CN100562507C - 一种装饰材料及其制备方法 - Google Patents
一种装饰材料及其制备方法 Download PDFInfo
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- CN100562507C CN100562507C CNB200510082981XA CN200510082981A CN100562507C CN 100562507 C CN100562507 C CN 100562507C CN B200510082981X A CNB200510082981X A CN B200510082981XA CN 200510082981 A CN200510082981 A CN 200510082981A CN 100562507 C CN100562507 C CN 100562507C
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- 239000007795 chemical reaction product Substances 0.000 claims abstract description 213
- 150000001875 compounds Chemical class 0.000 claims abstract description 179
- 239000002994 raw material Substances 0.000 claims description 119
- 238000000034 method Methods 0.000 claims description 76
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- 238000002425 crystallisation Methods 0.000 claims description 15
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- 238000002844 melting Methods 0.000 claims description 15
- 230000008018 melting Effects 0.000 claims description 15
- 230000006911 nucleation Effects 0.000 claims description 15
- 238000010899 nucleation Methods 0.000 claims description 15
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- 238000005498 polishing Methods 0.000 claims description 12
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- 238000006124 Pilkington process Methods 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- VEMKTZHHVJILDY-UHFFFAOYSA-N resmethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UHFFFAOYSA-N 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 abstract description 32
- 229910052783 alkali metal Inorganic materials 0.000 abstract description 26
- 150000001340 alkali metals Chemical class 0.000 abstract description 26
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract description 26
- 239000004579 marble Substances 0.000 abstract description 18
- 229910010413 TiO 2 Inorganic materials 0.000 abstract description 5
- 238000000280 densification Methods 0.000 abstract description 3
- 239000011734 sodium Substances 0.000 description 73
- 239000000047 product Substances 0.000 description 46
- 239000000126 substance Substances 0.000 description 41
- 230000008859 change Effects 0.000 description 27
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 26
- 239000011737 fluorine Substances 0.000 description 26
- 229910052731 fluorine Inorganic materials 0.000 description 26
- 239000011449 brick Substances 0.000 description 22
- 230000004927 fusion Effects 0.000 description 22
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 18
- 238000001816 cooling Methods 0.000 description 18
- 239000000919 ceramic Substances 0.000 description 16
- 238000010304 firing Methods 0.000 description 16
- 238000004519 manufacturing process Methods 0.000 description 15
- 229910004261 CaF 2 Inorganic materials 0.000 description 14
- 238000005352 clarification Methods 0.000 description 12
- 239000010438 granite Substances 0.000 description 12
- 238000001514 detection method Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 208000037656 Respiratory Sounds Diseases 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 10
- 239000011575 calcium Substances 0.000 description 10
- 239000011236 particulate material Substances 0.000 description 10
- 239000011148 porous material Substances 0.000 description 10
- 238000005245 sintering Methods 0.000 description 10
- 229910016569 AlF 3 Inorganic materials 0.000 description 9
- 229910052788 barium Inorganic materials 0.000 description 9
- 229910052791 calcium Inorganic materials 0.000 description 9
- 229910052749 magnesium Inorganic materials 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 9
- 239000011787 zinc oxide Substances 0.000 description 9
- 229910052733 gallium Inorganic materials 0.000 description 8
- 229910052712 strontium Inorganic materials 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 229910005269 GaF 3 Inorganic materials 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- 239000002826 coolant Substances 0.000 description 5
- 239000010433 feldspar Substances 0.000 description 5
- 239000010436 fluorite Substances 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 239000012299 nitrogen atmosphere Substances 0.000 description 5
- 235000010339 sodium tetraborate Nutrition 0.000 description 5
- 238000010792 warming Methods 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 229910016036 BaF 2 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- 230000003373 anti-fouling effect Effects 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 230000003670 easy-to-clean Effects 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910052738 indium Inorganic materials 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 239000001095 magnesium carbonate Substances 0.000 description 3
- 235000014380 magnesium carbonate Nutrition 0.000 description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 235000012222 talc Nutrition 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- 229910021532 Calcite Inorganic materials 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000002928 artificial marble Substances 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical class [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000748 compression moulding Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 239000004323 potassium nitrate Substances 0.000 description 2
- 235000010333 potassium nitrate Nutrition 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- 235000015193 tomato juice Nutrition 0.000 description 2
- 210000002700 urine Anatomy 0.000 description 2
- UPLPHRJJTCUQAY-WIRWPRASSA-N 2,3-thioepoxy madol Chemical compound C([C@@H]1CC2)[C@@H]3S[C@@H]3C[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@](C)(O)[C@@]2(C)CC1 UPLPHRJJTCUQAY-WIRWPRASSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910021537 Kernite Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000002742 anti-folding effect Effects 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- XDFCIPNJCBUZJN-UHFFFAOYSA-N barium(2+) Chemical compound [Ba+2] XDFCIPNJCBUZJN-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052728 basic metal Inorganic materials 0.000 description 1
- 150000003818 basic metals Chemical class 0.000 description 1
- 229910052790 beryllium Inorganic materials 0.000 description 1
- BRCWHGIUHLWZBK-UHFFFAOYSA-K bismuth;trifluoride Chemical compound F[Bi](F)F BRCWHGIUHLWZBK-UHFFFAOYSA-K 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- ZWKXRHMVHJMGCC-UHFFFAOYSA-N calcium sodium boric acid borate Chemical compound B([O-])([O-])[O-].B(O)(O)O.B(O)(O)O.B(O)(O)O.[Na+].[Ca+2] ZWKXRHMVHJMGCC-UHFFFAOYSA-N 0.000 description 1
- NWXHSRDXUJENGJ-UHFFFAOYSA-N calcium;magnesium;dioxido(oxo)silane Chemical compound [Mg+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O NWXHSRDXUJENGJ-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229910052637 diopside Inorganic materials 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910001512 metal fluoride Inorganic materials 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 238000004162 soil erosion Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- NFMWFGXCDDYTEG-UHFFFAOYSA-N trimagnesium;diborate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]B([O-])[O-].[O-]B([O-])[O-] NFMWFGXCDDYTEG-UHFFFAOYSA-N 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Abstract
Description
本发明 | 花岗石 | 大理石 | 陶瓷抛光砖 | |
密度:克/立方厘米 | 2.52-3.2 | 通常小于2.5不超过2.7 | 通常小于2.5不超过2.7 | 通常小于2.3不超过2.5 |
断裂模数MPa | 大于60 | 30 | 15 | 40 |
干燥后压缩强度:MPa | 大于280 | 150 | 50 | 200 |
吸水率% | 0--0.4 | 0.35-1.0 | 0.3-1.4 | 0.45-0.7 |
放射性 | 符合GB6566-2001标准 | / | / | / |
莫氏硬度 | 6-8 | 5.5 | 3.0--5.0 | 6.5 |
耐酸性 | 优越,外观无变化 | 有局部腐蚀 | 有局部腐蚀 | 稍有局部腐蚀 |
耐碱性 | 优越,外观无变化 | 有局部腐蚀 | 有局部腐蚀 | 稍有局部腐蚀 |
抗热震性 | 优越,无裂纹、无崩落,敲其声音无变化 | 一般,稍有裂纹和崩落,敲其声音有变化 | 一般,稍有裂纹和崩落,敲其声音有变化 | 一般,稍有裂纹和崩落,敲其声音有变化 |
本发明 | 对比1 | 对比2 | 对比3 | |
密度:克/立方厘米 | 2.52-3.2 | 2.3 | 2.2 | 2.1 |
断裂模数MPa | 大于60 | 40 | 30 | 15 |
干燥后压缩强度:MPa | 大于280 | 200 | 120 | 90 |
吸水率% | 0-0.4 | 0.8 | 0.9 | 2 |
莫氏硬度 | 6-8 | 5-7 | 5-7 | 5-7 |
本发明1 | 本发明2 | 本发明3 | 本发明4 | |
密度:克/立方 | 2.52 | 2.86 | 3.12 | 3.2 |
厘米 | ||||
断裂模数MPa | 60 | 67-98 | 129-176 | 180 |
干燥后压缩强度:MPa | 280 | 321-388 | 663-695 | 448-800 |
吸水率% | 0-0.18 | 0-0.09 | 0-0.009 | 0 |
莫氏硬度 | 6-7 | 6-7 | 7-8 | 7-8 |
抗热震性 | 本发明样品1 | 本发明样品2 | 本发明样品3 | 本发明样品4 |
检测方法1室温(12℃) | 优越,无裂纹、无崩落,敲其声音无变化 | 优越,无裂纹、无崩落,敲其声音无变化 | 优越,无裂纹、无崩落,敲其声音无变化 | 优越,无裂纹、无崩落,敲其声音无变化 |
检测方法1室温(25℃) | 优越,无裂纹、无崩落,敲其声音无变化 | 优越,无裂纹、无崩落,敲其声音无变化 | 优越,无裂纹、无崩落,敲其声音无变化 | 优越,无裂纹、无崩落,敲其声音无变化 |
检测方法2室温(15℃) | 一般,稍有裂纹和崩落,敲其声音有变化 | 一般,稍有裂纹和崩落,敲其声音有变化 | 优越,无裂纹、无崩落,敲其声音无变化 | 优越,无裂纹、无崩落,敲其声音无变化 |
检测方法2室温(28℃) | 一般,稍有裂纹和崩落,敲其声音有变化 | 一般,稍有裂纹和崩落,敲其声音有变化 | 优越,无裂纹、无崩落,敲其声音无变化 | 优越,无裂纹、无崩落,敲其声音无变化 |
项目 | 10分种后能否擦洗掉污染色点。 | 2小时后能否擦洗掉污染色点。 | 24小时后能否擦洗掉污染色点。 | 1个月后能否擦洗掉污染色点。 | 3个月后能否擦洗掉污染色点。 | |
吸水率% | ||||||
大理石 | 0.3 | 可以 | 不可以 | 不可以 | 不可以 | 不可以 |
花岗石 | 0.35 | 可以 | 可以 | 不可以 | 不可以 | 不可以 |
陶瓷砖 | 6 | 不可以 | 不可以 | 不可以 | 不可以 | 不可以 |
微晶砖 | 0.12 | 可以 | 可以 | 可以 | 不可以 | 不可以 |
本发明1# | 0.4 | 可以 | 可以 | 可以 | 不可以 | 不可以 |
本发明2# | 0.3 | 可以 | 可以 | 可以 | 可以 | 可以 |
本发明3# | 0.01 | 可以 | 可以 | 可以 | 可以 | 可以 |
本发明4# | 0.003 | 可以 | 可以 | 可以 | 可以 | 可以 |
Claims (1)
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Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101962288A (zh) * | 2010-09-19 | 2011-02-02 | 江西金枫玉石有限公司 | 一种装饰材料 |
CN102409821B (zh) * | 2011-08-09 | 2013-01-16 | 大连铭源全建材有限公司 | 一种超轻保温装饰板的制备方法 |
CN102795770A (zh) * | 2012-09-06 | 2012-11-28 | 北京大有盛和科技有限公司 | 一种用压延法或浇注法生产彩色花纹型微晶玻璃的方法 |
CN103641319B (zh) * | 2013-12-06 | 2016-10-19 | 辽宁红山玉科技有限公司 | 一种低氟微晶玻璃 |
CN103641323A (zh) * | 2013-12-06 | 2014-03-19 | 辽宁红山玉科技有限公司 | 一种低氟微晶玻璃 |
CN104030698A (zh) * | 2014-05-26 | 2014-09-10 | 浙江立鑫高温耐火材料有限公司 | 一种镁锆砖 |
CN112340995B (zh) * | 2017-11-28 | 2022-04-26 | 福建省德化县晖德陶瓷有限公司 | 无光陶瓷釉用低温熔块及利用该低温熔块制备无光釉陶瓷制品的制备工艺 |
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