CN100555544C - Field emission pixel tube - Google Patents

Field emission pixel tube Download PDF

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CN100555544C
CN100555544C CNB2006100618048A CN200610061804A CN100555544C CN 100555544 C CN100555544 C CN 100555544C CN B2006100618048 A CNB2006100618048 A CN B2006100618048A CN 200610061804 A CN200610061804 A CN 200610061804A CN 100555544 C CN100555544 C CN 100555544C
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field emission
emission pixel
pixel tube
metal cylinder
tube
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CN101114563A (en
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杨远超
唐洁
刘亮
范守善
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Tsinghua University
Hongfujin Precision Industry Shenzhen Co Ltd
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Hongfujin Precision Industry Shenzhen Co Ltd
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Abstract

本发明涉及一种场发射像素管。该场发射像素管包括:一个中空壳体,该中空壳体具有一出光部,该出光部的内壁依次设有一荧光层和一阳极层,所述中空壳体内部是真空密封的,该中空壳体内有一个金属筒,该金属筒内壁设有一层经固化的浆料层,该浆料层含有导电的纳米材料,该金属筒与至少一个阴极电极电连接。该场发射像素管的金属筒对电场有很强的屏蔽作用,可以有效的减弱碳纳米管表面的电场,使得碳纳米管可以在10千伏或更高的电压下稳定的工作。

Figure 200610061804

The invention relates to a field emission pixel tube. The field emission pixel tube includes: a hollow shell, the hollow shell has a light exit portion, the inner wall of the light exit portion is provided with a fluorescent layer and an anode layer in turn, the inside of the hollow shell is vacuum-sealed, There is a metal cylinder inside the hollow shell, and the inner wall of the metal cylinder is provided with a solidified slurry layer, the slurry layer contains conductive nanometer material, and the metal cylinder is electrically connected with at least one cathode electrode. The metal cylinder of the field emission pixel tube has a strong shielding effect on the electric field, which can effectively weaken the electric field on the surface of the carbon nanotube, so that the carbon nanotube can work stably at a voltage of 10 kV or higher.

Figure 200610061804

Description

场发射像素管 Field emission pixel tube

技术领域 technical field

本发明涉及一种场发射元件,尤其涉及一种场发射像素管。The invention relates to a field emission element, in particular to a field emission pixel tube.

背景技术 Background technique

场发射电子源以及利用该电子源轰击荧光物质而发光的场发射发光技术已经在场发射平面显示器等领域得到应用。这种场发射技术是在真空环境下,利用外加电场作用将尖端的电子激发出来,电子轰击荧光粉发出可见光从而进行显示。在传统场发射电子源中,一般采用微细钼金属尖端或矽尖端作为电子发射端,随着纳米技术的发展,最近还采用纳米碳管作为电子发射端。The field emission electron source and the field emission luminescence technology that uses the electron source to bombard fluorescent substances to emit light have been applied in fields such as field emission flat panel displays. This field emission technology uses an external electric field to excite the electrons at the tip in a vacuum environment, and the electrons bombard the phosphor to emit visible light for display. In traditional field emission electron sources, fine molybdenum metal tips or silicon tips are generally used as electron emission ends. With the development of nanotechnology, carbon nanotubes are also used as electron emission ends recently.

为了有效的利用荧光粉的发光效率,像素管一般工作在10千伏左右的高压下,然而碳纳米管在强电压下很容易损坏,导致发射不稳定。In order to effectively utilize the luminous efficiency of phosphor powder, pixel tubes generally work at a high voltage of about 10 kV, but carbon nanotubes are easily damaged under high voltage, resulting in unstable emission.

发明内容 Contents of the invention

有鉴于此,提供一种可以在高压下稳定工作的场发射元件实为必要。In view of this, it is necessary to provide a field emission device that can work stably under high voltage.

一种场发射像素管,其包括:一个中空壳体,该中空壳体具有一出光部,该出光部的内壁依次设有一荧光层和一阳极层,所述中空壳体内部是真空密封的,该中空壳体内有一个金属筒,该金属筒内壁设有一层经固化的浆料层,该浆料层含有导电的纳米材料,该金属筒与至少一个阴极电极电连接。A field emission pixel tube, which includes: a hollow casing, the hollow casing has a light outlet, the inner wall of the light outlet is sequentially provided with a fluorescent layer and an anode layer, the inside of the hollow casing is a vacuum Sealed, the hollow shell has a metal cylinder inside, and the inner wall of the metal cylinder is provided with a solidified slurry layer, the slurry layer contains conductive nano-materials, and the metal cylinder is electrically connected with at least one cathode electrode.

相对于现有技术,所述场发射像素管的金属筒对电场有很强的屏蔽作用,将含有碳纳米管的浆料涂于金属筒的内壁作为阴极,可有效的减弱碳纳米管周围的电场,使得碳纳米管可以在10千伏或更高的电压下稳定的工作。Compared with the prior art, the metal cylinder of the field emission pixel tube has a strong shielding effect on the electric field, and the slurry containing carbon nanotubes is coated on the inner wall of the metal cylinder as a cathode, which can effectively weaken the electric field around the carbon nanotubes. The electric field enables the carbon nanotubes to work stably at a voltage of 10 kV or higher.

附图说明 Description of drawings

图1是本发明实施例提供的场发射像素管的剖面示意图。FIG. 1 is a schematic cross-sectional view of a field emission pixel tube provided by an embodiment of the present invention.

图2是本发明实施例提供的场发射像素管沿图1中II-II方向的截面示意图。FIG. 2 is a schematic cross-sectional view of the field emission pixel tube provided by an embodiment of the present invention along the direction II-II in FIG. 1 .

具体实施方式 Detailed ways

以下将结合附图对本发明作进一步详细说明。The present invention will be described in further detail below in conjunction with the accompanying drawings.

本实施例提供一种场发射像素管10。请参阅图1和图2,该场发射像素管10包括:一个中空壳体11,该中空壳体11具有一出光部12,该出光部12的内壁依次设有一荧光层13和一阳极层14,所述中空壳体11内部是真空密封的,该中空壳体11内有一个金属筒16,该金属筒16内壁设有一层经固化的浆料层17,该浆料层17含有导电的纳米材料,该金属筒16与至少一个阴极电极电连接。在本实施例中该金属筒16分别与两个阴极电极电连接,该两个阴极电极分别为第一阴极电极18和第二阴极电极19。This embodiment provides a field emission pixel tube 10 . Please refer to FIG. 1 and FIG. 2, the field emission pixel tube 10 includes: a hollow housing 11, the hollow housing 11 has a light exit portion 12, the inner wall of the light exit portion 12 is provided with a fluorescent layer 13 and an anode in turn layer 14, the inside of the hollow shell 11 is vacuum-tight, and there is a metal cylinder 16 inside the hollow shell 11, and the inner wall of the metal cylinder 16 is provided with a solidified slurry layer 17, and the slurry layer 17 Containing conductive nanomaterials, the metal cylinder 16 is electrically connected to at least one cathodic electrode. In this embodiment, the metal cylinder 16 is electrically connected to two cathode electrodes respectively, and the two cathode electrodes are respectively a first cathode electrode 18 and a second cathode electrode 19 .

该中空壳体11内部是真空密封的,在本实施例中,该壳体11为中空圆柱体,且该壳体11的材料为石英玻璃或玻璃。可以理解的是,该壳体11还可以是中空的多边形棱柱,同时该壳体11的出光部12可以为平面也可以为球面或非球面,本领域技术人员可以根据实际情况进行选择。The inside of the hollow shell 11 is vacuum-tight. In this embodiment, the shell 11 is a hollow cylinder, and the material of the shell 11 is quartz glass or glass. It can be understood that the housing 11 can also be a hollow polygonal prism, and the light exit portion 12 of the housing 11 can be a plane or a spherical or aspherical surface, which can be selected by those skilled in the art according to the actual situation.

所述荧光层13沉积在出光部12的内壁上。该荧光层13可以由白色荧光粉或彩色荧光粉组成。当电子轰击荧光层13时可发出白色或彩色可见光。所述阳极层14镀在沉积有荧光层13的出光部12内壁上并将荧光层13覆盖,起到导电并反射荧光粉发光的作用。该阳极层14为金属膜,具有良好的导电性和镜面平整度,在本实施例中,该阳极层14为铝膜。The fluorescent layer 13 is deposited on the inner wall of the light emitting portion 12 . The fluorescent layer 13 can be composed of white fluorescent powder or colored fluorescent powder. White or colored visible light can be emitted when electrons bombard the fluorescent layer 13 . The anode layer 14 is plated on the inner wall of the light exit portion 12 deposited with the fluorescent layer 13 and covers the fluorescent layer 13 to conduct electricity and reflect the fluorescent powder to emit light. The anode layer 14 is a metal film with good electrical conductivity and mirror flatness. In this embodiment, the anode layer 14 is an aluminum film.

在本实施例中,所述金属筒16为一圆筒,且该金属筒16的中心轴垂直于出光部12。可以理解的是,该金属筒16还可以为方筒、多边形筒等其它筒状结构。In this embodiment, the metal cylinder 16 is a cylinder, and the central axis of the metal cylinder 16 is perpendicular to the light emitting portion 12 . It can be understood that the metal cylinder 16 can also be a square cylinder, a polygonal cylinder and other cylindrical structures.

所述金属筒16内壁有一层经固化的浆料层17,该浆料层17含有导电的纳米材料,所述纳米材料可以选自碳纳米管、碳纳米棒、碳60,碳纳米颗粒、导电金属或半导体的纳米管、纳米线、纳米棒,纳米带及其混合物中的任意一种,本实施例中选用碳纳米管。将配好的浆料层17涂敷于金属筒16内壁并将其固化,最后用橡皮摩擦金属筒16内壁,使更多的浆料层17中的碳纳米管露头,增强其场发射性能。金属筒16对碳纳米管发射体的屏蔽作用取决于浆料层17边缘与金属筒16边缘的距离,距离越大,屏蔽作用越强;还取决于金属筒16的直径,直径越小,屏蔽作用越强。The inner wall of the metal cylinder 16 has a solidified slurry layer 17, the slurry layer 17 contains conductive nanomaterials, and the nanomaterials can be selected from carbon nanotubes, carbon nanorods, carbon 60, carbon nanoparticles, conductive Any one of metal or semiconductor nanotubes, nanowires, nanorods, nanobelts and mixtures thereof, carbon nanotubes are selected in this embodiment. The prepared slurry layer 17 is coated on the inner wall of the metal cylinder 16 and cured, and finally the inner wall of the metal cylinder 16 is rubbed with a rubber to expose more carbon nanotubes in the slurry layer 17 and enhance its field emission performance. The shielding effect of the metal cylinder 16 on the carbon nanotube emitter depends on the distance between the edge of the slurry layer 17 and the edge of the metal cylinder 16, the larger the distance, the stronger the shielding effect; it also depends on the diameter of the metal cylinder 16, the smaller the diameter, the greater the shielding effect. The stronger the effect.

所述金属筒16分别与第一阴极电极18和第二阴极电极19电连接。该第一阴极电极18与该第二阴极电极19穿过所述壳体11并延伸至壳体11外部。在第一阴极电极18和第二阴极电极19穿过的部位可采用玻璃封接技术密封,以保证壳体11内部的密封性。The metal cylinder 16 is electrically connected to the first cathode electrode 18 and the second cathode electrode 19 respectively. The first cathode electrode 18 and the second cathode electrode 19 pass through the housing 11 and extend to the outside of the housing 11 . The part where the first cathode electrode 18 and the second cathode electrode 19 pass through can be sealed with glass sealing technology to ensure the airtightness inside the housing 11 .

该场发射像素管10进一步包括一个阳极电极15。该阳极电极15与阳极层14电连接。该阳极电极15穿过所述壳体11延伸至壳体11外部。在阳极电极15穿过的部位可采用玻璃封接技术密封,以保证壳体11内部的密封性。The field emission pixel tube 10 further includes an anode electrode 15 . The anode electrode 15 is electrically connected to the anode layer 14 . The anode electrode 15 extends through the casing 11 to the outside of the casing 11 . The part through which the anode electrode 15 passes can be sealed with glass sealing technology to ensure the sealing of the inside of the casing 11 .

该场发射像素管10进一步包括一吸气剂20,用于吸附场发射像素管10内残余气体,维持场发射像素管10内部的真空度。该吸气剂20可以为蒸散型吸气剂,在壳体11封接后通过高频加热蒸镀的方法形成在靠近第一阴极电极18和第二阴极电极19的壳体11内壁上。该吸气剂20也可以为非蒸散型吸气剂,固定在靠近第一阴极电极18和第二阴极电极19的壳体11内壁上,或者固定在金属筒16的内壁或外壁。The field emission pixel tube 10 further includes a getter 20 for absorbing residual gas in the field emission pixel tube 10 to maintain the vacuum inside the field emission pixel tube 10 . The getter 20 may be an evaporable getter, which is formed on the inner wall of the housing 11 close to the first cathode electrode 18 and the second cathode electrode 19 by high-frequency heating evaporation after the housing 11 is sealed. The getter 20 can also be a non-evaporable getter, fixed on the inner wall of the shell 11 close to the first cathode electrode 18 and the second cathode electrode 19 , or fixed on the inner or outer wall of the metal cylinder 16 .

该场发射像素管10进一步包括一排气孔21,该排气孔21外接真空泵,用以将壳体11抽真空。封装时,先通过排气孔21使场发射像素管10达到一定的真空度后再进行最后的封装。The field emission pixel tube 10 further includes an exhaust hole 21 , and the exhaust hole 21 is externally connected with a vacuum pump for evacuating the casing 11 . During encapsulation, the final encapsulation is performed after the field emission pixel tube 10 reaches a certain degree of vacuum through the exhaust hole 21 .

当该场发射像素管10工作时,分别给阳极电极15与第一阴极电极18、第二阴极电极19之间加上电压形成电场,通过电场作用,金属筒11内壁的浆料层17中的碳纳米管发射出电子,电子穿透阳极层14轰击荧光层13,发出可见光。可见光一部分直接从出光部12射出,一部分射在阳极层14上。阳极层14将其反射并最终透过出光部12射出。多个这样的场发射像素管10排列起来可以进行照明或信息显示。When the field emission pixel tube 10 was in operation, a voltage was applied between the anode electrode 15, the first cathode electrode 18, and the second cathode electrode 19 to form an electric field. The carbon nanotubes emit electrons, and the electrons penetrate the anode layer 14 and bombard the fluorescent layer 13 to emit visible light. A part of the visible light is directly emitted from the light exit portion 12 , and a part is emitted on the anode layer 14 . The anode layer 14 reflects it and finally passes through the light emitting portion 12 to emit. A plurality of such field emission pixel tubes 10 can be arranged for illumination or information display.

相对于现有技术,所述场发射像素管10的金属筒16对电场有很强的屏蔽作用,将含有碳纳米管的浆料涂于金属筒16的内壁作为阴极,则可以有效的减弱碳纳米管周围的电场,使得碳纳米管可以在10千伏或更高的电压下稳定的工作。Compared with the prior art, the metal cylinder 16 of the field emission pixel tube 10 has a strong shielding effect on the electric field, and coating the slurry containing carbon nanotubes on the inner wall of the metal cylinder 16 as a cathode can effectively weaken the carbon The electric field around the nanotubes enables the carbon nanotubes to work stably at voltages of 10 kilovolts or higher.

另外,本领域技术人员还可以在本发明精神内做其它变化,当然,这些依据本发明精神所做的变化,都应包含在本发明所要求保护的范围内。In addition, those skilled in the art can also make other changes within the spirit of the present invention. Of course, these changes made according to the spirit of the present invention should be included in the scope of protection claimed by the present invention.

Claims (9)

1. field emission pixel tube, it comprises:
A hollow housing, this hollow housing has a light out part, the inwall of this light out part is provided with a fluorescence coating and an anode layer successively, described hollow housing inside is vacuum-packed, it is characterized in that: a metal cylinder is arranged in this hollow housing, this metal cylinder inwall is provided with the pulp layer of one deck through solidifying, and this pulp layer contains the nano material of conduction, and this metal cylinder is electrically connected with at least one cathode electrode.
2. field emission pixel tube as claimed in claim 1 is characterized in that, this hollow housing is a hollow circular cylinder.
3. field emission pixel tube as claimed in claim 1 is characterized in that, this hollow housing is a glass.
4. field emission pixel tube as claimed in claim 1 is characterized in that, this anode layer is the aluminium film.
5. field emission pixel tube as claimed in claim 1 is characterized in that, further comprises an anode electrode, and this anode electrode is electrically connected with described anode layer, and passes described housing and extend to this outside.
6. field emission pixel tube as claimed in claim 1 is characterized in that, this at least one cathode electrode passes described housing and extends to this outside.
7. field emission pixel tube as claimed in claim 1 is characterized in that this fluorescence coating is made up of white fluorescent powder or color phosphor.
8. field emission pixel tube as claimed in claim 1 is characterized in that, further comprises getter, and this getter is formed near on the inner walls of this at least one cathode electrode.
9. field emission pixel tube as claimed in claim 1 is characterized in that, this nano material is selected from any one in carbon nano-tube, carbon 60, carbon nano-particle, nano wire, nanometer rods, nano belt and composition thereof.
CNB2006100618048A 2006-07-21 2006-07-26 Field emission pixel tube Active CN100555544C (en)

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CNB2006100618048A CN100555544C (en) 2006-07-26 2006-07-26 Field emission pixel tube
US11/565,528 US7635945B2 (en) 2006-07-21 2006-11-30 Field emission device having a hollow shaped shielding structure

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Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
碳纳米管场发射显示器的研究进展. 朱长纯,刘兴辉.发光学报,第26卷第5期. 2005
碳纳米管场发射显示器的研究进展. 朱长纯,刘兴辉.发光学报,第26卷第5期. 2005 *

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