CN1005096B - Method for prodn. of combustion trubine blade having single crystal portion - Google Patents

Method for prodn. of combustion trubine blade having single crystal portion Download PDF

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Publication number
CN1005096B
CN1005096B CN85106439.6A CN85106439A CN1005096B CN 1005096 B CN1005096 B CN 1005096B CN 85106439 A CN85106439 A CN 85106439A CN 1005096 B CN1005096 B CN 1005096B
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China
Prior art keywords
blade
root
crystallization
alar part
single crystal
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CN85106439.6A
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CN85106439A (en
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迈克尔·安东尼·布克
西里尔·格拉德·贝克
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CBS Corp
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Westinghouse Electric Corp
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Priority to CN85106439.6A priority Critical patent/CN1005096B/en
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Publication of CN1005096B publication Critical patent/CN1005096B/en
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Abstract

The present invention relates to a manufacturing method used for turbine blades of a combustion turbomachine. A mould filled with melted metal is cooled in a controlled mode, the occurrence of crystallization is slow enough, and single crystal is generated at a wing end. The crystallization process is monitored. Approximately, when the root of a blade starts to be crystallized, a melting metal solution is stirred by magnetic force, and the cooling speed of the blade is almost simultaneously enhanced, and is higher than the cooling speed of generating the single crystal. Approximately, a crystal boundary intensifying agent (carbon is the best.) can be added at the time at stirring is started. The manufactured blade is provided with a single crystal wing part and a fine particle body root.

Description

Manufacture method with combustion gas turbine blade of part monocrystal
The present invention is relevant with the manufacture method of the turbine blade of crystallographic orientation, and this kind blade applications is on the combustion gas turbine machine.
This is the method that a kind of manufacturing is used for the turbine blade on the combustion gas turbine machine; This class combustion gas turbine machine comprises aircraft turbine machine, navigation turbine engine and ground stationary gas turbine engine.The present invention adopts two one step crystallizings, so that produce particulate (on-monocrystalline) structure at root, and produces mono-crystalline structures at alar part.
When high temperature, high-pressure gas expanded and pass through turbine, the combustion gas turbine machine therefrom obtained energy and turns round.Generally made with nickel-base heat resisting superalloy by the actual rotary component that combustion gas promotes, these parts are commonly called blade.As shown in Figure 1, the alar part that blade is crossed by copying and the root of machining are formed, and alar part is driven by hot air flow, and root links to each other with the rotating shaft of turbine.According to the character of Carnot's cycle as can be known, under higher temperature, the combustion gas turbine machine will more effectively be worked, and this just needs the material that can bear higher temperature.For the turbine blade of using in aeroengine and ground stationary turbine generators and other machines, at high temperature the principal mode of mechanical failure is thermal fatigue and forfeiture plasticity_resistant deformation ability.Eliminate the solution that the grain boundary vertical with the principal axes of stress helps these two problems, therefore think that the blade of monocrystalline and crystallographic orientation can demonstrate the obvious improvement of hot strength.
Under the very high state of temperature, large scale crystal grain can be strengthened desirable performance; And under low-temperature condition, the less crystal grain of size can improve some mechanical property.What deserves to be mentioned is that the root of turbine blade is worked under the temperature of its temperature far below alar part, and it bears fatigue load basically, thereby the optimum structure of the alar part of blade and root is very different.And, to get a transition zone that declines as folding in all cross sections at least for traditional alar part.If can make a kind of blade with mixed construction, make it have the alar part of crystallographic orientation and the root of fine grained texture, then will obtain optimum performance.
According to patent specification 4,184,900, can make two kinds of different crystallographic orientation parts at alar part and root, so that obtain different performances.According to patent specification 3,790,303, available a kind of eutectic alloy manufacturing has the turbine blade (turbine blade) of mixed construction, and its alar part is a crystallographic orientation, and its root structure then is a nondirectional.Be noted that this eutectic composition can avoid the nonuniformity of composition,, then can cause the non-uniformity problem of composition if in the method, use non-eutectic composition.
In patent specification 3,695, introduced the method that a kind of controlled crystallization by liquid metal is made pure eutectic material in 941, it utilizes a stable directional magnetic field, the crystallization of the liquid-solid interface of control liquation.When liquation is exposed in the magnetic field, there are not additional power source and it to connect.In patent specification 3,494, a kind of single-crystal metal parts that are used on the combustion gas turbine machine have been proposed in 709, this comprises that the parts integral body of its root all is monocrystal.Patent specification 3,981,345 have introduced a kind of method of continuously casting metal, and in the method, metal is being subjected to the effect in a magnetic field in crystallization process.
The object of the present invention is to provide a kind of manufacturing to be used for the method for the crystallographic orientation turbine blade on the combustion gas turbine machine, its step has, and cooling fills the mould of molten metal under controlled way, makes crystallization occur enough slowly, so that monocrystal begins to generate at wing tip.Characteristics of the present invention are, monitor above-mentioned crystallization process; And when described root will crystallization, begin remaining molten metal is carried out magnetic agitation; Strengthen the rate of cooling of blade then, make it to be higher than the rate of cooling when crystallographic orientation occurring, method can produce the blade with monocrystal alar part and particulate body root whereby, and does not have tangible inhomogeneous part between the alar part of this blade and root.
Briefly, the object of the present invention is to provide a kind of turbine blade, it has the grainiess of mixing, and is that alloying constituent with non-eutectic processes.The blade alar part is a mono-crystalline structures, its root structure then be grain refined, nondirectional crystallization.
This method adopts enough slow crystallization velocity, makes monocrystal begin growth from wing tip; And crystallization process monitored.When the intersection between crystallization arrival alar part and the root, the beginning magnetic agitation is so that eliminate near the inhomogeneous band of crystalline portion just; Improve rate of cooling then, make it be higher than the growth velocity of monocrystalline or the speed of crystallographic orientation.The preferably big hardening agent (preferably carbon) that when beginning to stir, adds the grain boundary.So just, can produce a kind of blade, it has the alar part of mono-crystalline structures and the root of fine grained texture, and the intersection between alar part and root does not have tangible inhomogeneous part.
Referring now to following accompanying drawing, the present invention is done explanation with an example.
Fig. 1 represents typical, as to comprise an alar part and root turbine blade.
Fig. 2 is a figure group that comprises three figure, and it is illustrated in the solute enrichment region in the crystallization process and improves the nonuniformity that produces after the crystallization velocity.
When Fig. 3 is illustrated in the speed of pulling out from stove is controlled, the growing state of monocrystalline.
For the monocrystalline wing that has the fine grained texture root with non-eutectic alloy manufacturing, former process engineering is inapplicable.Because the serious uneven zone of component, the poor mechanical properties that this is regional can appear in the intersection between alar part and root.In crystallization process as shown in Figure 2, if have the blade of monocrystal alar part and particulate body root with one of non-eutectic alloy manufacturing, and do not use the present invention, (Fig. 2 A) so in the early stage, the blade alar part is in condition (the low production rate that helps monocrystal to generate, high-temperature gradient), with back root part (Fig. 2 C) crystallization under the condition that crystal growth rate increases.As can be seen, when the change of growth rate is had an effect, in zone just, have the obvious increase (projection in the curve left side among Fig. 2 C, the present invention can remove this projection effectively) of solutes content in crystallization.The most of nickel-base heat resisting superalloys that often are used to make combustion gas turbine machine blade all are non-eutectics.On this class blade, this nonuniformity will cause obviously inferior zone of a mechanical property.
In order to avoid occurring the uneven problem of component in the join domain of monocrystal alar part and particulate root, the present invention removes inhomogeneous section basically with the method for magnetic agitation.With the method for magnetic agitation can be in the sizable scope of still uncured root section blending solute enrichment region, thereby can avoid any significant change of component.The meaning of used here " inhomogeneous part " speech is the solute enrichment, and is not included in the variation (as the adding of grain boundary hardening agent) of the caused component of additive of adding intentionally in the crystallization process.
The principle of magnetic agitation institute foundation is: an electrical conductor in magnetic field will be subjected to the effect of a power, and this power is perpendicular to the plane at current phasor and magnetic vector place.If conductor is a liquid, this power will cause shear, and produce mixing effect.In patent specification 4,256, in 165, introduced the example that using magnetic force stirs aspect continuous casting.
The present invention just adopts the magnetic agitation method to make to be positioned at the redistribution of concentrating of the solute in monocrystalline alar part the place ahead of crystallization, to have desirable particulate body root and when improving rate of cooling, prevents the appearance of inhomogeneous section basically in order to make with box lunch.
In patent specification 3,494, introduced a kind of growing state of monocrystal in 709, shown in Figure 3 be a kind of embodiment, in this example, crystallization process begins to carry out from the Quench copper pedestal, and with the method crystallization control process that shifts out base and mold at leisure from the hot-zone of stove.Here, the root of blade up, what at first shift out from stove is alar part.Improving the speed that shifts out can make crystallization process accelerate.For the root at blade forms uniform fine grained texture, should be substantially when improving growth rate, the beginning magnetic agitation.Like this, crystallization is from alar part, and the growth of crystallization herein is to carry out shifting out under the quite slow situation of speed, and has only the flow disturbance natural convection form, faint, and along with mould is drawn out of, crystal plane reaches the intersection of the wing-Gen.On this point, draw speed is brought up on the required speed of single crystal growing, and beginning magnetic agitation (being shifted to an earlier date in the moment of improving draw speed simultaneously or slightly basically).Start-up system makes electric current by molten metal and field coil (so that producing required magnetic field), and magnetic stirs and just begins thereupon.In this case, it is fast more to shift out speed, and then crystallization process carries out soon more, and the granular structure that is produced is also careful more, also even more along each axial distribution.The solute that compulsory magnetic agitation will accumulate in before the crystal plane of expanding is broken into liquid, and forms chemically basic structure uniformly.
Because any current in magnetic field that places all can be subjected to an effect perpendicular to the power of magnetic field and electric current, in view of the above, can realize the stirring of liquation.Under the effect of stirring, not only the solute enrichment can be eliminated, and the temperature gradient in the liquation also can uniformity.Thereby it is overheated that the dendrimer in crystalline material takes place, and this is not only because of heat uniforming causes, and with structural relevant.Because dendrimer is to want coring, near the dendrimer root structural overheated (analogy of " structural cold excessively " effect of knowing) is very serious, cause making system to be tending towards balanced " melt back ", dendrimer is refinement thereupon, and loose under by the effect of the caused power of direct current and magnetic field and disconnect, take away by magnetic disturbance stream.For guaranteeing enough cooling rates, so that the disconnected dendrimer fragment that looses does not melt in liquation and keeps solid-state, the speed of pulling out should be enough fast.Above-mentioned fragment can be used as the host crystal of isotropy particle crystallization.
Another benefit that adopts magnetic agitation is to mix one or more grain boundary intensified elements (that is: " carbide formation agent " carbon, boron, zirconium, molybdenum, tungsten, tantalum).Do not strengthen because the monocrystal alloy does not need to do this class grain boundary, in the chemical structure of monocrystal alloy, do not add the element that this class can be strengthened intensity usually.Though the monocrystalline of blade part does not need to utilize the intensified element of grain boundary, the unit that the available interpolation of isotropy part can produce the invigoration effect of grain boundary " carbonization " usually improves.Yet, can increase the difficulty of Manufacture Order crystal foundry goods with the alloy casting blade that contains the grain boundary intensified element, utilize magnetic agitation just can add this dvielement, and can make them in the crystallization process of blade, be distributed to desirable point in time to get on.
In this way, can use practical non-eutectic alloy to produce turbine blade with mono-crystalline structures alar part and fine grained texture root, and at the unlikely generation solute enrichment section in position (root-wing intersection) that improves crystalline rate.
Certainly, the special device and the method for control rate of cooling, and the device of implementing magnetic agitation are some examples, also can adopt other some crystallographic orientations and the method for magnetic agitation.

Claims (7)

1, a kind of method of making combustion gas turbine machine blade, this blade has a root and an alar part, wherein this method is cooled off the mould of the molten metal of containing non-eutectic under controlled way, make crystallization occur enough slowly, so that monocrystal begins to generate to the root direction at wing tip, and this method characteristics are:
-monitor above-mentioned crystallization process;
-when about described root will begin crystallization, begin remaining metallic solution is carried out magnetic agitation;
-strengthen the cooling rate of blade then, make it to be higher than the cooling rate when crystallographic orientation occurring;
Method can produce the blade with monocrystal alar part and particulate body root whereby, and basic part is uniformly arranged between the alar part of this blade and root.
2, the method for claim 1 is characterized in that: in the time of the beginning magnetic agitation, add the intensified element of at least a grain boundary greatly.
3, the method described in claim 2 is characterized in that: described grain boundary intensified element is a carbon.
CN85106439.6A 1985-08-27 1985-08-27 Method for prodn. of combustion trubine blade having single crystal portion Expired CN1005096B (en)

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CN85106439.6A CN1005096B (en) 1985-08-27 1985-08-27 Method for prodn. of combustion trubine blade having single crystal portion

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CN85106439.6A CN1005096B (en) 1985-08-27 1985-08-27 Method for prodn. of combustion trubine blade having single crystal portion

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061123C (en) * 1993-08-06 2001-01-24 株式会社日立制作所 Blade for gas turbine, manufacturing method of the same, and gas turbine including the blade

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1317095C (en) * 2004-02-25 2007-05-23 中国科学院金属研究所 Crystalloid laminae composited from single crystal and directional column crystal and preparing method
CN108097909B (en) * 2016-11-25 2020-06-16 中国科学院金属研究所 Process method for eliminating recrystallization of single crystal high-temperature alloy casting
CN108080603A (en) * 2017-11-29 2018-05-29 中国科学院金属研究所 It is a kind of to reduce the method that stray crystal is formed at the single crystal super alloy abrupt change of cross-section
CN111468704A (en) * 2020-05-29 2020-07-31 鞍钢股份有限公司 Method for improving internal quality of large steel ingot

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061123C (en) * 1993-08-06 2001-01-24 株式会社日立制作所 Blade for gas turbine, manufacturing method of the same, and gas turbine including the blade

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