CN100528914C - 负载型助催化剂的制备 - Google Patents

负载型助催化剂的制备 Download PDF

Info

Publication number
CN100528914C
CN100528914C CNB2004800419359A CN200480041935A CN100528914C CN 100528914 C CN100528914 C CN 100528914C CN B2004800419359 A CNB2004800419359 A CN B2004800419359A CN 200480041935 A CN200480041935 A CN 200480041935A CN 100528914 C CN100528914 C CN 100528914C
Authority
CN
China
Prior art keywords
aryl
polymerization
alkyl
group
dichloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2004800419359A
Other languages
English (en)
Chinese (zh)
Other versions
CN1922217A (zh
Inventor
N·塞德尔
B·里希特
R·克拉策尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Basell Polyolefine GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine GmbH filed Critical Basell Polyolefine GmbH
Publication of CN1922217A publication Critical patent/CN1922217A/zh
Application granted granted Critical
Publication of CN100528914C publication Critical patent/CN100528914C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
CNB2004800419359A 2003-12-23 2004-12-22 负载型助催化剂的制备 Expired - Fee Related CN100528914C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP03029734 2003-12-23
EP03029734.5 2003-12-23
US60/541,667 2004-02-03

Publications (2)

Publication Number Publication Date
CN1922217A CN1922217A (zh) 2007-02-28
CN100528914C true CN100528914C (zh) 2009-08-19

Family

ID=37779308

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2004800419359A Expired - Fee Related CN100528914C (zh) 2003-12-23 2004-12-22 负载型助催化剂的制备

Country Status (7)

Country Link
US (1) US7442667B2 (https=)
EP (1) EP1697432B1 (https=)
JP (1) JP4794461B2 (https=)
KR (1) KR20060118563A (https=)
CN (1) CN100528914C (https=)
BR (1) BRPI0418117B1 (https=)
WO (1) WO2005063831A2 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5461409B2 (ja) * 2007-10-04 2014-04-02 バーゼル・ポリオレフィン・ゲーエムベーハー 触媒ペーストの製造法およびその生成物
EP2172493A1 (en) * 2008-10-02 2010-04-07 Total Petrochemicals Research Feluy Activating supports based on perfluorinated boronic acids
CN108610441B (zh) * 2016-12-13 2021-08-03 中国石油天然气股份有限公司 负载型烯烃聚合助催化剂及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5414180A (en) * 1993-07-14 1995-05-09 Phillips Petroleum Company Organo-aluminoxy product and use
JP3378073B2 (ja) * 1994-02-23 2003-02-17 三菱化学株式会社 熱可塑性エラストマー重合粒子並びにその製造法
JPH07292019A (ja) * 1994-04-28 1995-11-07 Mitsubishi Chem Corp オレフィン重合用触媒およびオレフィン重合体の製造法
BR9508487A (pt) 1994-08-03 1997-12-30 Exxon Chemical Patents Inc Composição de catalisador iônico suportado
US5939347A (en) 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
DE19710615A1 (de) 1997-03-14 1998-09-17 Studiengesellschaft Kohle Mbh Organochrom-Verbindungen enthaltende Katalysatoren und ihre Verwendung in der Alkenpolymerisation
JP4001386B2 (ja) * 1996-07-30 2007-10-31 バゼル・ポリオレフィン・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング アルケン重合のための有機クロム化合物を含有する触媒およびそれらの使用
PL188107B1 (pl) 1996-11-15 2004-12-31 Montell Technology Company Bv Metalocen, układ katalityczny do polimeryzacji, kationowe metaloceny, ligand oraz sposób polimeryzacji
CN1264869C (zh) 1997-08-21 2006-07-19 住友化学工业株式会社 改性粒子 ,用其制成的载体 ,用其制成的烯烃聚合用催化剂成分 ,用其制成的烯烃聚合用催化剂以及烯烃聚合物制备方法
DE19744102A1 (de) 1997-10-06 1999-04-15 Targor Gmbh Katalysatorsystem
DE19757540A1 (de) 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
DE19935592A1 (de) 1999-08-02 2001-02-08 Elenac Gmbh Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation
EP1153938A4 (en) 1999-09-29 2004-03-17 Sumitomo Chemical Co CATALYST FOR THE STEREOREGULAR POLYMERIZATION OF ALPHA OLEFINES AND METHOD FOR THE PRODUCTION OF STEREOREGULAR ALPHA OLEFIN POLYMER
US6759361B2 (en) 2001-06-04 2004-07-06 Equistar Chemicals, Lp Aluminoboronate activators for single-site olefin polymerization catalysts
AU2003257456A1 (en) 2002-07-15 2004-02-02 Basell Polyolefine Gmbh Preparation of supported catalyst systems

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
IMPROVING THE PERFORMANCE OFHETEROGENEOUSBORANE COCATALYSTS BYPRETREATMENT OF THESILICA SUPPORT WITHALKYLALUMINUM COMPOUNDS. CHAROENCHAIDET S ET AL.MACROMOLECULAR:RAPID COMMUNICATIONS,Vol.23 No.7. 2002 *

Also Published As

Publication number Publication date
EP1697432B1 (en) 2014-01-15
BRPI0418117B1 (pt) 2015-10-13
WO2005063831A2 (en) 2005-07-14
JP4794461B2 (ja) 2011-10-19
JP2007515531A (ja) 2007-06-14
US20070149387A1 (en) 2007-06-28
CN1922217A (zh) 2007-02-28
WO2005063831A3 (en) 2005-12-08
US7442667B2 (en) 2008-10-28
BRPI0418117A (pt) 2007-04-17
EP1697432A2 (en) 2006-09-06
KR20060118563A (ko) 2006-11-23

Similar Documents

Publication Publication Date Title
US7094724B2 (en) Catalytic solid supported on calcined hydrotalcite for olefinic polymerisation
JP2004523618A (ja) 混合触媒組成物による重合法
CN101652178B (zh) 铁络合物及其在聚合方法中的用途
EP1521782B1 (en) Preparation of catalyst systems
US7618912B2 (en) Preparation of supported catalyst systems
US7579416B2 (en) Catalyst system for olefin polymerization
JP4820361B2 (ja) オレフィン重合用触媒組成物、その製造方法及び使用方法
CN100528914C (zh) 负载型助催化剂的制备
EP1569968B1 (en) Preparation of catalyst compositions having improved activity
JP2006522189A (ja) 気相流動床反応器内における有機遷移金属化合物存在下での高分子量ポリオレフィンの製造

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20090819