CN100533640C - Plasma display panel - Google Patents

Abstract

A crystalline MgO layer is provided in a position facing a discharge cell formed in a discharge space between the front and back substrates. The crystalline MgO layer includes magnesium oxide crystals caused to emit ultraviolet light with a peak wavelength of between 230 nm and 250 nm by the action of ultraviolet light emitted from xenon in a discharge gas. A phosphor layer emits visible light by being excited by the ultraviolet light emitted from the magnesium oxide layer and the ultraviolet light emitted from the discharge gas.

Description

Plasmia indicating panel

Technical field

The present invention relates to the structure of Plasmia indicating panel.

Background technology

Face discharge mode AC type plasma displaying panel (hereinafter referred to as PDP) comprises mutual opposed two glass substrates that have the discharge space of discharge gas to be clipped in the middle to inclosure, on the glass substrate of a side therein, it is right to be set side by side with the column electrode that extends along column direction on line direction, on the glass substrate of opposite side, be set side by side with the row electrode that on column direction, extends along line direction, on the part that the column electrode of discharge space pair and row electrode intersect respectively, form rectangular unit light-emitting zone (discharge cell).

And; on this PDP; on the position in the unit light-emitting zone on the dielectric layer that forms in order to cover column electrode and row electrode, form magnesium oxide (MgO) film that has the defencive function of dielectric layer and in the unit light-emitting zone, emit the function of secondary electron by evaporation.

Formation method as the magnesium oxide films in the manufacturing process of this PDP, applying the method for printing screen that the cream sneak into magnesium oxide powder forms magnesium oxide films on dielectric layer is easier method, so open shown in flat 6-No. 325696 communiques as the spy, the application of this method studied.

But, as described in the prior art, sneaked into the refining leaf magnesian cream of polycrystalline sheet that obtains of magnesium hydroxide heat treatment utilizing silk screen print method to apply, form under the situation of magnesium oxide films at PDP thus, the flash-over characteristic of this PDP is with to utilize vapour deposition method to form the situation of magnesium oxide films roughly the same or slightly raising only arranged.

Therefore, more and more urgent hope can form the magnesium oxide films (diaphragm) that can further improve flash-over characteristic on PDP.

Summary of the invention

The present invention will solve the problem of PDP of above-mentioned existing formation magnesium oxide films as a problem.

That is, Plasmia indicating panel of the present invention disposes front substrate and back substrate in opposite directions across discharge space, is provided with between this front substrate and back substrate: a plurality of column electrodes are right; A plurality of row electrodes are extending the direction of intersecting with this column electrode, form the unit light-emitting zone at the discharge space with right each cross section of column electrode; And luminescent coating; And in discharge space, enclose discharge gas, it is characterized in that, the magnesium oxide layer that contains the magnesium oxide crystalline solid in part setting towards the light-emitting zone of unit at least between described front substrate and the back substrate, this magnesium oxide crystalline solid is ultraviolet ray exited by what radiate from discharge gas, thereby radiation has the ultraviolet ray of peak wavelength at 230～250nm, luminescent coating is by from the ultraviolet ray of this magnesium oxide layer radiation and ultraviolet ray exited from the discharge gas radiation, thereby it is luminous, and described magnesium oxide crystalline solid comprises the monocrystal of particle diameter more than or equal to 2000 dusts.The PDP of this execution mode, be located at towards the crystal magnesium oxide layer of the part of discharge cell, by electron ray excitation by discharge generation, carry out in wavelength region may 200～300nm, having the cathodoluminescence at peak, can improve the flash-over characteristic of the discharge delay etc. of PDP thus, obtain good flash-over characteristic.

And PDP of the present invention is provided with between substrate and the back substrate in front: right at the column electrode that line direction extends; Extend and form the row electrode of discharge cell (unit light-emitting zone) at discharge space with the right cross section of column electrode at column direction; And luminescent coating, in addition, utilize silk screen printing and hectographic printing, matching method, dispense method, roll coating process etc., discharge cell part in opposite directions at the dielectric layer right with covering column electrode applies the cream that contains the magnesium oxide crystalline solid, perhaps adopt the powder utilize gunite or electrostatic coating method etc. to make the magnesium oxide crystalline solid attached to the discharge cell part in opposite directions of dielectric layer on and form the method for powder bed etc., setting is towards the crystal magnesium oxide layer of discharge cell, by the discharge that in discharge cell, produces by column electrode and row electrode, ultraviolet ray by the radiation of the xenon the discharge gas in being filled in discharge space encourages, have the ultraviolet ray of peak wavelength from crystal magnesium oxide layer radiation at 230～250nm thus, this PDP as its preferred forms.

And, luminescent coating is ultraviolet ray exited and luminous by the radiation of the xenon from discharge gas by the discharge that produces in the discharge cell, and also by by from the ultraviolet ray of this xenon radiation and from the radiation of crystal magnesium oxide layer have the ultraviolet ray exited and luminous of 230～250nm peak wavelength, so the brightness of image increases.

In addition, ultraviolet launching efficiency from this crystal magnesium oxide layer radiation with 230～250nm peak wavelength, under the situation of BAM series blue fluorescent material, can not reduce because of the vacuum ultraviolet deterioration of radiating from xenon yet, so can keep the luminous efficiency of the luminescent coating of blueness, often the image of exhibit high brilliance.

Description of drawings

Fig. 1 is the front view of the embodiment of expression embodiments of the present invention.

Fig. 2 is the profile of V-V line of Fig. 1.

Fig. 3 is the profile of W-W1 line of Fig. 1.

Fig. 4 is the figure of SEM photograph image that expression has the magnesium oxide monocrystal of cube single crystals structure.

Fig. 5 is the figure of SEM photograph image that expression has the magnesium oxide monocrystal of cube polycrystalline structure.

Fig. 6 is a profile of representing in this embodiment to contain by coating the state of the single crystals magnesium oxide layer that the cream of magnesium oxide monocrystal powder forms.

Fig. 7 is the profile of representing in this embodiment by the state of the formed single crystals magnesium oxide layer of the powder bed that forms by adhering to of magnesium oxide monocrystal powder.

Fig. 8 is a profile of representing in this embodiment the single crystals magnesium oxide layer to be formed on the variation on the magnesium oxide layer that forms by evaporation.

Fig. 9 is the curve chart of the luminescence-utraviolet intensity of expression magnesium oxide monocrystal.

Figure 10 is the curve chart that the luminescence-utraviolet intensity of magnesium oxide monocrystal and evaporation magnesium oxide is compared in expression.

Figure 11 is the curve chart of the luminescent spectrum of expression magnesium oxide monocrystal.

Figure 12 is the curve chart of improvement state of the discharge delay of this embodiment of expression.

Figure 13 is expression from the curve chart of the relation of luminous peak strength of the CL of the 235nm of magnesium oxide monocrystal and discharge delay.

Figure 14 is the curve chart of ultraviolet luminous relatively speed of every kind of color of expression luminescent coating.

Figure 15 is the key diagram of the luminous principle of the luminescent coating of this embodiment of expression.

Figure 16 is the curve chart of the relative luminous efficiency of expression blue fluorescent material.

Embodiment

Fig. 1～Fig. 3 represents an embodiment of the execution mode of PDP of the present invention, and Fig. 1 is the front view that schematically illustrates the PDP of this embodiment, and Fig. 2 is the profile of V-V line of Fig. 1, and Fig. 3 is the profile of W-W line of Fig. 1.

This Fig. 1～PDP shown in Figure 3, at the back side as the front glass substrate 1 of display surface, a plurality of column electrodes to (X, Y) in front the line direction of glass substrate 1 (left and right directions of Fig. 1) extending and be arranged in parallel.

Column electrode X by: form the transparency electrode Xa that the nesa coating by ITO etc. of T word shape constitutes; The bus electrode Xb narrow and small base end part, that be made of metal film of extension of the line direction of glass substrate 1 and connection transparency electrode Xa constitutes in front.

Equally, column electrode Y by: form the transparency electrode Ya that the nesa coating by ITO etc. of T word shape constitutes; The bus electrode Yb narrow and small base end part, that be made of metal film of extension of the line direction of glass substrate 1 and connection transparency electrode Ya constitutes in front.

This column electrode X and the Y column direction of glass substrate 1 (above-below direction of Fig. 1) in front alternately arrange, along bus electrode Xb and Yb transparency electrode Xa separately and Ya arranged side by side, Xiang Yuqi is in right the other side's row electrode sides and extends, and the top margin of the wide width portion of transparency electrode Xa and Ya respectively across the discharging gap g of necessary width toward each other.

The back side of glass substrate 1 between the each other back-to-back bus electrode Xb and Yb of column electrode to (X, Y) of column direction adjacency, forms the black or the dark-coloured light absorbing zone (light shield layer) 2 that extend at line direction along this bus electrode Xb, Yb in front.

In addition, the back side of glass substrate 1 is formed with dielectric layer 3 in front, to cover column electrode to (X, Y), the back side at this dielectric layer 3, and the column electrode that adjoins each other to the adjacent back-to-back bus electrode Xb of (X, Y) and Yb in opposite directions the position and the bus electrode Xb adjacent and the area part between the Yb with this in opposite directions the position and bus electrode Xb, Yb be formed with extending in parallel rear side at dielectric layer 3 outstanding heave dielectric layer 4.

And,, form the magnesium oxide layer 5 (hereinafter referred to as the crystal magnesium oxide layer) that contains magnesium oxide crystalline solid described later with cube crystalline texture in this dielectric layer 3 and the rear side of heaving dielectric layer 4.

This crystal magnesium oxide layer 5 is formed at dielectric layer 3 and heaves on the whole surface of dielectric layer 4, or its part, for example is on the part of discharge cell described later.

In addition, in illustrated example, expression be that crystal magnesium oxide layer 5 is formed at dielectric layer 3 and heaves the example on the whole surface of dielectric layer 4.

On the other hand, on the demonstration side one side of the back side glass substrate 6 of discharge space S and front glass substrate 1 configured in parallel, the spaced and parallel arrangement that row electrode D separates each other and stipulates, be arranged in each column electrode to (X, Y) each other on right transparency electrode Xa and the Ya position in opposite directions, to the direction (column direction) of (X, Y) quadrature being extended with column electrode.

On the demonstration side of glass substrate 6 one side, also form the white columns electrode protecting layer (dielectric layer) 7 that covers row electrode D overleaf, on this row electrode protecting layer 7, form next door 8.

This next door 8 forms roughly ladder-shaped by a pair of cross wall 8A and longitudinal wall 8B, a pair of cross wall 8A is extending at line direction respectively the bus electrode Xb and the Yb position in opposite directions of (X, Y) with each column electrode, the centre position of longitudinal wall 8B between the row electrode D of adjacency, between a pair of cross wall 8A, extend at column direction, each next door 8 is set up in parallel at column direction across gap SL, gap SL extends at line direction at each other back-to-back between in opposite directions the cross wall 8A of other next doors 8 of adjacency.

And, next door 8 by this ladder shape, discharge space S between front glass substrate 1 and the back side glass substrate 6 according to being formed at and the discharge cell C each other in right transparency electrode Xa and Ya in opposite directions part of each column electrode to (X, Y), is divided into square respectively.

Be formed with luminescent coating 9 towards the cross wall 8A in the next door 8 of discharge space S and the side of longitudinal wall 8B and the surface of row electrode protecting layer 7; with these five faces of whole coverings; the color of this luminescent coating 9 is divided into redness, green, blueness according to each discharge cell C, and these colors are arranged in the line direction order side by side.

The crystal magnesium oxide layer 5 that dielectric layer 4 surfaces are heaved in covering (or only is formed at and during in opposite directions part of the discharge cell C that heaves dielectric layer 4 at crystal magnesium oxide layer 5, for heaving dielectric layer 4) the demonstration side one side (with reference to Fig. 2) of the cross wall 8A in butt next door 8, heave dielectric layer 4 thus with sealing respectively between discharge cell C and the gap SL, but the demonstration side of butt longitudinal wall 8B one side (with reference to Fig. 3) not, form gap r betwixt, between the discharge cell C of line direction adjacency, communicate with each other by this gap r.

In discharge space S, enclose the discharge gas that comprises more than or equal to the xenon of 10 volume %.

Above-mentioned crystal magnesium oxide layer 5 is to utilize methods such as gunite or electrostatic coating method, aforesaid magnesium oxide crystalline solid attached to dielectric layer 3 with heave and form on the rear side surface of dielectric layer 4.The magnesium oxide crystalline solid that forms this crystal magnesium oxide layer 5 is encouraged by electron ray, carrying out in wavelength region may 200～300nm (particularly in 230～250nm, 235nm near) thus, to have a CL of peak value luminous, by encouraging from the wavelength 142nm of xenon generation and the vacuum ultraviolet of 172nm by discharge, radiation has the ultraviolet ray of peak wavelength at 230～250nm simultaneously.

In this magnesium oxide crystalline solid, for example contain the monocrystal that the magnesium vapor that the magnesium heating produces will be carried out the magnesium that gaseous oxidation obtains (below, the monocrystal of this magnesium is called the smoked magnesium oxide monocrystal).

And, in this smoked magnesium oxide monocrystal, contain the magnesium oxide monocrystal shown in the SEM photograph image of Fig. 4 for example with cube single crystals structure, with the magnesium oxide monocrystal shown in the SEM photograph image of Fig. 5 with structure (that is the many crystalline textures of cube) that the cube crystalline solid embeds each other.

In addition, the magnesium oxide monocrystal with this cube single crystals structure mixes existence usually with the magnesium oxide monocrystal with the many crystalline textures of cube.

Synthetic about this smoked magnesium oxide monocrystal was documented in " material " in November, 1987 number, the 36th volume No. 410 the 1157th～1161 page " using the synthetic and character of the magnesium dust of vapor phase method " etc.

This magnesium oxide crystalline solid helps to shorten the improvement of flash-over characteristic of discharge delay time etc. of PDP and the raising of image brightness as hereinafter described.

And the smoked magnesium oxide monocrystal is compared with the magnesium oxide monocrystal that utilizes additive method to obtain, and it is high and can obtain particulate to have purity, and less etc. the feature of particle aggregation.

In this embodiment, use utilize that the BET method measures have average grain diameter more than or equal to 500 dusts, be preferably greater than the smoked magnesium oxide monocrystal of the particle diameter that equals 2000 dusts.

Fig. 6 represents to utilize silk screen printing or hectographic printing, branch to spread methods such as method, roll coating process, and the cream that will contain smoked magnesium oxide monocrystal p is coated in the structure when forming crystal magnesium oxide layer 5 on dielectric layer 3 (with the heaving dielectric layer 4) surface.

Fig. 7 represents to utilize methods such as adopting gunite or electrostatic coating method to make smoked magnesium oxide monocrystal p attached to the powder bed that forms on dielectric layer 3 (with the heaving dielectric layer 4) surface, the example when constituting crystal magnesium oxide layer 5.

In this case, for example utilize the air gunite, use spray gun, the suspension that is dispersed with smoked magnesium oxide monocrystal p in the medium (for example specific ethanol etc.), blow and be attached on dielectric layer 3 surface of (with heaving dielectric layer 4), make and adhere to smoked magnesium oxide monocrystal p, form powder bed thus.

In addition, above-mentioned expression only forms the example of crystal magnesium oxide layer 5 on dielectric layer 3 and the surface of heaving dielectric layer 4, but as shown in Figure 8, also can form evaporation magnesium oxide layer 5A on the surface of dielectric layer 3 (with heaving dielectric layer 4) earlier, on this evaporation magnesium oxide layer 5A, utilize gunite or electrostatic coating method etc. to adhere to smoked magnesium oxide monocrystal p, constitute the double-decker that is formed with crystal magnesium oxide layer 5.

And, in Fig. 8, also evaporation magnesium oxide layer 5A and crystal magnesium oxide layer 5 can be put upside down, on crystal magnesium oxide layer 5, form evaporation magnesium oxide layer 5A.

Above-mentioned PDP forms reset discharge and address discharge that image uses, keeps discharge in discharge cell C.

Promptly, during reset discharge, electrode pair (X is expert at, Y) each paired transparency electrode Xa, carry out reset discharge between the Ya simultaneously, make the whole cancellations of wall electric charge (or at all parts formation wall electric charges) dielectric layer 3 and part each discharge cell C adjacency, during the address of back, between the transparency electrode Ya of column electrode Y and row electrode D, produce the discharge of selectivity address, the corresponding image that will form, the wall electric charge that is formed with the luminescence unit of wall electric charge and dielectric layer 3 at dielectric layer 3 by the cell distribution of turning off the light of cancellation in panel surface, then at the interdischarge interval of keeping of back, in luminescence unit, electrode pair (X is expert at, Y) paired transparency electrode Xa, keep discharge between the Ya.

And, keep discharge by this, the vacuum ultraviolet of xenon from discharge gas radiation wavelength 142nm (resonance line) and 172nm (molecular line), color is divided into red, green, blue trichromatic luminescent coating 7 is by this vacuum ultraviolet excitation, luminous, thus at panel surface formation image.

The magnesium oxide crystalline solid that comprises in the crystal magnesium oxide layer 5 is by the electron ray excitation that produces from discharge gas by the discharge of carrying out in discharge cell C, carrying out in wavelength region may 200～300nm (particularly in 230～250nm, 235nm near) thus, to have a CL of peak value luminous, simultaneously by the excitation of the vacuum ultraviolet of wavelength 142nm that produces by the xenon from discharge gas and 172nm by the discharge of carrying out in this discharge cell C, as shown in Figure 9, radiation has the ultraviolet ray of peak wavelength at 230～250nm.

In addition, the ultraviolet ray that has peak wavelength at this 230～250nm, as represent the shown in Figure 11 of Figure 10 of 235nm luminescence-utraviolet intensity and the luminescent spectrum of representing single crystals magnesium oxide (smoked magnesium oxide monocrystal), be not utilized magnesium oxide layer (for example evaporation magnesium oxide layer 5A of Fig. 8) excitation that common vapour deposition method forms.

Figure 12 represents PDP only had when utilizing the magnesium oxide layer (for example evaporation magnesium oxide layer 5A of Fig. 8) that common vapour deposition method forms that ((curve b) when curve a), only has crystal magnesium oxide layer 5, the discharge delay time of (curve c) when having the double-decker that utilizes magnesium oxide layer (for example evaporation magnesium oxide layer 5A of Fig. 8) that common vapour deposition method forms and crystal magnesium oxide layer 5, dwell time is according to the rules tested and comparison.

In this Figure 12, with only have when utilizing the magnesium oxide layer that common vapour deposition method forms (curve a) is compared, when only having crystal magnesium oxide layer 5 (curve b) and when having the double-decker that utilizes magnesium oxide layer that common vapour deposition method forms and crystal magnesium oxide layer 5 discharge delay time during the arbitrary situation of (curve c) all obviously shorten.

Distinguish that thus the shortening of this discharge delay time results from the magnesia crystal (specifically being the smoked magnesium oxide monocrystal) that forms crystal magnesium oxide layer 5.

Infer and to result from machine-processed as follows that the discharge delay time of this magnesium oxide monocrystal shortens.

Promptly, improvement based on the flash-over characteristic of this crystal magnesium oxide layer 5 is speculated as, carry out in wavelength region may 200～300nm (particularly in 230～250nm, near the 235nm) have a luminous smoked magnesium oxide monocrystal of CL of peak value, have the energy level corresponding with this peak wavelength, the electronics that can when this energy level (is counted more than the mscc) seizure for a long time at reset discharge, produce, be applied in the electric field taking-up that address voltage forms by this electronics, thereby when the discharge beginning, obtain required initial stage electronics fast and fully, accelerate the discharge beginning, shorten discharge delay time thus.

Based on the flash-over characteristic of this magnesia crystal improve effect (shortening of discharge delay time), near the increase that has the luminous intensity of the CL of peak value with in wavelength region may 200～300nm (particularly in 230～250nm, 235nm) increases.

Figure 13 is the curve chart of the dependency relation of expression CL luminous intensity of magnesia crystal and discharge delay.

In addition, the data of this Figure 13 are data of measuring to the electron ray of the about 1kV of magnesia crystal direct irradiation that forms crystal magnesium oxide layer 5.

Distinguish that according to this Figure 13 the intensity luminous by the CL of the 235nm of crystal magnesium oxide layer 5 excitation is strong more, discharge delay time is short more.

Based on the shortening effect of the luminous discharge delay time of the CL of this magnesia crystal, and also have dependency relation between the particle diameter of magnesia crystal, the particle diameter of this magnesia crystal is big more, and the CL luminous intensity is big more, and discharge delay time is short more.

This is considered to, for example when wanting to form the bigger smoked magnesium oxide monocrystal of particle diameter, owing to need to improve the heating-up temperature that makes when producing magnesium vapor, the length of flame of magnesium and oxygen reaction is elongated, this flame and temperature difference on every side become greatly, thereby the smoked magnesium oxide monocrystal that particle diameter is bigger is just got over the energy level of the luminous peak wavelength of the above-mentioned CL of the more correspondence of formation.

And, about the smoked magnesium oxide monocrystal of cube polycrystalline structure, is comprised many crystal plane defectives by being speculated as, this planar defect energy level have an improvement that helps flash-over characteristic.

As mentioned above, by keeping discharge, the vacuum ultraviolet of xenon from discharge gas (Xe) radiation 146nm (resonance line) or 172nm (molecular line) utilizes red, green, the blue luminescent coating 9 of this vacuum ultraviolet excitation PDP, carries out luminous from versicolor luminescent coating 9.

At this moment, utilize the vacuum ultraviolet of keeping xenon (Xe) radiation of discharge from discharge gas by this, as mentioned above, have the ultraviolet ray of peak wavelength (with reference to Fig. 9～Figure 11) in 230～250nm scope from 5 radiation of crystal magnesium oxide layer.

Ultraviolet ray from the peak wavelength with 230～250nm of this single crystals magnesium oxide layer 5 radiation, as shown in figure 14, be effectively to encourage each red, green, blue luminescent coating 9 respectively and make its luminous optimal wavelength zone, except that the vacuum ultraviolet of the xenon from discharge gas (Xe) radiation, luminescent coating 9 is ultraviolet ray exited and luminous by from the peak wavelength with 230～250nm of this crystal magnesium oxide layer 5 radiation also, and the image brightness of PDP is increased.

In addition, the curve A among Figure 14 is represented red-emitting phosphors ((Y, Gd) BO ₃: Eu ³⁺) luminous relatively speed, curve B is represented green-emitting phosphor (ZnSiO ₄: Mn ²⁺) luminous relatively speed, curve C is represented blue emitting phophor (BaMgAl ₁₀O ₁₇: Eu ²⁺) luminous relatively speed, curve D is represented the mcl characteristics of luminescence of magnesium oxide in addition.

Figure 15 represents the schematic diagram that above-mentioned luminescent coating 9 is luminous, distinguish according to this figure, by the ultraviolet crystal magnesium oxide layer 5 that radiation has the peak wavelength of 230～250nm is set at PDP, with in the past like that luminescent coating 9 only rely on the luminous situation of the vacuum ultraviolet of xenon (Xe) radiation from discharge gas to compare, luminous quantity from luminescent coating 9 increases, and the brightness of PDP increases.

Figure 16 is the curve chart of the relation of the ultraviolet excitation wavelength of the expression BAM series blue fluorescent material that forms blue phosphor layers 9 and relative luminous efficiency.

In this Figure 16, the relative luminous efficiency of BAM when curve E represents to begin irradiation ultraviolet radiation series blue fluorescent material, curve F represents to shine the relative luminous efficiency of the BAM series blue fluorescent material after the ultraviolet ray of official hour.

Distinguish according to this Figure 16, in the vacuum ultraviolet of the 146nm of the xenon from discharge gas (Xe) radiation and 172nm, BAM series blue fluorescent material is because of the vacuum ultraviolet irradiation deterioration from the xenon radiation, luminous efficiency reduces, but the ultraviolet ray of the 230～250nm wavelength that radiates from crystal magnesium oxide layer 5, even BAM series blue fluorescent material shines under the situation of deterioration because of the vacuum ultraviolet from the xenon radiation, the luminous efficiency of this BAM series blue fluorescent material does not almost reduce yet.

Like this, this PDP can keep the luminous efficiency of blue phosphor layers 9 by crystal magnesium oxide layer 5 is set, so image that all the time can exhibit high brilliance.

In addition, crystal magnesium oxide layer 5 as mentioned above, may not necessarily form the whole surface of cover film magnesium oxide layer 4, for example, also can with transparency electrode Xa, the Ya of column electrode X, Y in opposite directions part or antithesis except that with transparency electrode Xa, Ya part in opposite directions other parts etc., form the part figure.

In addition, in the above description, illustrated the present invention be applicable in front glass substrate be formed with column electrode to and cover by dielectric layer, and the glass substrate side is formed with luminescent coating exchanges PDP with the reflection-type of row electrode example overleaf, but the present invention also goes in front the glass substrate side and forms column electrode to covering with the row electrode and by dielectric layer, and the glass substrate side reflection-type that forms luminescent coating exchanges PDP overleaf; Or the glass substrate side forms luminescent coating in front, and the glass substrate side forms column electrode to exchanging PDP with row electrode and the transmission-type that covered by dielectric layer overleaf; At the column electrode of discharge space to exchanging PDP with three electrode types that the cross section of row electrode forms discharge cell; Two electrode types that form discharge cell at the cross section of the column electrode of discharge space and row electrode exchange the various forms of PDP of PDP etc.

Claims (7)

1. a Plasmia indicating panel disposes front substrate and back substrate in opposite directions across discharge space, is provided with between this front substrate and back substrate: a plurality of column electrodes are right; A plurality of row electrodes are extending the direction of intersecting with this column electrode, form the unit light-emitting zone at the discharge space with right each cross section of column electrode; And luminescent coating; And in discharge space, enclose discharge gas, it is characterized in that,

At least be provided with the magnesium oxide layer that comprises the magnesium oxide crystalline solid towards the part of unit light-emitting zone between described front substrate and the back substrate, this magnesium oxide crystalline solid is by being encouraged by the ultraviolet ray from the discharge gas radiation, and radiation has the ultraviolet ray of peak wavelength at 230～250nm

Luminescent coating passes through to be encouraged by the ultraviolet ray of radiating from this magnesium oxide layer with from the ultraviolet of discharge gas radiation, and luminous,

Described magnesium oxide crystalline solid comprises the monocrystal of particle diameter more than or equal to 2000 dusts,

Described magnesium oxide crystalline solid is by the excitation of electron ray, and carries out having in wavelength region may 200～300nm the cathodoluminescence of peak value.

2. Plasmia indicating panel according to claim 1, it is characterized in that, described discharge gas comprises xenon, and the magnesium oxide crystalline solid is encouraged by the ultraviolet ray of radiating from xenon by the discharge that produces in discharge gas, and radiation is based on the ultraviolet ray of the wavelength of 230～250nm.

3. Plasmia indicating panel according to claim 1 is characterized in that described discharge gas comprises the xenon more than or equal to 10 volume %.

4. Plasmia indicating panel according to claim 1 is characterized in that, described luminescent coating is made of red-emitting phosphors layer and green-emitting phosphor layer, blue phosphor layers, and this blue phosphor layers comprises BAM series blue emitting phophor material.

5. Plasmia indicating panel according to claim 1 is characterized in that, described magnesium oxide crystalline solid is the monocrystal by steam generation gaseous oxidation that magnesium heating is produced is generated.

6. Plasmia indicating panel according to claim 1 is characterized in that, the magnesium oxide layer that contains described magnesium oxide crystalline solid is formed at and covers on the right dielectric layer of column electrode.

7. Plasmia indicating panel according to claim 1 is characterized in that, the magnesium oxide layer that contains described magnesium oxide crystalline solid is formed at by evaporation and is formed on other magnesium oxide layers that cover on the right dielectric layer of column electrode.

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