CN100515538C - Preparation of activated carbon fibre filtering core - Google Patents

Preparation of activated carbon fibre filtering core Download PDF

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Publication number
CN100515538C
CN100515538C CNB2007101586636A CN200710158663A CN100515538C CN 100515538 C CN100515538 C CN 100515538C CN B2007101586636 A CNB2007101586636 A CN B2007101586636A CN 200710158663 A CN200710158663 A CN 200710158663A CN 100515538 C CN100515538 C CN 100515538C
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China
Prior art keywords
activated carbon
carbon fiber
filtering core
carbon fibre
preparation
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Expired - Fee Related
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CNB2007101586636A
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CN101254379A (en
Inventor
龙晓飞
张作桢
陈惠龙
原天强
郑淑云
刘成华
王宏伟
朴成军
王小兵
崔欣
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ANSHAN SINOCRAB CARBON FIBER Co Ltd
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ANSHAN SINOCRAB CARBON FIBER Co Ltd
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Abstract

The invention relates to a method for preparing an activated carbon fiber filter core, and the method comprises the following steps: activated carbon fiber which carries with an bactericide is mixed with activated carbon after being crushed or ground, and then is blended with a hot melting binder, and beating is carried out in water; the beated material is put in a suction pool for being stirred, and the stirring is even; suction mold is carried out in the internal mold of an aspirator; the moulded activated carbon fiber filter core is put into an oven for drying, and the finished product is obtained after melting; the activated carbon fiber filter core prepared by the invention through the moulding mode of the internal mold arranged on the aspirator has the advantages that the fiber bonding is tight, the content of the binder is lower, and the specific surface area of the activated carbon fiber is not influenced; the bactericide is loaded on the activated carbon fiber, thereby not only restraining the growth of bacteria and algae on the filter core, but also killing the bacteria and the algae in water, and sterilization ions such as silver, copper, etc. cannot cause shedding easily, thereby greatly improving the purity and the germicidal efficacy of the activated carbon fiber.

Description

The preparation method of activated carbon fibre filtering core
Technical field
The present invention relates to a kind of product and preparation method who is used for drinking water and the purification of other clean water, medicine, wine brewing, food decolouring, organic solvent adsorption filtration, particularly a kind of preparation method of activated carbon fibre filtering core.
Background technology
Activated carbon fiber has very large specific area and very strong absorption, the performance of decolouring, eliminate the unusual smell, and can be widely used in water treatment and air filtration purification aspect, especially very big range of application is being arranged aspect the drink water purifying processing.
The moulding process that at present domestic activated carbon or activated carbon fiber filter core mainly adopt mold pressing or winding, the shortcoming of compression molding is that the filter core binder content is excessive, can obviously reduce the specific area of activated carbon or activated carbon fiber like this, make its absorption, the performance of decolouring, eliminate the unusual smell reduces greatly.The activated carbon fiber filter core that adopts Wrapping formed mode to make, fiber is in conjunction with very lax, and the slit between activated carbon fiber is big, can reduce the adsorption efficiency to the poisonous and harmful substance in the water, and causes the growth of bacterium on the filter core during stopping using easily.
Summary of the invention
Be to solve the problem that prior art exists, the purpose of this invention is to provide a kind of preparation method of new activated carbon fibre filtering core, this method can effectively suppress bacterium on the filter core, algae grows, and kills bacterium and algae in the water, good purification.
For achieving the above object, the present invention is by the following technical solutions:
A kind of preparation method of activated carbon fibre filtering core, this method may further comprise the steps:
1) activated carbon fiber is pulverized, mixed with active carbon, the percentage by weight that described active carbon accounts for mixture is 0-80%; Mix with hot-melt adhesive then, pull an oar in water, the part by weight of water, activated carbon fiber mixture, hot-melt adhesive is 1000: (5-50): (0.1-2);
2) material after the making beating is put to the suction pond and is stirred, and stirs;
3) aspirator that will install inner mold is put into pond suction 1-50 minute, and activated carbon fibre filtering core moulding on the inner mold of aspirator proposes inner mold;
4) the activated carbon fiber filter core of moulding is put into baking oven dry, dry by the fire after molten finished product; Bake out temperature is 60-170 ℃, and the baking melting temperatur is 110-300 ℃.
Be loaded with the metal bactericide in the described activated carbon fiber.
The preparation method of described a kind of activated carbon fibre filtering core, the activated carbon fiber filter core of moulding put into baking oven dry, dry by the fire molten after, externally compound again one deck filter cloth.
Described hot-melt adhesive is polyethylene binder, polypropylene adhesive, polyamide binders or polyester adhesive.
Compared with prior art, the invention has the beneficial effects as follows: be provided with the molding mode of inner mold by aspirator, the activated carbon fibre filtering core fiber that makes is in conjunction with closely, and binder content is low, can not influence the specific area and the adsorption function of activated carbon fiber, and very little to the resistance of water; And on activated carbon fiber, be written into silver, copper, zinc plasma with sterilizing function, not only can suppress bacterium on the filter core, algae grows, can also kill bacterium and algae in the water, and sterilization ions such as silver, copper can not come off human body is damaged, the purification and the bactericidal effect of activated carbon fiber have been improved greatly, and at the inside and outside filter cloth that all is coated with through specially treated of filter core, but the above suspended particulate of elimination 5 μ m but also can prevent that the leakage of NACF from causing secondary pollution not only.
Description of drawings
Fig. 1 is a process chart of the present invention.
Fig. 2 is a product schematic diagram of the present invention.
Among the figure: 1, troughing 2, suction pond 3, stirring pump 4, skeleton 5, filter cloth 6, suction tube 7, vavuum pump 8, surge tank 9, baffle plate 10, the outer filter cloth 12-of control valve 11-adsorption layer
The specific embodiment
Embodiment 1
A kind of preparation method of activated carbon fibre filtering core, this method may further comprise the steps:
1) activated carbon fiber that will be loaded with bactericide (containing silver, copper, the isoionic salt of zinc) is pulverized, mix with polypropylene adhesive then, pull an oar in making beating pond 1, the part by weight of water, activated carbon fiber, hot-melt adhesive is 1000: 15: 0.5.
2) material after the making beating is put to suction pond 2 and is stirred by stirring pump 3, stirs.
3) aspirator that will install inner mold is put into suction pond 2 suctions 1-50 minute, and activated carbon fibre filtering core moulding in the inner mold of aspirator forms adsorption layer 12, and inner mold is proposed; In this aspiration procedure, the filter cloth 5 that water enters the coating of skeleton 4 outsides enters surge tank 8 by suction tube 6, and surge tank 8 vacuumizes by vavuum pump 7; The material that activated carbon fiber and hot-melt adhesive mix rests in the annular section that the catch 9 of skeleton 4 and skeleton 4 both sides constitutes.
4) the activated carbon fiber filter core of moulding is put into baking oven dry, dry by the fire after molten finished product; Bake out temperature is 90 ℃, and the baking melting temperatur is 160 ℃.
Described hot-melt adhesive is polyethylene binder, polypropylene adhesive, polyamide binders or polyester adhesive.
Embodiment 2
A kind of preparation method of activated carbon fibre filtering core, this method may further comprise the steps:
1) the activated carbon fiber pulverizing that will be loaded with bactericide (containing silver, copper, the isoionic salt of zinc) mixes with active carbon, the active carbon proportion is a mixture weight percentage 50%, mix with polyamide binders then, pull an oar in making beating pond 1, the part by weight of water, activated carbon fiber mixture, polyamide binders is 1000: 5: 1.
2) material after the making beating is put to suction pond 2 and is stirred by stirring pump 3, stirs.
3) aspirator that will install inner mold is put into suction pond 2 suctions 1-5 minute, and activated carbon fibre filtering core moulding in the inner mold of aspirator forms adsorption layer 12, and inner mold is proposed, and forms adsorption layer 12; In this aspiration procedure, the filter cloth 5 that water enters the coating of skeleton 4 outsides enters surge tank 8 by suction tube 6, and surge tank 8 vacuumizes by vavuum pump 7; The material that activated carbon fiber and hot-melt adhesive mix rests in the annular section that the catch 9 of skeleton 4 and skeleton 4 both sides constitutes.
4) the activated carbon fiber filter core of moulding is put into baking oven dry, dry by the fire after molten finished product; Bake out temperature is 100 ℃, and the baking melting temperatur is 110 ℃.
Embodiment 3
A kind of preparation method of activated carbon fibre filtering core, this method may further comprise the steps:
1) the activated carbon fiber pulverizing that will be loaded with bactericide (containing silver, copper, the isoionic salt of zinc) mixes with active carbon, the shared mixture weight percentage 20% of active carbon, mix with hot-melt adhesive then, pull an oar in making beating pond 1, the part by weight of water, activated carbon fiber mixture, polyester adhesive is 1000: 20: 2.
2) material after the making beating is put to suction pond 2 and is stirred by stirring pump 3, stirs.
3) aspirator that will install inner mold is put into suction pond 2 suctions 1-5 minute, and activated carbon fibre filtering core moulding in the inner mold of aspirator forms adsorption layer 12, and inner mold is proposed; In this aspiration procedure, the filter cloth 5 that water enters the coating of skeleton 4 outsides enters surge tank 8 by suction tube 6, and surge tank 8 vacuumizes by vavuum pump 7; The material that activated carbon fiber and hot-melt adhesive mix rests in the annular section that the catch 9 of skeleton 4 and skeleton 4 both sides constitutes.
4) the activated carbon fiber filter core of moulding is put into baking oven dry, dry by the fire after molten finished product; Bake out temperature is 110 ℃, and the baking melting temperatur is 260 ℃.
5) the activated carbon fiber filter core of moulding put into baking oven dry, dry by the fire molten after, externally compound again one deck filter cloth 11.
Embodiment 4
A kind of preparation method of activated carbon fibre filtering core, this method may further comprise the steps:
1) the activated carbon fiber pulverizing that will not be loaded with bactericide mixes with active carbon, the shared mixture weight percentage 80% of active carbon, mix with hot-melt adhesive then, pull an oar in making beating pond 1, the part by weight of water, activated carbon fiber mixture, polyester adhesive is 1000: 50: 1.5.
2) material after the making beating is put to suction pond 2 and is stirred by stirring pump 3, stirs.
3) aspirator that will install inner mold is put into suction pond 2 suctions 1-5 minute, and activated carbon fibre filtering core moulding in the inner mold of aspirator forms adsorption layer 12, and inner mold is proposed; In this aspiration procedure, the filter cloth 5 that water enters the coating of skeleton 4 outsides enters surge tank 8 by suction tube 6, and surge tank 8 vacuumizes by vavuum pump 7; The material that activated carbon fiber and hot-melt adhesive mix rests in the annular section that the catch 9 of skeleton 4 and skeleton 4 both sides constitutes.
4) the activated carbon fiber filter core of moulding is put into baking oven dry, dry by the fire after molten finished product; Bake out temperature is 170 ℃, and the baking melting temperatur is 300 ℃.
5) the activated carbon fiber filter core of moulding put into baking oven dry, dry by the fire molten after, externally compound again one deck filter cloth 11.
In the foregoing description: described aspirator, as shown in Figure 1, form by skeleton 4, filter cloth 5, catch 9, suction tube 6, vavuum pump 7, surge tank 8, skeleton is the cylindrical structural that has hole, and the outside is coated with filter cloth 5, and skeleton 4 both sides are provided with baffle plate 9, suction tube 6 one ends are fixed on the baffle plate of skeleton 4 one sides, communicate with the skeleton inner space, suction tube 6 other ends connect surge tank 8, and surge tank 8 connects vavuum pump 7; On suction tube 6, be provided with control valve 10.
Product function characteristics of the present invention are described below, and as shown in Figure 2, are provided with the activated carbon fiber filter core of high accuracy filter course for the outside.
Among Fig. 2,11 is outer filter cloth, is the high accuracy filter course, and filtering accuracy reaches 5 μ m, and it act as the suspension in the water is filtered out, and prevents that inner adsorption layer is contaminated.
Among Fig. 2,12 is adsorption layer, be the compound adsorption layer of activated carbon fiber, its effect be absorption remove chlorine residue in the water, organic compound, heavy metal, microorganism etc. poisonous, harmful, coloured, have and distinguish the flavor of and the carcinogenicity material, the activated carbon fiber and the active carbon that are loaded with the metal bactericide can kill the bacterium of absorption, thereby prevent that bacterial reproduction from reducing the service life of product.Be characterized in fiber in conjunction with closely, so it is big to have treating capacity, the rate of adsorption is fast, clearance is high, to advantages such as the resistance of water are very little.
Among Fig. 2,5 is the filter cloth of internal layer, is the high accuracy filter course, and filtering accuracy reaches 5 μ m, and its effect prevents that the leakage of the NACF that adsorption layer comes off from causing secondary pollution.
Product of the present invention can not established filter cloth at skin yet, as embodiment 1, embodiment 2.
Use-case of the present invention:
1, be after activated carbon cartridge that the water of 130NTU directly prepares is handled with turbidity, turbidity<3NTU.
2, be that colourity was 1.5 degree after the activated carbon fiber filter core that directly prepares of water of 15 degree was handled with colourity.
3, with chlorinity be the water of 2.5mg/T after the activated carbon fiber filter core of preparation is handled, chlorine residue<0.05mg/T.
4, the water that will contain Pb0.49mg/T is after the activated carbon fiber filter core of preparation is handled, and Pb content is 0.0008%mg/T.
5, the water that will contain Cu2.7mg/T is after the activated carbon fiber filter core of preparation is handled, and Cu content is 0.053mg/T.
6, the water that will contain benzene 1.5mg/l is after the activated carbon fiber filter core of preparation is handled, and benzene content is 0.
7, the water that will contain the molten 0.289mg/l of dichloromethane is after the activated carbon fiber filter core of preparation is handled, and the molten content of dichloromethane is 0.
8, after the activated carbon fiber filter core processing of water through preparing with dimethylbenzene 1.56mg/l, xylene content is 0.
9, the water that will contain DDT1.5mg/l is after the activated carbon fiber filter core of preparation is handled, and DDT content is 0.
10, will contain colibacillus 2 * 10 6The water of/ml is after the activated carbon fiber filter core of preparation is handled, and colibacillus content is 0.
11, will contain blue-green algae 2 * 10 6The water of/ml is after the activated carbon fiber filter core of preparation is handled, and blue-green algae content is 0.

Claims (6)

1, a kind of preparation method of activated carbon fibre filtering core is characterized in that this method may further comprise the steps:
1) activated carbon fiber is pulverized, mixed with active carbon, the percentage by weight that described active carbon accounts for mixture is 0-80%; Mix with hot-melt adhesive then, pull an oar in water, the part by weight of water, activated carbon fiber mixture, hot-melt adhesive is 1000: (5-50): (0.1-2);
2) material after the making beating is put to the suction pond and is stirred, and stirs;
3) aspirator that will install inner mold is put into pond suction 1-50 minute, and activated carbon fibre filtering core moulding on the inner mold of aspirator proposes inner mold;
4) the activated carbon fiber filter core of moulding is put into baking oven dry, dry by the fire after molten finished product; Bake out temperature is 60-170 ℃, and the baking melting temperatur is 110-300 ℃.
2, the preparation method of a kind of activated carbon fibre filtering core according to claim 1 is characterized in that: be loaded with the metal bactericide in the described activated carbon fiber.
3, the preparation method of a kind of activated carbon fibre filtering core according to claim 1 is characterized in that: the activated carbon fiber filter core of moulding put into baking oven dry, dry by the fire molten after, externally compound again one deck filter cloth.
4, the preparation method of a kind of activated carbon fibre filtering core according to claim 1 is characterized in that: described hot-melt adhesive is polyethylene binder, polypropylene adhesive, polyamide binders or polyester adhesive.
5, the preparation method of a kind of activated carbon fibre filtering core according to claim 1, it is characterized in that: described aspirator is made up of skeleton, filter cloth, catch, suction tube, vavuum pump, surge tank, skeleton is the garden column construction that has hole, the outside is coated with filter cloth, the skeleton both sides are provided with baffle plate, and suction tube one end is fixed on the baffle plate of skeleton one side, communicate with the skeleton inner space, the suction tube other end connects surge tank, and surge tank connects vavuum pump; On suction tube, be provided with control valve.
6, the prepared activated carbon fibre filtering core of the preparation method of a kind of activated carbon fibre filtering core according to claim 1, it is characterized in that: activated carbon fibre filtering core comprises internal layer filter cloth, adsorption layer, outer filter cloth, internal layer filter cloth, adsorption layer, outer filter cloth are composited successively.
CNB2007101586636A 2007-12-03 2007-12-03 Preparation of activated carbon fibre filtering core Expired - Fee Related CN100515538C (en)

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