two (hexadecyl) oxyamine, N, N-two (octadecyl) oxyamine, N-hexadecyl-N-octadecyl oxyamine, N-heptadecyl-N-octadecyl oxyamine, and their mixture etc.

Metal passivator can exemplify as follows.

N; N '-phenylbenzene oxamide, N-salicylic aldehyde-N '-salicylyl hydrazine, N; N '-two (salicylyl) hydrazine, N, N '-two (3,5-di-tert-butyl-hydroxy phenyl propionyl) hydrazine, 3-salicylamide base-1; 2; 4-triazole, two (Ben Yajiaji) oxalic acid two hydrazides, N, N '-oxalyl pentanoic, isophthalic dihydrazide, the two phenyl hydrazides of sebacic acid, N, N '-two (salicylyl) oxalic acid two hydrazides, N; N '-two (salicylyl) sulfo-propionyl two hydrazides, and their mixture etc.

Peroxide scavenger, for example can enumerate ester, mercaptobenzimidazole, the zinc salt of 2-mercaptobenzimidazole, zinc salt, two (octadecyl) disulfide of dibutyl dithiocaarbamate, tetramethylolmethane four (β-dodecyl sulfydryl) propionic ester of β-thio-2 acid, and their mixture etc.

The polymeric amide stablizer for example can be enumerated the copper of iodide or phosphorus compound or the manganese salt of divalence, and their mixture etc.

Neutralizing agent for example can be enumerated calcium stearate, Zinic stearas, Magnesium Stearate, hydrotalcite (alkaline magnalium hydroxyl carbonate hydrate), trimeric cyanamide, amine, polymeric amide, urethane, and their mixture etc.

Lubricant for example can be enumerated the ester of the aliphatic monobasic alcohol of the higher fatty acid of fatty alcohol, polyoxyethylene glycol, carbon number 4～22 of the higher fatty acid of aliphatic hydrocarbons such as paraffin or wax, carbon number 8～22, the higher fatty acid metal-salt of carbon number 8～22 (Al, Ca, Mg or Zn salt), carbon number 8～22 and carbon number 4～18, senior aliphatic amide, silicone oil or the rosin derivative etc. of carbon number 8～22.

Nucleator can exemplify as follows.

2,2 '-methylene-bis (4, the 6-di-tert-butyl-phenyl) sodium phosphate, [phosphoric acid-2,2 '-methylene-bis (4, the 6-di-tert-butyl-phenyl)] dihydroxyl aluminium, two [phosphoric acid-2,2 '-methylene-bis (4, the 6-di-tert-butyl-phenyl)] oxyaluminum, three [phosphoric acid-2,2 '-methylene-bis (4, the 6-di-tert-butyl-phenyl)] aluminium, two (4-tert-butyl-phenyl) sodium phosphate, M-nitro benzoic acid metal-salts such as sodium benzoate, to tertiary butyl M-nitro benzoic acid aluminium, 1,3:2, two (O-Ben Yajiaji) Sorbitol Powders of 4-, 1,3:2, two (the O-methylbenzene methylene radical) Sorbitol Powders of 4-, 1,3:2, two (the O-ethylbenzene methylene radical) Sorbitol Powders of 4-, 1,3-O-3,4-dimethyl benzene methylene radical-2,4-O-Ben Yajiaji Sorbitol Powder, 1,3-O-Ben Yajiaji-2,4-O-3,4-dimethyl benzene methylene radical Sorbitol Powder, 1,3:2, the two (O-3 of 4-, 4-dimethyl benzene methylene radical) Sorbitol Powder, 1,3-O-is to chlorobenzene methylene radical-2,4-O-3,4-dimethyl benzene methylene radical Sorbitol Powder, 1,3-O-3,4-dimethyl benzene methylene radical-2,4-O-is to chlorobenzene methylene radical Sorbitol Powder, 1,3:2, two (O-is to the chlorobenzene methylene radical) Sorbitol Powders of 4-, and their mixture etc.

Filler, for example can enumerate glass fibre, carbon fiber, sapphire whisker, carbon black, graphite, titanium oxide, silica, talcum, mica, lime carbonate, calcium sulfate, barium carbonate, oxysulfate, stannic oxide, aluminum oxide, kaolin, silicon carbide, metal-powder, and their mixture etc.

Static inhibitor for example can be enumerated polyether ester amides, Zerol, Witco 1298 Soft Acid ammonium salt, Witco 1298 Soft Acid microcosmic salt, maleic anhydride direactive glyceride, maleic anhydride two glyceryl ester, carbon, graphite, metal-powder etc.

The typical example of dyestuff can be enumerated the MacrolexViolet B of CI.Solvent Violet13, BAYER company or Tetrazole Blue RLS etc.

Fire retardant can be enumerated polycarbonate type fire retardant, organic salt fire retardant, aromatic phosphate acid ester based flame retardant or the halogenated aromatic phosphate type fire retardant of halogenated bisphenol A, and their mixture etc.

The polycarbonate type fire retardant of halogenated bisphenol A can be enumerated the copolymerization polycarbonate type fire retardant etc. of polycarbonate type fire retardant, tetrabromo-bisphenol and the dihydroxyphenyl propane of tetrabromo-bisphenol.

The organic salt fire retardant, can enumerate hexichol sulfo group-3,3 '-disulfonic acid dipotassium, hexichol sulfo group-3-potassium sulfonate, 2,4,5-trichlorobenzene sodium sulfonate, 2,4,5-trichlorobenzene potassium sulfonate, two (2,6-two bromo-4-cumyl phenyl) potassiumphosphate, two (4-cumyl phenyl) sodium phosphate, two (to the toluene sulfo group) imide potassium, two (diphenylphosphoric acid) imide potassium, two (2,4,6-tribromo phenyl) potassiumphosphate, two (2, the 4-dibromo phenyl) potassiumphosphate, two (4-bromophenyl) potassiumphosphate, diphenylphosphoric acid potassium, diphenylphosphoric acid sodium, potassium perfluorobutane sulfonate, Sodium Lauryl Sulphate BP/USP, lauryl potassium sulfate, Sodium palmityl sulfate, or hexadecyl hydrosulfate potassium etc.

Halogenated aromatic phosphate type fire retardant can be enumerated three (2,4,6-tribromo phenyl) phosphoric acid ester, three (2, the 4-dibromo phenyl) phosphoric acid ester or three (4-bromophenyl) phosphoric acid ester etc.

The aromatic phosphate acid ester based flame retardant, can enumerate triphenyl, three (2, the 6-xylyl) phosphoric acid ester, four (2, the 6-xylyl) resorcinol diphosphate, four (2, the 6-xylyl) Resorcinol bisphosphate, four (2, the 6-xylyl)-4,4 '-bis-phenol bisphosphate, the tetraphenyl resorcinol diphosphate, tetraphenyl Resorcinol bisphosphate, tetraphenyl-4,4 '-bis-phenol bisphosphate, the aromatic ring supply source is Resorcinol and phenol and the aromatics poly phosphate that does not contain phenol OH base, the aromatic ring supply source is Resorcinol and phenol and the aromatics poly phosphate that contains phenol OH base, the aromatic ring supply source is Resorcinol and phenol and the aromatics poly phosphate that does not contain phenol OH base, the aromatic ring supply source is Resorcinol and phenol and the aromatics poly phosphate that contains phenol OH base, the aromatic ring supply source is the aromatics poly phosphate of dihydroxyphenyl propane and phenol, the aromatic ring supply source is the aromatics poly phosphate of tetrabromo-bisphenol and phenol, the aromatic ring supply source is Resorcinol and 2, the aromatics poly phosphate of 6-xylenol, the aromatic ring supply source is Resorcinol and 2, the aromatics poly phosphate of 6-xylenol, the aromatic ring supply source is dihydroxyphenyl propane and 2, the aromatics poly phosphate of 6-xylenol, the aromatic ring supply source is the aromatics poly phosphate of tetrabromo-bisphenol and 2 etc.

Releasing agent for example can be enumerated the ester of the pure and mild lipid acid of the part ester of ester, polyvalent alcohol and lipid acid of monohydroxy-alcohol and lipid acid or full ester of polyvalent alcohol and lipid acid etc.

The ester of monohydroxy-alcohol and saturated fatty acid can be enumerated stearic stearolactone, cetyl palmitate, butyl stearate, Laurate methyl, Wickenol 111 etc.

The ester of monohydroxy-alcohol and saturated fatty acid, preferred stearic stearolactone.

The part ester of polyvalent alcohol and saturated fatty acid or full ester can be enumerated the full ester of Dipentaerythritols such as glyceryl monostearate, stearic acid two glyceryl ester, glycerol stearate, stearic acid list sorbitan ester, mountain Yu acid direactive glyceride, pentaerythritol monostearate, pentaerythritol tetrastearate, tetramethylolmethane four pelargonates, propylene glycol monostearate, xenyl bis-phenol ester (PVC Off エニ Le PVC Off エネ one ト), sorbitan monostearate, 2-ethylhexyl stearate or Dipentaerythritol six stearates or part ester etc.

In these esters, preferably use the mixture of glyceryl monostearate, glycerol stearate, pentaerythritol tetrastearate or glycerol stearate and stearic stearolactone.

The acid number of above-mentioned fatty acid ester preferred 3 or littler, more preferably 2 or littler.

For glyceryl monostearate, preferred acid number 1.5 or littler, purity 95 weight % or higher, special preferred acid number 1.2 or littler, purity 98 weight % or higher.

Releasing agent beyond the above-mentioned ester can be enumerated olefines wax, contain carboxyl and/or acid anhydride's olefines wax, silicone oil, organopolysiloxane, paraffin or beeswax etc.

Organo-peroxide for example can be enumerated diisopropylbenzyl superoxide, ditertiary butyl peroxide, di-t-butyl cumyl superoxide, 2,5-dimethyl-2,5-two (tert-butyl peroxide) hexane, 2,5-dimethyl-2,5-two (tert-butyl peroxide) hexene, 1, two (tert-butyl hydroperoxide sec.-propyl) benzene or 3 of 3-, 6,9-triethyl-3,6,9-trimethylammonium-1,4, peroxidation alkylses such as 7-three peroxidation nonanes;

Peroxidation two acyl classes such as benzoyl peroxide, lauroyl peroxide or decanoyl peroxide;

Peroxidation neodecanoic acid-1,1,3,3-tetramethyl-butyl ester, new peroxide tert-butyl caprate, peroxidation neodecanoic acid-α-isopropyl benzene ester, the new enanthic acid tert-butyl ester, the peroxidation PIVALIC ACID CRUDE (25) tert-butyl ester, the own ester of peroxidation PIVALIC ACID CRUDE (25) uncle, peroxidation-2 ethyl hexanoic acid-1,1,3,3-tetramethyl-butyl ester, peroxidation-2 ethyl hexanoic acid tert-pentyl ester, the peroxidation tert-butyl isobutyrate, peroxidation six hydrogen terephthalic acid di tert butyl carbonates, peroxidation-3,5,5-tri-methyl hexanoic acid tert-pentyl ester, peroxide acetic acid butyl ester, peroxyesters such as peroxidized t-butyl perbenzoate or peroxidation trimethyladipic acid di tert butyl carbonate;

Peroxycarbonates classes such as peroxy dicarbonate two-3-methoxyl group butyl ester, peroxy dicarbonate two (2-ethylhexyl) ester, peroxidation carbonic acid diisopropyl ester, tert-butylperoxy isopropyl carbonate, two (4-tert-butylcyclohexyl) peroxy dicarbonate, peroxy dicarbonate two (hexadecyl) ester or peroxy dicarbonate two (tetradecyl) ester.

When organic materials is polycarbonate, processed under 250～400 ℃ temperature range usually, preferably, further preferred processed under 300～350 ℃ scope 280～360 ℃ scope.

Contain organic materials composition of the present invention as the polycarbonate of organic materials, can prevent the thermolysis of polycarbonate, for example with moulding such as sheet forming composition such as automotive components such as CDs such as electronics enclosure, optical lens, illumination cover, CD or DVD, head lamp lens lid, window glass, bicycle shed tops the time, can access the goods of outward appearance excellence.

Among the present invention, when in organic materials, being added with organic silicon compound (I) and used as required other additive, as long as can obtain the composition of homogeneous, method therefor and the no particular determination of device.

For example, when in manufacturing process's (polymerization process) of organic materials, being added with organic silicon compound (I) and used as required other additive, in the polymerization way or in the polymeric liquid after the polymerization end just, both can be added with organic silicon compound (I) and other used as required additive with the form of solution or dispersion liquid, also can add with the form of Rong Rong Zhuan .

When being added with organic silicon compound (I) and used as required other additive in the heating process after volatilization, both can be directly in organic materials, do and mix above-mentioned silicoorganic compound and other used as required additive, also can use mixing machine such as Henschel mixer to mix.

In addition, also can in organic materials, the form with masterbatch cooperate organosilicon compound (I) and other used as required additive.

Embodiment

Wait by the following examples and illustrate in greater detail the present invention, but the present invention is not limited to these embodiment.

Embodiment 1

1,1,3, the manufacturing of 3-four (2-p-methoxy-phenyl) sily oxide (hereinafter referred to as compound 1)

In four-hole boiling flask (i), under nitrogen gas stream, pack into magnesium 3.6g, tetrahydrofuran (THF) 50ml and small amount of bromine, under agitation splash into 2-bromoanisole 25g and tetrahydrochysene furan south 50ml mixed solution.After splashing into termination, be incubated 3 hours down at 70 ℃.With the reaction mixture of gained ice-cooled down, splash into and be loaded among the trichlorosilane 9g and the mixture of tetrahydrofuran (THF) 50ml of four-hole boiling flask in (ii).After splashing into termination, at room temperature stirred 18 hours.

With the gained reaction mixture with saturated common salt water washing 3 times after, with organic phase with anhydrous magnesium sulfate drying after, remove by filter sal epsom.From the filtrate that obtains, heat up in a steamer and desolvate.Residue after heating up in a steamer tetrahydrofuran (THF) recrystallization obtains the compound 1 of 5.6g.

The mass spectroscopy of＜compound 1 (FD～MS)〉m/z=502

The 1H-NMR of＜compound 1 (deuterium is for tetrahydrofuran (THF))〉δ 3.52 (s, 12H), 5.63 (s, 2H), 6.75 (d, 4H), 6.82 (t, 4H), 7.27 (t, 4H), 7.40 (m, 4H)

Embodiment 2

1,1,3, the manufacturing of 3-four (2-aminomethyl phenyl) sily oxide (hereinafter referred to as compound 2)

To four-hole boiling flask pack in (iii) trichlorosilane 6.8g and tetrahydrofuran (THF) 50ml.In this mixture, under nitrogen gas stream, under 0 ℃, splash into tetrahydrofuran solution (every 1ml contains the adjacent toluene magnesium bromide of the 1.0mmol) 100ml of adjacent toluene magnesium bromide.After splashing into termination, at room temperature stirred 5 hours.After stirring termination, add entry 50g and toluene 100g, be incubated 5 hours down at 113 ℃.After insulation stops, add 1N hydrochloric acid 30g, at room temperature place a night.Spend the night after the placement, be warming up to 111 ℃, and synthermal insulation down 1 hour.Then, after the saturated common salt water washing, with gained organic phase anhydrous magnesium sulfate drying.

After removing by filter anhydrous magnesium sulfate, distillation gained filtrate obtains lower boiling toluene and high boiling cut.With the high boiling cut ethyl alcohol recrystallization of gained, obtain the compound 2 of 1.4g.

The mass spectroscopy of＜compound 2 (FD-MS)〉m/z=438

The 1H-NMR of＜compound 2 (CDCl3)〉δ 2.22～2.26 (m, 12H), 5.75 (s, 2H), 7.07～7.14 (m, 8H), 7.26～7.29 (m, 4H), 7.54 (d, 4H)

Embodiment 3

1,1,3, the manufacturing of 3-four (2-methyl-4-p-methoxy-phenyl) sily oxide (hereinafter referred to as compound 3)

To four-hole boiling flask (iv) in, under nitrogen gas stream, pack into magnesium 1.6g, tetrahydrofuran (THF) 50ml and small amount of bromine.Then, under agitation, splash into the mixed solution of 2-bromo-5-methoxy toluene 12g and tetrahydrofuran (THF) 50ml.After splashing into termination, be incubated 2 hours down at 70 ℃.(mixture of pack into v) trichlorosilane 3.2g and tetrahydrofuran (THF) 50ml under-30 ℃, splashes into the reaction solution of above-mentioned insulation after 2 hours in this mixture to four-hole boiling flask.After splashing into termination, at room temperature stirred 1 hour.After in the gained reaction solution, splashing into saturated aqueous common salt under-30 ℃, splashing into termination, at room temperature stirred 12 hours.After gained organic phase usefulness saturated common salt water washing 2 times, with gained organic phase anhydrous magnesium sulfate drying.Remove by filter anhydrous magnesium sulfate.From the filtrate that obtains, heat up in a steamer and desolvate.Residue after will heating up in a steamer carries out recrystallization with tetrahydrofuran (THF)/normal hexane mixed solvent, obtains the compound 3 of 0.5g.

The mass spectroscopy of＜compound 3 (FD-MS)〉m/z=558

The 1H-NMR of＜compound 3 (CDCl3)〉δ 2.36 (s, 12H), 3.80 (s, 12H), 5.62 (s, 2H), 6.73～6.75 (m, 8H), 7.48 (d, 4H)

Embodiment 4

1,1,3, the manufacturing of 3-four (2, the 4-Dimethoxyphenyl) sily oxide (hereinafter referred to as compound 4)

(vi), under nitrogen gas stream, magnesium 3.1g and tetrahydrofuran (THF) 20ml pack into to four-hole boiling flask.In this mixture, under agitation, splash into 1-bromo-2, the mixed solution of 4-dimethoxy benzene 25g and tetrahydrofuran (THF) 80ml.After splashing into termination, insulation is 2 hours under refluxing.(vii), triethoxyl silane 9.5g and tetrahydrofuran (THF) 40ml pack into to four-hole boiling flask.In this mixture, under above-mentioned backflow, down splash into the reaction solution of insulation after 2 hours ice-cooled, splash into termination after, stirred 2 hours down at 80 ℃.The gained reaction mixture is washed according to the order of ammonium chloride water 100ml and saturated aqueous common salt.With the organic phase anhydrous magnesium sulfate drying after the washing.After removing by filter anhydrous magnesium sulfate, in the gained organic phase, add silica dioxide gel and decolour.Organic phase after the decolouring is concentrated, obtain two (2, the 4-Dimethoxyphenyl) Ethoxysilanes of 16.7g.In above-mentioned two (2, the 4-Dimethoxyphenyl) Ethoxysilanes, add tetrahydrofuran (THF) 50ml and 1N hydrochloric acid 50ml down at 0 ℃.Then, adding toluene 100g extracts.With organic phase saturated common salt water washing 2 times.Add anhydrous magnesium sulfate in the organic phase after washing and carry out drying.After removing by filter anhydrous magnesium sulfate, concentrated filtrate heats up in a steamer and desolvates.The residual component that will heat up in a steamer after desolvating after 2 hours, is incubated 5 hours down at 160 ℃ in insulation under 155 ℃ again.Then, under 230 ℃, heat up in a steamer low boiling point component.The mixing solutions that adds 2-propyl alcohol/toluene after heating up in a steamer low boiling point component in the reaction mixture that obtains makes it separate out crystallization, obtains the compound 4 of 5.3g.

The mass spectroscopy of＜compound 4 (FD-MS)〉m/z=622

The 1H-NMR of＜compound 4 (CDCl3)〉δ 3.55 (s, 12H), 3.77 (s, 12H), 5.54 (s, 2H), 6.29 (d, 4H), 6.41～6.43 (m, 4H), 7.32 (d, 4H)

Embodiment 5

1,1,3, the manufacturing of 3-four (4-p-methoxy-phenyl) sily oxide (hereinafter referred to as compound 5)

(viii), under nitrogen gas stream, pack into magnesium 3.6g, tetrahydrofuran (THF) 20ml and small amount of bromine under agitation splash into the mixed solution of 4-bromoanisole 25g and tetrahydrofuran (THF) 80ml to four-hole boiling flask.After splashing into termination, be incubated 3 hours down at 70 ℃.In four-hole boiling flask (ix), pack into the mixture of triethoxyl silane 11.0g and tetrahydrofuran (THF) 40ml, ice-cooled down, splash into above-mentioned 70 ℃ down insulation 3 hours and reaction mixtures.After splashing into termination, at room temperature stirred 18 hours.After gained reaction solution usefulness saturated common salt water washing 3 times, with the organic phase anhydrous magnesium sulfate drying.After removing by filter anhydrous magnesium sulfate, filtrate concentrates, and heats up in a steamer and desolvates.In the gained residual component, add the mixing solutions of ethanol/toluene, make it separate out crystallization.Then, the crystallization of separating out is carried out recrystallization with the mixed solvent of toluene/normal hexane, obtain the compound 5 of 7.8g.

The mass spectroscopy of＜compound 5 (FD-MS)〉m/z=502

The 1H-NMR of＜compound 5 (CDCl3)〉δ 3.78 (s, 12H), 5.54 (s, 2H), 6.87 (d, 8H), 7.46 (d, 8H)

Embodiment 6

1,1,3, the manufacturing of 3-four (2, the 5-Dimethoxyphenyl) sily oxide (hereinafter referred to as compound 6)

In four-hole boiling flask (x), under nitrogen gas stream, pack into magnesium 1.5g, tetrahydrofuran (THF) 50ml and small amount of bromine.Then, under agitation splash into 1-bromo-2, the mixed solution of 5-dimethoxy benzene 12g and tetrahydrofuran (THF) 50ml.After splashing into termination, be incubated 2 hours down at 70 ℃.Pack in four-hole boiling flask (xi) trichlorosilane 3.4g and tetrahydrofuran (THF) 50ml under-30 ℃, splash into above-mentioned at 70 ℃ of insulation reaction solutions after 2 hours down.After splashing into termination, at room temperature stirred 1 hour.After gained reaction mixture usefulness saturated common salt water washing 3 times, with gained organic phase anhydrous magnesium sulfate drying.After removing by filter anhydrous magnesium sulfate, concentrated filtrate heats up in a steamer and desolvates.Spissated residual component is carried out recrystallization with the mixed solvent of tetrahydrofuran (THF)/hexane, obtain the compound 6 of 2.2g.

The mass spectroscopy of＜compound 6 (FD-MS)〉m/z=622

The 1H-NMR of＜compound 6 (CDCl3)〉δ 3.54 (s, 12H), 3.64 (s, 12H), 5.61 (s, 2H), 6.67～6.68 (m, 4H), 6.83～6.85 (m, 4H), 7.03 (m, 4H)

Embodiment 7 and comparative example 1

In the polycarbonate (Calibre of Sumitomo Dow corporate system) of 100 weight parts, add the compound 1 of 0.025 weight part, use the single screw extrusion machine of 30mm φ, at 340 ℃ of following melting mixings, obtain the particle of poly carbonate resin composition.This particle is carried out moulding with injection moulding machine after being detained 10 fens under 360 ℃, obtaining thin slice (embodiment 7).In addition, except not adding compound 1, carry out operation similarly to Example 7, obtain thin slice (comparative example 1).Measure the aberration (Δ YI) of 2 plate sheets of embodiment 7 and comparative example 1 gained with colour-difference meter.The measurement result of the relative value during with the worthwhile work 1 of the Δ YI of comparative example 2 gained is shown in Table 1.What illustrated is that the value of Δ YI value is more little, represents that thermal degradation when not painted, when being detained is few more.

Embodiment 8～12

In 100 weight parts of the used polycarbonate of embodiment 7, with the amount identical, add compound 2,3,4,5,6 respectively and replace compound 1 with compound 1, in addition, operate similarly to Example 7, obtain thin slice.

The measurement result of the aberration of embodiment 8～12 gained thin slices (measuring in contrast with comparative example 1 gained thin slice) is shown in Table 1 side by side with the measurement result of the thin slice of embodiment 7.

Comparative example 2

In 100 weight parts of the used polycarbonate of embodiment 7, add 0.025 weight part tri-phenyl-silane and replace compound 1, operate similarly to Example 7, obtain thin slice.

In addition, under situation similarly to Example 7, measure the aberration of this thin slice.

Measurement result is shown in Table 1.

Table 1

The example numbering	Embodiment 7	Embodiment 8	Embodiment 9	Embodiment 10	Embodiment 11	Embodiment 12	Comparative example 2
The example numbering	Embodiment 7	Embodiment 8	Embodiment 9	Embodiment 10	Embodiment 11	Embodiment 12	Comparative example 2	Compound	1	2	3	4	5	6	Tri-phenyl-silane
Aberration Δ YI	-9	-6	-10	-11	-9	-7	1	Compound	1	2	3	4	5	6	Tri-phenyl-silane

Embodiment 13～18

In the polycarbonate (Calibre of Sumitomo Dow corporate system) of 100 weight parts, add 0.025 weight part compound 1 and 0.1 weight part 2-(2 '-hydroxyl-5 '-uncle's octyl phenyl) benzotriazole, use the single screw extrusion machine of 30mm φ, under 340 ℃, carry out melting mixing, obtain the particle of poly carbonate resin composition.This particle is carried out moulding with injection moulding machine under 340 ℃, obtain thin slice (embodiment 13).

In addition, except not adding compound 1, carry out operation similarly to Example 13, obtain thin slice (blank test).

Measure the aberration (Δ YI) of 2 plate sheets of embodiment 13 and blank test gained with colour-difference meter.

With the amount identical with compound 1, add the compound 1 that compound 2,3,4,5 and 6 replaces embodiment 13 respectively, in addition, operate similarly to Example 13, obtain thin slice.

The color difference measurement result of embodiment 14～18 gained thin slices and the thin slice measurement result of embodiment 13 are shown in Table 2 side by side.

What illustrated is, in the present embodiment, represents with the relative value the Δ YI worthwhile work-1 of embodiment 18 gained thin slices o'clock.The value of Δ YI value is more little, represents that thermal degradation when not painted more, when being detained is few more.

Table 2

Embodiment No.	13	14	15	16	17	18
Embodiment No.	13	14	15	16	17	18	Compound N o.	1	2	3	4	5	6
ΔYI	-1.8	-1.5	-2.5	-2.0	-1.5	-1.0	Compound N o.	1	2	3	4	5	6

Embodiment 19 and comparative example 3

In the polycarbonate (Calibre of Sumitomo Dow corporate system) of 100 weight parts, add 0.025 weight part compound 1 and 0.1 weight part glyceryl monostearate, use the single screw extrusion machine of 30mm φ, under 340 ℃, carry out melting mixing, obtain the particle of poly carbonate resin composition.Use injection moulding machine, this particle is carried out moulding after being detained 10 minutes under 360 ℃, obtain thin slice (embodiment 19).In addition, except not adding compound 1, carry out operation similarly to Example 19, obtain thin slice (comparative example 3).

Measure the form and aspect (YI) of the thin slice of embodiment 19 and comparative example 3 gained with colour-difference meter, the results are shown in the table 3.

What illustrated is, in the present embodiment, the relative value of YI value with the worthwhile work 1 of the YI of comparative example 3 gained thin slices the time represented.

The value of Δ YI value is more little, represents that thermal degradation when not painted more, when being detained is few more.

Table 3

Example No.	Embodiment 19	Comparative example 3
Example No.	Embodiment 19	Comparative example 3	YI	0.48	1

Embodiment 20 and comparative example 4

In the polycarbonate (Calibre of Sumitomo Dow corporate system) of 100 weight parts, add 0.025 weight part compound 1 and 0.025 weight part 3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid Octadecane base ester, use the single screw extrusion machine of 30mm φ, under 340 ℃, carry out melting mixing, obtain the particle of poly carbonate resin composition.Use injection moulding machine at 360 ℃ of compacted unders this particle, obtain thin slice (embodiment 20).

In addition, except not adding compound 1, carry out operation similarly to Example 20, obtain thin slice (comparative example 4).

Colour (YI) with colour-difference meter mensuration embodiment 20 and comparative example 4 gained thin slices the results are shown in the table 4.

What illustrated is, in the present embodiment, the relative value of YI value with the worthwhile work 1 of the YI of comparative example 4 gained thin slices the time represented.

The value of YI value is more little, represents that thermal degradation when not painted more, when being detained is few more.

Table 4

Example No.	Embodiment 20	Comparative example 4
Example No.	Embodiment 20	Comparative example 4	YI	0.78	1

Embodiment 21～23 and comparative example 5

In the polypropylene (Noblen of sumitomo chemical company system) of 100 weight parts, the antioxidant (with reference to following table 5) that adds compound 1 and following specified amount, use the single screw extrusion machine of 30mm φ, under 270 ℃, carry out melting mixing, obtain the particle of polypropylene resin composite.This particle is carried out moulding with injection moulding machine under 270 ℃, obtain thin slice.The measurement result of the colour of thin slice (YI) is shown in Table 5.

The relative value of YI with the worthwhile work 1 of comparative example 5 time represented.

Antioxidant AO-1: Ji Wusi base four (3,5-di-t-butyl-4-hydroxyl dihydro cinnamon acid esters)

Antioxidant P-1: three (2, the 4-di-tert-butyl-phenyl) phosphorous acid ester

Table 5

Example No.	Embodiment 21	Embodiment 22	Embodiment 23	Comparative example 5
Example No.	Embodiment 21	Embodiment 22	Embodiment 23	Comparative example 5	Compound 1	0.05 weight part	0.025 weight part	0.008 weight part	Do not have and add
Antioxidant	Do not have and add	AO-1/0.025 (weight part)	AO-1/0.021 weight part P-1/0.021 weight part	Do not have and add	Compound 1	0.05 weight part	0.025 weight part	0.008 weight part	Do not have and add
Antioxidant	Do not have and add	AO-1/0.025 (weight part)	AO-1/0.021 weight part P-1/0.021 weight part	Do not have and add	YI	0.92	0.96	0.97	1

Embodiment 24～26 and comparative example 6

With respect to polypropylene (Noblen of sumitomo chemical company system) 100 weight parts, do and mix calcium stearate 0.05 weight part, following homopolymer polypropylene (PO-1 concentration 8%) 0.31 weight part (PO-1 is 0.025 weight part), compound 1 and the PO-1 following additive in addition that is soaked with organo-peroxide PO-1 that contains.

Use 30mm φ single screw extrusion machine, under 250 ℃ design temperature, it is mixing that this mixture is carried out heating and melting, makes particle.The particle that makes is carried out heating and melting with 30mm φ single screw extrusion machine again under 270 ℃ design temperature mixing, preparation particulate operation 4 times repeatedly.The particulate MFR (M0) that will make after processing under 250 ℃ and 270 ℃ of differences that repeat 4 particulate MFR (M4) behind the melting mixings down are as Δ MFR.

Δ MFR is the relative value during the worthwhile work 1 of comparative example 6, is shown in the following table 6.

The value of Δ MFR is more little, and the expression thermal degradation when is few more.

PO-1:2,5-dimethyl-2,5-two (tert-butyl hydroperoxide) hexane

AO-2: three (3, the 5-di-tert-butyl-4-hydroxyl benzyl) isocyanuric acid ester

HA-1: Succinic acid dimethylester and 1-(2-hydroxyethyl)-4-hydroxyl-2,2,6, the polycondensate of 6-tetramethyl piperidine

Table 6

Example No.	Embodiment 24	Embodiment 25	Embodiment 26	Comparative example 6
Example No.	Embodiment 24	Embodiment 25	Embodiment 26	Comparative example 6	Compound 1	0.225 weight part	0.11 weight part	0.05 weight part	Do not have and add
Additive	Do not have and add	The AO-2/0.11 weight part	PO-1/0.12 weight part HA-1/0.05 weight part	Do not have and add	Compound 1	0.225 weight part	0.11 weight part	0.05 weight part	Do not have and add
Additive	Do not have and add	The AO-2/0.11 weight part	PO-1/0.12 weight part HA-1/0.05 weight part	Do not have and add	ΔMFR	0.79	0.26	0.16	1

Embodiment 27 and comparative example 7

With respect to the cyclic polyolefin resin (Topas of Ticona corporate system) of 100 weight parts, do the compound 1 that mixes 0.3 weight part.

With T type processing film machine, under 300 ℃ design temperature, this mixture is made film (embodiment 27).

In addition, make the film (comparative example 7) that does not add after compound 1 ground processes with additive method.

The generation shape of gained film range estimation being confirmed the flake glue thought is heavy, found that compare with comparative example 7, the film of embodiment 27 can suppress gel and produce.

Industrial applicibility

Anti-coloring agent, heat resistanceheat resistant degradation or gel that organo-silicon compound of the present invention can be used as the organic materials such as thermoplastic resin, natural rubber, synthetic rubber, mineral oil, lubricating oil, adhesive produce inhibitor.

In addition, by manufacture method of the present invention, can easily obtain above-mentioned organo-silicon compound.

And then organic material composition of the present invention can be widely used in construction materials such as electronics enclosure, optical lens or glass pane etc.

Claims

1. silicoorganic compound, it is represented with following formula (I):

In the formula (I), R ₁～R ₂₀Represent the alkyl of hydrogen atom, carbon number 1～30 or the alkoxyl group of carbon number 1～30 respectively independently, wherein, R ₁～R ₂₀Be not hydrogen atom entirely.

2. silicoorganic compound according to claim 1, wherein, in the formula (I), R ₁～R ₂₀Be hydrogen atom, methyl, ethyl, the tertiary butyl, methoxy or ethoxy.

3. silicoorganic compound according to claim 1 and 2, wherein, R in the formula (I) ₁And R ₆And R ₁₁And R ₁₆Identical, R ₂And R ₇And R ₁₂And R ₁₇Identical, R ₃And R ₈And R ₁₃And R ₁₈Identical, R ₄And R ₉And R ₁₄And R ₁₉Identical, R ₅And R ₁₀And R ₁₅And R ₂₀Identical.

4. the manufacture method of the silicoorganic compound of the described formula of claim 1 (I) expression, it is characterized in that, the phenide compound of following formula (III)～(VI) expression and the replacement silicon compound of following formula (VII) expression are reacted, reaction product with gained is hydrolyzed then, carry out condensation as required again

In the formula (III)～(VI), M represents MgX or Li, X represent halogen former in

～R ₂₀It is identical with the definition in the claim 1,

5. organic materials composition, it is characterized in that, contain the silicoorganic compound of the described formula of organic materials and claim 1 (I) expression, the weight ratio of this organic materials and silicoorganic compound was 100: 0.0001～100: 10 scope, wherein, organic materials is a thermoplastic resin.

6. R in the organic materials composition according to claim 5, formula (I) ₁And R ₆And R ₁₁And R ₁₆Identical, R ₂And R ₇And R ₁₂And R ₁₇Identical, R ₃And R ₈And R ₁₃And R ₁₈Identical, R ₄And R ₉And R ₁₄And R ₁₉Identical, R ₅And R ₁₀And R ₁₅And R ₂₀Identical.

7. according to claim 5 or 6 described organic materials compositions, wherein, thermoplastic resin is TPO or thermoplastic engineering resin.

8. organic materials composition according to claim 7, wherein, the thermoplastic engineering resin is a thermoplastic polyester.

9. organic materials composition according to claim 7, wherein, the thermoplastic engineering resin is a thermoplastic poly carbonic ether.

10. organic materials composition according to claim 7, wherein, TPO is thermoplastic polypropylene or thermoplasticity cyclic polyolefin resin.