CN100444912C - High water absorption resin water suction gel fire extinguisher and its application - Google Patents

High water absorption resin water suction gel fire extinguisher and its application Download PDF

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Publication number
CN100444912C
CN100444912C CNB2004100159090A CN200410015909A CN100444912C CN 100444912 C CN100444912 C CN 100444912C CN B2004100159090 A CNB2004100159090 A CN B2004100159090A CN 200410015909 A CN200410015909 A CN 200410015909A CN 100444912 C CN100444912 C CN 100444912C
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China
Prior art keywords
water
water absorption
fire
resin
gelatin
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Expired - Fee Related
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CNB2004100159090A
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CN1557516A (en
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孙维林
朱吕通
孙启杭
池临封
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Zhejiang University ZJU
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Zhejiang University ZJU
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Abstract

The present invention relates to a water absorption gelatin extinguishing agent and an application thereof. The water absorption gelatin extinguishing agent mainly improves the performance of water retention and fire extinguishing and saves water. The present invention is characterized in that high-water absorption resin of a synthetic resin series, a starch series and a fiber series is used as a kernel component and is mixed with the water to form an extinguishing agent. The application of the water absorption gelatin extinguishing agent can combine the fire extinguishing of the traditional water gun. The present invention has the method that the high-water absorption resin is mixed with the water for half an hour to generate water absorption gelatin, and the water gun sprays towards the ignition position; the high-water absorption resin fine powder is mixed with a large amount of water, the water gun sprays towards the ignition position, and the water absorption gelatin is generated within 15 to 60 seconds to carry out fire extinguishing; the high-water absorption resin is mixed with 0.5 to 5% of organic solvent to form pulp and is sprayed towards the ignition position with the water of the water gun; 100-mesh fine powder of the high-water absorption is spread over the surface of the position of possible ignition, the water is sprayed on the resin to reach the purpose of the fire prevention and the fire extinguishing of gelatinization. By using the water absorption gelatin extinguishing agent, water absorption gelatin of the ignition position forms a film on the surface of an object to isolate air, a large amount of heat is consumed by the water to reduce an ignition point, and the water absorption gelatin extinguishing agent has the superpower performance of fire prevention and fire extinguishing.

Description

The application of super absorbent resin water absorbent gel extinguishing chemical
Technical field
The invention belongs to the fire prevention field, relate to a kind of fire-extinguishing agent and application thereof,
Background technology
Fire is a current social calamity, and the whole nation almost all has fire to take place every day, often causes the massive losses of lives and properties.How to stamp out a fire rapidly, save life as far as possible, reduce economic loss, become the thing that the common people and government pay special attention to.Current fire extinguishing adopts hydraulic giant to carry out the fire extinguishing of high-voltage high-speed injection water particularly to the fire extinguishing in the large-scale scene of a fire usually.But since intensity of a fire ferociousness, extreme temperatures, water can be evaporated immediately to fire position, and water holding capacity is poor, is difficult to efficiently finish the important task that stamps out a fire.
Summary of the invention
The object of the invention provides a kind of fire-extinguishing agent, uses its fire extinguishing, and the water conservation extinguishing property is good, plays water saving effect simultaneously.
For achieving the above object, total inventive concept is to utilize the core component of super absorbent resin as this extinguishing chemical, and it is mixed with water, can generate the water absorbent gel extinguishing chemical, it is being ejected on the scene of a fire with hydraulic giant is putting out a fire.Key problem in technology is to locate super absorbent resin.Under this inventive concept,, there are three types of super absorbent resin series available through prolonged and repeated experimental study.The one, synthetic resin is super absorbent resin, can take acrylates resinoid or polyvinyl alcohol resin, and its water absorbing capacity is 300~2000g water/g resin; The 2nd, starch is super absorbent resin, can take starch grafted acrylate resin or starch graft acrylamide resin or starch-grafted vinyl cyanide resin, and water absorbing capacity is 200~2000g water/g resin; The 3rd, Super Absorbent Resin from Cellulose can be taken cellulose graft acrylic acid and resin thereof, and its water absorbing capacity is 200~2000g water/g resin.
According to the super absorbent resin water absorbent gel extinguishing chemical that foregoing invention design obtains, mainly be to be used for effective fire extinguishing to the scene of a fire, its application mode has following several:
1, a kind of water with 200~2000 times in the above-mentioned super absorbent resin is mixed, in half an hour, generates water absorbent gel, again with hydraulic giant with it to the place's ejecting extinguishing that catches fire;
2, super absorbent resin 100 purpose fine powders are mixed with its water of 1000 times, spray to fire position with hydraulic giant together, in 15~60 second time, generated the water absorbent gel fire extinguishing;
3, super absorbent resin is mixed into slurry with organic solvents such as 0.5~5% propane diols of its amount or ethanol and sprays to scene of a fire fire extinguishing from arm and water the hydraulic giant;
4,100 order fine powders with super absorbent resin are dispersed in the surface, position that may be caught fire, and on the resin of water spray above being attached to, make its gelation fire extinguishing then.
Substantive distinguishing features that the present invention gives prominence to and obvious improvement:
1, water retention property is strong, and particularly water retention property is good in hot water, and they are arrived fire position by using method, at first can be adsorbed on the body surface film forming, and secluding air simultaneously, makes the big calorimetric of water consumption, reduces ignition point, has good extinguishing property;
2, water-absorbing resin is the macromolecule powder, in aspect safety such as storage, transportations, stores (airtight anti-suction) stability and reaches more than 2 years avirulence;
3, the content of water-absorbing resin in whole water absorbent gel generally be water weight 0.05~0.5% between.Generally about 0.1%, flameproof effect is splendid, has water saving effect, and water absorbent gel is preserved to stablize and reached 6 months more than;
4, water absorbing agent is at Qiang Huozhong, and complete if water is dried, the low amounts of resin burning becomes carbon dioxide and water, plays the fire extinguishing effect equally, and is nontoxic to people, animal simultaneously.After fire put out, the residual water absorbing agent in the scene of a fire was nontoxic to people, animal.And the site clearing non-environmental-pollution really embodies environmental protection;
5, water absorbent gel is faintly acid, alkalescent or neutrality, does not corrode fire-fighting equipment, and existing fire equipment is transformed and can be used without transforming or doing slightly;
6, its effect is necessarily better in grassland and forest fire protection, and particularly after the fire extinguishing, residual super absorbent resin is stayed in the surface soil; swelling rapidly can drink up the rain; play water conservation and protection skin-grafting growth early effect, produce the effect of " Not even a prairie fire can destroy the grass, it grows again when the spring breeze blows ".In addition, these resins are because the molecular weight and the degree of cross linking are little, or natural polymer, generally at half a year to 1 year biodegradation and decomposition, environmentally safe.
The specific embodiment
The examples of implementation of technical solution of the present invention are as follows:
Embodiment 1: the generation and the use of the polyacrylic acid of invention (sodium) super absorbent resin water absorbent gel:
1, synthetic to be resin polyacrylic acid (sodium) mix (it is interior to add the fire fighting truck water tank) with 1000 times water, generates water absorbent gel in half an hour.This gel can spray in the fire with hydraulic giant, and gel is attracted to the surface that catches fire, and plays the fire extinguishing effect.
2, with polyacrylic acid (sodium) fine powder (about 100 orders) and 1000 times of water ratios, spray to fire position from spray gun together.In 15 seconds~60 second time, generate gel and play the fire extinguishing effect.
3, at the scene of catching fire (particularly grassland and forest) scatters polyacrylic acid (sodium) fine powder (about 100 orders) super absorbent resin respectively, sprays water then to resin, makes its gelation fire prevention and fire extinguishing.
4, will synthesize is the mixed with propylene glycol form slurry of polyacrylic acid (sodium) resin and 5%, draws an arm and spray to fire position with water from spray gun in spray gun, plays the fire extinguishing effect.
Embodiment 2: the generation and the use of the starch graft acrylic acid of invention (sodium) super absorbent resin water absorbent gel:
1, starch graft acrylic acid (sodium) mixes with 1000 times water, generates water absorbent gel in half an hour.This gel can spray in the fire with spray gun, and gel is attracted to the surface that catches fire, and plays the fire extinguishing effect.
2, with starch graft acrylic acid (sodium) fine powder (about 100 orders) and 1000 times of water ratios, spray to fire position from spray gun together.In 15 seconds~60 second time, generate gel and play the fire extinguishing effect.
3, at the scene of catching fire (particularly grassland and forest) scatters starch graft acrylic acid (sodium) fine powder (about 100 orders) super absorbent resin respectively, sprays water then to resin, makes its gelation fire prevention and fire extinguishing.
4, with the mixed with propylene glycol form slurry of starch graft acrylic acid (sodium) resin and 5%, in spray gun, draw an arm and from spray gun, spray to fire position with water, play the fire extinguishing effect.
Embodiment 3: the generation and the use of the carboxymethyl cellulose of invention (CMC) graft acrylic acid (sodium) super absorbent resin water absorbent gel:
Carboxymethyl cellulose (CMC) graft acrylic acid (sodium) mixed with 400 times water, generated water absorbent gel at 1 hour.This gel can spray in the fire with spray gun, and gel is attracted to the surface that catches fire, and plays the fire extinguishing effect.
At the scene of catching fire (particularly grassland and forest), scatter carboxymethyl cellulose (CMC) graft acrylic acid (sodium) fine powder (about 100 orders) super absorbent resin respectively, spray water then to resin, make its gelation fire prevention and fire extinguishing.
With the mixed with propylene glycol form slurry of carboxymethyl cellulose (CMC) graft acrylic acid (sodium) resin and 5%, in spray gun, draw an arm and from spray gun, spray to fire position with water, play the fire extinguishing effect.

Claims (1)

1, the application of super absorbent resin water absorbent gel extinguishing chemical, its characterization step is to be super absorbent resin with synthetic resin, promptly take the acrylates resinoid or polyvinyl alcohol resin 100 purpose fine powders mix with the ratio of 1000 times of water, spray to fire position from spray gun together, generate water absorbent gel in 15-60 time second and put out a fire.
CNB2004100159090A 2004-01-14 2004-01-14 High water absorption resin water suction gel fire extinguisher and its application Expired - Fee Related CN100444912C (en)

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CN100444912C true CN100444912C (en) 2008-12-24

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CN101560300A (en) * 2008-04-18 2009-10-21 张金柱 High water absorbent resin gel for blocking heat source and laminated structure utilizing same
CN101874917B (en) * 2009-04-30 2013-03-20 林健国 Fire-extinguishing mixture
CN102039020A (en) * 2010-11-17 2011-05-04 刘采联 Macromolecular bound water fire extinguishing agent
US9406917B2 (en) 2011-07-07 2016-08-02 Federal Express Corporation Battery cooling method and system
CN102849364B (en) * 2012-08-28 2015-04-29 奇瑞汽车股份有限公司 Safety protection device and method for lithium ion battery
CN103263746A (en) * 2013-06-06 2013-08-28 东靖飞 Novel fire extinguishing agent prepared from surface grafting starch
CN103550900A (en) * 2013-11-19 2014-02-05 宜兴丹森科技有限公司 Super absorbent flame retardant fire extinguishing agent for inflammables
CN103550899A (en) * 2013-11-19 2014-02-05 宜兴丹森科技有限公司 Super absorbent flame retardant fire extinguishing agent for storage
CN104072667A (en) * 2014-06-16 2014-10-01 山东科技大学 Synthesis method of forest fire extinguishing agent based on multi-component super absorbent nanometer material
CN105566580B (en) * 2014-09-15 2018-04-06 邹城市安德机械制修有限公司 A kind of preparation method of hydroscopic high-molecular resin extinguishing chemical
CN105176146A (en) * 2015-09-09 2015-12-23 天长市银狐漆业有限公司 High-adhesive-force environment-friendly diatom ooze coating material
CN106178375A (en) * 2016-04-06 2016-12-07 北京东霖消防科技有限公司 High-molecular gel extinguishing chemical
CN106111027B (en) * 2016-06-21 2019-03-19 山东创能机械科技有限公司 Naval vessel water cannon seawater additive and charging system
CN106075791A (en) * 2016-07-20 2016-11-09 周荣 A kind of preparation method of polymolecularity aerosol extinguishing agent
CN106621157A (en) * 2016-09-27 2017-05-10 刘辉 Fire extinguishing agent and preparing method thereof
CN107497088A (en) * 2017-09-22 2017-12-22 润泰救援装备科技河北有限公司 Hydrogel extinguishing chemical and its application method
CN108686321A (en) * 2018-05-25 2018-10-23 廊坊其利科技股份有限公司 Fire smothering blanket, and preparation method thereof and material
CN108926796A (en) * 2018-08-03 2018-12-04 常州大学 A kind of macromolecule temperature lowering water gel extinguishant and preparation method thereof
CN108992830A (en) * 2018-09-06 2018-12-14 牛俊峰 A kind of high-adhesiveness hydrogel extinguishing chemical and preparation method thereof
CN109651625A (en) * 2018-12-17 2019-04-19 北京理工大学 A kind of preparation method of high strength acrylic amide-carboxymethyl cellulose dual network constitution water gel smother pad
CN110437356B (en) * 2019-08-16 2020-09-25 中国科学院长春应用化学研究所 Super absorbent resin, preparation method and application thereof
CN110947128A (en) * 2019-12-25 2020-04-03 湖北及安盾消防科技有限公司 Hydrogel fire extinguishing agent preparation device
CN113134189A (en) * 2020-01-19 2021-07-20 山东昊星洁士新材料科技有限公司 Jet mixing fire-fighting device
CN113856127A (en) * 2021-10-11 2021-12-31 捷润科技(广州)有限公司 Fire extinguishing agent special for forest fire
CN114230837A (en) * 2021-12-28 2022-03-25 贵州国塑科技管业有限责任公司 Preparation method of FRPE buried sewage pipe

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