CN100429096C - Base fabric for air-bag - Google Patents

Base fabric for air-bag Download PDF

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Publication number
CN100429096C
CN100429096C CNB031434991A CN03143499A CN100429096C CN 100429096 C CN100429096 C CN 100429096C CN B031434991 A CNB031434991 A CN B031434991A CN 03143499 A CN03143499 A CN 03143499A CN 100429096 C CN100429096 C CN 100429096C
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China
Prior art keywords
gas bag
fabric
section
foundation fabric
processing
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CNB031434991A
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CN1603174A (en
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加纳宪一郎
浅井治夫
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Toyobo Co Ltd
Toyo Textile Co Ltd
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Toyo Textile Co Ltd
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Priority to CNB031434991A priority Critical patent/CN100429096C/en
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Publication of CN1603174A publication Critical patent/CN1603174A/en
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Abstract

The present invention relates to base fabrics for gas bags, particularly to base fabrics made by weaving synthetic fiber filaments through shrinking and processing. The present invention is characterized in that synthetic fiber filaments for forming the base fabrics for gas bags contain special-shaped cross section filaments, the monofilament cross section flatness of the special-shaped cross section filaments is from 1.5 to 5.0, and the boiling water shrinkage of synthetic fibers before shrinking and processing is from 6 to 15%. The base fabrics for gas bags with the advantages of light weight, low air permeability and outstanding economical efficiency can be provided according to the present invention.

Description

Foundation fabric for gas bag
Technical field
The present invention relates to a kind of lightweight, have the also excellent airbag (airbag) of low aeration and economy and use base fabric.
Background technology
In recent years; as one of automotive safety spare part; on most of automobile airbag is housed all; when automobile generation collision accident, after the sensor senses impact, produce high temperature and high pressure gas from force lift; and launch airbag hastily by this gas; when thereby the health of driver or co-driver flies out to the direction of colliding, can prevent that head from bumping against control wheel, Windshield, automobile door glass etc., therefore can utilize this airbag to protect.
What used on airbag is to be coated with elastomeric application base fabrics such as chloroprene, chlorosulfonylation alkene, polysiloxane in the past, and its reason is resistance to effect of heat, the air property cut off (low venting quality) and the flame resistance height of these materials.
Yet in these coating materials, its weight of base fabric that is coated with chloroprene or chlorosulfonylation alkene increases to some extent, and flexibility can not meet the demands, and cost is also higher, therefore if use as foundation fabric for gas bag, will have a lot of problems.In addition, though the polysiloxane application base fabric that still uses in part has improved above-mentioned shortcoming to a great extent so far, still can not meet the demands.
Therefore, adopted the airbag that is not coated with that is not coated with foundation fabric for gas bag of not implementing application just becoming main flow recently, and proposed following scheme for lightweight, the good property deposited and low venting quality.
For example, (1) is put down in writing as speciallyying permit No. 2538934 communique, the raw yarn above with 8.5g/d, that 3dpf is following, the method for the base fabric of the acquisition property deposited excellence; (2) open flat 1-122752 communique as the spy and put down in writing, weave after the high-density fabric,, obtain the method for lightweight, low venting quality base fabric by implementing to shrink processing or calendering processing; (3) open flat 4-2835 communique as the spy and put down in writing,, obtain lightweight and under the 124Pa differential pressure, have 0.5cc/cm by carrying out two sides calendering processing 2The method of the base fabric of/second following low venting quality; (4) open flat 6-41844 communique as the spy and put down in writing, handle, make the strand swelling that constitutes cloth and obtain the method for low venting quality base fabric by implement chemical shrinkage to fabric; (5) open flat 8-325888 communique as the spy and put down in writing, mix monofilament fineness and be the thermoplastic synthetic fiber's of the thermoplastic synthetic fiber of 1.5d~7.0d and 0.2d~1.5d method.
But above-mentioned in the past not being coated with in the airbag all has problems.That is, in the past in the example (1), though the property deposited excellence remains further to be improved aspect aeration.In addition, owing to dwindled monofilament fineness, therefore cause the disconnection of the long filament when weaving easily, at base fabric qualitatively or weave and have problems in the running, the rotating speed of loom also is difficult to improve, and it is higher to weave cost.With regard to example (2) in the past, owing to roll processing, many one procedure have so not only improved cost in Fabrication procedure, also impair flexibility.In example (3) in the past, though can obtain lightweight and low venting quality, also because of implementing calendering processing, increased one procedure this moment in Fabrication procedure, so not only improved cost, also impairs flexibility.In the example (4), because of implementing chemical treatment, manufacturing cost increased in the past, and chemical reagent can cause that the decline of former yarn intensity is the decline of base fabric intensity, if use as airbag, had problems on its reliability.With regard to example (5) in the past,, increased one procedure, therefore the problem that exists manufacturing cost to rise because of 2 kinds of strands of the different monofilament finenesses that will make respectively combine.
Summary of the invention
The present invention proposes in view of the problem that exists in the above-mentioned conventional art, and its purpose is to provide lightweight, has low venting quality and the also excellent foundation fabric for gas bag of economy.
In order to address this is that, the inventor has finished the present invention through studying intensively.Promptly, the present invention is by the long filament of weaving the syntheticfibres that contains (preparing also weaving) the odd-shaped cross section silk and through shrinking the foundation fabric for gas bag that processing is made, it is characterized in that, contain the odd-shaped cross section silk in the filament of synthetic fibre of formation foundation fabric for gas bag, the monofilament cross section flatness of this odd-shaped cross section silk is 1.5~5.0, and the boiling water shrinkage of shrinking the syntheticfibres before the processing is 7~13%, and the venting quality of described foundation fabric for gas bag under 20kPa pressure is at 0.38l/cm 2Below/the min.
In the desirable example of foundation fabric for gas bag of the present invention, comprise the odd-shaped cross section silk in the stage before weaving in the long filament of described syntheticfibres.
In addition, in the desirable example of another of foundation fabric for gas bag of the present invention, the long filament total fineness that constitutes the syntheticfibres of foundation fabric for gas bag is 100dtex~700dtex, and monofilament fineness is 0.1dtex~7.0dtex.
Description of drawings
Fig. 1 is the cross section example of flat filament.
Among the figure, a: major diameter, b: minor axis.
The specific embodiment
Foundation fabric for gas bag of the present invention is weaved the long filament of syntheticfibres after shrink processing and make, comprise odd-shaped cross section silk in the long filament of the syntheticfibres after it is characterized in that processing, and the syntheticfibres before the processing has specific boiling water shrinkage with specific flatness.
Be used for the syntheticfibres of foundation fabric for gas bag of the present invention, be not particularly limited, especially can use fatty polyamide fibers such as nylon 66, nylon 6, nylon 46, nylon 12 as raw MAT'L; Aromatic polyamide fibres such as polyamide-based fiber; Poly-ester fibres such as mekralon or polyethylene terephthalate, polybutylene terephthalate.As other raw MAT'L, also can use Wholly aromatic polyester fiber, superhigh molecular weight polyethylene fibers, PPS fiber, polyether ketone fiber etc.Wherein, from economic considerations, special preferred polyester fiber or polyamide fibre.In addition, part or all of these fibers obtained also can by reclaimed materials.In addition, in order to improve the processability in raw yarn Fabrication procedure or back manufacturing procedure, also can contain various additives in these syntheticfibress.For example can contain antioxidant, heat stabilizer, flatting agent, antistatic agent, thickening agent, fire retardant etc.Also have, these syntheticfibress also can be colored silk.
The maximum feature of foundation fabric for gas bag of the present invention is to constitute to contain in the long filament of syntheticfibres of foundation fabric for gas bag to be not common circular section silk but to have the odd-shaped cross section silk of specific flatness.Have the odd-shaped cross section silk (being designated hereinafter simply as flat filament) of specific flatness by employing, when being made into fabric, can make the major diameter in monofilament cross section mutually stacked, thereby reduce the space in the unit area on the fabric cross section.Therefore, be woven into the circular section silk that uses equal fineness and compare when knitting density on an equal basis, the throughput in the time of can suppressing airbag and launch.In addition, when being designed to equal throughput, total fineness can be reduced, thereby the thin and light flexible base fabric that has can be made.
The flatness in the monofilament cross section among the present invention is that the major diameter when being approximate ellipsoidal with the monofilament cross sectional shape is represented with the ratio of minor axis.This cross section is not required it must is strict ellipse, and in the scope that does not influence the flat property of single-piece, part exists projection or recess also without any influence, does not also need left-right symmetric.In this case, myopia is the ellipse of harmless its monnolithic case, and the longest length is made as major diameter, and the shortest length is made as minor axis, obtains flatness at last and gets final product.
Put down in writing the typical example of odd-shaped cross section among the present invention among Fig. 1.Certainly, this is a typical example, is not limited in this.The a of Fig. 1 is a major diameter, and b is a minor axis, and flatness is calculated by a/b.
In order to obtain effect of the present invention, described flatness is advisable in 1.5~5.0 scopes, is preferably 1.5~4.0.Preferred especially oval as the cross section.If flatness is less than 1.5, then flat effect can die down, and if greater than 5.0, the fracture of wire in the time of then can becoming throwing, the reason of fluffing, not ideal.In addition, there is no need all monofilament and all have the interior flatness of above-mentioned scope, as long as a part wherein is 1.5~5.0.But if will strengthen flat effect, the monofilament number that then has a flatness of above-mentioned scope accounts for being advisable more than 50% of total monofilament number of long filament, more preferably more than 70%.
Being used for flat filament of the present invention can adopt known in the past the whole bag of tricks to obtain.For example can obtain flat filament, perhaps also can adopt composite spinning method to spray simultaneously after the poly-mer more than 2 kinds, remove a kind of composition at least and obtain flat filament by the direct throwing method of the hole ejection poly-mer that reels off raw silk from cocoons from abnormity.Consider common preferably the former direct throwing method from the easy degree of throwing, the simple degree of operation.
When making the thin especially long filament of monofilament fineness, use the latter's composite spinning method to be advisable.At this moment, removing a kind of composition at least can carry out after stretching or after making cloth and silk.
Therefore, foundation fabric for gas bag of the present invention not only comprises from the raw yarn stage and begins just to carry out woven base fabric with flat filament, is also included within that the raw yarn stage weaves with common circular section silk and removes a part of composition and make the base fabric of flat filament after making cloth and silk.
Another feature of foundation fabric for gas bag of the present invention is that the boiling water shrinkage of syntheticfibres before shrinking processing that is used for foundation fabric for gas bag is 6~15%.If boiling water shrinkage is less than 6%, even then use flat filament, after shrinking processing, can not get low venting quality, and if surpass 15%, the thickness that shrinks the fabric after processing can increase, and impairs densification, and is not ideal.The preferred value of boiling water shrinkage is 7~13%.Cloth and silk of the present invention shrinks the furnace run temperature in the processing, is not particularly limited, usually 90~200 ℃ of enforcements.Consider from obtaining low aeration angle, preferably handling below 160 ℃.Can adopt heat setter, boiling water passage (pass) etc. to carry out during processing, be not particularly limited, also can use rising of fabric warp thread direction to feed the processing machine that (over feed) can reach 2~15% scopes.
In addition, the total fineness of filament of synthetic fibre that constitutes foundation fabric for gas bag of the present invention is at 100dtex~700dtex, and monofilament fineness is advisable at 0.1dtex~7.0dtex.Preferred total fineness is 120dtex~500dtex, and monofilament fineness is 0.1dtex~5.0dtex.That is, when total fineness less than 100 dtex, pulling strengrth and peel strength are abundant inadequately, if and surpass 700dtex, though then do not have problems on the intensity, impair the flexible and property deposited of fabric, and the hardening of cloth and silk surface might injure the skin of human body when therefore colliding, not too favourable.If the not enough 0.1dtex of monofilament fineness is difficult to carry out spinning, and the effect of flat filament of the present invention dies down, and is therefore not ideal.On the contrary,, impair the flexibility of fabric if surpass 7dtex, not too favourable, therefore undesirable during from the property deposited or to the influencing angle and consider of human body.
In addition, the venting quality of foundation fabric for gas bag of the present invention under 20kPa pressure is at 0.71/cm 2Be advisable below/the min, more preferably at 0.51/cm 2Below/the min.The base fabric venting quality here is to adopt high pressure venting quality experimental engine (OEM system (strain) system), and the throughput when being set at 20kPa pressure is obtained.If above-mentioned throughput surpasses 0.71/cm 2/ min, the moment during then as airbag launches performance and can descend, and is therefore not ideal.
The following describes one of the manufacture method example of the syntheticfibres that is used for foundation fabric for gas bag of the present invention.
Be configured for the poly-mer of the syntheticfibres of foundation fabric for gas bag of the present invention, extract out by the head that reels off raw silk from cocoons according to melt spinning method usually.When obtaining flat filament, use the head that reels off raw silk from cocoons to get final product here, with profile hole as this head that reels off raw silk from cocoons by above-mentioned direct throwing method.In addition, when obtaining flat filament by composite spinning method, the poly-mer that spins simultaneously more than 2 kinds gets final product.Spinning condition is different with employed poly-mer, can select suitable condition according to the viscosity of poly-mer or thermal property etc.Usually for the deterioration of the poly-mer that prevents to cause because of heat, the time that poly-mer is stranded in the spinning machine is short more good more, usually in 10 minutes, preferably in 1~5 minute.For example when using polyethylene terephthalate or poly-hexamethylene adipamide fiber, spinning temperature and is controlled so as to 85% cartridge heater inside by length 10-100 centimetre, 200-350 ℃, relative humidity under the head that reels off raw silk from cocoons in 280 ℃ of-310 ℃ of scopes.The length of cartridge heater and temperature and humidity conditions can carry out optimization according to fineness, flatness and the long filament number of gained strand to be decided.Described cartridge heater helps the curing of slow molten polymer, performance high strength.
Also have,, also can use the atmosphere in the high temperature inert gas heated sealed tube in case of necessity in order to prevent the elevated temperature heat deterioration.
The curing that is cooled in cold wind after by described high-temperature atmosphere of spun strand is endowed finish subsequently, and the nip rolls with the control spinning speed draw afterwards.
Be drawn to undrawn yarn bar on the nip rolls usually by continuously elongated, also can after batching, in other operation, stretch.Spinning speed is usually below 2000m/ minute, and adopts common hot-stretch when stretching.Preferred multistage more than 2 sections stretches as stretching.Draw ratio with the double refraction of undrawn yarn, draft temperature, and the draw ratio distribution of multistage when stretching etc. change, be generally 1.5-6.0 doubly, preferred 2.0-5.5 doubly.
Then, described drawn yarn is by heat fixation, and it is also harmless to change timer-operated tension force of thermosetting and temperature.
And then in stretching process and heat fixation operation, mobile strand can interweave.Interweave and can adopt methods such as known air interweaves, when for example adopting air to interweave method, the pressure by fineness and tension force according to used strand come the appropriate change air can reach high interleaving degree.In case of necessity, can implement heat fixation to the gained silk handles.
When obtaining flat filament, after it stretches back or base fabric described later making, remove at least a kind of composition and get final product by above-mentioned composite spinning method.
According to above method, the flatness that can obtain to contain the monofilament cross section be 1.5-5.0 the odd-shaped cross section silk, total fineness is 100dtex~700dtex, monofilament fineness is the syntheticfibres of 0.1dtex~7.0dtex.
Get final product as if will then the gained syntheticfibres directly being used as warp thread and weft yarn with described syntheticfibres making foundation fabric for gas bag, weaving according to usual way.At this moment, there is no need to carry out especially twist yarn or starching.Method for weaving is not had special qualification, but consider, preferred plain weave from the homogeneity of base fabric rerum natura.Used yarn is that warp thread or weft yarn can be mono-s, also can adopt the fiber of different fineness, yarn radical, kind.Loom can adopt air-jet loom, rapier loom, water-jet loom etc., not particular determination.When density is knitted in setting, preferably make throughput as mentioned above at 0.71/cm 2/ minute below.
In the foundation fabric for gas bag of the present invention, the flatness that contains the monofilament cross section in the long filament of the syntheticfibres of formation foundation fabric for gas bag is the odd-shaped cross section silk of 1.5-5.0, and the boiling water shrinkage of shrinking the syntheticfibres before the processing is 6-15%, therefore compare with the base fabric that circular section silk by equal fineness constitutes, can reduce venting quality.In addition,, then can subdue total fineness or knit density, can make thin and light cloth and silk if will obtain same low venting quality.
Foundation fabric for gas bag of the present invention can be implemented concise, heat setting, also have the calendering processing of single or double to base fabric in the scope of not damaging characteristic of the present invention in case of necessity by known method.In addition, in order to have flat cross section, boarding machine (セ Star one) can be set.
In addition, foundation fabric for gas bag of the present invention to be not coated with product, the application product are all effective, but from aspects such as economy, lightweight, compactnesses, and the easy degree of utilizing again consider, be preferred for not being coated with product.
Followingly explain the present invention according to embodiment.Each physical property measurement among this paper and the embodiment is as follows.
(1) flatness in monofilament cross section: the cross-section photograph of taking the cloth and silk of adjusting according to JIS-L-1096-3 with scanning electron microscope (SEM), and be benchmark with the unit length on this photo, position the wideest in the monofilament is made as a 1(mm), the narrowest position of width is made as b 1(mm), and with taking value after multiplying power T (doubly) is divided by respectively as major diameter a (mm), minor axis b (mm).
a(mm)=a 1/T
b(mm)=b 1/T
The flatness in monofilament cross section is the a/b value.
(2) boiling water shrinkage: boiling water shrinkage is measured according to JIS-L-1013 (100 ℃ of hot water shrinkage B methods).
(3) coverage coefficient of cloth and silk: cloth and silk coverage coefficient (cover factor) K calculates according to following formula.
K=NW×DW?0.5+NF×DF0.5
(wherein, NW: through density (root/inch), DW: warp thread total fineness (dtex), NF: weft density (root/inch), DF: weft yarn total fineness (dtex)).
(4) venting quality: venting quality is to adopt high pressure venting quality experimental engine (OEM system (strain) system), is obtained by the throughput under the 20kPa pressure.
(5) thickness: the thickness of cloth and silk is measured according to JIS-L-1096-6.5.
Embodiment 1
With total fineness be that 470dtex, 96 long filaments, boiling water shrinkage are 8.0%, the flatness in monofilament cross section is 3.3 nylon 66 raw yarns, after weaving by plain weave with water-jet loom, shrink processing with boiling water, and carry out drying at 110 ℃ and handle, obtaining through density is that 49 pieces/inch, weft density are 49 pieces/inch fabric.Estimate the characteristic of this base fabric, and be shown in Table 1.
Embodiment 2
With total fineness be that 350dtex, 144 long filaments, boiling water shrinkage are 8.3%, the flatness in monofilament cross section is 2.8 nylon 66 raw yarns, after weaving by plain weave with water-jet loom, shrink processing with boiling water, and carry out drying at 110 ℃ and handle, obtaining through density is that 52 pieces/inch, weft density are 52 pieces/inch fabric.Estimate the characteristic of this base fabric, and be shown in Table 1.
Comparative example 1 (effect of flat filament is confirmed)
Except use boiling water shrinkage as raw yarn is 8.0% as the circular section silk (flatness in monofilament cross section is 1.0), adopts the method identical with embodiment 1 to obtain fabric.Estimate the characteristic of this base fabric, and be shown in Table 1.
Comparative example 2 (effect of the boiling water shrinkage of long filament is confirmed)
Boiling water shrinkage is 5.8% except using as raw yarn, the flatness in monofilament cross section is 3.5 the flat filament, adopts the method identical with embodiment 1 to obtain fabric.Estimate the characteristic of this base fabric, and be shown in Table 1.
Table 1
Figure C0314349900101
As table 1 as can be known, the flatness in monofilament cross section and the boiling water shrinkage embodiment 1 and the venting quality of the base fabric of embodiment 2 within the scope of the present invention is all very low.In contrast, the flatness in monofilament cross section and the boiling water shrinkage comparative example 1 and the venting quality of the comparative example 2 of boiling water shrinkage the scope of the invention outside beyond the scope of the invention is all higher, if be used as foundation fabric for gas bag, will have some problems.
The present invention can provide lightweight, have low aeration and the also excellent foundation fabric for gas bag of economy because of having above-mentioned formation.

Claims (4)

1. foundation fabric for gas bag, be the long filament by weaving the syntheticfibres that contains the odd-shaped cross section silk and make through shrinking processing, it is characterized in that, contain the odd-shaped cross section silk in the filament of synthetic fibre of formation foundation fabric for gas bag, and the monofilament cross section flatness of this odd-shaped cross section silk is 1.5~5.0, the boiling water shrinkage of shrinking the preceding syntheticfibres of processing is 7~13%, and the venting quality of described foundation fabric for gas bag under 20kPa pressure is at 0.38 l/cm 2Below/the min.
2. foundation fabric for gas bag according to claim 1 is characterized in that, the total fineness that constitutes the filament of synthetic fibre of foundation fabric for gas bag is 100dtex~700dtex, and monofilament fineness is 0.1dtex~7.0dtex.
3. foundation fabric for gas bag according to claim 1 is characterized in that, it is 90~160 ℃ that contraction adds the furnace run temperature in man-hour.
4. foundation fabric for gas bag according to claim 3 is characterized in that, the boiling water shrinkage of shrinking the preceding syntheticfibres of processing is 8.3~13%.
CNB031434991A 2003-09-30 2003-09-30 Base fabric for air-bag Expired - Fee Related CN100429096C (en)

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Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
CN101608370B (en) * 2008-06-17 2013-04-24 东丽纤维研究所(中国)有限公司 Fabric for air bag and production method thereof
CN101634074B (en) * 2008-07-23 2012-01-25 东丽纤维研究所(中国)有限公司 Fabric for safety air bag and production method thereof
CN102144057B (en) * 2008-09-05 2013-11-20 可隆工业株式会社 Fabric for airbag and method of preparing the same
CN101984165A (en) * 2010-09-28 2011-03-09 杭州宏峰纺织集团有限公司 Uncoated automobile airbag fabric and preparation process thereof
PL3279378T3 (en) 2015-04-03 2021-11-22 Toyobo Co., Ltd. Airbag-use woven fabric and airbag
US10737656B2 (en) 2015-09-30 2020-08-11 Seiren Co., Ltd. Fabric for air bag and air bag

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Publication number Priority date Publication date Assignee Title
JPH09279437A (en) * 1996-04-17 1997-10-28 Toray Ind Inc Base fabric for air bag and air bag
US6182709B1 (en) * 1998-07-27 2001-02-06 Toyo Boseki Kabushiki Kaisha Uncoated woven fabric for air bags, and its production process and system
JP2002054049A (en) * 2001-06-13 2002-02-19 Toyobo Co Ltd Method of manufacturing textile for non-coated air bag
CN1381366A (en) * 2001-04-19 2002-11-27 东洋纺织株式会社 High-density textile for air bag
JP2003055861A (en) * 2001-08-17 2003-02-26 Toray Ind Inc Base cloth for non-coat airbag and fiber for airbag
JP2003213540A (en) * 2002-01-16 2003-07-30 Toray Ind Inc Fabric and air bag

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09279437A (en) * 1996-04-17 1997-10-28 Toray Ind Inc Base fabric for air bag and air bag
US6182709B1 (en) * 1998-07-27 2001-02-06 Toyo Boseki Kabushiki Kaisha Uncoated woven fabric for air bags, and its production process and system
CN1381366A (en) * 2001-04-19 2002-11-27 东洋纺织株式会社 High-density textile for air bag
JP2002054049A (en) * 2001-06-13 2002-02-19 Toyobo Co Ltd Method of manufacturing textile for non-coated air bag
JP2003055861A (en) * 2001-08-17 2003-02-26 Toray Ind Inc Base cloth for non-coat airbag and fiber for airbag
JP2003213540A (en) * 2002-01-16 2003-07-30 Toray Ind Inc Fabric and air bag

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