CN100400633C - Detergent for washing dishware with hand and its preparation method - Google Patents
Detergent for washing dishware with hand and its preparation method Download PDFInfo
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- CN100400633C CN100400633C CNB2006100125498A CN200610012549A CN100400633C CN 100400633 C CN100400633 C CN 100400633C CN B2006100125498 A CNB2006100125498 A CN B2006100125498A CN 200610012549 A CN200610012549 A CN 200610012549A CN 100400633 C CN100400633 C CN 100400633C
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Abstract
The present invention relates to a hand washing tableware detergent which comprises the following components according to the weight percent: 1 to 20% of anionic surface active agent, 1 to 20% of nonionic surface active agent, 0 to 4% of zwitterionic surfactant, 60% to 85% of liquid carrier, 0 to 5% of electrolyte, and 0.05 to 0.1% of spice. The hand washing tableware detergent has the preparation method that the anionic surface active agent, the nonionic surface active agent, the zwitterionic surfactant and the liquid carrier are stirred and evenly mixed at the temperature of 40 DEG C to 50 DEG C; the electrolyte can be added for evenly mixing at the same temperature under stirring; the spice can be added for evenly mixing after the mixture is cooled to 30 DEG C, and products can be obtained. The hand washing tableware detergent has the advantages of no harm to skin, mildness and strong degreasing capability.
Description
Technical field
The present invention relates to a kind of detergent for washing dishware with hand and preparation method of being applicable to.
Background of invention
Detergent for washing dishware with hand is being known in the art, and can be forms such as powdery, gel or bulk, but the most general form is a liquid.The topmost function of this series products is the performance that excellent removal tableware surface and oil contaminant is arranged, this performance is provided by tensio-active agent usually, this tensio-active agent provides certain solublization, and with food soil, especially the grease dirt is disposed on being cleaned tableware or the aqueous solution that this series products forms, secondly detergent for washing dishware with hand also should have low irritant or the nonirritant to skin, because may be residual in the minute quantity on tableware surface, this detergent for washing dishware with hand also should be nontoxic product, in addition, this product is owing to will be discharged in the sanitary sewage system, so its component all should fast degraded biologically.This detergent for washing dishware with hand also will have the sense organ operating effect that makes acceptable outward appearance of human consumer and the seasonal consumer satisfaction of operation, so detergent for washing dishware with hand should have certain viscosity and whipability.Suitable viscosity can avoid a usage quantity excessive, and suitable whipability requires to produce an amount of foam and form of foam and can continue in whole wash up process in initial washing water.Along with The development in society and economy; it has been recognized that foam might not be the indication of dish washing detergent validity; also not necessarily whether competent indication of dish washing detergent usage quantity; therefore overgenerous foam is not expected by the human consumer from point of view of environment protection; be the requirement of water saving on the one hand, increased the processing requirements of sanitary sewage on the other hand.
Therefore generally speaking, do not have a kind of tensio-active agent to have the desired all properties of above-mentioned detergent for washing dishware with hand, need to select several different tensio-active agents in addition composite, in addition, also add some thickening materials, solubilizing agent and other subsidiary.
At present commercially available detergent for washing dishware with hand is mainly based on anion surfactant, they can provide degreasing effect preferably and higher foaming power, but also there is the pungency problem of higher in anion surfactant, and especially the degreasing power to skin is stronger.Under the high density or the long period be soaked in wherein, can cause skin rubefaction, itch, phenomenon such as coarse.
Summary of the invention
The purpose of this invention is to provide does not a kind ofly have injury, detergent for washing dishware with hand and preparation method gentle, that ability of cleaning greasy dirt is strong to skin.
Detergent for washing dishware with hand weight percent of the present invention is formed and is comprised:
(a) anion surfactant 1～20%
(b) nonionogenic tenside 1～20%
(c) zwitterionics 0～4%
(d) liquid vehicle 60～85%
(e) ionogen 0～5%
(f) spices 0.05～0.1%
Aforesaid anion surfactant is to contain sulfonate type anion surfactant and/or sulphate anion surface active agent.
Aforesaid sulfonate type anion surfactant is water miscible, and following form: RSO is arranged
3M, wherein R is C
6～20Straight or branched alkyl, aryl or its mixture preferably contain C
10～ 18Alkyl, aryl, hydroxyalkyl or its mixture; M is a positively charged ion, as alkali metal cation, ammonium or replacement ammonium, preferred sodium ion or potassium ion.This class tensio-active agent is C
6～20Sodium alkyl benzene sulfonate, C
6～20Alkyl benzene sulphonate (ABS) potassium, C
6～20Alkyl benzene sulphonate (ABS) ammonium, C
6～20Alkyl benzene sulphonate (ABS) ethanolamine salt etc., C
8～18Chain alkyl sulfonate, C
10～24α-Xi Jihuangsuanyan.Comparatively ideal sulfonate type anion surfactant is C
12Alkyl group Phenylsulfonic acid sodium salt or sylvite.
Aforesaid sulphate anion surface active agent comprises water miscible alkyl-sulphate or alkyl polyoxyethylene ether sulfate anion surfactant, and following form: R-O (A) is arranged
nSO
- 3M
+, wherein R is unsubstituted straight or branched C
6～20Alkyl or hydroxyalkyl group, preferred C
12～20Alkyl or hydroxyalkyl, more preferably C
12～15Perhaps C
12～14Alkyl; A is oxyethyl group or propoxy-unit, preferred ethoxy unit; N is 0.5～5, preferred 0.5～3; M is an ammonium ion or a metal ion, is more preferably sodium ion.Sulfated alkyl ether generally exists with the R that comprises different chain length and the form of mixtures of different ethoxylation degrees, and the ideal sulfated surfactant is C
12～14Polyoxyethylene (3) ether sodium sulfate, C
12～15Polyoxyethylene (2) ether sodium sulfate.
Aforesaid nonionogenic tenside contains:
(a) the grease ethoxylate nonionic surfactant 1～100%
(b) the alkyl polyoxyethylene ether nonionogenic tenside 0～99%
(c) the alkyl polyglycoside nonionogenic tenside 0～99%
(d) the alkylolamide nonionogenic tenside 0～99%
Aforesaid grease ethoxylate is water-soluble, has following general formula:
Wherein R is C
1～30Alkyl or their mixture, preferred C
8～18Alkyl or their mixture, x, y, z can be identical or different, and x+y+z=n, n are 1～180, and be preferred 12～90, more preferably 18～60.Typical grease ethoxylate has: soybean oil ethoxylate (the average EO adduction several 14～20 of strand), cocounut oil ethoxylate (the average EO adduction several 6～12 of strand), rapeseed oil ethoxylate (the average EO adduction several 14～20 of strand), concrete preparation method sees that Chinese patent application number is 200510012771.3 patent.
Aforesaid alkyl polyoxyethylene ether (or claiming fatty alcohol-polyoxyethylene ether) nonionogenic tenside has following form: R-O-(C
2HO)
n-H, wherein R is C
8～22Alkyl or its mixture can be straight or branched, primary alkyl or secondary alkyl, preferred C
12～14, C
12～15Or C
12～16Alkyl; N is 1～22, preferred 7～10.Comparatively it is desirable to dodecyl polyoxyethylene (9) ether, 12, tetradecyl polyoxyethylene (9) ether, dodecyl polyoxyethylene (7) ether.
Aforesaid alkyl polyglycoside nonionogenic tenside has following general formula: RO (Z)
x, wherein Z is a glucosyl group, R is an alkyl, contains 8～22 carbon atoms, preferred 8～14 carbon atoms; X is the mean polymerisation degree of glucose, and x is 1.0～3.0, preferred 1.2～1.8.Comparatively it is desirable to lauryl glucosyl ester, cocounut oil alkyl-glucoside ester.
Aforesaid alkylolamide nonionogenic tenside is C
8～18Alkylolamide can be used as thickening material, has following general formula: R
1-CO-N (H)
m(R
2OH)
3-m,, wherein, R
1Be to contain 7～21, saturated or the unsaturated no hydroxyl aliphatic hydrocarbyl or their mixture of preferred 11～17 carbon atoms; R
2Expression methylene radical or ethylidene; M is 1 or 2, preferred 1.Specific examples is that the coconut oil single ethanol amide is or/and the dodecyl diglycollic amide.
Aforesaid amphoterics is betaine type amphoteric surfac-tant and/or amine oxide amphoterics.
Aforesaid water miscible amphoterics has good foam performance and washability in the present invention's prescription, stable to hard water, is the tensio-active agent of a class gentleness.
Aforesaid betaine type amphoteric surfac-tant has following general formula:
R wherein
1Be C
10～28Alkyl or their mixture, preferred C
12～18Alkyl, R
2, R
3Be C
1～3Alkyl, preferred CH
3 -, R
4For having the alkylidene group of 1～6 carbon atom.Typical trimethyl-glycine example comprises Varion CDG-K, palm oil base, lauryl, hexadecyl, stearyl dimethyl betaine.
Aforesaid amine oxide amphoterics as suds booster/stablizer comprises compound or its mixture with following formula:
R wherein
1Be alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl or 3-alkoxyl group-2-hydroxypropyl, wherein alkyl and alkoxyl group contain 8～18 carbon atoms of having an appointment, R respectively
2And R
3Be methyl, ethyl, propyl group, sec.-propyl, 2-hydroxyethyl, 2-hydroxypropyl or 3-hydroxypropyl.Comparatively it is desirable to dimethyl dodecyl amine oxide.
The effect of aforesaid liquid vehicle is that other necessity and optional component is dissolved, disperses or is suspended in wherein, and this liquid vehicle also comprises solubilizing agent (also claiming hydrotropic agent), solvent, pH regulator agent except that mainly being the deionized water.
Aforesaid liquid vehicle contains:
(a) deionized water 80～100%
(b) solvent or solubilizing agent 0～20%
(c) the pH regulator agent 0～10%
Aforesaid liquid vehicle can comprise one or more materials for solvent or solubilizing agent.Be applicable to having that the present invention fills a prescription: low-carbon alcohol, glycol, other polyvalent alcohol, ether, amine, C
1～3Alkylaryl sulphonate, C
6～12Alkanol, C
1～6Carboxyl vitriol and sulfonate, urea, C
1～6Hydrogenation of carboxylic acid salt, C
1～4Carboxylate salt, C
2～4Organic diacid and composition thereof.Typically have: C
1～4Alkanol, toluenesulfonic acid sodium salt, potassium and ammonium, sodium xylene sulfonate, potassium and ammonium replace or unsubstituted sodium naphthalene sulfonate, potassium and ammonium and their mixture; Sulfosuccinate, sulfo group phthalate; Acetate, propionic salt and Citrate trianion; Succsinic acid, pentanedioic acid and hexanodioic acid.Being used for preferred solvent of the present invention or solubilizing agent is ethanol, ethylene glycol, sodium xylene sulfonate, potassium, ammonium, toluenesulfonic acid sodium salt, potassium, ammonium and their mixture.
The present invention's prescription also can contain some pH regulator agent, comprises alkaline carbonate or bicarbonate solution and organic or inorganic acid solution, as Na
2CO
3, NaHCO
3, K
2CO
3, KHCO
3Reach the aqueous solution of citric acid, tartrate, sulfonic acid, phosphoric acid etc., select suitable add-on according to the pH value that prescription requires.
Aforesaid ionogen comprises salt such as sodium-chlor, Repone K, Trisodium Citrate, sodium acetate, sodium sulfate or vitriolate of tartar.Most preferred ionogen is sodium-chlor or Repone K.
Aforesaid spices is the water miscible flavouring agent of safety, as edible lemon flavour.
Preparation method of the present invention:
Detergent for washing dishware with hand of the present invention can be by with negatively charged ion, nonionic, positively charged ion, zwitterionics and liquid vehicle in the foregoing invention prescription under agitation, behind 40～50 ℃ of following mixings, adding ionogen under same temperature, stirring mixes, add the spices mixing after being cooled to 30～35 ℃, make product.
The present invention compared with prior art has following advantage:
The present invention adds a kind of new series of surfactants---grease ethoxylate in the detergent for washing dishware with hand prescription, product is nontoxic, and is non-stimulated, and skin-friendliness is good, and rich preferably fat effect is arranged, and can reduce the pungency of formulation product.Owing to the similar principle that mixes, the ethoxylate of natural fats and oils also has excellent greasy dirt solubilising and emulsifying power in addition; Obvious to negatively charged ion system thickening effectiveness, itself belong to medium foamed products, the formula system foam there is not obvious restraining effect, the HLB value is arbitrarily adjustable, and dissolution in low temperature is good, anti-hard water, characteristics such as readily biodegradable are class over-all properties higher surface activity agent.After in the detergent for washing dishware with hand prescription, adding the grease ethoxylate, product degreasing rate can improve 20～80%, and the prescription viscosity can improve 3～60 times not adding under the electrolytical situation, in addition because the low irritant and the rich fat effect of grease ethoxylate, therefore after being used for the detergent for washing dishware with hand prescription, can effectively improve the pungency and the degreasing of prescription, wash back skin smooth, tender, flexible.
Embodiment:
Comparative Examples 1:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives)
140g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 30g.
(2) nonionogenic tenside: lauryl glucosyl ester 10g.
(3) zwitterionics: Varion CDG-K 10g.
(4) deionized water: 799g.
(5) ionogen: sodium-chlor 10g.
(6) lemon flavour 1g.
(7) method for making: negatively charged ion, nonionic, zwitterionics and deionized water are existed
Stir down, behind 40～50 ℃ of following mixings, under same temperature, stirring, add electrolysis
Matter mixes, and adds the spices mixing after being cooled to 30 ℃, makes product.
Comparative Examples 2:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives)
140g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 30g.
(2) nonionogenic tenside: cocounut oil diglycollic amide (1: 1) 10g.
(3) zwitterionics: dimethyl dodecyl amine oxide 10g.
(4) deionized water: 799g.
(5) ionogen: sodium-chlor 10g.
(6) lemon flavour 1g.
(7) method for making is with Comparative Examples 1.
Embodiment 1:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives) 130g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 30g.
(2) nonionogenic tenside: soya-bean oil ethoxylate (n=48) 10g, lauryl glucosyl ester 10g.
(3) deionized water: 814g.
(4) ionogen: sodium-chlor 5g.
(5) lemon flavour 1g.
(6) method for making: with negatively charged ion, nonionogenic tenside and deionized water under agitation, behind 40～50 ℃ of following mixings, add ionogen in same temperature, under stirring and mix, add the spices mixing after being cooled to 30 ℃, make product.
Embodiment 2:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives) 100g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 30g.
(2) nonionogenic tenside: soya-bean oil ethoxylate (n=54) 40g, lauryl glucosyl ester 10g.
(3) deionized water: 814g.
(4) ionogen: sodium-chlor 5g.
(5) lemon flavour 1g.
(6) method for making is with embodiment 1.
Embodiment 3:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives) 80g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 30g.
(2) nonionogenic tenside: cocounut oil ethoxylate (n=24) 60g, lauryl glucosyl ester 10g.
(3) deionized water 814g.
(4) ionogen: sodium-chlor 5g.
(5) lemon flavour 1g.
(6) method for making is with embodiment 1.
Embodiment 4:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives) 50g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 30g.
(2) nonionogenic tenside: plam oil ethoxylate (n=42) 90g, lauryl glucosyl ester 10g.
(3) deionized water: 819g.
(4) lemon flavour 1g.
(5) method for making: with negatively charged ion, nonionogenic tenside and deionized water under agitation, in
40～50 ℃ of following mixings add the spices mixing after being cooled to 30 ℃, make product.
Embodiment 5:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives) 30g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 30g.
(2) nonionogenic tenside: rapeseed oil ethoxylate (n=48) 110g, lauryl glucosyl ester 10g.
(3) deionized water: 819g.
(4) lemon flavour 1g.
(5) method for making is with embodiment 4.
Comparative Examples 3:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives) 140g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 30g.
(2) solvent: 95% ethanol 50g.
(3) deionized water: 779g.
(4) lemon flavour 1g.
(5) method for making: with anion surfactant, solvent and deionized water under agitation,, add the spices mixing after being cooled to 30 ℃, make product in 40～50 ℃ of following mixings.
Embodiment 6:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives) 40g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 30g.
(2) nonionogenic tenside: soya-bean oil ethoxylate (n=54) 100g.
(3) solvent: 95% ethanol 50g.
(4) deionized water: 779g.
(5) lemon flavour 1g.
(6) method for making: with negatively charged ion, nonionogenic tenside, solvent and deionized water under agitation,, add the spices mixing after being cooled to 30 ℃, make product in 40～50 ℃ of following mixings.
Embodiment 7:
(1) anion surfactant: C
12～14Alkyl group Phenylsulfonic acid potassium (in 100% actives) 100g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 20g.
(2) nonionogenic tenside: soya-bean oil ethoxylate (n=48) 10g, lauryl glucosyl ester 20g, AEO
920g, cocounut oil diglycollic amide (1: 1) 10g.
(3) zwitterionics: dimethyl dodecyl amine oxide 10g.
(4) solubilizing agent: sodium xylene sulfonate 10g.
(5) solvent: 95% ethanol 20g.
(6) deionized water: 774.5g.
(7) ionogen: Trisodium Citrate 5g.
(8) lemon flavour 0.5g.
(9) method for making: under agitation with negatively charged ion, nonionic, zwitterionics and deionized water, solvent and solubilizing agent, behind 40～50 ℃ of following mixings, add ionogen in same temperature, under stirring and mix, add the spices mixing after being cooled to 35 ℃, make product.
Embodiment 8:
(1) anion surfactant: C
12～14Alkyl group Phenylsulfonic acid ammonia (in 100% actives) 10g, C
12～15Alcohol ether sodium sulfate (in 100% actives) 10g.
(2) nonionogenic tenside: soya-bean oil ethoxylate (n=48) 60g, lauryl glucosyl ester 10g, AEO
920g, cocounut oil diglycollic amide (1: 1) 10g.
(3) zwitterionics: hexadecyldimethyl benzyl ammonium trimethyl-glycine 20g, dimethyl dodecyl amine oxide 20g.
(4) solubilizing agent: toluenesulfonic acid sodium salt 20g.
(5) solvent: ethylene glycol 30g.
(6) deionized water: 788g.
(7) ionogen: sodium-chlor 1g.
(8) lemon flavour 1g.
(9) method for making: with negatively charged ion, nonionic, zwitterionics and remove Gao Zishui, solvent and solubilizing agent under agitation, behind 40～50 ℃ of following mixings, add ionogen in same temperature, under stirring and mix, add the spices mixing after being cooled to 35 ℃, make product.
Embodiment 9:
(1) anion surfactant: C
12～14Alkyl group benzene sulfonic acid sodium salt (in 100% actives) 10g.
(2) nonionogenic tenside: butter ethoxylate (n=54) 60g, AEO
930g, AEO
720g, coconut monoethanol amide 10g.
(3) zwitterionics: cocamidopropyl betaine 20g.
(4) solubilizing agent: urea 20g.
(5) solvent: ethylene glycol 30g.
(6) deionized water 799g.
(7) lemon flavour 1g.
(8) method for making is with embodiment 8.
The performance of Comparative Examples 1～3 and embodiment 1～5 relatively sees Table 1:
The performance of table 1 product
| Performance | The rate of deoiling (%) | Viscosity (centipoise) (25 ℃, shearing rate 100 seconds -1) | Foam (ml, instant) |
| Comparative Examples 1 | 27.52 | 326 | 290 |
| Comparative Examples 2 | 23.29 | 370 | 316 |
| Embodiment 1 | 29.15 | 275 | 287 |
| Embodiment 2 | 33.56 | 290 | 280 |
| Embodiment 3 | 38.79 | 338 | 274 |
| Embodiment 4 | 35.37 | 380 | 259 |
| Embodiment 5 | 39.81 | 457 | 212 |
| Comparative Examples 3 | 21.58 | 6.3 | 196 |
| Embodiment 6 | 41.12 | 402 | 177 |
| Embodiment 7 | 45.36 | 396 | 233 |
| Embodiment 8 | 40.55 | 416 | 256 |
| Embodiment 9 | 47.25 | 295 | 285 |
Table 1 as seen, embodiment 1～5 compares with the Comparative Examples 1,2 of non-refuelling fat ethoxylate, active matter content is identical, the rate of deoiling has improved 20～80%, foaming power does not obviously reduce.
Comparative Examples 3 and embodiment 6 all do not add arbitrary ionogen and active matter content suitable, under identical conditions (25 ℃, shearing rate 100 seconds
-1) latter's viscosity is the former 63 times, visible grease ethoxylate has and increases glutinous effect preferably.
Claims (16)
1. detergent for washing dishware with hand, the weight percent that it is characterized in that detergent for washing dishware with hand are formed:
Anion surfactant 1～20%, nonionogenic tenside 1～20%,
Zwitterionics 0～4%, liquid vehicle 60～85%,
Ionogen 0～5%, spices 0.05～0.1%;
Described nonionogenic tenside is made up of the weight percent of following material:
Grease ethoxylate nonionic surfactant 1～100%
Alkyl polyoxyethylene ether nonionogenic tenside 0～99%
Alkyl polyglycoside nonionogenic tenside 0～99%
Alkylolamide nonionogenic tenside 0～99%
Described anion surfactant is sulfonate type anion surfactant and/or sulphate anion surface active agent;
Described amphoterics is betaine type amphoteric surfac-tant and/or amine oxide amphoterics.
2. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described sulfonate type anion surfactant is RSO
3M, wherein R is C
6～20Straight or branched alkyl, aryl or its mixture; M is a positively charged ion.
3. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described sulfate type anion surfactant comprises water miscible alkyl-sulphate or alkyl polyoxyethylene ether sulfate anion surfactant, has following form: R-O (A)
nSO
- 3M
+, wherein R is unsubstituted straight or branched C
6～20Alkyl or hydroxyalkyl group; A is oxyethyl group or propoxy-unit; N is 0.5～5; M is an ammonium ion or a metal ion.
4. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described grease ethoxylate nonionic surfactant, has following general formula:
Wherein R is C
1～30Alkyl or their mixture, x, y, z are identical or different, and x+y+z=n, n are 1～180.
5. a kind of detergent for washing dishware with hand as claimed in claim 4 is characterized in that described grease ethoxylate nonionic surfactant is the cocounut oil ethoxylate of the average EO adduction several 6～12 of soybean oil ethoxylate, strand of the average EO adduction several 14～20 of strand or the rapeseed oil ethoxylate of the average EO adduction several 14～20 of strand.
6. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described alkyl polyoxyethylene ether nonionogenic tenside has R-O-(C
2H
4O)
n-H form, wherein R is C
8～22Alkyl or its mixture, n are 1～22.
7. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described alkyl polyglycoside nonionogenic tenside has RO (Z)
xGeneral formula, wherein Z is a glucosyl group, R is the alkyl that contains 8～22 carbon atoms; X is the glucose mean polymerisation degree, is 1.0～3.0.
8. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described alkylolamide nonionogenic tenside is C
8～8Alkylolamide has R
1-CO-N (H)
m(R
2OH)
3-m, general formula, wherein, R
1Be saturated or unsaturated no hydroxyl aliphatic hydrocarbyl or their mixture that contains 7～21 carbon atoms; R
2Expression methylene radical or ethylidene; M is 1 or 2.
9. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described betaine type amphoteric surfac-tant has following general formula:
R wherein
1Be C
10～20Alkyl or its mixture, R
2, R
3Be C
1～3Alkyl, R
4For having the alkylidene group of 1～6 carbon atom.
10. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described amine oxide amphoterics comprises compound or its mixture with following formula:
R wherein
1Be alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl or 3-alkoxyl group-2-hydroxypropyl, wherein alkyl and alkoxyl group contain 8～18 carbon atoms, R respectively
2And R
3Be methyl, ethyl, propyl group, sec.-propyl, 2-hydroxyethyl, 2-hydroxypropyl or 3-hydroxypropyl.
11. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described liquid vehicle is made up of the weight percent of following material:
Deionized water 80～100%
Solvent or solubilizing agent 0～20%
PH regulator agent 0～10%.
12. a kind of detergent for washing dishware with hand as claimed in claim 11 is characterized in that described solvent or solubilizing agent are low-carbon alcohol, glycol, polyvalent alcohol, ether or amine, C
1～3Alkylaryl sulphonate, C
6～12Alkanol, C
1～6Carboxyl vitriol and sulfonate, urea, C
1～6Hydrogenation of carboxylic acid salt, C
1～4Carboxylate salt, C
2～4Organic diacid and composition thereof.
13. a kind of detergent for washing dishware with hand as claimed in claim 11 is characterized in that described pH regulator agent is alkaline carbonate or bicarbonate solution and organic or inorganic acid solution.
14. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described ionogen is sodium-chlor, Repone K, Trisodium Citrate, sodium acetate, sodium sulfate or vitriolate of tartar.
15. a kind of detergent for washing dishware with hand as claimed in claim 1 is characterized in that described spices is water miscible flavouring agent.
16. preparation method as each described a kind of detergent for washing dishware with hand of claim 1～15, it is characterized in that under agitation anion surfactant, nonionogenic tenside, zwitterionics, liquid vehicle, behind 40～50 ℃ of following mixings, add ionogen in same temperature, under stirring and mix, add the spices mixing after being cooled to 30～35 ℃ to make product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006100125498A CN100400633C (en) | 2006-03-30 | 2006-03-30 | Detergent for washing dishware with hand and its preparation method |
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|---|---|---|---|
| CNB2006100125498A CN100400633C (en) | 2006-03-30 | 2006-03-30 | Detergent for washing dishware with hand and its preparation method |
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| Publication Number | Publication Date |
|---|---|
| CN1865422A CN1865422A (en) | 2006-11-22 |
| CN100400633C true CN100400633C (en) | 2008-07-09 |
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| CNB2006100125498A Active CN100400633C (en) | 2006-03-30 | 2006-03-30 | Detergent for washing dishware with hand and its preparation method |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101019815B (en) * | 2007-03-20 | 2010-05-19 | 中国日用化学工业研究院 | Bath lotion containing ethoxylated oil and grease and its preparation |
| CN103897882A (en) * | 2012-12-28 | 2014-07-02 | 青岛锦涟鑫商贸有限公司 | Preparation method of fruit and vegetable washing agent |
| CN109181894B (en) * | 2018-09-30 | 2020-07-03 | 北京洛娃日化有限公司 | Super-concentrated detergent and preparation method thereof |
| CN110236971B (en) * | 2019-04-17 | 2022-05-20 | 中国日用化学研究院有限公司 | Antibacterial hand sanitizer containing counter ion quaternary ammonium salt and preparation method thereof |
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| CN1017527B (en) * | 1987-03-10 | 1992-07-22 | 法米塔利亚·卡洛·埃巴公司 | Process for preparing optically active oxo-isoindolinyl derivatives |
| CN1120851A (en) * | 1993-02-11 | 1996-04-17 | 普罗克特和甘保尔公司 | Cleansing compositions |
| WO2000043477A1 (en) * | 1999-01-20 | 2000-07-27 | The Procter & Gamble Company | Dishwashing compositions containing alkylbenzenesulfonate surfactants |
| CN1262703A (en) * | 1997-05-16 | 2000-08-09 | 普罗格特-甘布尔公司 | Light-duty liquid or gel dishwashing detergent compositions having controlled pH and desivable food soil removal and sudsing characteristics |
| CN1267323A (en) * | 1997-06-13 | 2000-09-20 | 普罗格特-甘布尔公司 | Light-duty liquid dishwashing detergent compositions having desirable low temp. stability and desirable greasy soil removal and sudsing characteristics |
| WO2000055288A1 (en) * | 1999-03-15 | 2000-09-21 | The Procter & Gamble Company | Perfume compositions and methods to mask amine malodors |
| CN1478141A (en) * | 2000-11-29 | 2004-02-25 | 宝洁公司 | Hand dishwashing composition containing suds supperesser and method of use therefor |
-
2006
- 2006-03-30 CN CNB2006100125498A patent/CN100400633C/en active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1017527B (en) * | 1987-03-10 | 1992-07-22 | 法米塔利亚·卡洛·埃巴公司 | Process for preparing optically active oxo-isoindolinyl derivatives |
| CN1120851A (en) * | 1993-02-11 | 1996-04-17 | 普罗克特和甘保尔公司 | Cleansing compositions |
| CN1262703A (en) * | 1997-05-16 | 2000-08-09 | 普罗格特-甘布尔公司 | Light-duty liquid or gel dishwashing detergent compositions having controlled pH and desivable food soil removal and sudsing characteristics |
| CN1267323A (en) * | 1997-06-13 | 2000-09-20 | 普罗格特-甘布尔公司 | Light-duty liquid dishwashing detergent compositions having desirable low temp. stability and desirable greasy soil removal and sudsing characteristics |
| WO2000043477A1 (en) * | 1999-01-20 | 2000-07-27 | The Procter & Gamble Company | Dishwashing compositions containing alkylbenzenesulfonate surfactants |
| WO2000055288A1 (en) * | 1999-03-15 | 2000-09-21 | The Procter & Gamble Company | Perfume compositions and methods to mask amine malodors |
| CN1478141A (en) * | 2000-11-29 | 2004-02-25 | 宝洁公司 | Hand dishwashing composition containing suds supperesser and method of use therefor |
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| Publication number | Publication date |
|---|---|
| CN1865422A (en) | 2006-11-22 |
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Application publication date: 20061122 Assignee: China Light Technology Co., Ltd. Assignor: Chinese Daily Use Chemical Industry Research Inst. Contract record no.: 2013310000091 Denomination of invention: Detergent for washing dishware with hand and its preparation method Granted publication date: 20080709 License type: Exclusive License Record date: 20130807 |
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Effective date of registration: 20160429 Address after: 201512 Shanghai city Jinshan District Yuanwang Road No. 1 Patentee after: China Light Technology Co., Ltd. Address before: Taiyuan City, Shanxi Province, the source of lane 030001 No. 34 Patentee before: Chinese Daily Use Chemical Industry Research Inst. |