CN100519626C - Novel polyimide copolymer and metal laminate using the same - Google Patents
Novel polyimide copolymer and metal laminate using the same Download PDFInfo
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- CN100519626C CN100519626C CNB2006100718883A CN200610071888A CN100519626C CN 100519626 C CN100519626 C CN 100519626C CN B2006100718883 A CNB2006100718883 A CN B2006100718883A CN 200610071888 A CN200610071888 A CN 200610071888A CN 100519626 C CN100519626 C CN 100519626C
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Abstract
A novel polyimide copolymer, which is a copolymer comprising two kinds of tetracarboxylic acid dianhydrides consisting of (A) isopropylidene-bis(4-phenyleneoxy-4-phthalic acid) dianhydride and (B) 3,3',4,4'-biphenyltetracarboxylic acid dianhydride, and one kind of a diamine consisting of (C) 6-amino-2-(p-aminophenyl)benzimidazole, or two or three kinds of diamines consisting of component (C) and (D) at least one kind of diamines consisting of bis(4-amino-phenyl)ether (D1) and phenylenediamine (D2), and a metal laminate manufactured by laminating said polyimide copolymer to a metallic foil.
Description
The application is dividing an application of following application: application number: 038194376 (PCT/JP2003/008484); The applying date: on July 3rd, 2003; Denomination of invention: " novel polyimide copolymer and metal laminate thereof ".
Technical field
The present invention relates to polyimide copolymer and metal laminate thereof.Specifically, relate to polyimide copolymer and the metal laminate thereof that is suitable as flexible printed wiring board usefulness film.
Background technology
All the time, substrates such as flexible printed wiring board are mostly by adopting caking agents such as Resins, epoxy, urethane resin, with tinsel and aromatic polyimide is film adhered makes.But, there is shortcoming in these flexible printed wiring boards with the caking agent manufacturing, promptly usually can see apply in thereafter hot gluing hysteresis, the weldprocedure that high caking agent when hot is peeled off or bore process in the problem that causes because of binding agent such as scratch, and the cooling metacoxa curls, reverses, warpage etc., particularly makes troubles when the manufacturing fine pattern.
These problems exist the linear expansivity difference to produce because of conductor and insulating material, therefore propose to improve the thermotolerance of caking agent.Basically, if bond layer not then not only can solve the problems that produce because of bond layer, and can omit the operation that Kapton and caking agent are fitted.
For the foregoing reasons, someone is that polyamic acid is directly coated on the metallic conductor with the polyimide precursor multipolymer, carry out polyimideization by heating and form metal laminate, but metal laminate by this method acquisition, poor dimensional stability and generation are curled, and these situations are well-known.
For avoiding these shortcomings, at the fair 5-22399 communique of spy, special fair 6-93537 communique, disclose in the special fair 7-39161 communique etc. on conductor, form the multilayer of low heat expansion property polyimide resin layer and other polyimide resin layer and obtain have a good dimensional stability, cementability, planarity after the etching, the metal laminate of the curling generation property of reduction etc., but the metal laminate that obtains is used 2 kinds or 3 kinds of polyimide precursor multipolymers here, make the manufacturing of this metal laminate become complicated inevitably, as this copolymer solution being carried out multilayer insulation coating, the thickness of perhaps stipulating formed each polyimide resin layer compares etc.
The applicant has proposed (WO 01/29136) a kind of polyimide copolymer layer of contact laminating and the metal laminate that forms on metallic conductor.The polyimide copolymer of Shi Yonging is the multipolymer of isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dianhydride and 6-amino-2-(p-aminophenyl) benzoglyoxaline herein, the polyimide copolymer that obtains by described each component polycondensation, itself just has high-adhesive-strength, even do not engage with tinsel via bond layer, also can be met the metal laminate of stripping strength, and the welding thermotolerance is also fine, but is not purpose to reduce linear expansivity and heat shrink rate, to improve curling resistance.
Summary of the invention
The object of the present invention is to provide a kind of polyimide copolymer and metal laminate thereof, it is the metal laminate of making on metallic conductor, forming a kind of polyamide copolymer layer, by reducing the linear expansivity or the heat shrink rate of polyimide copolymer, perhaps make the linear expansivity or the heat shrink rate of conductor and polyimide copolymer approaching, even apply can suppress effectively also under thermal hysteresis and the situation that metal laminate is curled, reversed, warpage etc., and the flexible printed wiring board that can obtain to have enough bonding strengths and dimensional stability.
Described purpose of the present invention is by a kind of polyimide copolymer and this copolymer layer is pressed on the metal laminate that forms on the tinsel reaches, described multipolymer is by (A) isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dianhydride and (B) 3,3 ', 4,4 '-two kinds of tetracarboxylic acids that biphenyl tetracarboxylic dianhydride is formed complete dianhydride and a kind of diamines of being made up of (C) 6-amino-2-(p-aminophenyl) benzoglyoxaline or by this diamines and (D) two (4-aminophenyl) ether (D
1) and phenylenediamine (D
2) in the multipolymer of two or three diamines of at least a composition.This polyimide copolymer has film forming ability.
The tetracarboxylic dianhydride of employing has (A) isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dianhydride in polyimide copolymer of the present invention synthetic
(B) 3,3 ', 4,4 '-biphenyl tetracarboxylic dianhydride
These two kinds of acid dianhydrides.
Used (A) component and (B) ratio of component, (A) component is 10-80% mole, preferred 20-60% mole, and (B) component is 90-20% mole, preferred 80-40% mole.When the ratio of used (A) component during greater than above-mentioned value, curling when then forming metal laminate becomes big, and linear expansivity and heat shrink rate also become big.On the other hand, when used (A) component during less than aforementioned proportion, not only formed film becomes fragile, and can not see the performance that metal laminate has bonding strength.
Also have, in the scope that does not influence the object of the invention, allow to be used in combination other tetracarboxylic dianhydride.
As reacting the diamines that forms polyimide copolymer, adopt (C) 6-amino-2-(p-aminophenyl) benzoglyoxaline with these two kinds of tetracarboxylic dianhydrides.
This diamine compound (C) can with (D) two (4-aminophenyl) ether (D
1) and phenylenediamine, for example Ursol D (D
2) at least a being used in combination.
Diamine compound (D) adopts two (4-aminophenyl) ether (D
1) time, used (C) component is more than 60% mole, preferred 70-90% mole, and (D
1) component is below 40% mole, the ratio of preferred 30-10% mole.With respect to (C) component, used (D
1) ratio of component is when above-mentioned value is above, the curling change when forming metal laminate is big, and linear expansivity also becomes big.
In addition, diamine compound (D) adopts phenylenediamine (D
2) time, used (C) component is more than 20% mole, preferred 30-50% mole, and (D
2) component is below 80% mole, the ratio of preferred 70-50% mole.With respect to (C) component, used (D
2) ratio of component is when above-mentioned value is above, curling when forming metal laminate becomes big.
In addition, when being used in combination two (4-aminophenyl) ether (D
1) and phenylenediamine (D
2) during as diamine compound (D), according to diamine compound (D
1) and (D
2) usage ratio adopt, but general (C) component is more than 25% mole the time, (D
1) component and (D
2) the total amount of component is below 75% mole, do not produce mol ratio than major coil when forming metal laminate and adopt (C) component and (D) component.
Also have, in the scope that does not influence the object of the invention, allow to be used in combination other diamine compound.
The reaction of tetracarboxylic dianhydride and diamines is preferably carried out in N-N-methyl-2-2-pyrrolidone N-solvent, but in addition also can carry out in dimethyl formamide, N,N-DIMETHYLACETAMIDE, meta-cresol isopolarity solvent.In fact, be at about 0-60 ℃, drip diamines (mixture) or its polar solvent solution in the polar solvent solution of tetracarboxylic dianhydride's mixture, make its reaction about about 0.5-5 hour at about 0-60 ℃ then, forming the polyimide precursor multipolymer is polyamic acid.
It is on the tinsel of representative that the polar solvent solution of this polyamic acid is coated on the Copper Foil, make solvent seasoning after, heat and carry out the polyimide reaction.For promoting to be used for the cyclodehydration reaction of polyimideization, make it by being heated to about 150-450 ℃, the preferred drying oven of about 200-400 ℃ temperature, thereby can form not solvent-laden in fact metal laminate.As the polar solvent of polyamic acid, can directly use the polar solvent of the building-up reactions that is used for the polyimide precursor multipolymer, preferably adopt the N-N-methyl-2-2-pyrrolidone N-.
By the reaction of tetracarboxylic dianhydride (A) with diamines (C), the polyimide copolymer that can obtain having following repeating unit.
In addition, by the reaction of tetracarboxylic dianhydride (B), can obtain except that above-mentioned repeating unit, also having the polyimide copolymer of following repeating unit with diamines (C).
Also have, use diamines (C) and diamines (D simultaneously
1) time, by the reaction of tetracarboxylic dianhydride (A) with tetracarboxylic dianhydride (B), the polyimide copolymer that can obtain to have following repeating unit.
In addition, use diamines (C) and diamines (D simultaneously
2) time, by the reaction of tetracarboxylic dianhydride (A) with tetracarboxylic dianhydride (B), the polyimide copolymer that can obtain to have following repeating unit.
Polyimide copolymer with this repeating unit is insoluble to all kinds of SOLVENTS, therefore can not determining molecular weight or viscosity, and can't stipulate the scope of these values, but can determine to have the molecular weight that film forms ability.Also have, in the polyamic acid stage of thinking to form the polyimide precursor multipolymer, though can measure the viscosity of the reaction mixture solution with certain solid component concentration, this viscosity has can be with the character of changes such as reaction times.
In addition, put down in writing in described WO 01/29136 communique with the polyimide copolymer that obtains after isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dianhydride and the polycondensation of 6-amino-2-(p-aminophenyl) benzoglyoxaline, itself just dissolve in dimethyl formamide, N,N-DIMETHYLACETAMIDE, N-N-methyl-2-2-pyrrolidone N-, meta-cresol equal solvent, by this copolymer solution is coated on the tinsel, can form the metal laminate that satisfies stripping strength.
Relative therewith, as with the dicarboxylic anhydride of 6-amino-2-(p-aminophenyl) benzoglyoxaline polycondensation, use isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dicarboxylic anhydride and 3 simultaneously, 3 ', 4,4 '-biphenyl tetracarboxylic dianhydride and the polyimide copolymer of the present invention that obtains is insoluble to all kinds of SOLVENTS as mentioned above, it is laminated to the metal laminate that obtains on the tinsel has good curling resistance, and linear expansivity and heat shrink rate also improve.
By stripping metal paper tinsel on the metal laminate of such formation, can access the polyimide copolymer film about the about 5-50 μ of the thickness m of good thermal stability of physical strength and size.
The best mode that carries out an invention
According to embodiment the present invention is described below.
Embodiment 1
Under nitrogen replacement atmosphere, in the four neck flasks of the capacity 10L that whipping appts is housed, (A) isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dianhydride and 294.0g (1.0 moles) (B) 3 of 520.1g (1.0 moles) packs into, 3 ', 4,4 '-biphenyl tetracarboxylic dianhydride is dissolved in the solution in the 7150ml N-N-methyl-2-2-pyrrolidone N-, and reinstall (C) 6-amino-2-(p-aminophenyl) benzoglyoxaline of 448.0g (2.0 moles) while the temperature that keeps being no more than 60 ℃, at room temperature stirred 3 hours, (viscosity under 25 ℃ is 7900cps to obtain 8245g varnish shape polyimide precursor copolymer solution, solid component concentration is 15% weight).
At roller shape electrolytic copper foil (Furukawa goods; Thickness 10 μ m) on the roughening treatment face, adopt contrary roller spreader, it is thick that above-mentioned polyimide precursor copolymer solution is coated with 18 μ m, continuous removal of solvent in 120 ℃ hot-air drying stove, make it be warming up to 400 ℃ then in 10 minutes and heat-treat, on Copper Foil, form the polyimide layer of 12.5 μ m thickness.
Embodiment 2
Among the embodiment 1, respectively (A) group component is changed to 260.0g (0.5 mole), (B) group component changes to more 6510ml of 441.0g (1.5 moles), the quantitative change of N-methyl 2-Pyrrolidone, obtains 7572g varnish shape polyimide precursor copolymer solution (8200cps, 15% (weight)).The same with embodiment 1, adopt this polyimide precursor copolymer solution to make polyimide lamination Copper Foil.
Embodiment 3
Among the embodiment 2, respectively with the quantitative change of N-N-methyl-2-2-pyrrolidone N-more 6520ml, (C) group component change to 403.2g (1.8 moles), increase (D in addition
1) 40.0g (0.2 mole) two (4-aminophenyl) ether, obtain 7470g varnish shape polyimide precursor copolymer solution (5500cps, 15% (weight)).The same with embodiment 1, adopt this polyimide precursor copolymer solution to make polyimide lamination Copper Foil.
Embodiment 4
Among the embodiment 3, more 6200ml, (C) group component change to 313.6g (1.4 moles), (D with the quantitative change of N-N-methyl-2-2-pyrrolidone N-respectively
1) group component changes to 80.0g (0.6 mole), obtains 7221g varnish shape polyimide precursor copolymer solution (3800cps, 15% (weight)).The same with embodiment 1, adopt this polyimide precursor copolymer solution to make polyimide lamination Copper Foil.
Copper Foil/polyimide laminate and the Kapton after the Copper Foil part is removed in etching to being obtained by above each embodiment carry out the and the following purpose and measure.
Second-order transition temperature (Tg): according to the dynamic viscoelastic branch of making by Parkin Elmer company
The dynamic viscoelastic that parser DMe 7e measures is tried to achieve with Pa and is
The value of the loss Young's modulus E ＂ of unit, the maximum of establishing E ＂ is
Tg
Linear expansivity (100-200 ℃) is (CTE): the film that etching 10 * 10cm laminate is obtained adds
Heat will have been alleviated the sample of stress then to 400 ℃
Product are contained on the TMA device, at load 2g, sample
The stretching die that long 20mm, heat-up rate are 10 ℃/minute
Measure under the formula
Bonding strength:, measure according to JIS C-6481 to the laminate of 1 * 10cm
Tensile strength, extension at break: the film that etching 10 * 20cm laminate is obtained, according to ASTM
D-882-83 measures
Water-intake rate:, be determined at 150 ℃ of dryings 60 minutes to the film that etching 11 * 11cm laminate obtains
Clock (dry weight W
1), dipping (soaked after 24 hours in 23 ℃ distilled water then
The stain weight W
2) changes in weight (W
2-W
1)/W
1* 100
Etching post-shrinkage ratio:, obtain MD direction and TD direction before and after the etching according to JIS C-6481
Size changing rate
The heating post-shrinkage ratio: the film that etching 10 * 20cm laminate is obtained, at 150 ℃ hot blast
Heat treated is 30 minutes in the stove, obtains its front and back MD direction and TD side
To size changing rate
Curl: the laminate of 5 * 5cm is rested on the horizontal stand, make it be the concavity attitude, not special
Do not apply under the situation of external force, estimate its state
Mensuration and observations are as shown in table 1 below.
Table 1
Mensuration/observation item
Real-1
Real-2
Real-3
Real-4
Tg (℃) 306 323 318 301
CTE (ppm/℃) 32 17 23 32
Bonding strength (Kg/cm) 1.80 1.92 1.85 1.90
Tensile strength (MPa) 164 244 237 240
Extension at break (%) 46 36 47 66
Water-intake rate (%) 2.98 3.36 3.05 2.27
The etching post-shrinkage ratio
MD direction (%)-0.05 0.099 0.067-0.054
TD direction (%)-0.118 0.061 0.048-0.084
The heating post-shrinkage ratio
MD direction (%)-0.165 0.121 0.037-0.086
TD direction (%)-0.181 0.05 0.013-0.107
Curl
Laminate is average
Comparative example 1
Among the embodiment 1, need not (A) component, and respectively (B) group component is changed to more 5870ml of 588.0g (2.0 moles), the quantitative change of N-N-methyl-2-2-pyrrolidone N-, obtain 6699g varnish shape polyimide precursor copolymer solution (6450cps, 15% (weight)).With embodiment 1 the same operation, adopt this polyimide precursor copolymer solution to make polyimide lamination Copper Foil.
Comparative example 2
Among the embodiment 1, (A) group component is changed to 936.0g (1.8 moles) respectively, (B) group component changes to more 8170ml of 58.8g (0.2 mole), the quantitative change of N-N-methyl-2-2-pyrrolidone N-, obtains 9234g varnish shape polyimide precursor copolymer solution (2500cps, 15% (weight)).The same with embodiment 1, adopt this polyimide precursor copolymer solution to make polyimide lamination Copper Foil.
Comparative example 3
Among the embodiment 3, more 6400ml, (C) group component change to 224.0g (1.0 moles), (D with the quantitative change of N-N-methyl-2-2-pyrrolidone N-respectively
1) group component changes to 200.0g (1.0 moles), obtains 7375g varnish shape polyimide precursor copolymer solution (2700cps, 15% (weight)).The same with embodiment 1, adopt this polyimide precursor copolymer solution to make polyimide lamination Copper Foil.
Comparative example 4
Among the embodiment 3, more 6270ml, (C) group component change to 44.8g (0.2 mole), (D with the quantitative change of N-N-methyl-2-2-pyrrolidone N-respectively
1) group component changes to 360.0g (1.8 moles), obtains 6981g varnish shape polyimide precursor copolymer solution (7900cps, 15% (weight)).The same with embodiment 1, adopt this polyimide precursor copolymer solution to make polyimide lamination Copper Foil.
Copper Foil/polyimide laminate and the Kapton after the Copper Foil part is removed in etching to being obtained by above each comparative example carry out mensuration and the observation same with embodiment 1-4.Mensuration and observations are as shown in table 2 below.Also have, in the comparative example 1, the film after the etching is more crisp, therefore fails to measure etching post-shrinkage ratio and heating post-shrinkage ratio.
Table 2
Mensuration/observation item
Than-1
Than-2
Than-3
Than-4
Tg (℃) 341 301 276 266
CTE (ppm/℃) 6.5 48 39 47
Bonding strength (Kg/cm) 0.5---
Tensile strength (MPa) 329 133 191 185
Extension at break (%) 20 60 62 80
Water-intake rate (%) 3.75 2.61 1.93 1.20
The etching post-shrinkage ratio
MD direction (%)--0.163-0.136-0.285
TD direction (%)--0.228-0.242-0.270
The heating post-shrinkage ratio
MD direction (%)--0.404-0.237-0.401
TD direction (%)--0.411-0.346-0.495
Curl
Laminate greatly
Embodiment 5
Under nitrogen replacement atmosphere, in the four neck flasks of the capacity 10L that whipping appts is housed, pack into (A) isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dianhydride and 470.4g (1.6 moles) (B) 3 of 208.0g (0.4 mole), 3 ', 4,4 '-biphenyl tetracarboxylic dianhydride is dissolved in formed solution in the 5460ml N-N-methyl-2-2-pyrrolidone N-, while and keep being no more than 30 ℃ temperature and add 134.4g (0.6 mole) (C) 6-amino-2-(p-aminophenyl) benzoglyoxaline and 152.2g (1.4 moles) (D
2) mixture of Ursol D, at room temperature stirred 3 hours, obtain 6420g polyimide precursor copolymer solution (solid component concentration is that the viscosity under 15% (weight), 25 ℃ is 2150cps).
On the roughening treatment face of the roller shape electrolytic copper foil (Furukawa goods) of thick 10 μ m, adopt contrary roller spreader, it is thick that this polyimide precursor thing varnish is applied to 18 μ m continuously, continuous removal of solvent in 120 ℃ hot-air drying stove, be warming up to 400 ℃ of thermal treatments of carrying out polyimideization then in 10 minutes, obtaining the polyimide layer thickness is Copper Foil/polyimide laminate that 12.5 μ m, nothing are curled.
Embodiment 6
Among the embodiment 5, more 5730ml, (C) group component change to 224.0g (1.0 moles), (D with the quantitative change of N-N-methyl-2-2-pyrrolidone N-respectively
2) group component changes to 108.0g (1.0 moles), obtains 6736g polyimide precursor copolymer solution (solid component concentration is 15% (weight), viscosity 1850cps).Also, adopt this polyimide precursor thing varnish manufacturing not have curling Copper Foil/polyimide laminate with embodiment 5 the same operations.
Embodiment 7
Among the embodiment 5, respectively (A) group component is changed to 260.0g (0.5 mole), (B) group component and change to 441.0g (1.5 moles), the quantitative change of N-N-methyl-2-2-pyrrolidone N-more 5720ml, (C) group component change to 179.2g (0.8 mole), (D
2) group component changes to 129.2g (1.2 moles), obtains 6723g polyimide precursor copolymer solution (solid component concentration is 15% (weight), viscosity 2180cps).Also, adopt this polyimide precursor thing varnish manufacturing not have curling Copper Foil/polyimide laminate with embodiment 5 the same operations.
Embodiment 8
Among the embodiment 5, respectively (A) group component is changed to 260.0g (0.5 mole), (B) group component and change to 441.0g (1.5 moles), the quantitative change of N-N-methyl-2-2-pyrrolidone N-more 5850ml, (C) group component change to 224.0g (1.0 moles), (D
2) group component changes to 108.0g (1.0 moles), obtains 6880g polyimide precursor copolymer solution (solid component concentration is 15% (weight), viscosity 2300cps).Also, adopt this polyimide precursor thing varnish manufacturing not have curling Copper Foil/polyimide laminate with embodiment 5 the same operations.
Embodiment 9
Under nitrogen replacement atmosphere, in the four neck flasks of the capacity 10L that whipping appts is housed, pack into (A) isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dianhydride and 500.0g (1.7 moles) (B) 3 of 156.0g (0.3 mole), 3 ', 4,4 '-biphenyl tetracarboxylic dianhydride is dissolved in formed solution in the 5800ml N-N-methyl-2-2-pyrrolidone N-, while and keep being no more than 30 ℃ temperature and add 180.0g (0.8 mole) (C) 6-amino-2-(p-aminophenyl) benzoglyoxaline, 120.0g (0.6 mole) (D
1) two (4-aminophenyl) ethers and 64.0g (0.6 mole) (D
2) mixture of Ursol D, at room temperature stirred 3 hours, obtain 6800g polyimide precursor copolymer solution (solid component concentration is that the viscosity under 15% (weight), 25 ℃ is 5500cps).Also, adopt this polyimide precursor thing varnish manufacturing not have curling Copper Foil/polyimide laminate with embodiment 5 the same operations.
Comparative example 5
Among the embodiment 5, need not (A) component and respectively (B) group component is changed to 588.0g (2.0 moles), the quantitative change of N-N-methyl-2-2-pyrrolidone N-more 5260ml, (C) group component change to 134.4g (0.6 mole), (D
2) group component changes to 86.4g (0.8 mole), also use 120.0g (0.6 mole) two (4-aminophenyl) ether as diamine compound simultaneously, obtain 6182g polyimide precursor copolymer solution (solid component concentration is 15% (weight), viscosity 3200cps).Also, adopt this polyimide precursor thing varnish manufacturing copper foil/polyimide laminate with embodiment 5 the same operations.
Comparative example 6
Among the embodiment 5, need not (C) component and respectively with the quantitative change of N N-methyl-2-2-pyrrolidone N-more 5060ml, (D
2) group component changes to 216.0g (2.0 moles), obtains 5963g polyimide precursor copolymer solution (solid component concentration is 15% (weight), viscosity 1000cps).Also, adopt this polyimide precursor thing varnish manufacturing copper foil/polyimide laminate with embodiment 5 the same operations.
Copper Foil/polyimide laminate and the Kapton after the Copper Foil part is removed in etching to being obtained by above embodiment 5-9 and comparative example 5 carry out mensuration and the observation same with embodiment 1-4.Also have, Determination of Modulus and the evaluation of curling are carried out as follows.
Young's modulus:, measure according to ASTM D-882-83 to the film that etching 10 * 20cm laminate obtains
Curl: with the laminate of 5 * 5cm, the film after this laminate of etching and the film that this film is obtained after 1 hour 150 ℃ of heat treated, be placed on the horizontal stand, do not applying especially under the situation of external force, estimate its state so that the concavity attitude is quiet respectively
Mensuration and observations are as shown in table 3 below.In the comparative example 6, the etching rear film has been cut off, and therefore fails to carry out the mensuration of bonding strength (0.3Kg/cm) projects in addition, and can see that laminate itself takes place to curl.
Table 3
Mensuration/observation item
Real-5
Real-6
Real-7
Real-8
Real-9
Than-5
Tg (℃) 312 330 311 321 304 329
CTE (ppm/℃) 21 19 23 23 25 18
Bonding strength (Kg/cm) 1.2 1.5 1.1 1.2 1.0 1.2
Young's modulus (GPa) 4.8 3.8 4.2 3.9 4.2 4.1
Tensile strength (MPa) 256 204 202 193 198 239
Extension at break (%) 47 30 38 32 48 42
Water-intake rate (%) 2.3 3.0 2.3 2.8 2.1 3.0
The etching post-shrinkage ratio
MD direction (%) 0.049 0.085 0.023 0.043-0.013 0.069
TD direction (%) 0.060 0.109 0.035 0.049-0.011 0.076
The heating post-shrinkage ratio
MD direction (%) 0.039 0.081-0.022 0.016-0.084 0.083
TD direction (%) 0.058 0.110-0.019 0.035-0.062 0.090
Curl
A little
Laminate is average flat
Curl
The etching rear film is average flat
Curl
Pencil
The heat treated rear film is average flat
State
Notes) the pencil state is meant curling and is shrunk to bar-shaped state
Industrial applicability
The metal laminate that polyimide copolymer of the present invention is laminated on the metal forming and forms Part because the linear expansion coefficient of polyimide copolymer is little, relative temperature change produce curling, Reverse, the curling possibility of warpage etc. is littler, and has the heat of sufficient bonding force and size Stability, and water absorption rate is low, therefore is suitable for requiring the meticulous soft of high-dimensional stability Printed base plate.
And, the contact laminating polyimide copolymer layer via adhesive layer not on metal forming When forming metal laminate, need not to form the polyimide copolymer such as the plural layer of conventional art Layer has by only forming the short-cut method of single polyimide copolymer layer, can accessing The metal laminate of required character.
Claims (6)
1. polyimide copolymer, this multipolymer is by (A) isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dicarboxylic anhydride and (B) 3,3 ', 4, two kinds of tetracarboxylic dianhydrides that 4 '-biphenyl tetracarboxylic dianhydride is formed with by (C) 6-amino-2-(p-aminophenyl) benzoglyoxaline and (D) two (4-aminophenyl) ether (D
1) and phenylenediamine (D
2) in the multipolymer of two or three diamines of at least a composition, be that 10-80% mole, (B) component are that the ratio of 90-20% mole is used two kinds of tetracarboxylic dianhydrides wherein with (A) component; With (C) component be more than 60% mole, (D
1) component is below 40% mole, perhaps (C) component be more than 20% mole, (D
2) component is below 80% mole, perhaps (C) component be more than 25% mole, (D
1) component and (D
2) ratio that adds up to below 75% mole of component uses diamines.
2. polyimide copolymer as claimed in claim 1, this multipolymer has film forming ability.
3. film that forms by the described polyimide copolymer of claim 1.
4. metal laminate, the described polyimide copolymer layer of this laminate lamination claim 1 on tinsel and forming.
5. metal laminate as claimed in claim 4, this laminate is as flexible printed wiring board.
6. the manufacture method of a polyimide copolymer metal laminate, it is characterized in that: make by (A) isopropylidene two (4-phenylene oxygen base-4-phthalic acid) dicarboxylic anhydride and (B) 3,3 ', 4, two kinds of tetracarboxylic dianhydrides that 4 '-biphenyl tetracarboxylic dianhydride is formed with by (C) 6-amino-2-(p-aminophenyl) benzoglyoxaline and (D) two (4-aminophenyl) ether (D
1) and phenylenediamine (D
2) in (A), (B), (C), (D) each component of two or three diamines of at least a composition in polar solvent, react, the polar solvent solution of the polyamic acid that forms is thus coated on the tinsel, after making solvent seasoning, being heated to the polyimide temperature of reaction, is that 10-80% mole, (B) component are two kinds of tetracarboxylic dianhydrides of ratio use of 90-20% mole with (A) component wherein; With (C) component be more than 60% mole, (D
1) component is below 40% mole, perhaps (C) component be more than 20% mole, (D
2) component is below 80% mole, perhaps (C) component be more than 25% mole, (D
1) component and (D
2) ratio that adds up to below 75% mole of component uses diamines.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002239145 | 2002-08-20 | ||
| JP239145/2002 | 2002-08-20 | ||
| JP326599/2002 | 2002-11-11 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038194376A Division CN1311001C (en) | 2002-08-20 | 2003-07-03 | Novel polyimide copolymer and metal laminate comprising the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1827667A CN1827667A (en) | 2006-09-06 |
| CN100519626C true CN100519626C (en) | 2009-07-29 |
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ID=36946235
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006100718883A Expired - Lifetime CN100519626C (en) | 2002-08-20 | 2003-07-03 | Novel polyimide copolymer and metal laminate using the same |
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| Country | Link |
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| CN (1) | CN100519626C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101225166B (en) * | 2007-12-14 | 2010-12-08 | 哈尔滨工业大学 | Sulfonated naphthalene polyimide containing oxazole ring and preparation of proton exchange membrane thereof |
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2003
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