CN100441661C - Nanometer fire-retardant material for refrigerator - Google Patents
Nanometer fire-retardant material for refrigerator Download PDFInfo
- Publication number
- CN100441661C CN100441661C CNB2005100391951A CN200510039195A CN100441661C CN 100441661 C CN100441661 C CN 100441661C CN B2005100391951 A CNB2005100391951 A CN B2005100391951A CN 200510039195 A CN200510039195 A CN 200510039195A CN 100441661 C CN100441661 C CN 100441661C
- Authority
- CN
- China
- Prior art keywords
- fire
- nanometer
- present
- refrigerator
- retardant material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 title claims abstract description 14
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004709 Chlorinated polyethylene Substances 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 4
- 239000004014 plasticizer Substances 0.000 claims abstract description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract 3
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 7
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 101100277038 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) dbp-5 gene Proteins 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 4
- 235000012239 silicon dioxide Nutrition 0.000 abstract 2
- 239000000377 silicon dioxide Substances 0.000 abstract 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- 229910018404 Al2 O3 Inorganic materials 0.000 abstract 1
- HTPHKKKMEABKJE-UHFFFAOYSA-N calcium;octadecanoic acid Chemical compound [Ca].CCCCCCCCCCCCCCCCCC(O)=O HTPHKKKMEABKJE-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000010881 fly ash Substances 0.000 description 2
- JTYRXXKXOULVAP-UHFFFAOYSA-N 1,2-dibromo-3-phenoxybenzene Chemical compound BrC1=CC=CC(OC=2C=CC=CC=2)=C1Br JTYRXXKXOULVAP-UHFFFAOYSA-N 0.000 description 1
- KTADSLDAUJLZGL-UHFFFAOYSA-N 1-bromo-2-phenylbenzene Chemical group BrC1=CC=CC=C1C1=CC=CC=C1 KTADSLDAUJLZGL-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
Abstract
The present invention relates to a nanometer fire-retardant material applied to refrigerators, which is characterized in that raw materials comprise acrylonitrile, butadiene, a styrene terpolymer-an ABS powder material, polyvinyl chloride PVC, chlorinated polyethylene CPE, nanometer silicon dioxide SiO2, nanometer aluminium oxide Al2 O3, calcium stearic acid and a plasticizer DBP. The present invention has the advantages of extensive source of material, low cost, fine performance of fire retardance and high safety.
Description
Technical field:
The present invention relates to fire retardant material, more specifically saying so is applied in fire retardant material in the refrigerator.
Background technology:
Fire-retardant that is applied in the refrigerator should have safety in utilization, but materials such as fire-retardant flame-proof ABS that upward uses of present refrigerator, flame-retarding HIPS, fire-retardant PP, fire retardation PC, though cost is not high, flame retardant effect is good, but the fire retardant that it adopted is poly-bromo biphenyl PBB and poly-dibromodiphenyl ether PBDE, because the hazardous property of this based flame retardant progressively is being familiar with, therefore, the use for this based flame retardant must obtain restriction.
Summary of the invention:
The present invention is for avoiding above-mentioned existing in prior technology weak point, and a kind of nano flame retardant material that is applied in the refrigerator safe in utilization is provided.
Material of the present invention raw material by weight consists of:
Propylene is fine, divinyl, styrene copolymer (ABS) powder 90,
Polyvinyl chloride (PVC) 50,
Chlorinatedpolyethylene (CPE) 8,
Nano silicon (SiO
2) 6,
Nano-aluminium oxide (Al
2O
3) 10,
Calcium stearate 3,
Plasticizer DBP 5.
Material of the present invention is with nanometer SiO
2And Al
2O
3Be major ingredient, SiO
2And Al
2O
3Can from flyash, extract, with nanometer SiO
2And Al
2O
3With mixed with resin together, not only can improve the heat-resisting decomposability of resin, when on fire, also can impel resin carbonation.Experiment showed, and in resin, add about 10% nanometer SiO
2And Al
2O
3Just can reach fire retardant material standard UL specification (V-0/1.5mm) requirement of the U.S..
Compared with the prior art, beneficial effect of the present invention is embodied in:
1, material source of the present invention is extensive, can use the byproduct flyash of heat power station to be raw material production nanometer SiO
2And Al
2O
3, with low cost.
2, flame retardant properties of the present invention is good, and is safe in utilization.
Embodiment:
Present embodiment raw material by weight constitutes:
Propylene is fine, divinyl, styrene copolymer (ABS) powder 90,
Polyvinyl chloride (PVC) 50,
Chlorinatedpolyethylene (CPE) 8,
Nano silicon (SiO
2) 6,
Nano-aluminium oxide (Al
2O
3) 10,
Calcium stearate 3,
DBP softening agent 5.
Carry out granulation with above-mentioned raw materials according to the method for routine.
Claims (1)
1, be applied in nano flame retardant material in the refrigerator, it is characterized in that raw material by weight consists of:
Propylene is fine, divinyl, styrene copolymer ABS powder 90,
Polyvinylchloride 50,
Chlorinatedpolyethylene CPE 8,
Nano silicon SiO
26,
Nano-aluminium oxide Al
2O
310,
Calcium stearate 3,
Plasticizer DBP 5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100391951A CN100441661C (en) | 2005-04-27 | 2005-04-27 | Nanometer fire-retardant material for refrigerator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100391951A CN100441661C (en) | 2005-04-27 | 2005-04-27 | Nanometer fire-retardant material for refrigerator |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1854248A CN1854248A (en) | 2006-11-01 |
| CN100441661C true CN100441661C (en) | 2008-12-10 |
Family
ID=37194702
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100391951A Active CN100441661C (en) | 2005-04-27 | 2005-04-27 | Nanometer fire-retardant material for refrigerator |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100441661C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102219980A (en) * | 2011-05-31 | 2011-10-19 | 王剑伟 | Formula of ABS (acrylonitrile butadiene styrene) extinction board and manufacturing process of ABS extinction board |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6230035A (en) * | 1985-05-24 | 1987-02-09 | 高性能樹脂新製造技術研究組合 | Laminate and manufacture thereof |
| CN1107487A (en) * | 1994-10-31 | 1995-08-30 | 南开大学 | Sanitary and flame-retardant ABS/PVC injection moulding alloy |
| CN1358791A (en) * | 2000-12-12 | 2002-07-17 | 海尔科化工程塑料国家工程研究中心有限公司 | Polymer organic nano composite ocmposition for making agriculture greenhouse film and preparation process thereof |
| JP2008144954A (en) * | 2006-12-06 | 2008-06-26 | Norikazu Sato | Cam device |
-
2005
- 2005-04-27 CN CNB2005100391951A patent/CN100441661C/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6230035A (en) * | 1985-05-24 | 1987-02-09 | 高性能樹脂新製造技術研究組合 | Laminate and manufacture thereof |
| CN1107487A (en) * | 1994-10-31 | 1995-08-30 | 南开大学 | Sanitary and flame-retardant ABS/PVC injection moulding alloy |
| CN1358791A (en) * | 2000-12-12 | 2002-07-17 | 海尔科化工程塑料国家工程研究中心有限公司 | Polymer organic nano composite ocmposition for making agriculture greenhouse film and preparation process thereof |
| JP2008144954A (en) * | 2006-12-06 | 2008-06-26 | Norikazu Sato | Cam device |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1854248A (en) | 2006-11-01 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address |
Address after: 230601 No. 2163 Lianhua Road, Hefei economic and Technological Development Zone, Anhui Patentee after: Changhong MeiLing Limited by Share Ltd Address before: 230001 No. 48 Wuhu Road, Hefei City, Anhui Province Patentee before: Hefei Meiling Co., Ltd. |
|
| CP03 | Change of name, title or address |