CN100500983C - Needled felt surface processing agent and impregnation technology thereof - Google Patents
Needled felt surface processing agent and impregnation technology thereof Download PDFInfo
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- CN100500983C CN100500983C CNB2005100379502A CN200510037950A CN100500983C CN 100500983 C CN100500983 C CN 100500983C CN B2005100379502 A CNB2005100379502 A CN B2005100379502A CN 200510037950 A CN200510037950 A CN 200510037950A CN 100500983 C CN100500983 C CN 100500983C
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- surface processing
- emulsion
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- needled felt
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Abstract
The invention relates the needled felt surface processing agent and impregnation technology. The surface processing agent comprises film-forming agent, fabric finishing agent and coupling agent. The formulation is following: 1 4-15% fluoroplymer emulsion; 2 1-20% macromolecular ester polyaromatics; 3 1-8% silicon oil emulsion; 4 0.1-1% coupling agent; 5 0.3-3% nano materials; 6 water. The technology comprises the following steps: unfolding the needled felt, through impregnating bath, squeezing with pair roller extruding machine, drying the wet felt, wrapping the needled felt, and getting the product. The technology improves the physical chemical properties and durability of needled felt filter material.
Description
Technical field
A kind of needled felt surface processing agent and impregnation technology thereof relate to the prescription and the technique processing method thereof of Nomex filtering material (hereinafter to be referred as filter material) surface conditioning agent.
Background technology
Be the protection atmospheric environment, all there is strict demand various countries to the discharging of Industrial Stoves flue dust.Be discharged into the flue gas in the atmosphere, after must handling by cleaner, remove the various pernicious gases and the dust of contaminated environment in the flue gas, just can reach the requirement of national environmental protection pertinent regulations.
At present, the filter material that domestic and international coal-burning boiler generally uses Nomex to make comes the harmful components in the filtering flue gas, and this dust collection method is compared with existing Cottrell process, has higher dust removal efficiency.But the used coal of China's coal-fired boiler in power plant is poor, and the sulfur content height causes fire coal boiler fume oxysulfide and amount of nitrogen oxides height, and ash is many, and vapour quantity is big, and temperature brings very big difficulty for Nomex filter material filtering flue gas up to 180 ℃.And up to the present, the material of the used Nomex filter material of coal-burning boiler all adopts pure PPS (polyphenylene sulfide) material or PPS and P
84The manufacturing of (polyimides) hybrid materials.This Nomex filter material uses on China's coal-fired boiler in power plant and exists easily by major defects such as acidic materials burn into deashing difficulties, is difficult to satisfy the minimum requirement of China's coal-fired boiler in power plant continous-stable operation.In order to improve the physicochemical property and the dust removing effects of synthetic fiber Nomex filter material, must carry out surface treatment to the synthetic fiber Nomex filter material of existing use, to improve the acid resistance and the antioxygen of Nomex filter material, widen its scope of application, prolong its service life.
Summary of the invention
The objective of the invention is to: at the problem of above-mentioned existence, a kind of needled felt surface processing agent and impregnation technology thereof are proposed, with it existing organic synthetic fibers Nomex filter material is carried out surface treatment, make the polymeric membrane of Nomex surface of filter medium formation one deck function admirable, to improve the physicochemical property and the service life of Nomex filter material.
Technical solution of the present invention is, has proposed a kind of needled felt surface processing agent and impregnation technology thereof, and the prescription of surface conditioning agent comprises film forming agent, fabric finishing agent and coupling agent, and its concrete prescription is counted by weight percentage, and is composed as follows:
1) the fluoropolymer emulsion 4-15%;
2) the macromolecule ester polymer 1-20%;
3) silicone oil emulsion 1-8%;
4) coupling agent 0.1-1%;
5) nanometer materials 0.3-3%;
6) water surplus.
The fluoropolymer emulsion has anticorrosion, performance such as anti-oxidant in above prescription.As everyone knows, in the fluoropolymer molecule, contain a large amount of-(CF
2-CF
2)
n-group, fluoropolymer itself have excellent anticorrosion and resistance to elevated temperatures, and (heatproof can reach 260 ℃) is one of main component of this prescription.Its adding especially can improve the heat resistance of Nomex filter material except the antioxygen that helps improving filter material, resistance to water.The fluoropolymer emulsion can be ptfe emulsion (solid content is 60%), Kynoar emulsion (solid content 50%), poly-tetrafluoro hexafluoro copolymer emulsion (solid content 50%).When choosing ptfe emulsion, molecular weight ranges is 1000000-7000000, and optimum range is 2000000-4000000.
In coal-burning boiler institute discharged flue gas harmful components, be rich in a large amount of acidic oxides, as oxysulfide, (SO
X), nitrogen oxide (NO
X) or the like, the effect of macromolecule ester polymer is to make that each component anchors at the Nomex fiber surface uniformly in the composition, and forms continuous diaphragm, can improve the performance of the acidic oxide such as anti-oxysulfide, nitrogen oxide of Nomex surface of filter medium.Employed macromolecule ester polymer mainly comprises the emulsion or the aqueous solution of polyurethane (solid content 20%), polyacrylate (solid content 35%), polyvinyl acetate (solid content 40%) among the present invention, and the best is polyurethane or polyacrylate.Experimental result shows that its optimum concentration range is 1-20%.Content is low excessively, and filtering material finished product filming performance is poor, but too high concentration can cause influence service life because of Nomex filtering material finished product is hard and crisp, thereby and influences the filter efficiency of permeability reduction filter material.
Silicone oil emulsion is a kind of common fabric finishing agent, its function admirable, cheap, and raw material is easy to get.The use of silicone oil emulsion can make the Nomex surface of filter medium become soft, smooth, helps reducing the running resistance in the dust removal process, and is convenient to " deashing " operation of filter bag.Used silicone oil is methyl-silicone oil emulsion (oil content 30%), polymethylphenyl siloxane fluid emulsion (oil content 30%), hydroxy-silicone-oil emulsion (oil content 20%), containing hydrogen silicone oil emulsion (oil content 18%) or their mixture among the present invention, and the best is selected the polyphenyl methyl-silicone oil for use.The silicone oil content of 1-8% just can reach and can make surface of filter medium smooth, does not influence the filming performance of fiber surface again.
Coupling agent in this prescription is silane coupler or titanate coupling agent, and the best is a silane coupler.(Si-O-) strengthened bonding strength between inorganic material (for example titanium oxide) and organic synthetic fibers and the fluoropolymer resin, the high performance polymer diaphragm that makes the Nomex fiber surface form combines more firmly with Nomex filter material fiber base material silicon oxygen bond in the silane coupler.Used silane coupler is that gamma-aminopropyl-triethoxy-silane, KH-560 chemical name are γ-(2 for the KH-550 chemical name among the present invention, the 3-glycidoxy) propyl trimethoxy silicane, KH-570 chemical name are that γ-methacryloxypropyl trimethoxy silane or A-151 chemical name are vinyltriethoxysilane etc., and the best is KH-570.
Sodium meter level material is meant nano-scale oxide or sulfide, and they have the surface of good self-cleaning ability, their adding, use, self-cleaning, the deashing function of having given Nomex filter material finished product.But the nano material granularity is superfine, and it is difficult to evenly disperse in emulsion, so its addition is also unsuitable too high.Experimental result represents that its addition is excessive, both has been unfavorable for reducing cost, and it is inhomogeneous to cause nano material to disperse again, but is lower than 0.3% content, and self-cleaning effect again can be not obvious.So the consumption of generally controlling it is at 0.3-3%.It is many silica (SiOx), titanium oxide (TiO that the present invention selects nano material for use
2), alchlor (Al
2O
3), zinc oxide (ZnO), zinc sulphide (ZnS), calcium sulfide (CaS), vulcanized lead (PbS).The best is selected titanium oxide for use.The titanium oxide granularity is 10～150 nanometers, and the best is the 50-100 nanometer.
A kind of impregnation technology of needled felt surface processing agent comprises that dipping, pair roller extruding, drying oven oven dry, rolling get finished product in the unreeling of the plain felt of Nomex, the dipping tank, and it is characterized in that: technological process and condition are carried out in the following manner:
1) the plain felt of Nomex is put felt through let off roll;
2) the plain felt through unreeling floods by dipping tank, and plain felt must immerse handles following 30 centimetres of liquid level, and guarantees that plain felt dip time was at 0.1-0.2 minute;
3) behind the dipping, through the pair roller extruding, pressure is its deadweight;
4) after the extruding, send into the drying oven oven dry, bake out temperature is 120 ℃-220 ℃;
5) after above step process, with the oven dry Nomex through the winder rolling, finished product;
Whole piece unit linear velocity is 0.5-3 meters/minutes.
The Nomex that adopts prescription of the present invention and technology to make, owing to generated one deck macromolecule high-performance diaphragm at the Nomex surface of filter medium, the corrosion resistance of Nomex filter material is strengthened, especially anti-oxysulfide and nitrogen oxide ability are greatly improved, and antioxidant capacity brings up to 16% from 14%; Nomex surface of filter medium self-cleaning ability is strong, be easy to deashing, durable in use, practice shows, with the Nomex filter material after finishing agent of the present invention and the impregnation technology processing, approximately prolonged 30% service life, can reach the industry standard requirement of continuous use more than 30000 hours, can be widely used in electric power, iron and steel, carbon black, cement, etc. the field, be particularly useful for the smoke filtration of coal-fired boiler in power plant.
Description of drawings
Fig. 1 is the impregnation technology layout of equipment of the present invention.
The specific embodiment
The present invention is described in further detail below in conjunction with embodiment and accompanying drawing.
Table 1, the prescription of 9 needled felt surface processing agents choosing for the embodiment of the invention.In the gauge outfit of table 1 is blocked:
" PTFE emulsion " expression fluoropolymer emulsion (solid content 60%, commercially available).Used polytetrafluoroethylene (PTFE) molecular weight ranges is 2000000～4000000 in the fluoropolymer emulsion;
The commercially available aqueous polyurethane (solid content 35%, commercially available) of " A6 " expression.
" 285 silicone oil emulsion " expression commercially available 285 polymethylphenyl siloxane fluid emulsions (solid content is 35%, commercially available).
" TiO
2" represent that used nano material is the nanoscale titanium oxide, granularity is 50-100 nanometer (commercially available).
Select commercially available KH-570 for use, chemical name γ-methacryloxypropyl trimethoxy silane, molecular formula are CH
2=CCH
3COCH
2CH
2CH
2Si (OCH
2CH
3), as the silane coupler in the present embodiment.
All numerals are all represented the percentage by weight number in the table 1.
Table 1
| Sequence number | The PTFE emulsion | A6 | 285 silicone oil emulsions | TiO 2 | KH570 | |
| 1 | 4 | 20 | 8 | 0.3 | 0.5 | Surplus |
| 2 | 10 | 10 | 1 | 1 | 1.0 | Surplus |
| 3 | 15 | 1 | 4 | 3 | 0.1 | |
| 4 | 4 | 10 | 1 | 1 | 1.0 | |
| 5 | 10 | 1 | 4 | 3 | 0.1 | |
| 6 | 15 | 20 | 8 | 0.3 | 0.5 | Surplus |
| 7 | 4 | 1 | 4 | 3 | 0.1 | Surplus |
| 8 | 10 | 10 | 8 | 0.3 | 0.5 | Surplus |
| 9 | 15 | 20 | 1 | 1 | 1.0 | Surplus |
1 be example to fill a prescription below, the concrete compound method of this needled felt surface processing agent is described, the compound method of other 8 prescriptions is all identical with prescription 1.
To prepare 100 kilograms of needled felt surface processing agents is example, and concrete process for preparation is as follows:
1) at first taking by weighing 0.3 kilogram of granularity is 50-100 nano level titanium oxide (TiO
2), slowly join in 20 kg of water, use magnetic stirrer (rotating speed is 1000-2000 rev/mins) to stir at normal temperatures 10-15 minutes, leave standstill, stand-by.
2) take by weighing 20 kilograms of A6 aqueous polyurethanes, adding 4 kilogram molecular weights successively is 2000000-4000000 ptfe emulsion, 8 kilogram of 285 silicone oil emulsion, at normal temperatures, stirred (rotating speed is 30-60 rev/mins) 5-10 minutes with paddle stirrer, the nanoscale titanium oxide emulsion that will prepare again (sees that step 1) slowly adds, stir while adding, the mixer rotating speed is 30-60 rev/mins.
3) with glacial acetic acid the pH value of 47.2 kilograms water is transferred to 3-4, the silane coupler KH570 that adds 0.5 kilogram again, at normal temperatures, stirred 10-20 minutes with paddle stirrer, after (rotating speed is 30-60 rev/mins) leaves standstill, it is slowly joined in the emulsion that step 2 makes, stir, promptly get required needled felt surface processing agent finished product.
Needled felt surface processing agent impregnation technology process is as follows:
1) the plain felt 2 of Nomex (grammes per square metre be 500 grams/square metre) unreels through let off roll 1
2) the plain felt through unreeling 2 is by dipping tank 3 dippings.The plain felt 2 of Nomex must immerse dipping tank 3 handles following 30 centimetres of liquid level, and guarantees that dip time was controlled at 0.2 minute.
3) behind the dipping, through pair roller 4 extruding, the diameter of last compression roller is 20 centimetres, and pressure is its deadweight (about 30 kilograms), and unnecessary moisture content is removed in extruding, and the control pick-up is 100%.
4) the plain felt 2 after extruding is sent into oven dry in the drying oven 5, and bake out temperature is controlled at 200 ℃;
5) after above step process, Nomex winder 6 rollings with drying get finished product.
The linear velocity of whole piece unit is 2 meters/minute.
Embodiment 10
In the present embodiment, " FEP emulsion " adopts polytetrafluoroethylene (PTFE) hexafluoroethylene copolymer emulsion, and (solid content 50%), this weight percentages is constant; " A6 " adopts commercially available polyacrylate (solid content 38%), and this weight percentages is constant; Adopt the titanium oxide (TiO among commercially available nano zine oxide (ZnO) the replacement embodiment 1
2), granularity is the 50-100 nanometer, this weight percentages is constant.Other composition and formulated technology and impregnation technology are with embodiment 1-9.
Claims (10)
1, a kind of needled felt surface processing agent, it comprises film forming agent, fabric finishing agent and coupling agent, its concrete prescription is counted by weight percentage, and is composed as follows:
1) the fluoropolymer emulsion 4-15%;
2) the macromolecule ester polymer 1-20%;
3) silicone oil emulsion 1-8%;
4) coupling agent 0.1-1%;
5) nano-scale oxide or sulfide 0.3-3%;
6) water surplus;
Above-mentioned fluoropolymer emulsion is one of following several emulsions: 1) ptfe emulsion 2) Kynoar emulsion 3) poly-tetrafluoro hexafluoro copolymer emulsion, molecular weight ranges is 1000000-7000000.
Above-mentioned nano-scale oxide or sulfide are selected from many silica, titanium oxide, alchlor, zinc oxide, zinc sulphide, calcium sulfide or vulcanized lead.
2, a kind of needled felt surface processing agent according to claim 1, the molecular weight ranges that it is characterized in that the fluoropolymer emulsion is 2000000-4000000.
3, a kind of needled felt surface processing agent according to claim 1 is characterized in that one of following several silicone oil emulsions of choosing: 1) methyl-silicone oil emulsion; 2) polymethylphenyl siloxane fluid emulsion; 3) hydroxy-silicone-oil emulsion; 4) containing hydrogen silicone oil emulsion.
4, a kind of needled felt surface processing agent according to claim 3 is characterized in that silicone oil emulsion selects the polyphenyl methyl-silicone oil for use.
5, a kind of needled felt surface processing agent according to claim 1, it is characterized in that selecting for use one of following two kinds of coupling agents: 1) silane coupler 2) titanate coupling agent.
6, a kind of needled felt surface processing agent according to claim 5 is characterized in that coupling agent is a silane coupler.
7, a kind of needled felt surface processing agent according to claim 1 is characterized in that nano-scale oxide or sulfide chooses titanium oxide.
8, a kind of needled felt surface processing agent according to claim 7, the granularity that it is characterized in that titanium oxide is 50～100 nanometers.
9, a kind of needled felt surface processing agent according to claim 1 is characterized in that, the macromolecule ester polymer is one of following three kinds of materials: 1) polyether polyols with reduced unsaturation 2) polyacrylate polymers 3) polyvinyl acetate polymer.
10, adopt the impregnation technology of any described needled felt surface processing agent of claim 1-9, comprise that dipping, pair roller extruding, drying oven oven dry, rolling get finished product in the unreeling of the plain felt of Nomex, the dipping tank, it is characterized in that: technological process and condition are carried out in the following manner:
1) the plain felt of Nomex unreels through let off roll;
2) the plain felt through unreeling, by dipping tank, the plain felt of Nomex must immerse handles following 30 centimetres of liquid level, guarantees that plain felt dip time was at 0.1-0.2 minute;
3) behind the dipping, through the pair roller extruding, the diameter of last compression roller is 20 centimetres, and pressure is its deadweight;
4) the wet felt after extruding is sent into the drying oven oven dry again, and bake out temperature is 120 ℃ one 220 ℃;
5) after above step process,, get finished product with the winder rolling of the Nomex of drying;
Whole piece unit linear velocity is 0.5-3 meters/minutes.
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|---|---|---|---|
| CNB2005100379502A CN100500983C (en) | 2005-03-03 | 2005-03-03 | Needled felt surface processing agent and impregnation technology thereof |
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|---|---|---|---|
| CNB2005100379502A CN100500983C (en) | 2005-03-03 | 2005-03-03 | Needled felt surface processing agent and impregnation technology thereof |
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| CN100500983C true CN100500983C (en) | 2009-06-17 |
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| CN102031693B (en) * | 2010-11-15 | 2012-07-25 | 山东新力环保材料有限公司 | Film forming agent used for after finishing of medium low temperature composite needled filter felt and preparation method thereof |
| CN102101943A (en) * | 2010-12-09 | 2011-06-22 | 南京际华三五二一特种装备有限公司 | Aqueous adhesive emulsion for high-temperature-resistant and corrosion-resistant filtering material and preparation method thereof |
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| CN110644249A (en) * | 2019-08-26 | 2020-01-03 | 安徽华烨特种材料有限公司 | Dustproof and antibacterial canvas and preparation method thereof |
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| CN114990789B (en) * | 2022-04-20 | 2023-08-01 | 巩义市泛锐熠辉复合材料有限公司 | Device and method for continuously preparing silica gel felt |
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