CN100493930C - Biological cleaning and repairing method for paper cultural relics - Google Patents
Biological cleaning and repairing method for paper cultural relics Download PDFInfo
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- CN100493930C CN100493930C CNB2004100610935A CN200410061093A CN100493930C CN 100493930 C CN100493930 C CN 100493930C CN B2004100610935 A CNB2004100610935 A CN B2004100610935A CN 200410061093 A CN200410061093 A CN 200410061093A CN 100493930 C CN100493930 C CN 100493930C
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- historical relic
- cleaning fluid
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Abstract
The present invention relates to biological cleaning and repairing method for paper cultural relics and paper cultural relics is cleaned and reinforced through biotechnical process. Biological surfactant and re-compounded enzyme of proteinase, lipase, amylase, deformed streptococcus and armillaria are used in cleaning, repairing and reinforcing paper cultural relics. They are used in eliminating harmful crystals, plaque, and oil stain, and armillaria metabolite is utilized in improving acidifying, crisp and cracking state of paper cultural relics. The present invention can raise the quality of paper cultural relics.
Description
Affiliated technical field:
The present invention relates to a kind of reparation of papery historical relic, particularly a kind of biology that adopts biotechnology that the papery historical relic is cleared up, reinforced cleans repairing method.The cleaning and the reparation field that belong to historical relic.
Background technology:
The papery historical relic has directly been put down in writing human important information on production, life and the history of social development thereof for a long time, is research China history, culture and arts and the extremely important precious historical of scientific technological advance history, and it is non-renewable historical resource.The papery historical relic is generally organic material, as time goes by, the pollution of harmful substance and oxidation etc. in human use, the nature air, the physical property of capital degraded paper, make aging, the deterioration of paper, they are had experienced various vicissitudes of life mostly in addition, and therefore in various degree jaundice, embrittlement, mouldy, fracture phenomena are all arranged.After the paper invention, people just in the guard method of constantly exploring it, go through as the cork tree of the Wei Jin Northern Dynasties and dye paper method, female xanthochromia paper method, fragrance repellent method etc. by history; The anti-moth-eaten method of paper of dying of " the dying paper " in Song Yuan period with green pepper; The anti-moth-eaten paper method of the red lead of period of Ming and Qing, medicine repellent method, airing method and Chinese honey locust protection against rodents and breeze, lime, pot rust are made into the anti-ant method of tabia in addition.Now, for this non-renewable historical resource being repaired and protecting, the historical relic's protection worker has also worked out a lot of methods to the protection of papery historical relic, concludes the processing method of getting up to be mainly chemistry and physics.Rather query, these methods have played positive effect to protection papery historical relic, but also exist the drawback that can't overcome simultaneously, as have material aging, chemical substance is residual and difficult point such as color and luster variation.Though above-mentioned restorative procedure exists defective, the antiquary suffers from does not have better reparation way, can only continue to use these methods that have defective yet the papery historical relic is repaired.
Summary of the invention:
The objective of the invention is to: a kind of biochemical reaction that utilizes in the biological metabolic processes is provided, clean antiquated paper spot with biology and derivative thereof as material, fill the material of paper internal losses, the fiber of bonding fracture, recover the physical property of antiquated paper, clean biology cleaning repairing method with repairing and reinforcement papery historical relic.
The present invention realizes above-mentioned purpose by following technical solution:
The specific operation process that the biology of this papery historical relic cleans repairing method is as follows:
(1) preparation of cleaning repair materials:
1. the preparation of biological cleaning fluid: biosurfactant 14%, proteinase-10 .2%, lipase 0.1%, amylase 0.1%, white sulfur bacteria 3%, zoogloea 5%, deionized water surplus evenly mixed.
2. the preparation of repair materials: close ring bacterium 20% (every milliliter is not less than 50,000), starch 65%, glucose 8%, wood pulp 6%, B family vitamin surplus evenly mixed.
(2) clean the reparation step:
1. the papery historical relic that desire is handled lies on the tyre cushion, and tyre cushion is fixed on the wet frame of filter with the silk support is flat;
2. with biological cleaning fluid the papery historical relic is soaked into, covers silk screen, put into cleaning machine or rinse bath after, add deionized water along wall historical relic flooded;
3. add the biological cleaning fluid of the water yield 15% in cleaning machine or the rinse bath after 2 days, water is at the uniform velocity slowly stirred with air pump;
4. after the no spot of range estimation, the biological cleaning fluid in the drain tank is removed residual biological cleaning fluid with deionized water;
When no obvious water droplet falls down on the historical relic 5. to be cleaned, repair materials is evenly spilt, checked effect after 4 hours, should fill immediately if any omitting;
6. kept 5 days under 70-90% damp condition, waiting to occur white filiform is that available glass plate is added a cover;
7. see after 7-10 days when filiform becomes the tabular material that is similar to paper, take down glass plate and change silk screen;
8. keep 70-90% humidity, treat that fiber is aging after, heat to 50 ℃ of dryings and carry out shaping.
The present invention compared with prior art has following beneficial effect:
Because being the spot of utilizing biosurfactant, protease, lipase, amylase, white sulfur bacteria, zoogleic acting in conjunction to carry out paper, operation principle of the present invention cleans, utilize close ring bacterium and derivative thereof to penetrate into and carry out repairing and reinforcement in the paper fiber, recover the physical property of antiquated paper, therefore, it has following advantage:
1. follow the principle that law of cultural relics " does not change the historical relic original state ", adopt brand-new biological method that the papery historical relic is protected processing, technology path is reasonable.
2. good reversibility, papery historical relic after treatment can also be handled later again.
3. the simple science of method is effective, pollution-free.
The specific embodiment:
(1) preparation of cleaning repair materials
1. the preparation of biological cleaning fluid: biosurfactant 14%, proteinase-10 .2%, lipase 0.1%, amylase 0.1%, white sulfur bacteria 3%, zoogloea 5%, deionized water surplus evenly mixed.
The function of above-mentioned each raw material is: white sulfur bacteria can be decomposed sulfur-containing compound; The sulphur sphaerobacteria is a kind of common trichobacteria, causes when breeding in a large number that sulfur-containing compound expands, and makes the loose separation of bonding ply of paper and reaches the purpose of opening.Zoogloea is the fine particle that the colloid material of bacterium and secretion thereof is formed, and is the main body of biological cleaning fluid, and zoogloea has performances such as absorption property, oxidative decomposition capacity and flocking settling.
2. the preparation of repair materials: close ring bacterium 20% (every milliliter is not less than 50,000), starch 65%, glucose 8%, wood pulp 6%, B family vitamin surplus evenly mixed.
(2) clean the reparation step
1. the papery historical relic that desire is handled lies on the tyre cushion, and tyre cushion is fixed on the wet frame of filter with the silk support is flat.
2. with biological cleaning fluid the papery historical relic is soaked into, covers silk screen, put into cleaning machine or rinse bath after, add deionized water along wall historical relic flooded.
3. add after 2 days that the biological cleaning fluid of the water yield 15% at the uniform velocity slowly stirs water with air pump in cleaning machine or the rinse bath, make biology dirt, condensation product of oxidation Decomposition and absorption from antiquated paper dissolve in fast and fall to the biological cleaning fluid.
4. after the no spot of range estimation, the biological cleaning fluid in the drain tank is removed residual cleaning fluid with deionized water.
When no obvious water droplet falls down on the historical relic 5. to be cleaned, just repair materials evenly can be spilt.Check effect after 4 hours, should fill immediately if any omitting.
6. kept 5 days under 70-90% damp condition, close ring bacterium and derivative thereof progressively penetrate into the paper fibrous inside, fill the material of loss, and the fiber of bonding fracture is connected into one with the paper fiber, and waiting to occur white filiform is that available glass plate is added a cover.
7. see after 7-10 days that filiform becomes the tabular material approximate with paper, at this moment, takes down glass plate and changes silk screen.
8. keep 70-90% humidity, treat that fiber is aging after, heat to 50 ℃ of dryings and carry out shaping.
Claims (2)
1. the biology of a papery historical relic cleans repairing method, it is characterized in that: (1) cleans the preparation of repair materials:
1. the preparation of biological cleaning fluid: biosurfactant 14%, proteinase-10 .2%, lipase 0.1%, amylase 0.1%, white sulfur bacteria 3%, zoogloea 5%, deionized water surplus evenly mixed;
2. the preparation of repair materials: close ring bacterium 20%, starch 65%, glucose 8%, wood pulp 6%, B family vitamin surplus evenly mixed;
(2) clean the reparation step:
1. the papery historical relic that desire is handled lies on the tyre cushion, and tyre cushion is fixed on the wet frame of filter with the silk support is flat;
2. with biological cleaning fluid the papery historical relic is soaked into, covers silk screen, put into cleaning machine or rinse bath after, add deionized water along wall historical relic flooded;
3. add the biological cleaning fluid of the water yield 15% in cleaning machine or the rinse bath after 2 days, water is at the uniform velocity slowly stirred with air pump;
4. after the no spot of range estimation, biological cleaning fluid in the drain tank is removed residual cleaning fluid with deionized water;
When no obvious water droplet falls down on the historical relic 5. to be cleaned, repair materials is evenly spilt, checked effect after 4 hours, should fill immediately if any omitting;
6. kept 5 days under 70-90% damp condition, waiting to occur white filiform is that available glass plate is added a cover;
7. see after 7-10 days when filiform becomes the tabular material that is similar to paper, take down glass plate and change silk screen;
8. keep 70-90% humidity, treat that fiber is aging after, heat to 50 ℃ of dryings and carry out shaping.
2. the biology of papery historical relic according to claim 1 cleans repairing method, and it is characterized in that: described close ring bacterium is not less than 50,000 for every milliliter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100610935A CN100493930C (en) | 2004-11-09 | 2004-11-09 | Biological cleaning and repairing method for paper cultural relics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100610935A CN100493930C (en) | 2004-11-09 | 2004-11-09 | Biological cleaning and repairing method for paper cultural relics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1683171A CN1683171A (en) | 2005-10-19 |
| CN100493930C true CN100493930C (en) | 2009-06-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100610935A Expired - Fee Related CN100493930C (en) | 2004-11-09 | 2004-11-09 | Biological cleaning and repairing method for paper cultural relics |
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| Country | Link |
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| CN (1) | CN100493930C (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481870B (en) * | 2009-01-20 | 2011-10-26 | 荆州文物保护中心 | Method for cleaning ancient low-intensity silk fabric cultural relics |
| CN101857880B (en) * | 2010-05-20 | 2012-05-23 | 首都博物馆 | Cleaning method for removing crystal salt cakings by biological cleaner |
| CN105755900B (en) * | 2016-03-07 | 2017-09-12 | 辽宁大学 | Paper relics mildew cleaning method |
| CN105695113B (en) * | 2016-03-07 | 2019-01-01 | 辽宁大学 | Paper relics mildew bio-enzyme cleaning agent and application thereof |
| CN106274260A (en) * | 2016-08-20 | 2017-01-04 | 陕西师范大学 | Antiquated calligraphy and painting draws that the heart is lossless tears off method |
| CN111849340A (en) * | 2020-07-17 | 2020-10-30 | 金陵科技学院 | Unearthed silk paper cultural relic treatment protective solution and treatment method thereof |
| CN114074096B (en) * | 2020-08-14 | 2023-08-08 | 王振牛 | Flexible sucking method for uniform gas-phase pollution on surface of wall painting of temple-like cultural relics |
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2004
- 2004-11-09 CN CNB2004100610935A patent/CN100493930C/en not_active Expired - Fee Related
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| Publication number | Publication date |
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| CN1683171A (en) | 2005-10-19 |
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